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Introduction of a 7-aza-6-MeO-indoline auxiliary in Lewis-acid/photoredox cooperative catalysis: highly enantioselective aminomethylation of α,β-unsaturated amides

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01890B, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Santosh K. Pagire, Naoya Kumagai, Masakatsu Shibasaki
An efficient cooperative chiral Lewis acid and photoredox catalytic system towards the highly enantioselective radical conjugate addition of α-amino radicals to α,β-unsaturated amides is developed with the implementation of unique auxiliaries.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(II)-based porous cages

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01833C, Edge Article
Open Access
Meaghan Deegan, Tonia Ahmed, Glenn Yap, Eric D Bloch
We describe the synthesis of Fe(II)-based octahedral coordination cages supported by calixarene capping ligands. The most porous of these molecular cages has an argon accessible BET surface area of 898...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01445A, Edge Article
Open Access
Lei Zhang, Xile Hu
A direct arylation of benzylic C–H bonds is achieved by integrating Ni-catalyzed benzyl–aryl coupling into convergent paired electrolysis.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Asymmetric synthesis of primary amines catalyzed by thermotolerant fungal reductive aminases

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC02253E, Edge Article
Open Access
Juan Mangas-Sanchez, Mahima Sharma, Sebastian C. Cosgrove, Jeremy I. Ramsden, James R. Marshall, Thomas W. Thorpe, Ryan B. Palmer, Gideon Grogan, Nicholas J. Turner
Fungal reductive aminases as effective biocatalysts for the preparation of chiral primary amines.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Redox-responsive supramolecular polymeric networks having double-threaded inclusion complexes

Chem. Sci., 2020, 11,4322-4331
DOI: 10.1039/C9SC05589D, Edge Article
Open Access
Hikaru Aramoto, Motofumi Osaki, Subaru Konishi, Chiharu Ueda, Yuichiro Kobayashi, Yoshinori Takashima, Akira Harada, Hiroyasu Yamaguchi
A hydrogel actuator with a 1:2 host–guest complex controlled by redox stimuli has been developed to realize faster and larger deformation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Redox-inactive ions control the redox-activity of molecular vanadium oxides

Chem. Sci., 2020, 11,4450-4455
DOI: 10.1039/D0SC01401J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Simon Greiner, Benjamin Schwarz, Mark Ringenberg, Maximilian Dürr, Ivana Ivanovic-Burmazovic, Maximilian Fichtner, Montaha Anjass, Carsten Streb
The enhanced redox-activity of a molecular vanadium oxide cluster upon functionalization with redox-inert Ca2+ ions is reported together with initial insights into its performance as a lithium ion battery cathode.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hydrogen peroxide reduction on single platinum nanoparticles

Chem. Sci., 2020, 11,4416-4421
DOI: 10.1039/D0SC00379D, Edge Article
Open Access
Xin Chang, Christopher Batchelor-McAuley, Richard G. Compton
At the single platinum nanoparticle scale the hydrogen peroxide reduction reaction is a surface limited process.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The structures of ordered defects in thiocyanate analogues of Prussian Blue

Chem. Sci., 2020, 11,4430-4438
DOI: 10.1039/D0SC01246G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthew J. Cliffe, Evan N. Keyzer, Andrew D. Bond, Maxwell A. Astle, Clare P. Grey
We report the structures of six new divalent transition metal hexathiocyanatobismuthate Prussian Blue analogues frameworks, which contain complex ordered defect structures.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates

Chem. Sci., 2020, 11,4475-4481
DOI: 10.1039/D0SC01194K, Edge Article
Open Access
Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-Ewing
Short-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Redox deracemization of β,γ-alkynyl α-amino esters

Chem. Sci., 2020, 11,4444-4449
DOI: 10.1039/D0SC00944J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lu Zhang, Rongxiu Zhu, Aili Feng, Changyin Zhao, Lei Chen, Guidong Feng, Lei Liu
A one-pot deracemization of β,γ-alkynyl α-amino esters consisting of an aerobic oxidation and chiral phosphoric acid-catalyzed asymmetric transfer hydrogenation has been described.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Selective electrochemical reduction of carbon dioxide to ethanol via a relay catalytic platform

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01133A, Edge Article
Open Access
Juan Du, Shaopeng Li, Shulin Liu, Yu Xin, Bingfeng Chen, Huizhen Liu, Buxing Han
The relay catalytic platform is very efficient and selective for CO2 electroreduction to ethanol.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Near-infrared light-activated membrane fusion for cancer cell therapeutic applications

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00863J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fujian Huang, Ruilin Duan, Zhixin Zhou, Margarita Vázquez-González, fan xia, Itamar Willner
The spatiotemporal stimulation of liposome-liposome or liposome-membrane fusion processes attracts growing interest as a means to mimic cell-cell interactions in nature and for using these processes for biomedical applications. We...
The content of this RSS Feed (c) The Royal Society of Chemistry




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What is draft red herring prospectus?

The document clarifies the reason why the company wants to raise money from the public, how the money will be used and risks involved in investing in the company.




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The value of international education to Australia / prepared by Deloitte Access Economics

Deloitte Access Economics




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Learning English as a second language in the early years : hundreds of ideas for supporting children with English as an additional language / Anita Soni & Liz Rouse

Soni, Anita, (Educational psychologist), author




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Developing the curriculum : improved outcomes through systems approaches / William R. Gordon II, Ed.D. (Chief Operations Officer, Retired, Florida virtual School, Orlando, Florida), Rosemarye T. Taylor, Ph.D. (Professor, Educational Leadership, University

Gordon, William, II, author




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A recipe for success : small business growth through training opportunities for women : a report on skills required and training developed for women to expand their businesses / by Susan Barrera and Rachel Robertson

Barrera, Susan




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Effect of red tape on private education : interim report / The Senate, Select Committee on Red Tape

Australia. Parliament. Senate. Select Committee on Red Tape, author, issuing body




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Numerical Simulation, An Art of Prediction 1: Theory


 
Numerical simulation is a technique of major importance in various technical and scientific fields. Used to understand diverse physical phenomena or to design everyday objects, it plays a major role in innovation in the industrial sector. Whilst engineering curricula now include training courses dedicated to it, numerical simulation is still not well-known in some economic sectors, and even less so among the general public. Simulation involves the

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Finding Einstein's brain / Frederick E. Lepore, MD

Hayden Library - QC16.E5 L378 2018




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Nature's prophet: Alfred Russel Wallace and his evolution from natural selection to natural theology / Michael A. Flannery

Hayden Library - QH375.F57 2018




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Frontier applications of nature inspired computation / Mahdi Khosravy, Neeraj Gupta, Nilesh Patel, Tomonobu Senjyu, editors

Online Resource




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Bio-inspired computing: 14th International Conference, BIC-TA 2019, Zhengzhou, China, November 22-25, 2019, Revised Selected Papers. / Linqiang Pan, Jing Liang, Boyang Qu (eds.)

Online Resource




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Bio-inspired computing: theories and applications: 14th International Conference, BIC-TA 2019, Zhengzhou, China, November 22-25, 2019, Revised selected papers. / Linqiang Pan, Jing Liang, Boyang Qu (eds.)

Online Resource




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A journey towards bio-inspired techniques in software engineering / Jagannath Singh, Saurabh Bilgaiyan, Bhabani Shankar Prasad Mishra, Satchidananda Dehuri, editors

Online Resource




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Building React apps with server-side rendering: use React, Redux, and Next to build full server-side rendering applications / Mohit Thakkar

Online Resource




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Veggie-powered bus road-trips across America

Will visit Morehead June 18




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Explore "Code Red" with Morehead Monday

This new program for children in grades 6-8 focuses on hands-on learning activities.




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Telescope Tune-up <font color=red>POSTPONED</font>

Due to forecasts of wintry weather, "Telescope Tune-up" is cancelled for tonight and will be rescheduled at a later date.




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Audit and accounting guide [electronic resource] : depository and lending institutions : banks and savings institutions, credit unions, finance companies, and mortgage companies




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Redefining business models [electronic resource] : strategies for a financialized world / Colin Haslam ... [et al.]




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Play Test cricket with a red ball, experiment in other formats: Gautam Gambhir

Interview with Cricketer




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En Italia, he redescubierto el poder de tres tipos de oración

Los Salmos de lamento se sentían hiperbólicos antes de COVID-19. Pero en medio de 13,000 muertes, mi iglesia en Roma, cerrada por el encierro obligatorio, resuena con el lamento de David más que nunca.




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Bioinspired reconfiguration of 3D printed microfluidic hydrogels via automated manipulation of magnetic inks

Lab Chip, 2020, Advance Article
DOI: 10.1039/D0LC00280A, Communication
Amin Mansoorifar, Anthony Tahayeri, Luiz E. Bertassoni
We proposed a novel concept for reconfiguration of hydrogel microfluidic devices, where multiple fluidic pathways could be generated via reversible manipulation of magnetic inks.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Microfluidic assessment of red blood cell mediated microvascular occlusion

Lab Chip, 2020, Accepted Manuscript
DOI: 10.1039/D0LC00112K, Paper
Yuncheng Man, Erdem Kucukal, Ran An, Quentin Watson, Jürgen Bosch, Peter A. Zimmerman, Jane A Little, Umut A. Gurkan
Abnormal red blood cells (RBC) deformability contributes to hemolysis, thrombophilia, inflammation, and microvascular occlusion in various circulatory diseases. A quantitative and objective assessment of microvascular occlusion mediated by RBCs with...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A high-throughput system combining microfluidic hydrogel droplets with deep learning for screening the antisolvent-crystallization conditions of active pharmaceutical ingredient

Lab Chip, 2020, Accepted Manuscript
DOI: 10.1039/D0LC00153H, Paper
Zhening Su, Jinxu He, Peipei Zhou, Lu Huang, Jianhua Zhou
Crystallization of active pharmaceutical ingredients (APIs) is a crucial process in the pharmaceutical industry due to its great impact in drug efficacy. However, conventional approaches for screening the optimal crystallization...
The content of this RSS Feed (c) The Royal Society of Chemistry




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PM Narendra Modi’s day at the Red Fort through 10 Express photos




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See India’s first solar-powered DEMU trains




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[ASAP] Combining Docking Pose Rank and Structure with Deep Learning Improves Protein–Ligand Binding Mode Prediction over a Baseline Docking Approach

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.9b00927




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[ASAP] Will Cryo-Electron Microscopy Shift the Current Paradigm in Protein Structure Prediction?

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.0c00177




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[ASAP] Development and Evaluation of MM/GBSA Based on a Variable Dielectric GB Model for Predicting Protein–Ligand Binding Affinities

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.0c00024




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[ASAP] Evaluating Scalable Uncertainty Estimation Methods for Deep Learning-Based Molecular Property Prediction

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.9b00975




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[ASAP] Prototype Selection Method Based on the Rivality and Reliability Indexes for the Improvement of the Classification Models and External Predictions

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.0c00176




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[ASAP] Multisolvent Models for Solvation Free Energy Predictions Using 3D-RISM Hydration Thermodynamic Descriptors

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.0c00065




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[ASAP] Scope of 3D Shape-Based Approaches in Predicting the Macromolecular Targets of Structurally Complex Small Molecules Including Natural Products and Macrocyclic Ligands

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.0c00161




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[ASAP] Matched Molecular Series Analysis for ADME Property Prediction

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.0c00269




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Moral combat: how sex divided American Christians and fractured American politics / R. Marie Griffith

Hayden Library - BR516.G75 2017




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Islamist party mobilization: Tunisia's Ennahda and Algeria's HMS compared, 1989-2014 / Chuchu Zhang

Online Resource




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Sacred heritage: monastic archaeology, identities, beliefs / Roberta Gilchrist

Online Resource




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The lost art of Scripture: rescuing the sacred texts / Karen Armstrong

Dewey Library - BL71.A76 2019