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Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02656J, Paper
Tomasz Wojnowski, Anna Ordyszewska, Hanna Halenka, Iwona Anusiewicz, Jarosław Chojnacki, Kinga Kaniewska-Laskowska, Rafał Grubba
The reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the...
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Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02825B, Communication
Meysam Kakavand, Anna Kozakiewicz, Abdollah Neshat
To develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series...
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Structure modification and luminescence regulation in new violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors via cation substitution

Dalton Trans., 2024, 53,17989-18002
DOI: 10.1039/D4DT02195A, Paper
Jie Zhang, Langping Dong, Feng Wang, Jingshan Hou, Yongzheng Fang
A series of violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors with tunable luminescence for high-quality white LEDs was developed through cation regulation.
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The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions

Dalton Trans., 2024, 53,18013-18020
DOI: 10.1039/D4DT02533D, Paper
Open Access
Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. Nolan
Despite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.
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A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors

Dalton Trans., 2024, 53,17783-17788
DOI: 10.1039/D4DT02336F, Communication
Danijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. Swiegers
Ca-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.
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Women’s Asian Champions Trophy: Sangita’s double strike hands India comfortable 4-0 win over Malaysia 

India scored through Sangita Kumari (8th, 55th minutes), Preeti Dubey (43rd) and Udita (44th).




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Enhanced removal efficiency of Tetradesmus obliquus for nevirapine removal via co-substrate supplementation: removal mechanisms, relative gene expression and metabolomics

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00576G, Paper
Karen Reddy, Nirmal Renuka, Muneer Ahmad Malla, Brenda Moodley, Faizal Bux, Sheena Kumari
The bioremediation of pharmaceutical wastewater by microalgae has gained scientific attention due to its cost-effectiveness and environmental friendliness.
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Carbon flows and biochar stability during co-pyrolysis of human faeces with wood biomass

Environ. Sci.: Water Res. Technol., 2024, 10,2709-2722
DOI: 10.1039/D4EW00513A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. E. Koulouri, M. Qiu, M. R. Templeton, G. D. Fowler
The systematic quantification of carbon flows and biochar stability when co-pyrolysing human faeces with wood biomass at different blending ratios and temperatures.
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Mathematical modeling to size anaerobic stabilization ponds intended for slaughterhouse wastewater treatment – the role of temperature and hydraulic retention time

Environ. Sci.: Water Res. Technol., 2024, 10,2882-2896
DOI: 10.1039/D4EW00557K, Paper
P. E. S. Soldera, R. F. Dantas, E. Fagnani
A new mathematical model for constructing anaerobic stabilization pond treatment systems for high organic load wastewater, based on biochemical oxygen demand, temperature and hydraulic retention time, is discussed.
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Improved microbial water quality and ozone performance following coagulation: implications for carbon based advanced treatment for potable reuse

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00638K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christina M. Morrison, Ariel J. Atkinson, Daniel Gerrity, Eric C. Wert
Coagulation/flocculation of secondary effluent with FeCl3 (1) removed MS2 bacteriophage and bacterial endospores up to 2–3 LRVs, (2) removed rapid surrogates at levels correlative with microbial removal, and (3) improved downstream O3 performance.
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Digital creator Gokul Raj’s takes on everyday life appeal to all ages with relatable Kerala sketches

The former radio and television jockey usually does a solo act that looks at the funny side of domestic life



  • Life & Style

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Campaign against British tabloids gathers momentum

The ‘Stop Funding Hate’ campaign is urging companies to stop advertising with tabloids




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Centuries-old Ten Commandments tablet goes under hammer for $850,000

The tablet was put up for sale by Rabbi Shaul Deutsch, founder of the Living Torah Museum, in Brooklyn, New York, with the stipulation that the buyer must put it on public display, the auction house said.




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36% surge in vegetable prices lifts September inflation to 9-month high

Retail inflation touches nine-month high of 5.5% in September




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At nearly 5-year high, 42.2% vegetable price rise propelled October retail inflation past 6.2% 

“High food inflation in October, 2024 is mainly due to increase in inflation of vegetables, fruits and oils and fats,” the National Statistical Office said




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Top IT leaders to establish ISB-like institute for deep tech and entrepreneurship in Sri City

The institute aims to provide a comprehensive approach to nurturing startups and addressing the skill gaps faced by entrepreneurs.




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Shriram Group establishes RT Chair in Computational Mechanics at IISc Bangalore

This distinguished academic position aims to enhance research in computational mechanics, including areas such as novel numerical methods and data-driven modelling.




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IIT Madras partners with ISRO to establish Research Centre to study Spacecraft & launch vehicle Thermal Management

This ‘Centre of Excellence in the area of Fluid and Thermal Sciences’ will be the Nodal Centre to study Thermal problems regarding design, analysis and testing of various components




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Consensus across all establishments in Pakistan for healthy ties with India, says former Pakistan PM Kakar

Senator seen as close to Islamabad’s military establishment says Jaishankar’s visit is an opportunity to explore sentiments on both sides




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Well-regulated structure-featuring giant-molecule acceptors enable long-term stability and high-performance binary organic solar cells

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03754E, Paper
Jingyu Shi, Pengfei Ding, Jintao Zhu, Zhenyu Chen, Shuangjiao Gao, Xueliang Yu, Xiaochun Liao, Quan Liu, Ziyi Ge
Through systematically selecting the numbers and positions of selenium atom of giant-molecule acceptors, the device based on PM6:GMA-SSeS yields the highest PCE of 19.37% with high VOC of 0.917 V and exhibits extended t80% lifetimes of 5600 h.
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Stabilizing doped Spiro-OMeTAD by organic molten salt for efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04310C, Paper
Tengfei Pan, Zhiwei Li, Biyun Ren, Wan Yang, Xueqin Ran, Yajing Li, Yutian Xu, Yue Wang, Deli Li, Yingdong Xia, Xingyu Gao, Lingfeng Chao, Yonghua Chen
Bis(trifluoromethane)sulfonimide (LiTFSI) and 4-tert-butylpyridine (TBP) have been currently suggested to be irreplaceable in classic doped 2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD) for high-performance perovskite solar cells (PSCs). However, the stability of Spiro-OMeTAD was...
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The construction of multifunctional solid electrolyte interlayers for stabilizing Li6PS5Cl-based all-solid-state lithium metal batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03289F, Paper
Ya Chen, Xin Gao, Zheng Zhen, Xiao Chen, Ling Huang, Deli Zhou, Tengfei Hu, Bozhen Ren, Runjing Xu, Jiayi Chen, Xiaodong Chen, Lifeng Cui, Guoxiu Wang
The established multifunctional interlayers effectively eliminate both anode-initiated and GB-initiated dendrites and guarantee satisfactory battery performance for ASSLMBs.
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A donor:hole-transport layer alloy for high-efficiency and stable binary organic solar cells with promoted hole collection and suppressed recombination

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04072D, Paper
Xianghui Zeng, Ting Xu, Hansheng Chen, Baoshen Deng, Qing Yan, Xuanlin Wen, Zijian Li, Haoxuan Zeng, Chuanlin Gao, Yaodong Xiao, Jiwei Liao, Hui Liu, Bin He, Peigang Han, Guangye Zhang, Shunpu Li, Yiwang Chen, Chen Xie
A donor-based nanoparticle (NPs)-incorporated hole-transport layer was synthesized for fine-tuning the energy level of anodes in organic solar cells. The conventional and inverted devices achieved record efficiencies of 19.9% and 17.2%, respectively.
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Metastable interphase induced pre-strain compensation enables efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03801K, Paper
Hongyu Xu, Yun Xiao, Karim A Elmestekawy, Pietro Caprioglio, Qiuyang Li, Qixuan Zhong, Yongqiang Ji, Tianyu Huang, Haoming Yan, Yingguo Yang, Laura M Herz, Qihuang Gong, Henry Snaith, Rui Zhu, Lichen Zhao
High-efficiency metal halide perovskite solar cells (PSCs) include the rigid substrates with low thermal-expansion coefficients (TECs), resulting in a significant TEC mismatch with the perovskites with high TECs at the...
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Interfacial coordination utilizing chelating ligands for operationally stable perovskite solar modules

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02803A, Paper
Bingkun Tian, Peikun Zhang, Tianjun Liu, Weicun Chu, Yuyang Long, Peng Xu, Ying Jiang, Jinping Zhang, Yajing Tang, Xiangnan Sun, Riming Nie, Xiaoming Zhao, Wanlin Guo, Zhuhua Zhang
Perovskite solar cells (PSCs) feature a higher maximum theoretical efficiency and a lower cost than silicon-based solar cells, while also offering additional advantages of being flexible and transparent. However, the...
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A monolithic Co-FeCo8S8 electrode for stable anion exchange membrane water electrolyzer driven by fluctuating power supply

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04993D, Communication
Jahangir Khan, Heming Liu, Tianhao Zhang, Xin Kang, Zhiyuan Zhang, Yuxiao Dong, Shanlin Li, Jiarong Liu, Qiangmin Yu, Bilu Liu
Integrating water electrolysis and green electricity offers a promising approach towards sustainable and clean energy. However, such a system demands electrodes that can swiftly and stably adapt to fluctuating power...
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Superhalide structure and iodide-proof interphase via electrolyte regulation enable ultrastable zinc-iodine batteries

Energy Environ. Sci., 2024, 17,8643-8657
DOI: 10.1039/D4EE02192D, Paper
Wenjing Deng, Renfei Feng, Xiaolei Wang
A superhalide electrolyte structure and iodide-proof solid electrolyte interphase are introduced to simultaneously obtain efficient conversion activity and anode stability for reversible zinc–iodine batteries.
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Circular battery design: investing in sustainability and profitability

Energy Environ. Sci., 2024, 17,8529-8544
DOI: 10.1039/D4EE03418J, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andreas Wolf, Felix Nagler, Philip Daubinger, Christoph Neef, Karl Mandel, Andreas Flegler, Guinevere A. Giffin
The market share of low-cost battery chemistries, which offer little to no recycling profitability with current methods, is growing. Design for circularity could be the key to reducing costs and enhancing sustainability for these batteries.
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Towards efficient and stable organic solar cells: fixing the morphology problem in block copolymer active layers with synergistic strategies supported by interpretable machine learning

Energy Environ. Sci., 2024, 17,8954-8965
DOI: 10.1039/D4EE03168G, Paper
Yu Cui, Qunping Fan, Hao Feng, Tao Li, Dmitry Yu. Paraschuk, Wei Ma, Han Yan
Interpretable machine learning identifies the causal structure–property relationships and key control factors in block copolymer organic solar cells with excellent power conversion efficiency and thermal stability.
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Weaving electron-rich alkynes: a durable in situ skin for stabilizing zinc anodes

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03164D, Paper
Xin Liu, Weimian Zhang, Ying Liu, Xiaodong Li, Deyi Zhang, Kun Wang, Lifeng Liu, Changshui Huang
An electron-rich alkyne of thiophdiyne (e-TDYP) is engineered in situ onto a zinc anode to regulate the EDL properties. The synergy between the conjugated thiophene and alkyne groups of e-TDYP facilitates the desolvation and ion-capture.
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Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
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Impact of complementary feeding on infant gut microbiome, metabolites and early development

Food Funct., 2024, 15,10663-10678
DOI: 10.1039/D4FO03948C, Paper
Open Access
Yudong Shi, Ran Yin, Jinzhu Pang, Yun Chen, Zhouyong Li, Shengpeng Su, Yongping Wen
Introducing complementary foods is critical for promoting infant health and development.
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Specific vegetable types are associated with lower long-term risk for late-life dementia: the Perth Longitudinal Study of Aging Women

Food Funct., 2024, 15,10885-10895
DOI: 10.1039/D4FO03239J, Paper
Negar Ghasemifard, Simone Radavelli-Bagatini, Simon M. Laws, Helen Macpherson, Emma Stevenson, Jonathan M. Hodgson, Richard L. Prince, Joshua R. Lewis, Marc Sim
This study found an association between total vegetable intake as well as specific types of vegetables including yellow/orange/red, green leafy, and allium vegetables with lower long-term risk for late-life dementia in older women.
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Novel selenium-enriched Pichia kudriavzevii as a dietary supplement to alleviate dextran sulfate sodium-induced colitis in mice by modulating the gut microbiota and host metabolism

Food Funct., 2024, 15,10698-10716
DOI: 10.1039/D4FO02598A, Paper
Huijuan Wang, Yue Chen, Zhouli Wang, Yahong Yuan, Tianli Yue
Inflammatory bowel disease (IBD) poses persistent challenges due to its chronic and recurrent nature, exacerbated by the unsatisfactory outcomes of the traditional treatment approaches.
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Integrated transcriptomics and untargeted metabolomics reveal bone development and metabolism of newly weaned mice in response to dietary calcium and boron levels

Food Funct., 2024, 15,10853-10869
DOI: 10.1039/D4FO03657C, Paper
Shuo Li, Xuehai Cao, Tiande Zou, Zirui Wang, Xingping Chen, Jun Chen, Jinming You
Boron supplementation in diets with varying calcium levels modulates bone development and bone parameters in mice by regulating calcium signaling, lipid metabolism, and neural signaling and inflammatory signaling.
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Dietary supplementation with novel selenium-enriched Pichia kudriavzevii regulates gut microbiota and host metabolism in mice

Food Funct., 2024, 15,10896-10912
DOI: 10.1039/D4FO03633F, Paper
Huijuan Wang, Dan Shi, Yue Chen, Zhouli Wang, Yahong Yuan, Tianli Yue
Insufficient selenium intake can lead to serious health problems.
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Interaction of oat bran and exercise training improved exercise adaptability via alleviating oxidative stress and promoting energy homeostasis

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03374D, Paper
Rui Dong, Hamad Rafique, Qianwen Niu, Xin Zeng, Maria Cristina Messia, Li Yuan, Lin Shi, Liang Zou, Lu Li, Xinzhong Hu
Interaction of oat bran (OB) diet and moderate intensity exercise training (MlET) reinforced the positive effect on skeletal muscle function.
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Correlation between vitamin D metabolic pathway-related gene polymorphisms and cardiovascular disease

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03234A, Review Article
Jiao Pang, Chunshuo Yang, Jiaqi Liu, Zhilin Wang, Xueshu Tao, Zhipeng Cao
Polymorphisms in key genes in the vitamin D metabolic pathway affect susceptibility to cardiovascular disease (CVD) and play potential roles in the pathogenesis of CVD.
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Protein-bound AGEs derived from methylglyoxal induce pro-inflammatory response and barrier integrity damage in epithelial cells by disrupting the retinol metabolism

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO00364K, Paper
Gang Yu, Jianxin He, Zhongshan Gao, Linglin Fu, Qiaozhi Zhang
Protein-bound advanced glycation end-products (AGEs) induce pro-inflammatory response and barrier integrity damage in epithelial cells by disrupting the retinol metabolism.
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The quercetin metabolite 4-methylcatechol causes vasodilation via voltage-gated potassium (KV) channels

Food Funct., 2024, 15,11047-11059
DOI: 10.1039/D3FO04672A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Patrícia Dias, Rudy Salam, Jana Pourová, Marie Vopršalová, Lukáš Konečný, Eduard Jirkovský, Jurjen Duintjer Tebbens, Přemysl Mladěnka
One of important metabolites of dietary polyphenols is 4-methylcatechol (4-MC). This compounds causes vasodilation likely due to an effect on voltage-dependent potassium channels (KV) as suggested by our ex vivo and in silico docking study.
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Influence of dairy matrix on the prebiotic effects of inulin related to gut metabolic activity and bone health

Food Funct., 2024, 15,11129-11140
DOI: 10.1039/D4FO01635A, Paper
Xiaorui Zhao, Weiwei He, Louise M. A. Jakobsen, Farhad M. Panah, Banny Silva Barbosa Correia, Dennis Sandris Nielsen, Axel K. Hansen, Hanne Christine Bertram
This study investigated if the prebiotic efficacy of inulin depends on the dairy matrix used as vehicle.
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Human milk oligosaccharides and milk fat globule membrane reduce allergic reactions in mice through the modulation of gut microbiota and metabolic functions

Food Funct., 2024, 15,11252-11265
DOI: 10.1039/D4FO03851G, Paper
Xinzhang Chen, Shengjun Yang, Zhengtao Guo, Bailiang Li, Zhongjiang Wang, Lianzhou Jiang
Human milk oligosaccharides (HMOs) and the milk fat globule membrane (MFGM) represent novel treatments for cow's milk allergy (CMA).
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Development of Pickering water-in-oil emulsions using a dual stabilization of candelilla wax and acylated EGCG derivatives to enhance the survival of probiotics (Lactobacillus plantarum) powder

Food Funct., 2024, 15,11141-11157
DOI: 10.1039/D4FO01342E, Paper
Zhaojuan Shi, Jun Wu, Xingting Wang, Tongqiao Nie, Qingmei Zeng, Chuanxun Yuan, Risheng Jin
Candelilla wax reinforced the stability of Pickering W/O emulsions with a three-dimensional crystal network. The oil phase volume fraction of the emulsions showed dramatic differences in protecting probiotic viability from environmental stresses.
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Correction: Using integrated transcriptomics and metabolomics to explore the effects of infant formula on the growth and development of small intestinal organoids

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO90094D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xianli Wang, Yuxin Jing, Chengdong Zheng, Chenxuan Huang, Haiyang Yao, Zimo Guo, Yilun Wu, Zening Wang, Zhengyang Wu, Ruihong Ge, Wei Cheng, Yuanyuan Yan, Shilong Jiang, Jianguo Sun, Jingquan Li, Qinggang Xie, Xiaoguang Li, Hui Wang
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Editorial. India needs a stable population, not more children

Southern States’ concerns need to be addressed by the Finance panel




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Jaipur-based South Western Command establishes think tank Gyan Shakti

The think tank aims to create a combined pool of talent of all stakeholders, which would be ideally suited to advise the industry and the government on the way forward




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Cost of commotion: each MCD House session comes with a ₹3 lakh tab





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Amitabh@80: His Best May Be Yet To Come

'For an introduction to his career-spanning genius, watch just five of his movies: Anand, Saudagar, Abhiman, Black and Pink,' notes Kalyan Singhal, McCurdy Professor of Business at the University of Baltimore.




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What Makes Jaya-Amitabh A Golden Couple

One of Hindi cinema's most high-profile couples celebrated their 50th wedding anniversary on June 3.