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Evaluating metal-free quaternized boronate esters as efficient catalysts for the fixation of CO2 with epoxides to form cyclic carbonates under suitable conditions

By pubs.rsc.org
Published On ::

React. Chem. Eng., 2024, 9,2938-2953
DOI: 10.1039/D4RE00282B, Paper
Eyyup Yasar, Emine Aytar, Ahmet Kilic
The conversion of CO2 into high value-added chemicals is receiving increasing attention from the scientific community, commercial enterprises, and policymakers due to environmental problems like global warming.
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A computational study of nematic core structure and disclination interactions in elastically anisotropic nematics

By pubs.rsc.org
Published On ::

Soft Matter, 2024, 20,2900-2914
DOI: 10.1039/D3SM01616A, Paper
Lucas Myers, Carter Swift, Jonas Rønning, Luiza Angheluta, Jorge Viñals
The structure of isolated disclinations and disclination dipoles in anisotropically elastic nematic liquid crystals is explored via a singular potential computational model.
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Pinning–depinning transition of droplets on inclined substrates with a three-dimensional topographical defect

By pubs.rsc.org
Published On ::

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00081A, Paper
Ninad V. Mhatre, Satish Kumar
The influence of defect geometry on the critical inclination angle required for droplet depinning on inclined substrates is studied.
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Kinetic and reactivity of gas-phase reaction of acyclic dienes with hydroxyl radical in the 273–318 K temperature range

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12303-12312
DOI: 10.1039/D3RA08750F, Paper
Open Access
Chenyang Xue, Xinmiao Xu, Han Lyu, Yunfeng Li, Yangang Ren, Jinhe Wang, Yujing Mu, Abdelwahid Mellouki, Zongzheng Yang
The relative position of two CC on the acyclic dienes could determine its reactivity. The number and type of alkyl group and the number of addition sites on diene could also strongly affect its reactivity toward OH radical.
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Electrochemical oxidative radical cascade cyclization of dienes and diselenides towards the synthesis of seleno-benzazepines

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12556-12560
DOI: 10.1039/D4RA01914H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling Hu, Jingyi Zhang, Minghan Li, Yulin Feng, Fangling Lu
An electrochemical approach to access seleno-benzazepines through an oxidative radical cascade cyclization of dienes with diselenides under metal-free, external oxidant-free and base-free conditions.
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Construction of glutathione-responsive paclitaxel prodrug nanoparticles for image-guided targeted delivery and breast cancer therapy

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12796-12806
DOI: 10.1039/D4RA00610K, Paper
Open Access
Weiwei Ma, Qiufeng Zhao, Shilong Zhu, Xinyue Wang, Chuangchuang Zhang, Daming Ma, Na Li, Yanyan Yin
HA-coated redox sensitive visualized nano-prodrug HA/TPE-CS-SS-PTX were exploited in order to highly efficient treatment of cancer and real-time monitoring of drug localization.
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Self-healable, reprocessable and anti-flammable eugenol-derived covalent adaptable thermosets based on dynamic covalent boronic esters and thiol–ene click chemistry

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00684D, Paper
Haoxin Niu, Yu Li, Ping Zhang, Wenwen Guo, Xin Wang, Yuan Hu
Self-healable and reprocessable eugenol-derived covalent adaptable thermosets were fabricated via dynamic covalent boronic esters and thiol–ene click chemistry.
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[Ru]-Catalyzed Olefin Metathesis and Ethenolysis for the Synthesis and Recycling of Bio-Based Polycarbonates and Polycyanurates

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00940A, Paper
Dana M. Pinson, Francesca D. Eckstrom, Gregory S. Ostrom, K. Randall McClain, Lawrence Baldwin, Benjamin Grant Harvey
Eugenol, an abundant, naturally occurring phenolic compound, was converted into a thermoplastic polycarbonate by olefin metathesis followed by interfacial polymerization with triphosghene. This resulted in polymers with Mn ranging from...
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Combined and rapid detection of anti-Brucella IgG/IgM in clinical samples based on surface-enhanced Raman scattering-lateral flow immunochromatography

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, 12,11012-11024
DOI: 10.1039/D4TB01367K, Paper
Yongwei Zhang, Ziyue Li, Aolin Zhu, Qian Zhang, Hao Zhou, Xuelei Zhou, Tingwei Liu, Chunyan Liu, Hefei Zha, Xin Zhang, Hui Zhao, Jiutong Li, Guodong Lü, Xinxia Li
Brucellosis is a bacterial infectious disease caused mainly by Brucella. Transmission is mainly by contact with infected domestic or wild animals or their excreta.
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Efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01987C, Paper
Wan Huang, Song Zhang, Li Luo, Yalong Pan, Lijun Han, Yao Yu
Novel efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy.
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Polycyclic aromatic polymer nanoparticles show potent infectious particle adsorption capability

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01793E, Paper
Yudai Oishi, Mako Toyoda, Nanami Hano, Chihiro Motozono, Takamasa Ueno, Makoto Takafuji
Nonspecific viral adsorption by polymer nanoparticles is more economical and superior in terms of operating cost and energy efficiency than viral adsorption using virus-specific antibodies and filtration techniques involving size...
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Advancing cancer therapy with a heptamethine carbocyanine dye-conjugated radionuclide drug

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01798F, Paper
Mingxing Huang, Weichen Wang, Yingwei Wang, Rang Wang, Lili Pan, Xin Li, Bo Li, Jingsong Zhang, Ruoxiang Wang, Yi Zhang, Rong Tian
Malignant tumors pose substantial treatment challenges due to their heterogeneity, metastatic potential, and therapeutic resistance, underscoring the urgent need for more effective treatment options.
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Anthropocene: A response to the contagion and climate change

By www.thehindubusinessline.com
Published On :: Sun, 04 Jul 2021 10:34:37 +0530

Five poems from Sudeep Sen’s new collection of poetry, prose and photography


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Dilip Kumar’s take on Heathcliff

By www.thehindubusinessline.com
Published On :: Wed, 07 Jul 2021 13:08:18 +0530

‘Arzoo’ consolidated the legendary actor’s image as the tormented lover


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Mumbai Mapped: Click to find geckos, sunbirds, and turtles

By www.thehindubusinessline.com
Published On :: Thu, 08 Jul 2021 13:43:37 +0530

A new interactive map of Maximum City plots the flora and fauna of the megapolis


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DFT rationalization of the mechanism and selectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols

By pubs.rsc.org
Published On ::

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP01700E, Paper
Guowei Yan, Ji Ma, Simeng Qi, Alexander M. Kirillov, Lizi Yang, Ran Fang
The mechanism, regioselectivity, and chemoselectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols to give furan-3-carboxylate derivatives were explored by density functional theory (DFT).
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How climate change has helped vineyards in Britain thrive

By www.thehindu.com
Published On :: Fri, 18 Oct 2024 16:07:43 +0530

Discover the rise of English wines, from picturesque vineyards to award-winning bottles, amidst a changing climate and growing acclaim


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Climbing up the wall

By www.thehindu.com
Published On :: Fri, 16 Aug 2013 16:58:09 +0530

Vertical gardens can breathe life into smaller urban spaces. Teja Lele Desai finds out how


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How to Survive a Client Meeting When They Say ‘Make It Pop’!!!!

By webdesignerdepot.com
Published On :: Mon, 11 Nov 2024 13:38:56 +0000

As a graphic designer, you've probably heard the three little words that can strike terror into the hearts of even the most seasoned creatives: “Make it pop.” These words are so vague, so void of meaning, yet so charged with expectation that they deserve their own horror film.


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Recycling of spent lithium-ion batteries for a sustainable future: recent advancements

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00898C, Review Article
Open Access
Basanta Kumar Biswal, Bei Zhang, Phuong Thi Minh Tran, Jingjing Zhang, Rajasekhar Balasubramanian
A critical review of the recent developments in the recycling of spent Li-ion batteries using five major technologies (direct recycling, pyrometallurgy, hydrometallurgy, bioleaching and electrometallurgy) and evaluation of their sustainability.
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National Motorcycle Racing Championship set for grand climax at MIC

By www.thehindu.com
Published On :: Thu, 03 Oct 2024 15:14:10 +0530

Over 100 entrants, representing 19 teams, will vie for top honours across 19 races at MRF MMSC FMSCI Indian National Motorcycle Racing Championship in Chennai on October 4


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Sarthak Chavan clinches maiden National crown

By www.thehindu.com
Published On :: Sat, 05 Oct 2024 19:32:12 +0530


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Paris Olympics 2024: I watch clips of my goals to boost confidence ahead of debut, says Sukhjeet Singh

By www.thehindu.com
Published On :: Thu, 25 Jul 2024 15:02:53 +0530

Sukhjeet Singh is one of the five debutants — Sanjay, Abhishek, Rajkumar Pal, and Jarmanpreet Singh — who have joined the 11 members of Tokyo Olympic bronze medalist team for the Paris Games.


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India defeats Spain 2-1 to clinch second consecutive bronze medal at Paris Olympics

By www.thehindu.com
Published On :: Thu, 08 Aug 2024 19:24:45 +0530

The bronze medal was indeed a fitting farewell for the goalkeeper P.R. Sreejesh. India wins back-to-back medals in hockey after 52 years.


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Asian Champions Trophy final: India edges past China 1-0; clinches record-extending fifth title

By www.thehindu.com
Published On :: Tue, 17 Sep 2024 17:26:51 +0530

It was the record-extending fifth Asian Champions Trophy title for India.


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School in Raj Bhavan sees decline in number of students

By www.thehindu.com
Published On :: Tue, 31 May 2016 00:00:00 +0530


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Change is in the air : carbon, climate, Earth, and us / Debbie Levy ; illustrated by Alex Boersma

By darius.uleth.ca
Published On ::

Levy, Debbie, author


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Climate / by Christina Earley

By darius.uleth.ca
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Earley, Christina, author


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Funding climate favours clean tech

By www.thehindubusinessline.com
Published On :: Sun, 17 Dec 2023 21:20:00 +0530

Why Orios Venture Partners wants to double down on clean tech and climate investments


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The Dr is in... the e-clinic

By www.thehindubusinessline.com
Published On :: Sun, 14 Jan 2024 21:30:00 +0530

CureBay mobilises digitisation to take quality medical care to underserved areas


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Twinning climate tech with profits

By www.thehindubusinessline.com
Published On :: Sun, 28 Jan 2024 21:55:00 +0530

Avaana Capital looks for problem solvers with a differentiated approach


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Carboxylative cyclization of atmospheric CO2 with alkynol catalyzed by a 1-methylhydantoin anion-functionalized ionic liquid via chelative interactions

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03586K, Communication
Yujun Guo, Tingting Chen, Yingjie Xu
[1-MHy]− acts as a “pincer ligand” to form chelative interactions with –OH to enhance MBY activation, thus ensuring efficient [P4442][1-MHy]-catalyzed reaction of atmospheric pressure CO2 with MBY under metal- and solvent-free conditions.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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Intramolecular cyclization of N-aryl amides for the synthesis of 3-amino oxindoles

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05259E, Communication
Haitao Yang, Yu Pan, Yijing Tian, Kaili Yu, Yifeng Bai, Yonggang Jiang, Hongbin Zhang, Guogang Deng, Xiaodong Yang
A mild and efficient strategy to synthesize pharmaceutically important 3-amino oxindoles from readily available N-aryl amides has been developed.
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Laccase-catalyzed tyrosine click reaction with 1-methyl-4-arylurazole: rapid labeling on protein surfaces

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03802A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Keita Nakane, Chizu Fujimura, Shogo Miyano, Zhengyi Liu, Tatsuya Niwa, Hafumi Nishi, Tetsuya Kadonosono, Hideki Taguchi, Shusuke Tomoshige, Minoru Ishikawa, Shinichi Sato
Our study shows efficient tyrosine labeling using 1-methyl-4-arylurazole (MAUra) with laccase under mild conditions. This method achieves a high efficiency (kcat/Km = 7.88 × 104 M−1 s−1), selectively targeting exposed tyrosine sites on proteins.
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IADE, Infirmier anesthésiste : S'entraîner à la pratique clinique avec 20 cas concrets

By www.vuibert.fr
Published On :: Mon, 11 Nov 2024 05:01:16 +0000

19,90 €

Garry Laudren, Michaël Mimouni
1re édition
novembre 2024
176 pages
Le tout premier cahier d’exercices pour s’entraîner à la pratique et au raisonnement clinique IADE
Livre
Nouveau
978-2-311-66519-2
Disponible
Livre


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Photocatalytic degradation of tetracycline hydrochloride by BiVO4/MIL-88B(Fe) heterojunction

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01500B, Paper
Ziwei Zhao, Qi Ling, Shangkun Deng, Ziliang Li, Jianguo Lv, Lei Yang, Chunbin Cao, Zhaoqi Sun, Miao Zhang
A type II heterostructured BiVO4/MIL-88B(Fe) composite was successfully synthesised for the photocatalytic degradation of tetracycline hydrochloride (TC-HCl) by a simple hydrothermal method. Thin film materials avoid secondary pollution of powder...
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Unraveling the inhibitory potential of Rosetta designed de novo cyclic peptides on PARP7 through molecular dynamics simulations

By pubs.rsc.org
Published On ::

New J. Chem., 2024, 48,7347-7355
DOI: 10.1039/D4NJ00016A, Paper
Yuqi Zhu, Aamir Mehmood, Daixi Li
Cyclic peptides have the characteristics of antibodies and small molecules and have better advantages over small molecules.
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Theoretical investigation of the effect of radical substituents on the open-shell character of polycyclic aromatic hydrocarbons

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00555D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tomohito Shinozuka, Daiki Shimizu, Kenji Matsuda
Radical substituents was found to significantly alter the open-shell character y of PAHs compared to non-radical substituents.
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Facile synthesis of spiro-pyrazolone-tetrahydrofurans/pyrans: ipso-cyclization of arylidene pyrazolones with haloalcohols

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00447G, Paper
Kavyashree Kuppayya Gond, Mahagundappa Rachappa Maddani
Facile synthesis of spiro-pyrazolone-tetrahydrofurans & pyrans by base-mediated cascade ipso-cyclization of haloalcohols & arylidine pyrazolones is realised. Features include brief reaction time, practicality, good yields and mild reaction conditions.
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Evaluation of adsorption and degradation performance of lanthanum modified mesoporous carbon nitride composite materials for tetracycline wastewater

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00864B, Paper
Zhiqiang Wu, Yueyi Li, Pengxi Jiang, Sisi Ma, Wenfei Dong, Hongjian Zhao, Enke Feng, Xuming Wang
The lanthanum modified mesoporous graphite nitride carbon composites (La-g-C3N4) were synthesized using a thermal shrinkage polymerization method. The samples underwent characterization through the X-ray diffraction (XRD), the fourier transform infrared...
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Web AI Summit 2024 Recap: Client-Side AI for Developers

By developers.googleblog.com
Published On ::

The first Web AI Summit, hosted by Google on October 18, 2024, brought together experts in machine learning models for web browsers.


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These motorcyclists at the India Bike Week shatter myths about ‘women bikers’

By www.thehindu.com
Published On :: Mon, 28 Nov 2022 16:10:28 +0530

Maral Yazarloo-Pattrick, Sameera Dahiya, and Urvashi Patole smash stereotypes about female bikers in India


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A novel CuAl2O4/MoS2/BaFe12O19 magnetic photocatalyst simultaneously coupling type I and Z-scheme heterojunctions for the sunlight-driven removal of tetracycline hydrochloride

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00970J, Paper
Mengjun Han, Shifa Wang, Xinmiao Yu, Xianlun Yu, Huajing Gao, Xianju Zhou, Dengfeng Li, Leiming Fang, Jagadeesha Angadi V., Mohd Ubaidullah, Bidhan Pandit
A novel CuAl2O4/MoS2/BaFe12O19 photocatalyst is synthesized that simultaneously couples type I and Z-scheme heterojunctions and exhibits high photocatalytic activity for the degradation of TC under simulated sunlight irradiation.
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Recycling and repurposing of waste carbon nanofiber polymers: a critical review

By pubs.rsc.org
Published On ::

Environ. Sci.: Nano, 2024, 11,1394-1411
DOI: 10.1039/D3EN00784G, Critical Review
Zhihao Liu, Zhijie Chen, Zimin Wang, Daijun Zhang, Bing-Jie Ni
Carbon nanofibers are a class of lightweight, high-performance composite materials.
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Incisive analysis of hydrogen-bonded supramolecular architectures in designer polycyclitols: observation of some interesting self-assembly patterns

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,1952-1961
DOI: 10.1039/D4CE00010B, Paper
Showkat Rashid, Ahmad Husain, Bilal A. Bhat, Goverdhan Mehta
This article examines C–H⋯O and O–H⋯O hydrogen-bonded patterns in polyoxygenated decalins, showcasing varied supramolecular architectures influenced by oxyfunctionalisation and surrogate carbonate groups.
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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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Degradation of tetracycline by visible light using Ca2Nb2O7 composite oxides with perovskite and pyrochlore sub-crystalline phases

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00044G, Paper
Junwei Xu, Chengxin Lu, Xianfeng Zhang, Rumeng Ouyang, Xiuzhong Fang, Xianglan Xu, Xiang Wang
We synthesized two paramorphs of Ca2Nb2O7 for visible light degradation of tetracycline, and found that pyrochlore phase has better reactivity compared to perovskite phase, which is attributed to the intrinsic oxygen vacancies and lattice disorder of pyrochlore phase.
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Can climate-resilient farming become a profitable venture?  

By www.thehindubusinessline.com
Published On :: Mon, 28 Nov 2022 21:27:33 +0530

The mantra of climate-resilient farming was simple but difficult to digest for traditional farming households


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Outstanding power sector dues of States decline by ₹24,680 crore

By www.thehindubusinessline.com
Published On :: Wed, 30 Nov 2022 18:48:11 +0530

It is expected that strict implementation of the LPS rules will bring back financial viability of the power sector in the country and would attract investment to ensure reliable 24x7 electricity to the consumers


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