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A liquid-infiltrated Al2O3 framework electrolyte enables aqueous zinc batteries

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04928D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rongyu Deng, Yi Yuan, Zixuan Li, Feixiang Wu, Alex W Robertson
Aqueous zinc-ion battery anodes face the twin challenges of dendrite growth and severe side reactions. Here a liquid-infiltrated Al2O3 framework electrolyte (LIAFE) is developed to address these issues and enables...
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Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04293J, Communication
Tiantian Yin, Shiyuan Sui, Shuqi Li, Junbiao Chang, Dachang Bai
Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis of axially chiral organosilanes.
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Moringa honey: How Italian bees are helping farmers in sweet enterprise

Moringa honey is among the most popular varieties of floral nectar in the food sector. Farmer and beekeeper N Dhandayuthapani is one of those in the Cauvery delta reaping the benefit of combining apiary with agriculture




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Coimbatore’s Kaapi 2.0 offers healthy snacks with strong filter coffee

Kaapi 2.0, a new chain of minimalist cafes in the city, offers healthy snack options to munch on along with filter coffee



  • Life & Style

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Watch | Masterchef Australia 2018 winner Sashi Cheliah opens restaurant in Chennai 

A video on Pandan Club, a new restaurant in Chennai with a unique Peranakan Malaysian menu




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In Auroville, try a mac and ‘sheeze’ as vegan chefs set up cafes and create healthy alternatives to meat

We sample inventive menus across the lush, experimental township, which draws visitors from across the world



  • Life & Style

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Kozhikode’s iconic sharbat shop downs shutters

The shop, near the C.H. Flyover junction, often has around twenty people waiting outside at any time of the day




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Home bakers and chefs in Thiruvananthapuram have spread out a delectable platter for Christmas

Cakes, cookies, puddings and more are in the Christmas hampers sold by home cooks




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The story behind Goila butter chicken

Saransh Goila tells how Goila Butter Chicken was born and why it is less sweet




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Chances of infection: food safety squad continues aggressive checking in eateries

Nearly 70 shops dealing with food-based business inspected; flash inspections conducted considering the crowd turnout for Kerala State School Kalolsavam




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Gambling and problem gambling in Washington State : report to the Washington State Lottery / by Rachel A. Volberg

Albany, NY : Gemini Research, [1993]




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Introducing Env: a better way to read environment variables in JavaScript

If you write server-side JavaScript, chances are you’ve need to read information from environment variables. It’s considered a best practice to share sensitive information, such as access tokens, inside of environment variables to keep them secure. However, the way environment variables are read from JavaScript is error-prone in subtle ways that might take you hours...




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The lazy-loading property pattern in JavaScript

Traditionally, developers have created properties inside of JavaScript classes for any data that might be needed within an instance. This isn’t a problem for small pieces of data that are readily available inside of the constructor. However, if some data needs to be calculated before becoming available in the instance, you may not want to...




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In silico investigation of the interaction between α-synuclein aggregates and organic supramolecular assemblies

Mol. Syst. Des. Eng., 2024, 9,1155-1166
DOI: 10.1039/D4ME00071D, Paper
Laura Le Bras, Yves L. Dory, Benoît Champagne
An α-synuclein aggregate with the PreNAC and NACore areas, responsible for the aggregation, highlighted.
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Design strategy and molecular level understanding: hole transport materials with suitable transition dipole orientation for OLEDs

Mol. Syst. Des. Eng., 2024, 9,1116-1129
DOI: 10.1039/D3ME00127J, Paper
Krishan Kumar, Sunil Kumar, Anirban Karmakar, Dipanshu Sharma, Feng-Rong Chen, Mangey Ram Nagar, Jwo-Huei Jou, Subrata Banik, Subrata Ghosh
A combined experimental and theoretical study on a group of phenothiazine-substituted pyridine is reported.
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Selective mineralization at hydrogel interface induced by fusion between peptide hydrogels

Mol. Syst. Des. Eng., 2024, 9,1107-1115
DOI: 10.1039/D4ME00112E, Paper
Yongbaek Kim, Hiroto Isobe, Keishi Nishio, Kazuki Murai
Biomineralization has garnered attention not only for its fundamental role in understanding the mechanisms of biomineral formation but also as a method for fabricating next-generation functional materials.
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Elucidating the interplay between entropy-driven and patch-mediated bonding in directing nanoscale assemblies

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00153B, Paper
Kireeti Akkunuri, Xiangyu Zhang, Thi Vo
The interplay between directional patchy attraction and shape-driven entropic forces sculpts the spatial and orientational orderings between anisotropic building blocks, giving rise to symmetry breaking of pre-programmed interactions between particles.
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Unveiling the influence of oxidation state and heavy atom effects in chalcogen group on boron centered D(X)BNA core: a computational study on RTP versus TADF

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00131A, Paper
Ramalingam Mahaan, Murugesan Panneerselvam, Luciano T. Costa, Aruljothy John Bosco
The effects of heavy atoms and oxidation states in chalcogen groups on D(X)BNA cores, combined with substitutions of weak and strong donors, led to the identification of potential TADF and RTP molecules among the 14 molecules.
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Development of xanthan gum-based solid desiccants for the extraction of water vapors from humid air

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00134F, Paper
Hemant Mittal, Ali Al Alili, Saeed M. Alhassan, Naved I. Malek, Md. Didarul Islam
A xanthan gum-acrylamide desiccant with interconnected capillary channels was prepared and showed 1.38 g g−1 water adsorption at 90% RH and 25 °C, retaining 70% capacity over 20 cycles, proving its effectiveness as a salt-free desiccant.
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Interruption volontaire de grossesse médicamenteuse

24,00 €

Philippe Faucher, Danielle Hassoun
4e édition
octobre 2024
160 pages
Un guide simple et concis pour bien prescrire l'IVG médicamenteuse
Livre
Nouveau
978-2-311-66541-3
Toutes les informations utiles - La prise en charge - La législation à jour
Disponible
Livre




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The eternal dilemma




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Esoteric knowledge




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Scriptural literacy




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Mother Teresa declared Saint Teresa of Calcutta

In his homily after Mother Teresa’s canonisation, Pope Francis admitted even he would find it hard to call her “St. Teresa” since her tenderness was so maternal.




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Mystery of creation




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The Eternal Tatva




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Importance of laughter




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Ultrafine VN quantum dots modified with a nitrogen-doped reduced graphene oxide anode material for enhanced rate capability and lifespan of lithium-ion batteries

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00502C, Paper
Dong Wang, Zihan Guo, Zhiwei Wang, Yanfang Gao
The excellent electrochemistry performance is attributed to vanadium nitride quantum dots (VNQDs) offering large capacity and nitrogen-doped reduced graphene oxide (NrGO) acting as a conductive network and buffer skeleton.
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Ni–Co alloys via controlled pyrolysis of NiCo–MOF as heterogeneous hydrogenation catalysts

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00664J, Paper
Lidan Deng, Xingwang Liu, Chong Chen, Lu Wang, Fan Liu, Jie Zhang
The pyrolysis in H2 at lower temperatures can obtain MNP/MOF with more complete MOFs structure and dispersed Ni–Co alloy nanoparticles, which display significantly better activity for the hydrogenation of toluene to methylcyclohexane.
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Photocatalytic degradation of tetracycline hydrochloride by BiVO4/MIL-88B(Fe) heterojunction

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01500B, Paper
Ziwei Zhao, Qi Ling, Shangkun Deng, Ziliang Li, Jianguo Lv, Lei Yang, Chunbin Cao, Zhaoqi Sun, Miao Zhang
A type II heterostructured BiVO4/MIL-88B(Fe) composite was successfully synthesised for the photocatalytic degradation of tetracycline hydrochloride (TC-HCl) by a simple hydrothermal method. Thin film materials avoid secondary pollution of powder...
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A Novel In-Syringe Cloud Point Extraction Method for the Determination of Cadmium and Lead in Human Hair Samples

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00335G, Paper
Hesane Zolfaghari, Seyed Mosayeb Daryanavard, Aqil Gholamshahzadeh
The measurement of contaminant elements, especially cadmium and lead, in biological samples typically requires time-consuming sample preparation methods that consume organic solvents that are harmful to humans and the environment....
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Isolation and characterization of novel degradation products in Fenoverine by LC-QTOF-MS/MS, LC-MSn and 2D-NMR

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ05623F, Paper
Krishnam Raju CH, Shanmukha Kumar Jagarlapudi, Yesudas Kada, Sanath Kumar Goud Palusa
This study investigates the degradation profile of Fenoverine (FEN), an antispasmodic drug, following the International Conference on Harmonization (ICH) Q1A (R2) guidelines. FEN is stable in the presence of light,...
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Mesoporous carbon hollow spheres loaded with Fe/Fe3C as efficient solar vapour generation materials

New J. Chem., 2024, 48,7168-7175
DOI: 10.1039/D4NJ00424H, Paper
Jianfeng Gao, Hui Zhang, Zhaoshun Zhang, Changcheng Lin, Qun Yang, Shiwei Shi, Xueqin Zuo, Shaowei Jin, Guang Li
An evaporator has two major advantages: excellent interfacial evaporation efficiency and organic pollution treatment capacity.
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Photothermal properties of MXenes and sterilization of MRSA by Nb2C/Gel with a low power NIR-II laser

New J. Chem., 2024, 48,7045-7051
DOI: 10.1039/D4NJ00245H, Paper
Yekai Zheng, Xinyi Fu, Li Jiang, Denghao Li, Weidan Zhao, Mi Liu, Jiali Liu, Shangzhong Jin, Yan Zhou
A comparative study on the photothermal properties of MXenes (Ti3C2, V2C and Nb2C) and MXene/Gels (Ti3C2/Gel, V2C/Gel and Nb2C/Gel). The fast and efficient sterilization of MRSA was achieved using Nb2C/Gel at low laser power.
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Efficient elimination of Hg(II) from water bodies with acid-modified magnetic biomass spent tea leaves: conditional optimization and application

New J. Chem., 2024, 48,7413-7429
DOI: 10.1039/D4NJ00576G, Paper
Dingli Cheng, Yiwen Li, Xinyu Zheng, Yongfu Guo
To effectively enhance the resource utilization of biomass waste, a acid-modified magnetic biomass spent tea leaves (NiFe2O4/STLs) was prepared via the pyrolysis and co-precipitation methods and used to eliminate mercury (Hg(II)) from water bodies.
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Research progress of Co-based spinel oxide materials for direct methanol fuel cells

New J. Chem., 2024, 48,7148-7167
DOI: 10.1039/D3NJ05431D, Paper
Zhiyang Zhong, Qinghui Zhang, Yingying Zhu, Bingyu Chen, Siyan Xu, Tianyu Shen, Aijuan Xie, Shiping Luo
With decades of research, both the synthesis and applications of spinels have achieved greatly increased development. The preparation, regulation strategies, and their application in MOR of Co based spinels are reviewed in this paper.
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3D interconnected polymer/mesoporous silica nanoparticle hybrid materials with hierarchical macro/meso-structures for heavy metal adsorption

New J. Chem., 2024, 48,7503-7516
DOI: 10.1039/D3NJ05887E, Paper
Jae-Seo Park, Young Sunwoo, Debabrata Chakraborty, Chamila Gunathilake, Yanhai Du, Eun-Bum Cho
This work offers nanohybrid structures for heavy metal ion adsorption from water, which include a unique 3D cross-linked structure that combines organic polymer chains with mesoporous materials to improve adsorption efficiency.
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Novel composite of ZnMoO4/Ni(OH)2 as an electrode material for enhanced performance in energy-storage applications

New J. Chem., 2024, 48,7362-7369
DOI: 10.1039/D4NJ00513A, Paper
Barani Kumar Duvaragan, Ganesan Shanmugam, Arif Mohamed Shahul Hameed, Vetrivel Ramalingam
The as-prepared composite of micro-flower structure of ZnMoO4 with Ni(OH)2 nano-flower were employed as electrode materials for supercapacitors.
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Synthesis of copper(II) complex-functionalized Fe3O4@ISNA (ISNA = isonicotinic acid) as a magnetically recoverable nanomaterial: catalytic studies in alcohol oxidation and nitrophenol reduction, and TD-DFT studies

New J. Chem., 2024, 48,7308-7322
DOI: 10.1039/D3NJ05440C, Paper
Rimpa Mondal, Aratrika Chakraborty, Ennio Zangrando, Madhulata Shukla, Tanmay Chattopadhyay
The synthesis of a magnetically separable nanocatalyst Fe3O4@ISNA@CuL1 used as a catalyst for oxidation of alcohols and reduction of nitrophenols.
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Highly crystalline graphite nanofibers as an anode for high-performance potassium-ion batteries

New J. Chem., 2024, 48,7497-7502
DOI: 10.1039/D4NJ00662C, Paper
Kaixuan Sun, Kun Chang, Jinshuo Tan, Chuan-Fu Sun, Qin Liu
Graphite nanofibres with high crystallinity and low defect levels for potassium-ion batteries with high initial Coulombic efficiency and long cycling stability are reported in this study.
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In situ fabrication of a robust P–N heterojunction based on Mn–Zn–S–ethylenediamine hybrid nanorods for boosting photocatalytic performance

New J. Chem., 2024, 48,7287-7299
DOI: 10.1039/D3NJ05879D, Paper
Zhi-Yu Liang, Wang-Jun Huang, Er-Da Zhan, Peng Yang, Ren-Kun Huang, Ying Wang, Gui-Yang Yan
Multifarious novel photocatalysts based on hybrid nanocomposites have been developed to boost photocatalytic efficiency.
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Design and synthesis of few-layer molybdenum oxide selenide encapsulated in a 3D interconnected nitrogen-doped carbon anode toward high-performance sodium storage

New J. Chem., 2024, 48,7370-7378
DOI: 10.1039/D4NJ00389F, Paper
Yonghong Qin, Shahriman Zainal Abidin, Azhari Bin Md Hashim, Oskar Hasdinor Hassan, Xiaojun Zhao
Novel few-layered MoO3–MoSe2 encapsulated in a 3D NC skeleton is constructed to improve the electrochemical performances of SIBs.
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Mechanochemical synthesis of biphenyl-derived organic fluorescent materials via solvent-free and ligand-free oxidative homocoupling reactions

New J. Chem., 2024, 48,7356-7361
DOI: 10.1039/D4NJ00886C, Paper
Zefeng Li, Caihang Zhang, Yingxuan Zheng, Ping Deng, Yan Yu
The palladium-catalyzed solvent-free and ligand-free oxidative homocoupling reactions of aryl boronic acids via ball-milling are developed to synthesize a series of biphenyl-derived organic fluorescent materials.
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Rhodium-catalysed homo-coupling of terminal alkynes: divergent synthesis of bioactive 1,3-diynes and conjugated enediynes

New J. Chem., 2024, 48,7517-7523
DOI: 10.1039/D4NJ00366G, Paper
Yijie Xiao, Lijie Lv, Nanxuan Luo, Peirui Zhao, Yao Chen, Zhangshun Luo, Houhua Yin, Yi He, Shenyou Nie
C(sp)–C(sp) cross-coupling of terminal alkynes represents a robust tool for building biologically active 1,3-diynes although confronted with huge challenges regarding selectivity control.
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Tannic acid induced in situ growth of an underwater superoleophobic ZIF-8 composite membrane for emulsion separation

New J. Chem., 2024, 48,7384-7393
DOI: 10.1039/D4NJ00623B, Paper
Wanyu Lu, Qijin Tang, Huajing Cheng, Shudi Li, Cailong Zhou, Hao Yang
Tannic acid induced in situ growth of ZIF-8 crystals on a nylon membrane, creating a multifunctional composite membrane that exhibits remarkable underwater superhydrophobicity and resistance to oil adhesion.
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Copper(II) complexes of sterically hindered phenolic Schiff bases: synthesis, characterization, interaction with biomolecules, and antioxidant and antimicrobial activity

New J. Chem., 2024, 48,7134-7147
DOI: 10.1039/D4NJ00430B, Paper
Iveta S. Turomsha, Maxim Y. Gvozdev, Nikolai P. Osipovich, Viktoryia A. Staravoitava, Dmitriy I. Shiman, Natalia V. Loginova
Phenolic Schiff bases and their Cu(II) complexes have been synthesized and characterized by physicochemical methods. The complexes exhibit low cell toxicity and high antioxidant and antibacterial activity, as evidenced by molecular docking studies.
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Performance analysis and structure characterization of polylactic acid modified with three flame retardants

New J. Chem., 2024, 48,7469-7479
DOI: 10.1039/D3NJ05967G, Paper
Zhu Yuqin, Wang Di, Guo Zhongliang, Wen Huiying
Three flame retardant composites were prepared by incorporating flame retardants (FRs), including triphenyl phosphate (TPP), polysiloxane (PSQ) and phosphite functionalized polysiloxane (PPSQ), respectively into a polylactic acid (s/PLLA) matrix.
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Persulfate promoted regioselective C-1 thiocyanation of imidazo[1,5-a]pyridines under visible light irradiation in water

New J. Chem., 2024, 48,7041-7044
DOI: 10.1039/D4NJ00327F, Communication
Pallavi Saha, Samarpita Das, Harish K. Indurthi, Rohit Kumar, Deepak K Sharma
A visible light-mediated, photocatalyst-free, persulfate-promoted approach has been explored for regioselective C-1 thiocyanation of imidazo[1,5-a]pyridines.
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Vacancy engineering modulates spin polarization to enhance the charge dynamics of CuIn5S8 for photocatalytic sterilization

New J. Chem., 2024, 48,7394-7404
DOI: 10.1039/D3NJ05482A, Paper
Wenbin Wu, Jing Wang, Xiaojie Liang, Laixi Luo, Yaohong Yang, Fan Zhou, Shuduan Deng, Yumin Song, Le Yang, Kunyong Kang
Photocatalytic sterilization technology is a strategy that is environmentally friendly for killing drug-resistant bacteria using solar energy.
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High proficiency Ag/β-Ag2WO4/V3O4/g-C3N4 heterojunction photocatalyst for the actuation of C(OH)–H bond

New J. Chem., 2024, 48,7430-7438
DOI: 10.1039/D4NJ00395K, Paper
Fereshteh Zolfi, Mahdieh Ghobadifard, Sajjad Mohebbi
Ag/β-Ag2WO4/V3O4/g-C3N4 heterojunction photocatalyst was prepared for the actuation of the C(OH)–H bond with a mechanistic point of view.
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