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[ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene

Organometallics
DOI: 10.1021/acs.organomet.0c00061




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[ASAP] Transformation of a Norbornadiene Unit to Ethylenylcyclopentene Requiring Cooperation between Boron and Rhodium Centers

Organometallics
DOI: 10.1021/acs.organomet.0c00155




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[ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00049




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[ASAP] <italic toggle="yes">O</italic>-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes

Organometallics
DOI: 10.1021/acs.organomet.0c00208




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One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00428F, Paper
Song Li, Long Yan, Qiying Liu, Jianguo Liu, Qiyu Liu, Wei Fan, Xuelai Zhao, Xinghua Zhang, Chenguang Wang, Longlong Ma, Qi Zhang
One-pot hydrodeoxygenation of δ-furfurylidenelevulinic acid over Pd/C combined with phosphotungstic acid through successive hydrogenolysis and HDO of furans and lactones.
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Methylation-triggered fractionation of lignocellulosic biomass to afford cellulose-, hemicellulose-, and lignin-based functional polymers via click chemistry

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00451K, Paper
Kentaro Miki, Hiroshi Kamitakahara, Arata Yoshinaga, Yuki Tobimatsu, Toshiyuki Takano
This paper reports a new concept for the biorefinery of lignocellulosic biomass where the derivatisation and fractionation of lignocellulose are accomplished at the same time.
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Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04275J, Communication
Xiao Shu, Yuan-Yuan Jiang, Lei Kang, Luo Yang
A novel Ni-catayzed hydrocyanation of various alkenes to provide aliphatic nitriles is developed by generating hydrocyanic acid in situ from safe and readily available formamide.
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Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00853B, Paper
Diego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge Aburto
A series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...
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Aqueous miscible organic layered double hydroxides as catalyst precursors for biodiesel synthesis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00571A, Paper
Chunping Chen, Maxwell Greenwood, Jean-Charles Buffet, Dermot O'Hare
Surface area and basicity density dependence of base-catalysed transesterification of sunflower oil by potassium salt prepared AMO-layered double hydroxides.
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Synthesis of amorphous Geobacter-manganese oxide biohybrid as efficient water oxidation catalysts

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04353E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shafeer Kalathil, Krishna Katuri, Pascal Saikaly
The development of low cost and efficient oxygen evolution reaction (OER) catalyst has paramount importance to meet future sustainable energy demand. Nature’s photosynthetic machinery deploy manganese-based complex in photosystem II...
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Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment

Green Chem., 2020, 22,2443-2458
DOI: 10.1039/C9GC02088H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts, Stefaan M. A. De Wildeman
We studied the solvent-free hydrogenation of levulinic acid to γ-valerolactone with the Shvo catalyst involving comparative catalysis, DFT, and LCA.
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Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen

Green Chem., 2020, 22,2403-2418
DOI: 10.1039/C9GC03408K, Paper
Kristiina Iisa, Yeonjoon Kim, Kellene A. Orton, David J. Robichaud, Rui Katahira, Michael J. Watson, Evan C. Wegener, Mark R. Nimlos, Joshua A. Schaidle, Calvin Mukarakate, Seonah Kim
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
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Synthesis of renewable C–C cyclic compounds and high-density biofuels using 5-hydromethylfurfural as a reactant

Green Chem., 2020, 22,2468-2473
DOI: 10.1039/D0GC00195C, Paper
Taimei Cai, Qiang Deng, Hailong Peng, Jin Zhong, Rui Gao, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Renewable C–C six-membered ring compound and high-density biofuel are synthesized using 5-hydromethylfurfural as a reactant.
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Visible-light-induced photocatalyst-free C-3 functionalization of indoles with diethyl bromomalonate

Green Chem., 2020, 22,2543-2548
DOI: 10.1039/D0GC00292E, Paper
Guangmiao Gu, Mengmeng Huang, Jung Keun Kim, Jianye Zhang, Yabo Li, Yangjie Wu
A visible-light-induced and XB-promoted green approach to construct α-indolyl diethyl malonates was developed.
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Reusable, homogeneous water soluble photoredox catalyzed oxidative dehydrogenation of N-heterocycles in a biphasic system: application to the synthesis of biologically active natural products

Green Chem., 2020, 22,2575-2587
DOI: 10.1039/D0GC00569J, Paper
S. Srinath, R. Abinaya, Arun Prasanth, M. Mariappan, R. Sridhar, B. Baskar
Herein, a simple and efficient method for the oxidative dehydrogenation (ODH) of tetrahydro-β-carbolines, indolines and (iso)quinolines is described using a reusable, homogeneous cobalt-phthalocyanine photoredox catalyst in a biphasic medium.
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One-pot synthesis of 1,3-butanediol by 1,4-anhydroerythritol hydrogenolysis over a tungsten-modified platinum on silica catalyst

Green Chem., 2020, 22,2375-2380
DOI: 10.1039/D0GC00244E, Communication
Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige
Chemical production of 1,3-butanediol from biomass-derived compounds was first reported by 1,4-anhydroerythritol hydrogenolysis over a Pt–WOx/SiO2 catalyst.
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Using dialkyl amide via forming hydrophobic deep eutectic solvents to separate citric acid from fermentation broth

Green Chem., 2020, 22,2526-2533
DOI: 10.1039/C9GC04401A, Paper
Lijuan Liu, Qifeng Wei, Yong Zhou, Xiulian Ren
The separation of citric acids was realized by utilizing hydrophobic deep eutectic solvents (DESs), which were formed by using N,N-dibutylacetamide as a hydrogen acceptor and citric acid as the hydrogen bond.
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Double-metal cyanide as an acid and hydrogenation catalyst for the highly selective ring-rearrangement of biomass-derived furfuryl alcohol to cyclopentenone compounds

Green Chem., 2020, 22,2549-2557
DOI: 10.1039/C9GC04432A, Paper
Xiang Li, Qiang Deng, Lian Yu, Rui Gao, Zhikun Tong, Chenxi Lu, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Herein, novel green synthetic routes to 4-hydroxy-2-cyclopentenone (HCP) and 2-cyclopentenone (CPE) from biomass-derived furfuryl alcohol via double-metal cyanide catalysis are proposed.
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Evaluating lignin valorization via pyrolysis and vapor-phase hydrodeoxygenation for production of aromatics and alkenes

Green Chem., 2020, 22,2513-2525
DOI: 10.1039/C9GC04245H, Paper
Open Access
Alireza Saraeian, Alvina Aui, Yu Gao, Mark M. Wright, Marcus Foston, Brent H. Shanks
Lignin valorization to chemicals is an important component of creating economically viable biofuels production from lignocellulosic biomass.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Improving process efficiency of gold-catalyzed hydration of alkynes: merging catalysis with membrane separation

Green Chem., 2020, 22,2598-2604
DOI: 10.1039/D0GC00498G, Paper
Tahani A. C. A. Bayrakdar, Fady Nahra, Oihane Zugazua, Lies Eykens, Dominic Ormerod, Steven P. Nolan
In this report, we investigate the integration of a membrane separation protocol in line with the gold-catalyzed hydration of alkynes.
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Scalable synthesis of hydroxymethyl alkylfuranoates as stable 2,5-furandicarboxylic acid precursors

Green Chem., 2020, 22,2399-2402
DOI: 10.1039/D0GC00770F, Communication
Martin Jæger Pedersen, Arminas Jurys, Christian Marcus Pedersen
Hydroxymethyl furanoic acid and its derivatives have been synthesized in high yields and purity from gluconolactone.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalytic transfer hydrogenolysis of aromatic ketones using alcohols

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00732C, Paper
Hongji Li, Zhuyan Gao, Lijun Lei, Huifang Liu, Jianyu Han, Feng Hong, Nengchao Luo, Feng Wang
A mild method of photocatalytic deoxygenation of aromatic ketones to alkyl arenes was developed, which utilized alcohols as the green hydrogen donor. No hydrogen evolution during this transformation suggested a...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Continuous hydroformylation of 1-decene in an aqueous biphasic system enabled by methylated cyclodextrins

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00820F, Paper
Open Access
K. U. Künnemann, L. Schurm, D. Lange, T. Seidensticker, S. Tilloy, E. Monflier, D. Vogt, J. M. Dreimann
Long-term applications of cyclodextrins in the aqueous biphasic hydroformylation of higher olefins with high selectivities and simultaneous catalyst recycling.
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Boron-doped CuO nanobundles for electroreduction of carbon dioxide to ethylene

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00730G, Communication
Qiang Wan, Jianling Zhang, Bingxing Zhang, Dongxing Tan, Lei Yao, Lirong Zheng, Fanyu Zhang, Lifei Liu, Xiuyan Cheng, Buxing Han
Herein, we synthesize B-doped CuO nanobundles for electrocatalytic CO2 reduction. Ethylene is the only multi-carbon product and a maximum ethylene faradaic efficiency (FE) of 58.4% can be achieved at −1.1 V (versus the reversible hydrogen electrode).
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Degradation of poly(ethylene terephthalate) catalyzed by metal-free choline-based ionic liquids

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00327A, Paper
Yachan Liu, Xiaoqian Yao, Haoyu Yao, Qing Zhou, Jiayu Xin, Xingmei Lu, Suojiang Zhang
Glycolysis of PET is a prospective way for degradation of PET to its monomer bis(hydroxyethyl)terephthalate (BHET) which can be polymerized again to form new qualified PET materials, and hence provides possibilities for a permanent loop recycling.
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One-step catalytic amination of naphthalene to naphthylamine with exceptional yield

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00633E, Communication
Fang Hao, Xin Wang, Linfang Huang, Wei Xiong, Pingle Liu, Hean Luo
This is the first time to synthesize naphthylamine from one-step naphthalene amination by vanadium catalysts with high yield under mild condition. It could obtain ∼70% yield of naphthylamine, with major product of valuable 1,5-diaminonaphthalene.
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Achieving visible light-driven hydrogen evolution at positive bias with a hybrid copper–iron oxide|TiO2-cobaloxime photocathode

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00979B, Paper
C. Tapia, E. Bellet-Amalric, D. Aldakov, F. Boudoire, K. Sivula, L. Cagnon, V. Artero
H2 is an environmentally-friendly fuel that would allow for a circular economy but its sustainable production from solar energy and water using stable, efficient and scalable Earth-abundant materials, remains a challenge.
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Ethyl lactate participated three-component dehydrogenative reactions: biomass feedstock in diversity oriented quinoline synthesis

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00738B, Communication
Lu Yang, Jie-Ping Wan
Ethyl lactate participated three-component dehydrogenative reactions: biomass feedstock in diversity oriented quinoline synthesis
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Photocatalytic Hydrogen Atom Transfer: the Philosopher’s Stone for Late-Stage Functionalization?

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01035A, Tutorial Review
Luca Capaldo, Lorenzo Lafayette Quadri, Davide Ravelli
An overview about the potentialities of photocatalytic Hydrogen Atom Transfer (HAT) for the Late-Stage Functionalization (LSF) of complex molecules is offered. The examined approach allows the smooth homolytic cleavage of...
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Clean synthesis of linear and star amphiphilic poly(ε-caprolactone)-block-poly(ethyl ethylene phosphonate) block copolymers: assessing self-assembly and surface activity

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00819B, Paper
Payal Baheti, Timo Rheinberger, Olinda Gimello, Cécile Bouilhac, Frederik R. Wurm, Patrick Lacroix-Desmazes, Steven M. Howdle
Synthesis by ROP of star-like amphiphilic block copolymer surfactants composed of PCL hydrophobic segments and poly(phosphonate) as biodegradable segments.
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Metal-catalysed selective transfer hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00855A, Critical Review
Ronald Alvaro Alvaro Farrar Tobar, Andrea Dell'Acqua, Sergey Tin, Johannes G. de Vries
Allylic alcohols are highly important compounds which are used in a variety of processes. They can be obtained from α,β-unsaturated carbonyl compounds via stoichiometric or catalytic reductions. Catalytic transfer hydrogenation...
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Humidity-responsive Molecular Gate-opening mechanism for Gas Separation in Ultraselective Nanocellulose/IL Hybrid Membranes

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00544D, Paper
Saravanan. Janakiram, Luca Ansaloni, Soo Ah Jin, Xinyi Yu, Zhongde Dai, Richard J Spontak, Liyuan Deng
Nanofibrillated cellulose (NFC) represents an important class of bio-based nanomaterials that possess favorable properties including hydrophilicity, 1D structure, biodegradability, and surface tunability. Although widely known for its effective gas-barrier attributes...
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Facile one-pot synthesis of self-assembled nitrogen-doped carbon dots/cellulose nanofibril hydrogel with enhanced fluorescence and mechanical properties

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00845A, Paper
Xueqi Chen, Zihui Song, Shaopeng Li, Nguyen Tat Thang, Xing Gao, Xinchao Gong, Minghui Guo
A facile one-pot method is used to synthesize and self-assemble nanofibril cellulose hydrogels with carbon dots as intensity enhancement and fluorescent emission factors.
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Catalyst-Free Photodecarbonylation of 2-Amine Benzaldehyde

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01256D, Communication
Jingwei Zhou, Lamei Li, Songping Wang, Ming Yan, Wentao Wei
It is almost a consensus that decarbonylation of aldehyde group (-CHO) need to not only be mediated by transition metal catalysts, but also react under severe reaction conditions (high temperature...
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Don’t Look Away: Why Ahmaud Arbery’s Tragedy Must Be Addressed Head On

The unfortunate truth is that even in our ability to retreat into ignorance, we betray the disparity in our experiences and the systemic injustice in our culture.

For many in America, responding to the seemingly-endless shootings of African Americans has become a horrific form of muscle memory. After yet another tragedy like the shooting of Ahmaud Arbery occurs, we see similar patterns: an initial burst of reporting, followed quickly by social media commentary, followed by think-pieces across various platforms, followed by social media commentary on the think-pieces.

Within a week, however, the entire matter is tied up nicely and everyone is able to move on. Most of us forget as we return to being engrossed in our lives, only to be thrust back into this cycle when another new shooting is jarring enough to penetrate the blaring noise of our daily news-cycle.

The fact that Arbery was killed in February and many didn’t know until May speaks to our dependence upon images to incite response—a dependency that, as many have pointed out, dehumanizes victims and establishes a bar of proof we don’t demand of others.

Moreover, the fact that only images push us to take seriously these stories underlines the frenetic nature of our media landscape. So few stories not drenched in the political and culture wars theming our day are able to rise above the chaos to capture our attention. That many are feeling oversaturated and digitally burned out during our current crisis has only exacerbated this problem of ignorance.

The unfortunate truth is that even in our ability to retreat into ignorance, we betray the disparity in our experiences and the systemic injustice in our culture. While this story (despite being so relevant and discussed currently) will fade for most of us, for others this story is their experience. They carry it with them when they wonder if it is safe to go for runs in ...

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Want a Healthy Society? Support Moms

How politicians and leaders on both the Left and Right fail to adequately aid mothers.

Every election cycle, women’s issues are a flashpoint in the public square. This year is no exception: Candidates on both sides are debating abortion, equal pay, family leave, and maternal mortality.

These political clashes often hinge on deeply held views about who women are, how they’re wired, and what they need. One of the most salient aspects of female identity is our maternal nature—the inclination (broadly speaking) to foster enduring ties with our offspring. Gender essentialism is fraught with land mines and dangerous generalities, and not all women experience the maternal pull. Nonetheless, most of us would agree that women’s biology is in fact distinctive, and the innate potential to bear children and bond with them not only carries great weight for the family but also shapes our commonwealth.

The political Left and Right mishandle these maternal instincts in different ways. For hard-line progressives, female “nature” is a social construct to embrace or escape—it doesn’t serve a normative purpose. We see this view play out legislatively. Liberal Democrats rightly pride themselves on defending family-friendly policies. But they concurrently promote pro-abortion policies that treat a woman’s bond with her child as entirely voluntary and even arbitrary—severed here, supported there. “To Planned Parenthood, an undesired life is no life at all,” writes Russell Moore in National Review.

Those on the Right have a nearly inverse enigma. Both center-right and far-right Republicans tend to value a woman’s distinct maternal nature and the children who come with it. But that helping hand comes up short in other arenas, as mothers are too often left to ...

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Autobiography of a person who insisted on writing one




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Understanding pathophysiology / Judy A. Craft, Christopher J Gordon, Sue E. Huether, Kathryn L. McCance, Valentina L. Brashers, Neal S. Rote

Craft, Judy A., author




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Pathophysiology made incredibly easy! / clinical editors, Cherie R. Rebar, PhD, MBA, RN, COI, Nicole Heimgartner, DNP, RN, COI, Carolyn Gersch, PhD, RN, CNE




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Principles of pathophysiology / Shane Bullock and Majella Hales

Bullock, Shane, author




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Pet-to-man travelling staphylococci : a world in progress / edited by Vincenzo Savini




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Respiratory physiology / Michelle M. Cloutier

Cloutier, Michelle M., author




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Human anatomy & physiology / Elaine N. Marieb, Katja Hoehn

Marieb, Elaine Nicpon, 1936- author




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Radiographic image analysis / Kathy McQuillen Martensen

McQuillen-Martensen, Kathy, author




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Ganong's review of medical physiology / Kim E. Barrett, PhD, Susan M. Barman, PhD, Heddwen L. Brooks, PhD, Jason X.-J. Yuan, MD, PhD

Barrett, Kim E., author




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Measurement in physical education / Donald K. Mathews; illus. by Todd Wallis

Mathews, Donald K




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Professional guide to pathophysiology / Clinical Editor, Laura M. Willis




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Creative arts and play therapy for attachment problems / edited by Cathy A. Malchiodi, David A. Crenshaw

Malchiodi, Cathy A




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Guide to cancer immunotherapy / edited by Suzanne Walker, CRNP, MSN, AOCN, BC, Elizabeth Prechtel Dunphy, DNP, RN, CRNP, BC, AOCN




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Introduction to health psychology in Australia / [Val] Morrison, [Paul] Bennett, [Phyllis] Butow, [Barbara] Mullan, [Louise] Sharpe

Morrison, Val, 1961- author