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Informality Revisited: Latin American Perspectives on Housing, the State and the Market

By www.wiley.com
Published On :: 2020-04-20T04:00:00Z


 

Informality Revisited offers an overview of recent debates about Latin American government programmes for the formalisation of informal settlements and housing provision in a neo-liberal context. Contributions from Latin American researchers analyse the contradictions in government actions and evaluate the consequences for urban poverty.



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Transferring Axial Molecular Chirality Through a Sequence of On-Surface Reactions

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01653E, Edge Article
Open Access
Néstor Merino-Díez, Mohammed S. G. Mohammed, Jesus Castro, Luciano Colazzo, Alejandro Berdonces-Layunta, James Lawrence, Jose Ignacio Pascual, Dimas G. de Oteyza, Diego Peña
Fine management of chiral processes on solid surfaces has progressed over the years, yet still faces the need for the controlled and selective production of advanced chiral materials. Here, we...
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Structure-mechanics statistical learning unravels the linkage between local rigidity and global flexibility in nucleic acids

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00480D, Edge Article
Open Access
Yi-Tsao Chen, Haw Yang, Jhih-Wei Chu
The mechanical properties of nucleic acids underlie biological processes ranging from genome packaging to gene expression. We devise structural mechanics statistical learning method to reveal their molecular origin in terms of chemical interactions.
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Aerosol-assisted route to low-E transparent conductive gallium-doped zinc oxide coatings from pre-organized and halogen-free precursor

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00502A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Clara Sanchez-Perez, Sebastian C. Dixon, Jawwad A. Darr, Ivan P. Parkin, Claire J. Carmalt
A pre-organised and halogen-free ZnO precursor is used to deposit GZO coatings via aerosol-assisted CVD with properties that exceed industrial standards for low-E coatings and photovoltaics.
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Spontaneous mirror symmetry breaking in benzil-based soft crystalline, cubic liquid crystalline and isotropic liquid phases

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01396J, Edge Article
Open Access
Tino Reppe, Silvio Poppe, Xiaoqian Cai, Yu Cao, Feng Liu, Carsten Tschierske
Benzil (diphenylethane-1,2-dione), which is a long known example for an achiral molecule crystallizing in a chiral space group, can also show mirror symmetry breaking in the fluid state if it...
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Transformation from helical to layered supramolecular organization of asymmetric perylene diimides via multiple intermolecular hydrogen bonding

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01911A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mengmeng Li, Wojciech Zajaczkowski, Gangamallaiah Velpula, Daniel Jänsch, Robert Graf, Tomasz Marszalek, Sapun H. Parekh, Yulian Zagranyarski, Kunal Mali, Manfred Wagner, Steven De Feyter, Chen Li, Klaus Müllen, Wojciech Pisula
The solid-state supramolecular organization of asymmetric perylene diimide is transformed from helical to layered self-assembly after thermal annealing.
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Ultrafast Amidation of Esters using Lithium Amides under Aerobic Ambient Temperature Conditions in Sustainable Solvents

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01349H, Edge Article
Open Access
Michael Fairley, Leonie Bole, Florian Mulks, Laura Main, Alan Kennedy, Charles T. O'Hara, Joaquín García-Álvarez, Eva Hevia
Lithium amides constitute one of the most commonly used class of reagents in synthetic chemisty. However, despite many applications, their use is handicapped by their requirements of low temperatures, in...
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Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystals

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00676A, Edge Article
Open Access
Bryan Owens-Baird, Juliana P. S. Sousa, Yasmine Ziouani, Dmitri Y. Petrovykh, Nikolai A. Zarkevich, Duane D. Johnson, Yury V. Kolen'ko, Kirill Kovnir
The effect of the crystal structure of ordered transition-metal phosphide catalysts on the hydrogen-evolution reaction is investigated using single crystals of iron-phosphide (FeP) and monoclinic nickel-diphosphide (m-NiP2).
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A straightforward approach to antibodies recognising cancer specific glycopeptidic neoepitopes

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00317D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hajime Wakui, Yoshikazu Tanaka, Toyoyuki Ose, Isamu Matsumoto, Koji Kato, Yao Min, Taro Tachibana, Masaharu Sato, Kentaro Naruchi, Fayna Garcia Martin, Hiroshi Hinou, Shin-Ichiro Nishimura
We developed new class of designated antibodies targeting of “dynamic neoepitopes” elaborated by disease-specific O-glycosylation at the immunodominant mucin domains.
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Molecular recognition of pyrazine N,N'-dioxide using aryl extended calix[4]pyrroles

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01496F, Edge Article
Open Access
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Chenxing Guo, Hu Wang, Vincent M. Lynch, Xiaofan Ji, Zachariah A. Page, Jonathan L. Sessler
The molecular recognition of pyrazine N,N'-dioxide by aryl extended 'two-walled' calix[4]pyrrole-based receptors is seen to stabilise two different binding modes in the solid state.
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Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00463D, Edge Article
Open Access
Georgina L. Gregory, Gregory S. Sulley, Leticia Peña Carrodeguas, Thomas T. D. Chen, Alba Santmarti, Nicholas J. Terrill, Koon-Yang Lee, Charlotte K. Williams
A new series of block polyester thermoplastic elastomers are prepared by a one-pot procedure; they show properties competitive or better than conventional materials and can be fully degraded after use.
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Ring-Fused Cyclobutanes via Cycloisomerization of Alkylidenecyclopropane Acylsilanes

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02224A, Edge Article
Open Access
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Erick M Carreira, Sarah S Eichenberger, Moritz Hönig, Matthieu JR Richter, Renana Gershoni-Poranne
A novel Lewis acid-catalyzed cycloisomerization of alkylidenecyclopropane acylsilanes is disclosed. The readily available starting materials participate in tandem Prins addition/ring expansion/1,2-silyl shift to grant access to bicyclo[4.2.0]octanes and bicyclo[3.2.0]heptanes, which...
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Protease-Responsive Mass Barcoded Nanotranslaters for Simultaneously Quantifying the Intracellular Activity of Cascaded Caspases in Apoptosis Pathways

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01534B, Edge Article
Open Access
Hongmei Xu, Xiaodan Huang, Zhenzhen Zhang, xuemeng zhang, Qianhao Min, Jun-Jie Zhu
Quantitatively delineating the activation network of multiple proteases that participate in cellular processes is highly essential to understanding physiological and pathological states of cells. In this study, protease-responsive mass barcoded...
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Structure and redox tuning of gas adsorption properties in calixarene-supported Fe(II)-based porous cages

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01833C, Edge Article
Open Access
Meaghan Deegan, Tonia Ahmed, Glenn Yap, Eric D Bloch
We describe the synthesis of Fe(II)-based octahedral coordination cages supported by calixarene capping ligands. The most porous of these molecular cages has an argon accessible BET surface area of 898...
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Pore engineering of ultrathin covalent organic framework membranes for organic solvent nanofiltration and molecular sieving

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01679A, Edge Article
Open Access
Digambar B. Shinde, Li Cao, A. D. Dinga Wonanke, Xiang Li, Sushil Kumar, Xiaowei Liu, Mohamed N. Hedhili, Abdul-Hamid Emwas, Matthew Addicoat, Kuo-Wei Huang, Zhiping Lai
Pore surface engineering of ultrathin COF membranes by introducing different lengths of alkyl chains into the skeleton, which allows us to precisely control the pore size of COF membranes for OSN applications and molecular sieving.
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Asymmetric synthesis of primary amines catalyzed by thermotolerant fungal reductive aminases

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC02253E, Edge Article
Open Access
Juan Mangas-Sanchez, Mahima Sharma, Sebastian C. Cosgrove, Jeremy I. Ramsden, James R. Marshall, Thomas W. Thorpe, Ryan B. Palmer, Gideon Grogan, Nicholas J. Turner
Fungal reductive aminases as effective biocatalysts for the preparation of chiral primary amines.
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Rapidly Self-deoxygenating Controlled Radical Polymerization in water via in-situ Disproportionation of Cu(I)

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01512A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David Haddleton, Evelina Liarou, Yisong Han, Marc Walker, Ana Sanchez
The first rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first...
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Evolution of pure hydrocarbon hosts: simpler structure, higher performance and universal application in RGB phosphorescent organic light-emitting diodes

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01238F, Edge Article
Open Access
Qiang Wang, Fabien Lucas, Cassandre Quinton, Yang-Kun Qu, Joëlle Rault-Berthelot, Olivier Jeannin, Sheng-Yi Yang, Fan-Cheng Kong, Sarvendra Kumar, Liang-Sheng Liao, Cyril Poriel, Zuo-Quan Jiang
In this work, we propose pure hydrocarbon materials as universal hosts for high-efficiency red, green and blue phosphorescent organic light-emitting diodes.
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Redox-responsive supramolecular polymeric networks having double-threaded inclusion complexes

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Chem. Sci., 2020, 11,4322-4331
DOI: 10.1039/C9SC05589D, Edge Article
Open Access
Hikaru Aramoto, Motofumi Osaki, Subaru Konishi, Chiharu Ueda, Yuichiro Kobayashi, Yoshinori Takashima, Akira Harada, Hiroyasu Yamaguchi
A hydrogel actuator with a 1:2 host–guest complex controlled by redox stimuli has been developed to realize faster and larger deformation.
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Exploiting single-electron transfer in Lewis pairs for catalytic bond-forming reactions

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Chem. Sci., 2020, 11,4305-4311
DOI: 10.1039/D0SC01159B, Edge Article
Open Access
Yoshitaka Aramaki, Naoki Imaizumi, Mao Hotta, Jun Kumagai, Takashi Ooi
Radical–ion pair generation from common Lewis pairs and its application to catalytic carbon–carbon bond formation.
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General and selective synthesis of primary amines using Ni-based homogeneous catalysts

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Chem. Sci., 2020, 11,4332-4339
DOI: 10.1039/D0SC01084G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
A Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.
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An RGB-emitting molecular cocktail for the detection of bacterial fingerprints

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Chem. Sci., 2020, 11,4403-4409
DOI: 10.1039/D0SC01704C, Edge Article
Open Access
Sheng Hong, Di-Wei Zheng, Qiu-Ling Zhang, Wei-Wei Deng, Wen-Fang Song, Si-Xue Cheng, Zhi-Jun Sun, Xian-Zheng Zhang
A technique named the Microcolor system was developed to detect microbes and diagnose diseases based on changes in microbiota signatures.
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Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal–organic frameworks

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Chem. Sci., 2020, 11,4297-4304
DOI: 10.1039/D0SC00735H, Minireview
Open Access
Eike Brunner, Marcus Rauche
Metal–organic frameworks (MOFs) gain increasing interest due to their outstanding properties like extremely high porosity, structural variability, and various possibilities for functionalization.
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A pH ratiometrically responsive surface enhanced resonance Raman scattering probe for tumor acidic margin delineation and image-guided surgery

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Chem. Sci., 2020, 11,4397-4402
DOI: 10.1039/D0SC00844C, Edge Article
Open Access
Wenjia Duan, Qi Yue, Ying Liu, Yunfei Zhang, Qinghua Guo, Cong Wang, Shujie Yin, Dandan Fan, Wenjing Xu, Jiexian Zhuang, Jiachao Gong, Xinwei Li, Ruimin Huang, Liang Chen, Silvio Aime, Zhongliang Wang, Jianfeng Feng, Ying Mao, Xiao-Yong Zhang, Cong Li
A novel pH ratiometrically responsive surface-enhanced resonance Raman scattering (SERRS) probe was developed for tumor acidic margin delineation and image-guided surgery.
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What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts

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Chem. Sci., 2020, 11,4381-4390
DOI: 10.1039/D0SC01026J, Edge Article
Open Access
Dennis Jansen, Johannes Gramüller, Felix Niemeyer, Torsten Schaller, Matthias C. Letzel, Stefan Grimme, Hui Zhu, Ruth M. Gschwind, Jochen Niemeyer
Supramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.
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Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation

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Chem. Sci., 2020, 11,4439-4443
DOI: 10.1039/D0SC01289K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Arunachalam Sagadevan, Anastasios Charitou, Fen Wang, Maria Ivanova, Martin Vuagnat, Michael F. Greaney
A ruthenium-catalyzed ortho C–H arylation process is described using visible light.
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Hydrogen peroxide reduction on single platinum nanoparticles

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Chem. Sci., 2020, 11,4416-4421
DOI: 10.1039/D0SC00379D, Edge Article
Open Access
Xin Chang, Christopher Batchelor-McAuley, Richard G. Compton
At the single platinum nanoparticle scale the hydrogen peroxide reduction reaction is a surface limited process.
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Self-assembly of reversed bilayer vesicles through pnictogen bonding: water-stable supramolecular nanocontainers for organic solvents

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Chem. Sci., 2020, 11,4374-4380
DOI: 10.1039/D0SC00206B, Edge Article
Open Access
Shiva Moaven, Brandon T. Watson, Shelby B. Thompson, Veronica J. Lyons, Daniel K. Unruh, Dominick J. Casadonte, Dimitri Pappas, Anthony F. Cozzolino
A new air and moisture stable antimony thiolate compound has been prepared that spontaneously forms stable hollow vesicles.
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Biocatalytic reversible control of the stiffness of DNA-modified responsive hydrogels: applications in shape-memory, self-healing and autonomous controlled release of insulin

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Chem. Sci., 2020, 11,4516-4524
DOI: 10.1039/D0SC01319F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chen Wang, Amit Fischer, Avner Ehrlich, Yaakov Nahmias, Itamar Willner
Biocatalytic control over the stiffness of pH-responsive hydrogels is applied to develop shape-memory, self-healing and controlled release matrices.
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Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing

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Chem. Sci., 2020, 11,4499-4507
DOI: 10.1039/D0SC00135J, Edge Article
Open Access
Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming Hu
Metal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.
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Machine-enabled inverse design of inorganic solid materials: promises and challenges

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00594K, Minireview
Open Access
Juhwan Noh, Geun Ho Gu, Sungwon Kim, Yousung Jung
The grand challenge of materials science, discovery of novel materials with target properties, can be greatly accelerated by machine-learned inverse design strategies.
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Correction: Metal complexes as a promising source for new antibiotics

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Chem. Sci., 2020, 11,4531-4531
DOI: 10.1039/D0SC90075C, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Angelo Frei, Johannes Zuegg, Alysha G. Elliott, Murray Baker, Stefan Braese, Christopher Brown, Feng Chen, Christopher G. Dowson, Gilles Dujardin, Nicole Jung, A. Paden King, Ahmed M. Mansour, Massimiliano Massi, John Moat, Heba A. Mohamed, Anna K. Renfrew, Peter J. Rutledge, Peter J. Sadler, Matthew H. Todd, Charlotte E. Willans, Justin J. Wilson, Matthew A. Cooper, Mark A. T. Blaskovich
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Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates

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Chem. Sci., 2020, 11,4475-4481
DOI: 10.1039/D0SC01194K, Edge Article
Open Access
Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-Ewing
Short-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.
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Chemical control of competing electron transfer pathways in iron tetracyano-polypyridyl photosensitizers

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Chem. Sci., 2020, 11,4360-4373
DOI: 10.1039/C9SC06272F, Edge Article
Open Access
Kristjan Kunnus, Lin Li, Charles J. Titus, Sang Jun Lee, Marco E. Reinhard, Sergey Koroidov, Kasper S. Kjær, Kiryong Hong, Kathryn Ledbetter, William B. Doriese, Galen C. O'Neil, Daniel S. Swetz, Joel N. Ullom, Dale Li, Kent Irwin, Dennis Nordlund, Amy A. Cordones, Kelly J. Gaffney
Photoinduced intramolecular electron transfer in Fe tetracyano-polypyridyl complexes was investigated with static and time-resolved UV-visible absorption and resonant inelastic X-ray scattering which revealed a competition of two relaxation pathways.
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Designing naphthopyran mechanophores with tunable mechanochromic behavior

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Chem. Sci., 2020, 11,4525-4530
DOI: 10.1039/D0SC01359E, Edge Article
Open Access
Brooke A. Versaw, Molly E. McFadden, Corey C. Husic, Maxwell J. Robb
Structure–activity relationships for strategic substitution of the naphthopyran mechanophore scaffold enable polymeric materials with tunable mechanochromic behavior.
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Small-molecule fluorescent probes for imaging gaseous signaling molecules: current progress and future implications

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01482F, Perspective
Open Access
Mingwang Yang, Jiangli Fan, Jianjun Du, Xiaojun Peng
This perspective article aims to introduce the design principles and recognition strategies of small-molecule fluorescent probes which are applied for the detection of gas signaling molecules including NO, CO and H2S in biological systems.
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Determination of protein-ligand binding modes using fast multi-dimensional NMR with hyperpolarization

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00266F, Edge Article
Open Access
Yunyi Wang, Jihyun Kim, Christian Hilty
Elucidation of small molecule-protein interactions provides essential information for understanding biological processes such as cellular signaling, as well as for rational drug development. Here, multi-dimensional NMR with sensitivity enhancement by...
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Enlightening advances in polymer bioconjugate chemistry: light-based techniques for grafting to and from biomacromolecules

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01544J, Perspective
Open Access
Rebecca A. Olson, Angie B. Korpusik, Brent S. Sumerlin
Light-driven synthetic techniques have revolutionized polymer–biomacromolecule conjugation. This Perspective discusses the benefits of photochemistry for polymer–protein ligation and considerations when designing a new light-driven conjugation approach.
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Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02020F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey Stephenson
Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...
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Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01025A, Edge Article
Open Access
Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor Alabugin
How far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...
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Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01290D, Edge Article
Open Access
Leland Bruce Gee, Vladimir Pelmenschikov, Hongxin Wang, Nakul Mishra, Yu-Chiao Liu, Yoshitaka Yoda, Kenji TAMASAKU, Ming-Hsi Chiang, Stephen P Cramer
A diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(μ,κ2-bdtH)(μ-PPh2)(μ-H)Fe2(CO)5]+ has been investigated through 57Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density...
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Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00021C, Edge Article
Open Access
Koichiro Masuda, Shū Kobayashi
A direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.
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Cancer cell discrimination and dynamic viability monitoring through wash-free bioimaging using AIEgens

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Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01213K, Edge Article
Open Access
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Ruoyao Zhang, Guangle Niu, Qing Lu, Xiaolin Huang, Joe H. C. Chau, Ryan T. K. Kwok, Xiaoqiang Yu, Min-Hui Li, Jacky W. Y. Lam, Ben Zhong Tang
We present a series of AIEgens for cancer cell discrimination and dynamic viability monitoring.
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The Role of Porphyrin Peripheral Substituents in Determining the Reactivities of Ferrous Nitrosyl Species

By feeds.rsc.org
Published On ::

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01625J, Edge Article
Open Access
Sk Amanullah, Abhishek Dey
Ferrous nitrosyl {FeNO}7 species are intermediates common to the catalytic cycles of Cd1NiR and CcNiR, two heme-based nitrite reductases (NiR), and its reactivity vary dramatically in these enzymes. The former...
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Observations of tetrel bonding between sp3–carbon and THF

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Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01559H, Edge Article
Open Access
Victoria V. L. Heywood, T. P. J. Alford, Julius J.J. Roeleveld, Siebe S. J. Lekanne-Deprez, Abraham A. Verhoofstad, Jarl Ivar van der Vlugt, Melanie Schnell, Sérgio R Domingos, Anthony P. Davis, Tiddo Jonathan Mooibroek
We report the direct observation of tetrel bonding interactions between sp3-carbons of the supramolecular synthon 3,3-dimethyl-tetracyanocyclopropane (1) and tetrahydrofuran in the gas and crystalline phase. The intermolecular contact is established...
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N2Phos – an easily made, highly effective ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura cross couplings in water

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Published On ::

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00968G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nnamdi Akporji, Ruchita R. Thakore, Margery Cortes-Clerget, Joel Andersen, Evan Landstrom, Donald H. Aue, Fabrice Gallou, Bruce H. Lipshutz
A new, biaryl phosphine-containing ligand, N2Phos, forms a 1 : 1 complex with Pd resulting in an active catalyst at the ppm level for Suzuki–Miyaura couplings in water, enabled by an aqueous micellar medium. Notably, aryl chlorides are shown to be amenable substrates.
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Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework

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Published On ::

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01796E, Edge Article
Open Access
David Zhi Hong Zee, T. David Harris
Catalytic heme active sites of enzymes are sequestered by the protein superstructure and are regulated by precisely defined outer coordination spheres. Here, we emulate both of these protective functions in...
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BS Insurance Round Table 2020: No major impact of tax change, say experts

By www.business-standard.com
Published On :: Thu, 27 Feb 2020 22:30:00 +0530

Six top life insurance executives brainstorm on the impact of tax exemption removal and the upcoming IPO of Life Insurance Corporation. Edited Excerpts:


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BS Insurance Round Table: Sandbox opens up avenues for bundling services

By www.business-standard.com
Published On :: Thu, 27 Feb 2020 22:38:00 +0530

A power-packed panel said that AI is the game changer in the non-life insurance business and underlined the need to generate underwriting profits and rely less on investment gains


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Issue closing stats for any repo

By feedproxy.google.com
Published On :: Fri, 13 Dec 2019 23:05:38 +0000

tl;dr: If you just want to quickly get stats for a repo, you can find the app here. The rest of this post explains how it’s built with Mavo HTML, CSS, and 0 lines of JS. Or, if you’d prefer, you can just View Source — it’s all there! One of the cool things about […]


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