it Publicitarul Bogdan Naumovici lansează lungmetrajul „Țăndări” în ianuarie 2025 By www.forbes.ro Published On :: Wed, 13 Nov 2024 10:40:58 +0000 Bogdan Naumovici, om de publicitate, își lansează lungmetrajul de debut pe 28 ianuarie 2025. Comedia „Țăndări”, distribuită de Forum Film, are în distribuție actori precum Alin Florea, Constantin Florescu, Cristian Bota, Nicodim Ungureanu, Cătălin Neamțu, Carmen Tănase, Dan Badea, Alex Conovaru, Sergiu Costache, Robert Tudor, Andreea Samson, și Gabriel Spahiu. De la spoturi publicitare pentru ... The post Publicitarul Bogdan Naumovici lansează lungmetrajul „Țăndări” în ianuarie 2025 appeared first on Forbes Romania. Full Article Afaceri Media şi entertainment Bogdan Naumovici lungmetraj publicitate Țăndări
it Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:08:08 +0000 Commerzbank analizează opțiunea de a achiziționa o bancă germană de dimensiuni medii ca parte a strategiei de a evita o posibilă preluare de către UniCredit, potrivit Reuters. Planurile sunt într-o etapă incipientă, iar posibilele ținte ar putea include Hamburg Commercial Bank sau Oldenburgische Landesbank. Potrivit surselor Reuters, Commerzbank încearcă să conceapă un plan de apărare, ... The post Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii
it Pehart Grup promovează evenimentele cu tradiție de la noi din țară printr-o campanie națională By www.forbes.ro Published On :: Wed, 13 Nov 2024 15:06:09 +0000 Pehart Grup, una dintre cele mai mari companii producătoare de hârtie tissue din Sud-Estul Europei, celebrează tradițiile românești prin cea de-a doua ediție a campaniei naționale Pufina Tradiții Românești. După ce anul trecut, de 1 Decembrie, producătorul a dat startul campaniei naționale Pufina Tradiții Românești, anul acesta, la debutul lui noiembrie a lansat cea de-a ... The post Pehart Grup promovează evenimentele cu tradiție de la noi din țară printr-o campanie națională appeared first on Forbes Romania. Full Article Actualitate Pehart Grup producator de hartie Pufina traditii romanesti
it Florin Talpeș: grupul Bitdefender a avut venituri nete de peste 391 mil. dolari și profit operațional de 85 mil. dolari în 2023, cele mai mari din istorie By www.forbes.ro Published On :: Wed, 13 Nov 2024 16:55:16 +0000 Grupul Bitdefender, cea mai importantă companie din domeniul tehnologiei cu sediul central în România, a înregistrat venituri nete de 391,9 milioane de dolari, în creștere cu 16% comparativ cu anul anterior, și un profit operațional ajustat (EBITDA) de 85 de milioane de dolari, cu 21,7% mai mare decât în 2022. Florin Talpeș, CEO și cofondator ... The post Florin Talpeș: grupul Bitdefender a avut venituri nete de peste 391 mil. dolari și profit operațional de 85 mil. dolari în 2023, cele mai mari din istorie appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii Tech
it Bogdan Speteanu, Moov Leasing: “Utilizatorii pot închiria o mașină pe o perioadă medie, de la unu la cinci ani, și au posibilitatea de a o schimba în funcție de nevoile de moment” By www.forbes.ro Published On :: Wed, 13 Nov 2024 21:44:31 +0000 Moov Leasing, un start-up românesc lansat de Bogdan Speteanu și Mircea Dihel, propune o schimbare radicală în leasingul auto, transformând experiența de utilizare a unei mașini într-una simplă și accesibilă, la fel ca utilizarea unui telefon mobil. După 20 de ani de experiență la BCR, timp în care a ocupat mai multe funcții de conducere, printre care și ... The post Bogdan Speteanu, Moov Leasing: “Utilizatorii pot închiria o mașină pe o perioadă medie, de la unu la cinci ani, și au posibilitatea de a o schimba în funcție de nevoile de moment” appeared first on Forbes Romania. Full Article Emisiuni Online | Proiecte Forbes Bogdan Speteanu Moov Leasing
it Who is Rajan Shaw, named in Ratan Tata's Rs 10000 crore will, now given responsibility to look after... By www.dnaindia.com Published On :: Thu, 14 Nov 2024 02:15:00 GMT Known for his humility, Ratan Tata leaves behind a legacy of compassion and generosity Full Article Business
it 'Priyanka Chopra was out...': Arjun Kapoor talks about his terrific chemistry with Ranveer Singh in Gunday By www.dnaindia.com Published On :: Wed, 13 Nov 2024 16:22:00 GMT Talking about Priyanka Chopra, Arjun admitted that she was already a big star when they made the film. Full Article Entertainment
it Delhi becomes world's most polluted city, overtakes Pakistan's Lahore, AQI recorded at... By www.dnaindia.com Published On :: Wed, 13 Nov 2024 16:46:22 GMT At 9 am on Wednesday, the air quality was 'very poor' with a reading of 366 which later rose to 418. Full Article India
it Synthesis of multisubstituted carbazol-4-amines from tetrahydrocarbazol-4-one oximes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00386A, Research ArticleJiahua Wang, Dandan Gao, Aanuoluwapo O. Oyejobi, Na Ji, Xiang-Ying Tang, Long WangA sequential synthetic method toward 1,3-disubstituted carbazol-4-amines is reported and an interesting C–S metathesis process is disclosed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00228H, Research ArticleEkaterina V. Malakhova, Vladislav S. Kostromitin, Vitalij V. Levin, Alexander D. DilmanCommodity chemicals are used as alkylating and reducing agents for radical addition to alkenes. The method is based on activation of the strong C–Cl bond by the radical anion of carbon dioxide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it A Pd(II)-catalyzed denitrative alkyne annulation reaction for the synthesis of cyclopenta[b]chromanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00344F, Research ArticlePratiksha Bhorali, Deep J. Kalita, Babulal Das, Sanjib GogoiThe first denitrative Pd(II)-catalyzed alkyne annulation reaction is reported for the synthesis of cyclopenta[b]chromanes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it DBU-catalyzed substitution-controlled synthesis of oxa[3.3.1] bridged ring and naphthylamine derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00012A, Research ArticleShiyu Xu, Zhihui Sun, Pengyutian Liu, Yuanlin Wei, Fan Sun, Man Zhao, Ying Wang, Ming Zhang, Guofeng Li, Hong LiangA switchable cascade cyclization reaction of ortho-alkynyl arylketones with amines has been developed, where the different reaction pathways are controlled by the substituent on the α-carbon of in-situ-generated ortho-alkynyl arylaldimines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Modular synthesis of C2-symmetric nitrogen-containing polyaromatics via visible light-enabled reductive aza-6π electrocyclization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00140K, Research ArticleQun-Liang Zhang, Qing-Tian Fan, Yirong Zhou, Jingli Zhang, Fang-Lin ZhangHere, an unprecedented one-step modular construction of C2-symmetric N-PACs through reduction/aza-6π electrocyclization was reported and the resultant C2-symmetric N-PAC could be converted into a powerful organic photocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates: access to bridged eight-membered oxygen heterocycles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00329B, Research ArticleHuawei Lin, Biming Mao, Bing Han, Jiayi Luo, Yanqing Ge, Xuerui Zhang, Chang Wang, Hongchao Guo, Chunhao YuanA novel palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates has been developed for the synthesis of bridged eight-membered oxygen heterocycles in good yields and with excellent stereoselectivities.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition to access C–N axially chiral indoles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00042K, Research ArticleXuan Zhang, Qi Teng, Yanru Ren, Baitong Wei, Chen-Ho Tung, Zhenghu XuA Rh-catalyzed neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition of 1,6-diynes and ynamides to generate C–N axially chiral indole derivatives has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Chiral guanidine catalyzed cyclization reactions of 1,3-enynes for lactone synthesis: switchable H-bond catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00374H, Research ArticleYongyan Zhang, Lichao Ning, Tianxin Zhu, Zheng Xie, Shunxi Dong, Xiaoming Feng, Xiaohua LiuCyclization and 1,4-conjugate addition/cyclization between 2-activated 1,3-enynes and azlactones were achieved with chiral guanidine-amides for enol-type activation to yield a range of δ-lactone derivatives.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Asymmetric [3 + 2] cycloaddition of donor–acceptor cyclopropanes with azadienes enabled by Brønsted base catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00002A, Research ArticleShu Li, Zhi-Hong Dong, Si-Yu Dan, Mei-Jun Zheng, Teng Long, Jie Zhan, Qing Zhou, Wen-Dao Chu, Quan-Zhong LiuA chiral bifunctional Brønsted base-catalyzed enantioselective [3 + 2] cycloaddition of D–A cyclopropanes and azadienes is reported. The protocol features broad substrate scope, mild reaction conditions and high functional group tolerance.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Organocatalytic formal [4 + 2] cycloaddition of o-quinone-methyl derivatives and 2-isocyanatomalonate diesters for the construction of chroman derivatives with adjacent quaternary chiral centers By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00141A, Research ArticleTong Xiong, Yi-Zhao Xu, Yao Wang, You-Cai Xiao, Fen-Er ChenAn asymmetric organocatalytic formal [4 + 2] cycloaddition/annulation cascade of ortho-quinone methides with 2-isocyanatomalonate diesters has been reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Stereodivergent synthesis of chiral spiropyrazolones through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes: unusual solvent effects on the enantioselectivity By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00358F, Research ArticleShan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui ShaoChiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Vaska's complex–PMHS combination enabled mild and chemoselective reduction of sulfoxides to sulfides with low catalyst loading By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00312H, Research ArticleFang-Fang Xu, Zhong-Lei Ruan, Pei-Qiang HuangWe report a highly efficient, versatile, and chemoselective method for the catalytic reduction of sulfoxides to sulfides under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium/cobalt co-catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00305E, Research ArticleChen He, Zhiyong Song, Wei Yao, Rui Lin, Yuanhong MaHerein, we report a decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium and cobalt co-catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z-enol esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00265B, Research ArticleShuncheng Wang, Hua Zhang, Jin Yang, Dongfang Zhang, Xin-Ping HuiAn efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produced tetrasubstituted Z-enol esters containing arylsulfur groups in good yields under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Iodine-catalyzed intermolecular 1,2-thio (seleno)amination of alkenes with 1,2,3-triazoles and disulfides (diselenides) in air By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00246F, Research ArticleJian Ji, Xuwen Chen, Zongjing Hu, Cong Guan, Jinhua Liu, Yaqi Deng, Shunying LiuIodine-catalyzed 1,2-thio (seleno)amination of alkenes via direct N- and C-centered radical cross-coupling was established to elicit highly regioselective β-triazolized thioalkyl compounds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Electrochemical switching in mechanically interlocked molecules (MIMs) By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00061G, Review ArticleAyush Bhadani, Murugavel KathiresanMechanically interlocked molecules (MIMs) which include rotaxanes and catenanes are formed by the mechanical linking of two or more components and has the ability to switch between different states in the presence of an external stimuli.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Spiro-centre substitution effects in the intramolecular spin–spin interactions of spirobiacridine diradicals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00419A, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shinichi Ogawa, Takuya Kanetomo, Masaya EnomotoSpirodiradicals with the Si and Ge spiro atoms exhibit a S = 1 state. The magnetic interaction in the Si derivative was found to be lower than that in the Ge derivative, implying a negative effect on σ*(Si–Cα)–π* hyperconjugation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Three-component Friedel–Crafts-type difunctionalization of ynamides with (hetero)arenes and iodine(III) electrophile By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00489B, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jun Kikuchi, Toya Nagata, Shingo Ito, Naohiko YoshikaiA three-component Friedel–Crafts type difunctionalization of ynamides with an iodine(III) electrophile and electron-rich (hetero)arenes has been developed, enabling regio- and stereoselective synthesis of densely functionalized enamides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Metal-Free Cascade O-H Double Insertion Between I(III)/S(VI)-Ylides, Carboxylic Acids, and Alcohols: Modular Access to Unsymmetrical α,α-O,O-Substituted Ketones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00453A, Research ArticleShang-Shi Zhang, Jiaohang Wei, Wen-Xuan Zou, Qiong Hu, Mei-Zhu Bao, Dan-Ting Shen, Lin Xiao, Jia-Lin Song, Xiang LiuThe synthesis of unsymmetrical α,α-O,O-substituted ketones via O-H double insertion is appealing but remains constrained due to the lack of compatible coupling partners or uncontrollable selectivity. Herein, we present a...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Sulfamide instead of urea in Biginelli reaction: from black box to reality By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2155-2160DOI: 10.1039/D3QO01926H, Research ArticleAlexander Yu. Lyapunov, Andriy V. Tarnovskiy, Sergey Yu. Boron, Eduard B. Rusanov, Galyna P. Grabchuk, Dmytro M. Volochnyuk, Serhiy V. RyabukhinThe scope and limitations of the classical Biginelli reaction have been expanded to principally novel substrates: sulfamide and its monosubstituted analogues.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Iron(III)/quinoxaline-derived N,N-ligand catalyzed oxygen transfer reaction of N-vinyl nitrones through selective 4π-electrocyclization and N–O bond cleavage By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2277-2282DOI: 10.1039/D3QO01999C, Research ArticleYan-Jiao Lu, Feng-Lan Lu, Jin-Qi Zhang, Chun-Hua Chen, Cui Liang, Xiao-Pan Ma, Dong-Liang MoWe describe an iron(III)/quinoxaline-derived N,N-ligand promoted O-transfer reaction of N-vinyl nitrones through selective O-4π-electrocyclization and N–O bond cleavage to prepare a variety of 2,5-dihydrooxazoles in good yields.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Synthesis of benzothiophenes via sulfonium-[3,3]-rearrangement of aryl sulfoxides with allenenitriles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2208-2214DOI: 10.1039/D4QO00121D, Research ArticleLei Zhang, Kun Wan, Huanhuan Wang, Mengyao Wang, Ao Cui, Xin Huang, Bo PengA facile synthesis of benzothiophenes from readily available aryl sulfoxides and allenenitriles has been established through sulfonium-rearrangement triggered cyclization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Electrode-switchable: exploring this new strategy to achieve regiodivergent azidoiodination of alkenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2189-2194DOI: 10.1039/D3QO01935G, Research ArticleXin-Lei Sun, Chen-Xi Xia, Yue Ren, Yu-Jin Li, Zhi-Qian Cao, Ling-Guo MengAn “electrode-switchable” organic electrochemistry method for the azidoiodination of alkenes, where the choice of anode dictates the regiodivergent alkene azidoiodination, reveals a novel pathway for controlled regioisomers.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Selective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2313-2318DOI: 10.1039/D4QO00116H, Research ArticleZhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong XueThe selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Origin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations via photoredox catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2269-2276DOI: 10.1039/D4QO00073K, Research ArticleYujie Ji, Lingfei Hu, Han Gao, Yan-Bo Wu, Xiangying Lv, Gang LuTwo major factors, i.e., C–H σ orbital energy and C–H BDE, account for the HAT site-selectivity of carbohydrates with the quinuclidine radical cation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Nickel/photoredox-catalyzed carbonylative transformations of α-phosphorus-, α-sulfur-, and α-boron-substituted alkyl halides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2297-2305DOI: 10.1039/D4QO00167B, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Le-Cheng Wang, Xiao-Feng WuA novel dual nickel/photoredox catalyzed direct amino- and alkoxycarbonylation of α-heteroatom substituted organohalides has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2326-2331DOI: 10.1039/D4QO00064A, Research ArticleTing-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping DengAn efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Advancement in the C–H bond alkylation of (hetero)arenes catalyzed by the most abundant transition metal–iron By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2397-2417DOI: 10.1039/D4QO00063C, Review ArticleChandini Pradhan, Benudhar PunjiAdvancement in the direct C–H bond alkylation of arenes and heteroarenes using the catalysts based on the most abundant transition metal, iron, is summarized.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Correction: Cu-catalyzed arylation of S-tosyl peptides with arylboronic acids By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2418-2418DOI: 10.1039/D4QO90029D, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Junjie Ying, Jingrong Huang, Chenguang Liu, Fa-Jie Chen, Chunfa Xu, Fen-Er ChenThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00351A, Research ArticleFei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng ZhuLovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Cr-mediated Photocatalytic Decarboxylative Coupling of alpha-Oxo Acids with Benzylic Pyridinium Salts By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00475B, Research ArticleJia Cao, Yan Liu, Zhixiang Wang, Le LiuHerein, we report the chromium/photoredox dual catalytic synthesis of ketones using α-oxo acids with benzylic pyridinium salts. This reaction proceeded by photocatalytic generation of acyl radical from α-oxo acids and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Visible-light Induced [1, 3]-Brook Rearrangements of α-Ketoacylsilanes and Its Subsequent Trapping in a Tandem Annulation with 1, 3, 5-Triazinanes and Azomethine Imines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00463A, Research ArticleZhong Zhang, Sirui Wu, Yuqiao Zhou, Bao-Lin Li, Siyue Xiao, Xiaohu Zhao, Zhipeng YuAn unusual visible light-induced [1, 3]-Brook rearrangement of α-ketoacylsilanes for cascade cyclization with 1,3,5-triazinanes and C,N-cyclic azomethine imines has been developed under catalyst-free and mild reaction conditions. The strategy offers...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Concise synthesis of succinimide-fused densely 1,3-cyclohexadienes via Co-catalyzed [2+2+2] cycloaddition of 1,6-diynes and maleimides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00435C, Research ArticleJinhui Cai, Kaili Cen, Ziyi Zhai, Yuan Liu, Jiahao Wei, Mixia Ouyang, Guojun He, Shuyu Huang, Feng ZhaoHerein, we report a new route towards succinimide-fused densely 1,3-cyclohexadienes through the reaction of 1,6-diynes with electron-deficient alkenes under cobalt catalysis. This method shown high efficiency, wide substrate scope, good...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Cobalt-catalysed Csp3–Csp3 cross-coupling of benzyl Katritzky pyridinium salts with Callyl–O electrophiles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00402G, Research ArticleMengyu Gao, Corinne GosminiDifferent allylbenzyl derivatives are synthesized by Co-catalyzed reductive cross-coupling from functionalized benzyl Katritzky pyridinium salts and various allylic acetates, ethers or carbonates in moderate to good yields under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it NBN/BNB-doped phenalenyl homo- and heterodyads: structural uniformity but optoelectronic diversity By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00468J, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alexander S. Scholz, Thomas Froitzheim, Michael Bolte, Hans-Wolfram Lerner, Jan-M. Mewes, Matthias WagnerPhenylene-bridged homo- and heterodyads of NBN- and BNB-phenalenyls were synthesized. The heterodyads show ambipolar redox character and aggregation-induced emission in the solid state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Metal-free photoinduced denitrogenative alkylation of vinyl azides with alkyl radicals toward ketones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00280F, Research ArticleHui Yin, Siqi Jian, Xiujuan Feng, Ming Bao, Xuan ZhangA metal-free method for the synthesis of ketones via a visible-light induced denitrogenative alkylation of vinyl azides with alkyl radicals is presented.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Copper-catalyzed oxidative sulfenylation and alkylation of indolin-2-ones for direct construction of sulfur-substituted quaternary carbons By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00491D, Research ArticleYun-Hao Zhang, Yi-Nuo Wang, Zi-Yu Liu, Si-Han Zheng, Guang-Lin Li, Dexin Feng, Da-Zhen XuA rapid and green one-pot access to S-substituted quaternary carbon centers from commercially available feedstock chemicals has been established, providing complex molecules with high chemoselectivity by the use of air as the terminal oxidant.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Base- and metal-free visible-light driven site-selective α-C(sp3)–H functionalization reaction of glycine derivatives with hydroxamic acid derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00425F, Research ArticleShiyun He, Hongying Fan, Xue Zhang, Meiling Ye, Jian Chen, Jinyu Hou, Tianle Huang, Li Guo, Guanghui Lv, Yong WuA visible-light-mediated radical–radical cross-coupling reaction between hydroxamic acid and N-phenyl glycine derivatives under base and metal free conditions is reported. A series of unnatural amino acids and peptides were obtained in good to excellent yields with good chemo-selectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it A retro-Mannich mediated transformation of Morita–Baylis–Hillman ketones to saturated imidazo[1,2-a]pyridines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00352G, Research ArticleSachin Sharma, Ajit Kumar Jha, Srinivasan EaswarTwo fruits felled with one stone! – a proof of mechanism and a synthetic method that delivers a privileged heterocyclic motif.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Development of a photoenzymatic one-pot hybrid system for the direct synthesis of 3,3-disubstituted indole-2-ketones from N-methyl indoles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00371C, Research ArticleYao Yao, Yuan Yu, Ming-Liang Shi, Xin-Yue Fan, Ru-De Lin, Kun Li, Wen-Dian Li, Fei-Yan Tao, Na WangThe effective combination of photocatalysis and enzyme catalysis has been widely utilized for the synthesis of high-value-added products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00317A, Research ArticleGuohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin YinAmine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Photochemical [2 + 2 + 1] annulation of 2-vinyloxy arylalkynes with bromomalonates via energy transfer By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00249K, Research ArticleShuo Tang, Jiupeng Liu, Min Zhang, Dan Wang, Yong Wang, Jingjing Zhao, Pan LiA transition-metal-free, oxidant-free and base-free photochemical [2 + 2 + 1] radical annulation of 2-vinyloxy arylalkynes with bromomalonates has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
