it Self-assembly of mixed-valent and heterometallic metallocycles: efficient catalyst for oxidation of alcohols to aldehydes with ambient air By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01340D, CommunicationYa-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan LiTwo mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Modulation of the driving forces for adsorption on MIL-101 analogues by decoration with sulfonic acid functional groups: superior selective adsorption of hazardous anionic dyes By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00978D, PaperJi-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan TongMIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Structural, spectroscopic and electronic properties of a family of bi-octahedral Ru25+/6+ complexes with a bridging 2,5-di(2-pyridyl)pyrrolide ligand By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01325K, PaperShi-Rui Kang, Qin Zi Zhou, Chang-Fang Xiong, Bin Liu, John E. McGrady, Mohammed Obies, Chao Liu, Piao He, Xiao-Yi YiA family of Ru2 dimers, [Ru2(μ-κ2N,N’:κ2N’,N’’-dpp)2(μ-X)(X)2]q+ (X = Cl, Br, q = 0 and X = I, q = 1) is synthesized from a [Ru2(OAc)4Cl] paddlewheel starting material. The neutral...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Color Tuning in Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) Phosphors via Cation Substitution By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01130D, PaperHuiling Zhang, Dengwen Yuan, Xiaoyun Mi, Xiuling Liu, Jun LinA series of Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) phosphors were prepared via high-temperature solid-state reaction process. The X-ray diffraction and Rietveld refinements were used to verify the incorporations of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Multicolor tunable luminescence and energy transfer of core-shell structured SiO2@Gd2O3 microspheres co-activated with Dy3+/Eu3+ under single UV excitation By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00735H, PaperJie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui JinOptimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it The role of the excited state dynamic of the antenna ligand in the Lanthanide sensitization mechanism By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01132K, PaperMaría Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-HernandezA fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Influence of Eu valence in the optical activity of BaTiO3 decorated with CaF2 synthesized by microwave-assisted hydrothermal method By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01321H, PaperTatiane Strelow Lilge, Adriano Borges Andrade, Claudiane dos Santos Bezerra, Giordano Frederico da Cunha Bispo, Zélia Soares Macedo, Mario Lucio Lúcio Moreira, Mário Ernesto Giroldo ValerioInorganic hybrid materials are promising applications in absorbers and photon harvesting of solar irradiation, such as DSSC cell photoanodes. Moreover, the investigation of the interaction between the photoanode constituent materials...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Probing the limits of linker substitution in aluminum MOFs through water vapor sorption studies: Mixed-MOF instead of mixed-linker CAU-23 and MIL-160 materials By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01044H, PaperCarsten Schlüsener, Dustin Nils Jordan, Mergime Xhinovci, Tobie J. Matemb Ma Ntep, Alexa Schmitz, Beatriz Giesen, Christoph JaniakWe report the systematic study on the possibility of forming mixed-linker MOFs spanning between the aluminum metal-organic frameworks CAU-23 and MIL-160 with their 2,5-thiophenedicarboxylate (TDC) and 2,5 furandicarboxylate (FDC) linkers,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01054E, PaperSankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra JanaMnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Three diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2: influences of co-substitution on the crystal structure By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01070G, PaperMing Wen, Cong Hu, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie PanWe reported the synthesis, structure, characterization and first-principles calculations of diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2, and studied the influences of co-substitution on the crystal structure.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(II) template By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00466A, PaperManas Khatua, Bappaditya Goswami, Subhas SamantaA Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Effects of ligand substituents on the single-molecule magnetic behavior of quinonoid-bridged dicobalt compounds By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00033G, PaperXiao-Quan Zhu, Wen-Hai Cao, Shao-Dong Su, Xin-Tao Wu, Tian-Lu ShengThe SMM behavior weakens until its disappearance with the substituent changing from Br, H to OMe in the quinonoid-bridged dicobalt compounds [(N4Co)2LX](ClO4)2, (X = H, Cl, Br, and OMe).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Amorphous Ni–Fe–Se hollow nanospheres electrodeposited on nickel foam as a highly active and bifunctional catalyst for alkaline water splitting By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/C9DT04755G, PaperXuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang YinThe electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01227K, CommunicationNatsuki Yabune, Hiroshi Nakajima, Takanori NishiokaA triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Synthesis and reactivity of cyclobutadiene nickel bromide By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01510E, PaperNikita V. Shvydkiy, Egor A. Dlin, Klimentiy V. Ivanov, Anastasiya G. Buyanovskaya, Yulia V. Nelyubina, Dmitry S. PerekalinThe reaction of NiBr2 with 3-hexyne provides new access to various cyclobutadiene nickel complexes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Luminescent lanthanide complexes with a pyridine-bis(carboxamide)-bithiophene sensitizer showing wavelength-dependent singlet oxygen generation By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT01034K, PaperKatherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-DiasA new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Tin based organic-inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01401J, PaperZhenhong Wei, Xiuli You, Jiaojiao YaoOrganic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)](Pt–Pt) By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00923G, PaperStefano Todisco, Mario Latronico, Vito Gallo, Nazzareno Re, Alessandro Marrone, Iogann Tolbatov, Piero MastrorilliDouble addition of phenylacetylene onto the Pt(I)–Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)] (Pt–Pt) affords the η1-alkenyl-μ,η1:η2-alkynyl complex [(η1-trans-(Ph)HCCH)(PHCy2)Pt(μ-PCy2)(μ,η1:η2-PhCC)Pt{κP-P(O)Cy2}(PHCy2)].To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it A molecular boron cluster-based chromophore with dual emission By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00826E, PaperKierstyn P. Anderson, Mary A. Waddington, Gary J. Balaich, Julia M. Stauber, Nicholas A. Bernier, Justin R. Caram, Peter I. Djurovich, Alexander M. SpokoynyBromination of the luminescent borane, anti-B18H22, via electrophilic substitution using AlCl3 and Br2, yields the monosubstituted derivative 4-Br-anti-B18H21 as an air-stable crystalline solid.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00798F, PaperAnuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoeGas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Heat-resistant Pb(II)-based X-ray scintillating metal-organic frameworks for sensitive dosage detection via the aggregation-induced luminescent chromophore By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT00974A, CommunicationJian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong GuoThe synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it High Pressure and Elastic properties of a Guanidinium -formate Hybrid Perovskite By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/C9DT04805G, PaperHong-Qiang Gao, Chao Li, Lin-Sui Li, Wen-Juan Wei, Yu-hui Tan, Yun Zhi TangThe high pressure and elastic properties in a hybrid ABX3-type perovskite, [C(NH2)3][Cd(HCOO)3] (CdGF), based on the A-site guest molecular is revealed via combining the high-pressure synchrotron X-ray diffraction experiments with...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Spin-frustration with two quasi-degenerated spin states of a copper(II) heptanuclear complex obtained from an amino acid ligand By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/C9DT04501E, PaperCatiúcia Rodrigues Marcelino Oliveira Matos, Henrique Silva Jr, Dayenny D’Amato, Guilherme Guedes, Glaucio Braga Ferreira, Odivaldo Cambraia Alves, Filipe Barra de Almeida, Sergio Pinheiro, Acácio Souza, Flavio Garcia, Célia Machado RonconiThe Cu(II) heptanuclear complex (Cu7atac) was synthesised using the hydrated amino acid ligand 2-(5-amino-1H-1,2,4-triazol-3-yl)acetic acid (Hatac.H2O). Single crystal X-ray diffraction analysis revealed a μ3-hydroxo bridged Cu(II) heptanuclear complex, consisting of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Impacts of hydrogen bonding interactions with Np(V/VI)O2Cl4 complexes: vibrational spectroscopy, redox behavior, and computational analysis By feeds.rsc.org Published On :: Dalton Trans., 2020, Advance ArticleDOI: 10.1039/D0DT00848F, PaperMikaela M. Pyrch, Jennifer L. Bjorklund, James M. Williams, Daniel L. Parr IV, Sara E. Mason, Johna Leddy, Tori Z. ForbesCrystallization of neptunyl(V) tetrachlorides over neptunyl(VI) species occurs simultaneously with charge assisted hydrogen bonding in our solid state materials, which we explored by DFT calculations, cyclic voltammograms, and Raman spectroscopy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it Highly cytotoxic gold(I)-phosphane dithiocarbamate complexes trigger an ER stress-dependent immune response in ovarian cancer cells By feeds.rsc.org Published On :: Dalton Trans., 2020, Accepted ManuscriptDOI: 10.1039/D0DT01411G, PaperHai Van Le, Maria Babak, Muhammad Ali Ehsan, Mohammad Altaf , Lisa Reichert, Artem Gushchin, Wee Han Ang, Anvarhusein IsabOvarian cancer is a highly aggressive disease which is treated by surgery and platinum chemotherapy. However, a significant proportion of treated patients develop resistance to platinum treatment resulting in tumor...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
it The Spirit of Sustainability: print or digital, which is “greener”? By www.berkshirepublishing.com Published On :: Thu, 12 Dec 2019 17:04:40 +0000 When we published the Encyclopedia of Sustainability in 2012, a librarian wrote, “That goes against the spirit of sustainability.” I got a similar response this week, so I want to explain why we publish in print and online, and why online is not “green.” An ebook probably kills more trees through deforestation than an equivalent print book, The post The Spirit of Sustainability: print or digital, which is “greener”? appeared first on Berkshire Publishing. Full Article Berkshire Blog books digital printing Sustainability
it Berkshire Joins COVID-19 Support Efforts With JStor, EBSCO, ProQuest By www.berkshirepublishing.com Published On :: Tue, 07 Apr 2020 08:45:20 +0000 We want to make sure you know about some of the ways in which publishers - including Berkshire - are making our books and reference publications available online at reduced cost, or even free, during the COVID-19 crisis. We're well aware that taking classes and doing research papers online is a huge challenge for many The post Berkshire Joins COVID-19 Support Efforts With JStor, EBSCO, ProQuest appeared first on Berkshire Publishing. Full Article Oddments
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