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TVS Supply Chain Solutions posts consolidated Q2 net profit of ₹11 crore




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Karur Vysya Bank hopes to continue growth momentum in H2




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‘Vinaro Bhagyamu Vishnu Katha’ movie review: A concoction of absurd ideas

The twists and turns notwithstanding, it’s tough to sit through the Telugu film ‘Vinaro Bhagyamu Vishnu Katha’




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‘Custody’ movie review: Venkat Prabhu’s mix of conflict and humour works for this Naga Chaitanya, Arvind Swami actioner

Director Venkat Prabhu’s Telugu-Tamil bilingual ‘Custody’ is not among his best, but has plenty going for it




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Macrotech Developers’ net debt rises 43.5% in Q1 on higher capex for land, construction




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GoM on real estates remains inconclusive

The group will meet one more time before making suggestions




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India in consultation with Indonesia at WTO over duty on ceramic tiles

Exports from India dipped since Indonesia imposed safeguard duties on the product




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L&T Construction reduces timelines by 50% with 3D printing technology

‘By using this technology, a villa project that would typically take 24 to 36 months can be completed in 12 months’




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Meghna Infracon expands portfolio with new Mumbai residential project 

The project aims to offer 1 and 2 BHK luxurious apartments, with construction already underway




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Brookfield-led consortium completes acquisition of American Tower’s operations in India

The acquisition, valued at $2.2 billion, encompasses approximately 76,000 communications sites, solidifying the consortium’s commitment to advancing India’s connectivity




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Bengaluru leads retail/consumer packaged goods GCC boom as India sees rapid growth in the sector

The ANSR report anticipates over 25 new GCCs in the sector to emerge in the next 2-3 years, further solidifying India’s position as a global hub




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DLF Q2 consolidated net profit up 121 per cent

Consolidated revenues saw a 48 per cent increase y-o-y to ₹2,181 crore. It stood at ₹1,477 crore in the year-ago-period.




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WeHouse streamlines home construction with transparency, expands to Tier-II cities

By dividing the construction journey into 24 well-defined milestones, the startup provides clients with complete visibility into their projects, aligning payments with milestones to build trust




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Call to use of path-breaking technology in construction sector

Adoption of insulation technology is currently delivering substantial benefits, including a massive 80 per cent reduction in energy utilization for homes using air conditioning




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Non-IT services tenants, SEZ conversions aid occupancies in REITs

Brookfield India Real Estate Trust, which was hit by exits by tenants in the IT and IT services segments, has only 26 per cent of its tenant base in the technology sector




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Traditional Indian art is witnessing a contemporary makeover. And the art market is loving it

Tribal and traditional artists explore novel ways of storytelling, experimenting with colour, techniques and contemporary themes, to connect with younger, mainstream audiences




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Isomeric diazapyrene–thiophene conjugated systems: synthesis, characterization, and transport properties

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01305K, Research Article
Open Access
Honglei Li, Guodong Zhao, Qingxin Tang, Hongkun Tian, Lixiang Wang
Three key dihalogenated diazapyrene intermediates were synthesized and the corresponding isomeric co-oligomers with bithiophene demonstrated distinct position-dependence in the crystal structures, and optoelectronic and charge transport properties.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Lewis acid-controlled Pd-catalyzed chemodivergent hydrocyanation of cyclopropenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01609B, Research Article
Rongrong Yu, Song-Zhou Cai, Xianjie Fang
We report a Lewis acid-controlled Pd-catalyzed chemodivergent hydrocyanation of cyclopropenes. In the absence of Al Lewis acid, the reaction predominantly yields ring-opened allylic nitrile products while the addition of Lewis acid favors the formation of cyano-substituted cyclopropane products.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Towards the total synthesis of mandelalide B: construction of the tetrahydrofuran/α-hydroxyl lactone fragment

Org. Chem. Front., 2024, 11,6353-6357
DOI: 10.1039/D4QO01433B, Research Article
Jia-Lei Yan, Jie Yu, Yingying Cheng, Mingze Yang, Zhengshuang Xu, Tao Ye
A stereocontrolled synthesis of the tetrahydrofuran/α-hydroxy lactone fragment of mandelalide B has been accomplished. The synthesis features a Horner-Wadsworth-Emmons fragment assembly strategy and a highly stereospecific iodine-induced cyclization.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Pd-catalyzed S-glycosylation of cysteine-containing peptides at room temperature

Org. Chem. Front., 2024, 11,6347-6352
DOI: 10.1039/D4QO01389A, Research Article
Linhua Shen, Franck Le Bideau, Gong Chen, Samir Messaoudi
This study reports the synthesis of thioglycopeptides via a Pd-catalyzed coupling of cysteine-containing peptides with iodoglycals. A variety of cysteine-containing peptides and other thiol nucleophiles including thiosugars and thiophenols were used.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives

Org. Chem. Front., 2024, 11,6418-6425
DOI: 10.1039/D4QO01298D, Research Article
Wei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun Yao
A phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.
The content of this RSS Feed (c) The Royal Society of Chemistry




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18F-labelling of nitrogen-containing aryl boronates – anti-cancer drug melflufen as a case study

Org. Chem. Front., 2024, 11,6411-6417
DOI: 10.1039/D4QO01594K, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kevin Bajerke, Fredrik Lehmann, Gunnar Antoni, Kálmán J. Szabó
This study addresses the 18F-labelling of nitrogen-containing arenes via copper-mediated radiofluorination (CMRF). In this case study, derivatives/fragments of the anti-cancer drug melflufen were targeted.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible-light-promoted catalytic epoxidation of alkenes under metal-free conditions

Org. Chem. Front., 2024, 11,6437-6443
DOI: 10.1039/D4QO01265H, Research Article
Dabao Tan, Xiaoyan Cai, Lele Zhang, Boyu Liu, Jianbin Zeng, Feiming Li, Zhixiong Cai, Mingqiang Huang, Xiaoping Chen, Shunyou Cai
In this work, we report a method for the synthesis of functionalized epoxy analogues using the synergistic interaction of 4CzIPN and oxygen under visible light stimulation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Activation of donor–acceptor cyclopropanes under basic conditions: ring opening of 2-(p-siloxyaryl)cyclopropane 1,1-dicarboxylates with nitro compounds and other C-nucleophiles

Org. Chem. Front., 2024, 11,6483-6494
DOI: 10.1039/D4QO01472C, Research Article
Yulia A. Antonova, Andrey A. Tabolin
A new activation mode for donor–acceptor cyclopropanes was proposed and implemented in their reaction with nitro compounds and other common C-nucleophiles.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Cobalt-catalyzed enantioselective reductive addition of ketimine with cyclopropyl chloride to construct chiral amino esters bearing cyclopropyl fragments

Org. Chem. Front., 2024, 11,6311-6318
DOI: 10.1039/D4QO01474J, Research Article
Jiangtao Hu, Tingting Xia, Xianqing Wu, Hongrui Feng, Jingping Qu, Yifeng Chen
Co-catalyzed asymmetric reductive addition of ketimine with cyclopropyl chloride has been realized to access diverse chiral amino esters bearing cyclopropyl fragments with broad functional group tolerance and excellent enantioselectivities.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dendron-mediated control over self-assembly of chlorophyll rosettes into columnar vs. discrete aggregates

Org. Chem. Front., 2024, 11,6304-6310
DOI: 10.1039/D4QO01629G, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ryo Kudo, Hiroki Hanayama, Balaraman Vedhanarayanan, Hitoshi Tamiaki, Nobuyuki Hara, Sarah E. Rogers, Martin J. Hollamby, Biplab Manna, Koji Harano, Shiki Yagai
By controlling the π-π stacking of chlorophyll supramolecular rosettes through steric hindrance of alkyl dendrons, it become possible to create chlorophyll tubes and discrete rings that resemble to natural chlorophyll assemblies.
The content of this RSS Feed (c) The Royal Society of Chemistry




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LiTMP-LiBr complex-induced lateral lithiation and cross ester condensation: direct access to isocoumarins from 2-methoxy o-toluate esters

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01678E, Research Article
Open Access
Mintu Rehman, Sajib Daimary, Rasajna Madhusudhana, Rajendar Goreti
LiTMP-LiBr complex promotes cross-ester coupling of 2-methoxy o-toluate esters to directly yield isocoumarin is demonstrated. Method applied to many natural product precursors including synthesis of (+)- and (−)-lunatinins.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01388C, Research Article
Shanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian Cai
A two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01771D, Research Article
Bendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin Qiu
An efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01627K, Research Article
Bo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long Zhu
We report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.
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Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01877J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cintya Pinilla, Mario García-Zarza, Ana C. Albéniz
The mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.
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PIFA-Mediated cyclization of methyl(2-(1-phenylvinyl)phenyl)sulfane for the concise, flexible, and scalable de novo synthesis of C3-arylated benzo[b]thiophenes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01589D, Research Article
Xinya Liu, Olivier Provot, Christine Tran, Jean-Francois Soule, Abdallah Hamze
The well-decorated arylated benzo[b]thiophene scaffold is a pivotal structural motif with diverse applications in medicinal chemistry. This paper outlines a de novo synthesis of C3-arylated benzo[b]thiophenes, showcasing its flexibility and...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01641F, Research Article
Peng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai Li
An FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.
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Convergent Synthetic Approaches to Polycyclic Aromatic Dicarboximides

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01828A, Review Article
Kazutaka Shoyama, Frank Wuerthner
Polycyclic aromatic dicarboximides (PADIs) as represented by naphthalene and perylene bis(dicarboximide) are useful molecules for a variety of functional materials and remain important synthetic targets for organic chemists. In this...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Telangana Cyber Security Bureau conducts digital awareness campaign for senior citizens




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Cong. govt cheating paddy farmers on procurement: Kishan Reddy




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Congress shedding ‘çrocodile tears’ over BCs welfare: BJP leader Laxman




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Raid on hospitals in Hyderabad and Secunderabad leads to seizure of controlled drugs

The raiding teams found substances which are are classified as controlled drugs and their sale and possession are strictly regulated under the Narcotic Drugs and Psychotropic Substances (NDPS) Act




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District Consumer Commission dismisses complaint against Google Pay due to lack of evidence




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Pending bills paid to contractors, but situation of BC students remains unchanged: National BC welfare association chief

He demanded Telangana government to immediately release reimbursement and scholarship dues amount to about ₹4,000 crore




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KTR’s Delhi visit to lobby with BJP to save him in Formula-E race case: Congress




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Officials demand strict action against those involved in ‘confrontation’ at Vikarabad village




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Ind vs NZ 3rd Test: India hand New Zealand control after batting flop show on Day 1

India’s batting collapse makes a comeback as they face the horror of a clean sweep at home against New Zealand.




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World Test Championship standing: India loses top spot to Australia, slips to second

India lost to New Zealand by 25 runs in the third and final Test in Mumbai resutling in a 0-3 whitewash, their first in a home Test series since South Africa's 2-0 win in 1999-2000




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Ball-change controversy involving Kishan dominates India A's 7-wicket loss to Australia A

Resuming at the overnight score of 139 for 3 while chasing 225, skipper Nathan McSweeney (88 not out) and Beau Webster (61) remained unbeaten, stitching unconquered 141 runs for the fourth wicket to ensure the comfortable win for the hosts.




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Ranji Trophy | Lad revels in second innings for Mumbai

The batter’s unbeaten 169 against Odisha in the Ranji Trophy marks his highest First Class score




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Ranji Trophy | Sachin Baby, Salman help Kerala seize control

The duo’s 99-run partnership for the sixth wicket helps the host reach 340 for seven; the home team leads by 178 at the end of day two




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Haris Rauf, Saim Ayub shine as Pakistan crushes Australia in second ODI

Replying to the hosts’ modest 163 all out, thanks to pace spearhead Haris Rauf’s 5-29, Pakistan reached 169-1 with a huge 141 balls to spare.




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Conquer ‘planning fallacy’

Research suggests people have an innate tendency to be overoptimistic about their capacity to meet deadlines. How can we guard ourselves against it?




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The challenge of Economics

How prepared are you to face the CBSE exam on this application-oriented subject?