metal

Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01227K, Communication
Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka
A triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.
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metal

Rapid mechanochemical synthesis of metal–organic frameworks using exogenous organic base

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01240H, Paper
Zihao Wang, Zongzhe Li, Marcus Ng, Phillip J. Milner
We describe the mechanochemical, solvent-free synthesis of metal–organic frameworks using liquid organic base for the first time.
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metal

Selenotungstates incorporating organophosphonate ligands and metal ions: synthesis, characterization, magnetism and catalytic efficiency in Knoevenagel condensation reaction

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00444H, Paper
Jingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping Wang
Three sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...
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metal

Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper
Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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metal

Heat-resistant Pb(II)-based X-ray scintillating metal-organic frameworks for sensitive dosage detection via the aggregation-induced luminescent chromophore

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication
Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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metal

Dual-fixations of europium cation and TEMPO species on metal-organic frameworks for aerobic oxidation of alcohols

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01324B, Paper
Seongwoo Kim, Jooyeon Lee, Sungeun Jeoung, Hoi Ri Moon, Min Kim
The efficient and selective aerobic oxidation of alcohols has been investigated with judicious combinations of europium-incorporated and/or TEMPO ((2,2,6,6-tetramethylpiperidin-1-yl)oxyl)-functionalized zirconium-based porous metal-organic frameworks (MOFs). Although MOFs are well-known catalytic platform...
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metal

Career Opportunities at EPSRC & SFI Centre: EPSRC & SFI Centre for Doctoral Training in Advanced Metallic Systems (AMS-CDT)

£Attractive: EPSRC & SFI Centre for Doctoral Training in Advanced Metallic Systems (AMS-CDT)
For more latest jobs and jobs in North East England visit brightrecruits.com



  • North East England

metal

[ASAP] Developing a Novel Nanoscale Porphyrinic Metal–Organic Framework: A Bifunctional Platform with Sensitive Fluorescent Detection and Elimination of Nitenpyram in Agricultural Environment

Journal of Agricultural and Food Chemistry
DOI: 10.1021/acs.jafc.0c01313




metal

How to make aziridines from olefins without expensive metals

Double bonds form nitrogen-containing 3-membered rings thanks to a reactive, yet fleeting, oxaziridine intermediate




metal

How to make aziridines from olefins without expensive metals

Double bonds form nitrogen-containing 3-membered rings thanks to a reactive yet fleeting oxaziridine intermediate




metal

Vaping exposes users to more toxic metals than smoking cigarettes

E-cigarettes deliver lead, arsenic, nickel, and other metals at harmful levels




metal

Huge 2-D metallo-supramolecule

Self-assembled supramolecular grid measures 20 nm across




metal

Investigation of metaldehyde removal by powdered activated carbon from different water samples

Environ. Sci.: Water Res. Technol., 2020, 6,1432-1444
DOI: 10.1039/C9EW00962K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhuojun Li, Juntao Li, Zhengxiao Guo, Luiza C. Campos
Applying PAC to the water sample collected after static flocculation (position 2) gave the best result regarding the removal of metaldehyde.
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metal

Stable immobilized amine sorbents for heavy metal and REE removal from industrial wastewaters

Environ. Sci.: Water Res. Technol., 2020, 6,1286-1299
DOI: 10.1039/C9EW00915A, Paper
Walter Christopher Wilfong, Brian W. Kail, Qiuming Wang, Fan Shi, Greg Shipley, Thomas J. Tarka, McMahan L. Gray
Stable and immobilized amine sorbents can simultaneously remove/recover cationic and oxyanionic toxic metals plus valuable rare earth elements from industrial and mining effluents prior to discharging into environmental water systems.
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metal

Angle resolved photoemission spectroscopy of delafossite metals Veronika Sunko

Online Resource




metal

Plasmonics and light-matter interactions in two-dimensional materials and in metal nanostructures: classical and quantum considerations / Paulo André Dias Gonçalves

Online Resource




metal

[ASAP] Conductometric Response-Triggered Surface-Enhanced Raman Spectroscopy for Accurate Gas Recognition and Monitoring Based on Oxide-wrapped Metal Nanoparticles

ACS Sensors
DOI: 10.1021/acssensors.0c00188




metal

[ASAP] Metal-Free Colorimetric Detection of Pyrophosphate Ions by Inhibitive Nanozymatic Carbon Dots

ACS Sensors
DOI: 10.1021/acssensors.9b02486




metal

Transition metal dichalcogenides for alkali metal ion batteries: engineering strategies at the atomic level

Energy Environ. Sci., 2020, 13,1096-1131
DOI: 10.1039/C9EE03549D, Review Article
Biao Chen, Dongliang Chao, Enzuo Liu, Mietek Jaroniec, Naiqin Zhao, Shi-Zhang Qiao
This review provides enriched information for understanding the charge storage mechanisms of transition metal dichalcogenides (TMDs), as well as the importance of intrinsic structure engineering for enhancing the performance of TMDs in energy storage.
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metal

A new lithium diffusion model in layered oxides based on asymmetric but reversible transition metal migration

Energy Environ. Sci., 2020, 13,1269-1278
DOI: 10.1039/C9EE04123K, Paper
Kyojin Ku, Byunghoon Kim, Sung-Kyun Jung, Yue Gong, Donggun Eum, Gabin Yoon, Kyu-Young Park, Jihyun Hong, Sung-Pyo Cho, Do-Hoon Kim, Hyungsub Kim, Eunsuk Jeong, Lin Gu, Kisuk Kang
We propose a new lithium diffusion model involving coupled lithium and transition metal migration, peculiarly occurring in a lithium-rich layered oxide.
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metal

From metal–organic frameworks to single/dual-atom and cluster metal catalysts for energy applications

Energy Environ. Sci., 2020, Advance Article
DOI: 10.1039/C9EE04040D, Review Article
Chun-Chao Hou, Hao-Fan Wang, Caixia Li, Qiang Xu
Single/dual-atom and cluster metal catalysts have emerged as a new frontier in catalysis. This review highlights recent advances and provides a state-of-the-art understanding of MOF-based synthesis strategies and their prospective applications.
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metal

Metal composition influences optoelectronic quality in mixed-metal lead-tin triiodide perovskite solar absorbers

Energy Environ. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0EE00132E, Paper
Matthew Thomas Klug, Rebecca L. Milot, Jay Patel, Thomas Green, Harry C. Sansom, Michael Farrar, Alexandra J Ramadan, Samuele Martani, Zhiping Wang, Bernard Wenger, James M Ball, Liam Langshaw, Annamaria Petrozza, Michael B Johnston, Laura M Herz, Henry Snaith
Current designs for all-perovskite multi-junction solar cells require mixed-metal Pb-Sn compositions to achieve narrower band gaps than are possible with their neat Pb counterparts. The lower band gap range achievable...
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metal

Bridging the immiscibility of an all-fluoride fire extinguishant with highly-fluorinated electrolyte toward safe sodium metal batteries

Energy Environ. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0EE00694G, Paper
Xueying Zheng, Zhen-Yi Gu, Xuyang Liu, Zhongqiang Wang, Jiayun Wen, Xing-Long Wu, Wei Luo, Yunhui Huang
Room-temperature sodium metal batteries with metallic Na anode and flammable organic solvent-based electrolyte are breeding severe safety concerns. Herein, by introducing non-flammable, highly-fluorinated ethers as the bridge solvents, we enable...
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metal

A transversal low-cost pre-metallation strategy enabling ultrafast and stable metal ion capacitor technologies

Energy Environ. Sci., 2020, Advance Article
DOI: 10.1039/D0EE00351D, Paper
María Arnaiz, Devaraj Shanmukaraj, Daniel Carriazo, Dhrubajyoti Bhattacharjya, Aitor Villaverde, Michel Armand, Jon Ajuria
A low-cost pre-metallation strategy based on inorganic sacrificial salts that decompose on the first charge.
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metal

[ASAP] Bioinspired Enzymatic Synthesis of Terpenoid-Based (Meth)acrylic Monomers: A Solvent-, Metal-, Amino-, and Halogen-Free Approach

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c02307




metal

[ASAP] Two-Dimensional Metal Hexahydroxybenzene Frameworks as Promising Electrocatalysts for an Oxygen Reduction Reaction

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c01908




metal

[ASAP] Catalyzed Hydrolysis of Tetrahydroxydiboron by Graphene Quantum Dot-Stabilized Transition-Metal Nanoparticles for Hydrogen Evolution

ACS Sustainable Chemistry & Engineering
DOI: 10.1021/acssuschemeng.0c02496




metal

Metallic iron in cornflakes

Food Funct., 2020, 11,2938-2942
DOI: 10.1039/C9FO02370D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Frederik Lermyte, Wen-Ying Zhang, Jake Brooks, Steven Huband, Joanna F. Collingwood, Martin R. Lees, Margaret P. Rayman, Peter J. Sadler
Magnetometry and X-ray analysis show that the iron in cornflake-style cereals fortified with this essential element at levels up to 14 mg per 100 g, is micron-sized body-centred cubic metallic iron, partially soluble at stomach pH.
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metal

Effect of Biolimus-Eluting Stents With Biodegradable Polymer vs Bare-Metal Stents on Cardiovascular Events Among Patients With Acute Myocardial Infarction: The COMFORTABLE AMI Randomized Trial

Interview with Stephan Windecker, MD, author of Effect of Biolimus-Eluting Stents With Biodegradable Polymer vs Bare-Metal Stents on Cardiovascular Events Among Patients With Acute Myocardial Infarction: The COMFORTABLE AMI Randomized Trial




metal

Metallography [electronic resource].

Publisher New York : American Elsevier Pub.
Location World Wide Web
Call No. TN690




metal

Progress in metal physics [electronic resource].

Publisher London : Butterworths Scientific Publications, 1949-1959.
Location World Wide Web
Call No. TN600




metal

[ASAP] Collagen-Targeted Theranostic Nanosponges for Delivery of the Matrix Metalloproteinase 14 Inhibitor Naphthofluorescein

Chemistry of Materials
DOI: 10.1021/acs.chemmater.9b02840




metal

[ASAP] Tuning the Structures of Metal–Organic Frameworks <italic toggle="yes">via</italic> a Mixed-Linker Strategy for Ethylene/Ethane Kinetic Separation

Chemistry of Materials
DOI: 10.1021/acs.chemmater.9b04177




metal

[ASAP] Insights into the Electronic Properties and Charge Transfer Mechanism of a Porphyrin Ruthenium-Based Metal–Organic Framework

Chemistry of Materials
DOI: 10.1021/acs.chemmater.0c00356




metal

[ASAP] Nanoscale Metal Phosphide Phase Segregation to Bi/P Core/Shell Structure. Reactivity as a Source of Elemental Phosphorus

Chemistry of Materials
DOI: 10.1021/acs.chemmater.0c00478




metal

[ASAP] NMR-Enhanced Crystallography Aids Open Metal–Organic Framework Discovery Using Solvent-Free Accelerated Aging

Chemistry of Materials
DOI: 10.1021/acs.chemmater.0c00894




metal

[ASAP] Evaluation of Sponge Metal Catalysts in a Trickle Bed Reactor for the Continuous Hydrogenation of an Aliphatic Nitro Intermediate

Organic Process Research & Development
DOI: 10.1021/acs.oprd.9b00447




metal

Atomic-scale engineering of metal–oxide interfaces for advanced catalysis using atomic layer deposition

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00304B, Perspective
Lina Cao, Junling Lu
Two main routes to optimization of metal–oxide interfaces: reducing metal particle size and oxide overcoating.
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metal

Metal free alkene hydrogenation by B-doped graphitic carbon nitride

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00488J, Paper
Ashima Dogra, Ilaria Barlocco, Amritpal Singh, Ferenc Somodi, Alberto Villa, Neeraj Gupta
Metal free hydrogenation of styrene under mild conditions employing boron-doped carbon nitride catalysts is reported.
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metal

Molybdenum carbide supported metal catalysts (Mn/MoxC; M = Co, Ni, Cu, Pd, Pt) – metal and surface dependent structure and stability

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00504E, Paper
Fan Wang, Teng Li, Yun Shi, Haijun Jiao
The surface and metal-dependent morphologies and energies of molybdenum carbide supported metal catalysts (Mn/MoxC; M = Co, Ni, Cu, Pd, Pt) have been systematically investigated on the basis of periodic density functional theory computations.
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metal

Pd–Au bimetallic catalysts supported on ZnO for selective 1,3-butadiene hydrogenation

Catal. Sci. Technol., 2020, 10,2503-2512
DOI: 10.1039/C9CY02395J, Paper
Open Access
Belén Bachiller-Baeza, Ana Iglesias-Juez, Giovanni Agostini, Eva Castillejos-López
The effect of the ZnO morphology on the properties of Pd–Au bimetallic catalysts has been discussed.
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metal

Hourglass-type polyoxometalate-based crystalline materials as efficient cooperating photocatalysts for the reduction of Cr(VI) and oxidation of dyes

Catal. Sci. Technol., 2020, 10,2593-2601
DOI: 10.1039/D0CY00208A, Paper
Xuerui Tian, Yaqi Zhang, Yuanyuan Ma, Qing Zhao, Zhangang Han
Hourglass-type polyoxometalate-based crystalline materials exhibit efficient photocatalytic activities towards simultaneous photocatalytic Cr(VI) reduction and organic MB oxidation.
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metal

Bimetallic scorpionate-based helical organoaluminum complexes for efficient carbon dioxide fixation into a variety of cyclic carbonates

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00593B, Paper
Marta Navarro, Luis F. Sánchez-Barba, Andrés Garcés, Juan Fernández-Baeza, Israel Fernández, Agustín Lara-Sánchez, Ana M. Rodríguez
The binuclear aluminum complexes [AlR22-NN';κ2-NN')AlR2] with TBAB/PPNCl behave as excellent systems for cyclic carbonate formation from CO2 with challenging epoxides.
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metal

Photocatalytic hydrogen evolution over nickel cobalt bimetallic phosphate anchored graphitic carbon nitrides by regulation of d-band electronic structure

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00556H, Paper
Yuanzheng Zhang, Yunrong Dai, Lifeng Yin, Huihui Li, Xiang Chen, Bin Chen
Non-precious metal co-catalysts with high activity and stability are extremely desirable for economically viable photocatalytic molecular hydrogen (H2) evolution. Herein, nickel cobalt phosphate (NiCo-Pi) was introduced into graphitic carbon nitride...
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metal

Impact of edge structures on interfacial interactions and efficient visible-light photocatalytic activity of metal–semiconductor hybrid 2D materials

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00420K, Paper
Open Access
Deobrat Singh, Pritam Kumar Panda, Nabil Khossossi, Yogendra Kumar Mishra, Abdelmajid Ainane, Rajeev Ahuja
The present work systematically investigates the structural, electronic, and optical properties of MoS2/Si2BN heterostructures based on first-principles calculations.
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metal

Homogeneous vs. Heterogeneous: Mechanistic Insights into Iron Group Metal-Catalyzed Reductions from Poisoning Experiments

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00644K, Minireview
Axel Jacobi von Wangelin, Sebastian Sandl, Dominik Gärtner
Iron group metal catalysts constitute a promising alternative to well-established noble metal catalysts in reduction reactions. However, the development of effective 3d metal catalysts has largely been hampered by their...
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metal

Heterogenization for polyoxometalates as solid catalysts in aerobic oxidation of glycerol

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00403K, Paper
Meilin Tao, yue li, Yiming Li, Xueyan Zhang, Yurii Geletii, Xiaohong Wang, Craig L Hill
A series of heterogeneous catalysts based on phosphomolybdic salts with different Lewis metals in counter or substituent places LnPMo12O40 (L = Al3+, Fe3+, Cr3+, Ti4+, Zr4+ and Zn2+, abbreviated as...
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metal

Photoswitchable catalysis using organometallic complexes

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00431F, Minireview
Zoraida Freixa
Photoswitchable catalysis using organometallic complexes: a ligand design perspective.
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metal

High antimicrobial photodynamic activity of photosensitizer encapsulated dual-functional metallocatanionic vesicles against drug-resistant bacteria S. aureus

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00323A, Paper
Bunty Sharma, Gurpreet Kaur, Ganga Ram Chaudhary, Santosh L. Gawali, P. A. Hassan
Developments in the field of photodynamic therapy (PDT) are being made by investigating appropriate photosensitizers (PSs) and enhancing the penetration effect of light by developing new metallocatanionic vesicles.
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metal

A multifunctional metal-biopolymer coordinated double network hydrogel combined with multi-stimulus responsiveness, self-healing, shape memory and antibacterial properties

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00425A, Paper
Kun Yan, Feiyang Xu, Chunyu Wang, Yingying Li, Yuanli Chen, Xiufang Li, Zhentan Lu, Dong Wang
A universal, straightforward macroscale assembly technology has been presented for fabrication of polysaccharide-based multifunctional DN gels based on metal coordination chemistry.
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