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Si–C(sp3) bond activation through oxidative addition at a Rh(I) centre

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Dalton Trans., 2020, 49,5416-5419
DOI: 10.1039/D0DT00725K, Communication
S. Azpeitia, A. J. Martínez-Martínez, M. A. Garralda, A. S. Weller, M. A. Huertos
Rhodium promoted a fast, quantitative and room temperature Si–CH3 bond activation.
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Enhanced piezoelectric properties of (1 − x)BiFe0.98(Zn0.5Hf0.5)0.02O3-xBaTiO3 ceramics near the morphotropic phase boundary

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Dalton Trans., 2020, 49,5573-5580
DOI: 10.1039/C9DT04664J, Paper
Yunjing Shi, Hairui Bai, Fei Yan, Rui Hu, Kaikai Chen, Bo Shen, Jiwei Zhai
The component with the R–T phase coexistence near MPB affords an optimal piezoelectric coefficient (d33) of 130 pC N−1.
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Hierarchical Mo-doped CoP3 interconnected nanosheet arrays on carbon cloth as an efficient bifunctional electrocatalyst for water splitting in an alkaline electrolyte

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Dalton Trans., 2020, 49,5563-5572
DOI: 10.1039/D0DT00671H, Paper
Shasha Zhang, Mingjing Guo, Shuyi Song, Ke Zhan, Ya Yan, Junhe Yang, Bin Zhao
Hierarchical Mo-doped CoP3 nanosheet arrays were fabricated on carbon cloth to serve as an efficient and robust bifunctional electrocatalyst for overall water splitting in alkaline media.
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Responsive ruthenium complex probe for phosphorescence and time-gated luminescence detection of bisulfite

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Dalton Trans., 2020, 49,5531-5538
DOI: 10.1039/C9DT04614C, Paper
Wenzhu Zhang, Xiuyan Xi, Yong-Lei Wang, Zhongbo Du, Chaolong Liu, Jianping Liu, Bo Song, Jingli Yuan, Run Zhang
We report the design, synthesis, and characterization of a responsive Ru(II) complex probe for background-free time-gated luminescence detection of bisulfite.
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Three metal–organic framework isomers of different pore sizes for selective CO2 adsorption and isomerization studies

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Dalton Trans., 2020, 49,5618-5624
DOI: 10.1039/D0DT00793E, Paper
Rui Zhang, Ju-Hua Huang, De-Xian Meng, Fa-Yuan Ge, Li-Fei Wang, Yong-Kai Xu, Xing-Gui Liu, Mei-Mei Meng, Zhen-Zhong Lu, He-Gen Zheng, Wei Huang
Three MOF isomers including framework-catenation and framework-topological isomers were synthesized for adsorbing carbon dioxide with high selectivity.
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Carbazole-based green and blue-BODIPY dyads and triads as donors for bulk heterojunction organic solar cells

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Dalton Trans., 2020, 49,5606-5617
DOI: 10.1039/D0DT00637H, Paper
Jian Yang, Charles H. Devillers, Paul Fleurat-Lessard, Hao Jiang, Shifa Wang, Claude P. Gros, Gaurav Gupta, Ganesh D. Sharma, Haijun Xu
Two BODIPY derivatives with one (B2) and two (B3) carbazole moieties were synthesized and applied as electron-donor materials in organic photovoltaic cells (OPV), showing an overall PCE of 6.41% and 7.47%, respectively.
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Phosphacycloalkyldiones: synthesis and coordinative behaviour of 6- and 7-member cyclic diketophosphanyls

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Dalton Trans., 2020, 49,5482-5492
DOI: 10.1039/D0DT00864H, Paper
Kyle G. Pearce, Vladimir Simenok, Ian R. Crossley
Condensation of glutaryl and adipoyl chlorides with bis(silyl)phosphanes RP(SiMe3)2 (R = Me, nBu, tBu, Ph, Mes) affords the conformationally fluxional phosphacycloalkyldiones (CH2)n(CO)2PR (n = 3, 4); their coordination behaviour is explored.
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Diamidophosphites from β-hydroxyamides: readily assembled ligands for Pd-catalyzed asymmetric allylic substitution

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Dalton Trans., 2020, 49,5625-5635
DOI: 10.1039/D0DT00741B, Paper
Ilya V. Chuchelkin, Konstantin N. Gavrilov, Nataliya E. Borisova, Alexander M. Perepukhov, Alexander V. Maximychev, Sergey V. Zheglov, Vladislav K. Gavrilov, Ilya D. Firsin, Vladislav S. Zimarev, Igor S. Mikhel, Victor A. Tafeenko, Elena V. Murashova, Vladimir V. Chernyshev, Nataliya S. Goulioukina
Novel diamidophosphites based on β-hydroxyamides were prepared, and their individual and in situ formed complexes were tested in Pd-mediated allylations.
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Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

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Dalton Trans., 2020, 49,5420-5423
DOI: 10.1039/D0DT00842G, Communication
Luis M. Aguirre Quintana, Ningxin Jiang, John Bacsa, Henry S. La Pierre
The synthesis of coinage metal tris(dialkylamido)imidophosphorane complexes is reported, and the use of the silver(I) salt as an oxidative transmetallation reagent for the formation of a cerium(IV) complex is described.
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Prediction of ternary fluorooxoborates with coplanar triangular units [BOxF3−x]x− from first-principles

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Dalton Trans., 2020, 49,5424-5428
DOI: 10.1039/D0DT00160K, Communication
Zhonglei Wei, Wenyao Zhang, Hao Zeng, Hao Li, Zhihua Yang, Shilie Pan
From first-principles prediction, we got all the basic structural units of fluorooxoborates, namely, tetrahedral elements [BOxF4−x] (x = 1,2,3) like [BO4] and triangular elements [BOxF3−x] (x = 1,2) like [BO3].
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Efficient CO2 electroreduction to CO at low overpotentials using a surface-reconstructed and N-coordinated Zn electrocatalyst

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Dalton Trans., 2020, 49,5434-5439
DOI: 10.1039/D0DT00800A, Communication
Wanan Deng, Shixiong Min, Fang Wang, Zhengguo Zhang, Chao Kong
A surface-reconstructed and N-coordinated Zn electrocatalyst exhibits enhanced activity and selectivity for CO2 electroreduction to CO at reduced overpotentials.
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Coordination chemistry of [Y(pypa)]− and comparison immuno-PET imaging of [44Sc]Sc- and [86Y]Y-pypa-phenyl-TRC105

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Dalton Trans., 2020, 49,5547-5562
DOI: 10.1039/D0DT00437E, Paper
Lily Li, María de Guadalupe Jaraquemada-Peláez, Eduardo Aluicio-Sarduy, Xiaozhu Wang, Todd E. Barnhart, Weibo Cai, Valery Radchenko, Paul Schaffer, Jonathan W. Engle, Chris Orvig
H4pypa was conjugated to an antibody via a newly synthesized H4pypa-phenyl-NCS; promising immuno-PET imaging with 44Sc was demonstrated.
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Trinuclear Mn2+/Zn2+ based microporous coordination polymers as efficient catalysts for ipso-hydroxylation of boronic acids

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Dalton Trans., 2020, 49,5454-5462
DOI: 10.1039/D0DT00794C, Paper
Sanchay J. Bora, Rima Paul, Anurag Dutta, Shyam Goswami, Ankur K. Guha, Ashim J. Thakur
Two efficient catalysts based on trinuclear Mn(II)/Zn(II) clusters were synthesized and used for ipso-hydroxylation of phenylboronic acids into the corresponding phenols with excellent yields.
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Hollow-structure engineering of a silicon–carbon anode for ultra-stable lithium-ion batteries

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Dalton Trans., 2020, 49,5669-5676
DOI: 10.1039/D0DT00566E, Paper
Hongbin Liu, Yun Chen, Bo Jiang, Yue Zhao, Xiaolin Guo, Tingli Ma
Hollow silicon nanotubes were successfully synthesized in situ on a carbon substrate, which effectively accommodate the volume expansion of silicon and exhibit ultra-stable performance as the anode of lithium-ion batteries.
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Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(I) carbonyl complex

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Dalton Trans., 2020, 49,5463-5470
DOI: 10.1039/C9DT04878B, Paper
Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam
Photolysis of [Mn(C^N)(CO)4] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)3(N2)].
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Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

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Dalton Trans., 2020, 49,5684-5694
DOI: 10.1039/D0DT01144D, Paper
Thomas Scattolin, Claudio Santo, Nicola Demitri, Luciano Canovese, Fabiano Visentin
We have examined in depth the features of oxidative addition of (E)-1,2 ditosylethene on palladium(0) complexes bearing picolyl-N-heterocyclic carbenes.
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Efficient removal of methyl orange by a flower-like TiO2/MIL-101(Cr) composite nanomaterial

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Dalton Trans., 2020, 49,5722-5729
DOI: 10.1039/D0DT00778A, Paper
Wan Wu, Tiantian Yao, Ye Xiang, Hao Zou, Yi Zhou
Nano-scale MOF composite materials prepared by combining inorganic semiconductors with controllable pore structures and functional active sites for the effective removal of organic dyes will exhibit more excellent adsorption activity.
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A bimetallic MOF@graphene oxide composite as an efficient bifunctional oxygen electrocatalyst for rechargeable Zn–air batteries

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Dalton Trans., 2020, 49,5730-5735
DOI: 10.1039/D0DT00976H, Paper
Yao Xiao, Beibei Guo, Jing Zhang, Chun Hu, Ruguang Ma, Deyi Wang, Jiacheng Wang
A bimetallic ZnCo-ZIF@graphene oxide (ZnCo-ZIF@GO) composite was synthesized via an in situ growth strategy. As the air cathode of Zn–air batteries, ZnCo-ZIF@GO showed good charge/discharge performance and long-term stability.
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Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction

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Dalton Trans., 2020, 49,5440-5444
DOI: 10.1039/D0DT00966K, Communication
Lijuan Huang, Lei Wang, Yan Zhao, Ling Huang, Jian Bi, Guohong Zou, Zhien Lin, Daojiang Gao
An amino acid-templated gallium phosphate with a zeolitic topology has been prepared under surfactant-thermal conditions and it shows exceptional water stability and interesting proton-conducting properties.
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Two novel lead-based coordination polymers for luminescence sensing of anions, cations and small organic molecules

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Dalton Trans., 2020, 49,5695-5702
DOI: 10.1039/D0DT00533A, Paper
Xue-Yan Zhao, Bing Liang, Ke-Cai Xiong, Yu-Wen Shi, Si-Lei Yang, Ting-Yu Wei, Hui Zhang, Qing-Fu Zhang, Yan-Li Gai
A novel lead-based compound is reported as a multi-responsive luminescent sensor for detecting anions, cations and small organic molecules, especially Cr2O72−, CrO42−, Fe3+ and nitrobenzene.
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Oxaliplatin and [Pt(R,R-DACH)(panobinostat-2H)] show nanomolar cytotoxicity towards diffuse intrinsic pontine glioma (DIPG)

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Dalton Trans., 2020, 49,5703-5710
DOI: 10.1039/C9DT04862F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marie H. C. Boulet, Laura K. Marsh, Alison Howarth, Alice Woolman, Nicola J. Farrer
Oxaliplatin and the platinum(II) panobinostat complex (2) demonstrate nanomolar cytotoxicity towards diffuse intrinsic pontine glioma cells (DIPG); with 2 exhibiting improved solubility in comparison to panobinostat.
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Photo-reduction enables catalyst regeneration in Fenton reaction on an Fe2O3-decorated TiO2 nanotube-based photocatalyst

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00670J, Paper
Quanming Peng, Guiming Peng, Liangpeng Wu, Yaqian Chen, Bin Han, Qiucheng Su, Shijun Liu, Xinjun Li
Active Fe2+ sites of TNT(Pd)/Fe2O3 with a unique electronic structure for the Fenton reaction can be self-generated.
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A novel self-assembled-derived 1D MnO2@Co3O4 composite as a high-performance Li-ion storage anode material

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00980F, Paper
Zongtang Li, Xiao Lian, Mingzai Wu, Fangcai Zheng, Yuanhao Gao, Helin Niu
Manganese dioxide (MnO2) is a high-performance anodic material and applied widely in lithium-ion batteries (LIBs).
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Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds” by Shriparna Mukherjee et al., Dalton Trans., 2019, 48, 1040

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Dalton Trans., 2020, 49,5736-5737
DOI: 10.1039/C9DT03607E, Comment
Aarón H. Barajas-Aguilar, A. M. Garay-Tapia, Sergio J. Jiménez-Sandoval
Copper telluride sensitivity to laser power: effect on the Raman spectra.
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Reply to the ‘Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds”’ by A. H. Barajas-Aguilar, A. M. Garay-Tapia, and S. J. Jiménez-Sandoval, Dalton Trans., 2020, 49, DOI: 10.1039/C9DT03607E

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Dalton Trans., 2020, 49,5738-5740
DOI: 10.1039/D0DT00412J, Comment
Shriparna Mukherjee, Raju Chetty, P. V. Prakash Madduri, Ajaya K. Nayak, Krzysztof Wojciechowski, Tanmoy Ghosh, Kamanio Chattopadhyay, Satyam Suwas, Ramesh Chandra Mallik
In a communication to Dalton Transaction and in a paper in Journal of Physics: Condensed Matter, Aarón H. Barajas-Aguilar et al. have raised comments on our paper published earlier in Dalton Transactions.
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Syntheses, characterization and properties of two new dodeca-niobates presenting unprecedented features

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00953A, Paper
Ting-Ting Zhang, Po-Han Lin, Gui-Yang Yu, Xiao Zhang, Xiao-Bing Cui
Two new dodeca-niobate materials, K3[Nb2O2][H7SiNb12O40]·16H2O (1) and [Cu(en)2]9[(VNb12V1.69Nb0.31O42en0.31)2]·20.69H2O (2), have been obtained and characterized by IR, UV-Vis, XRD, and single crystal X-ray diffraction analysis.
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Retraction: Determination of chemical affinity of graphene oxide nanosheets with radionuclides investigated by macroscopic, spectroscopic and modeling techniques

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Dalton Trans., 2020, 49,5741-5741
DOI: 10.1039/D0DT90074E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Congcong Ding, Wencai Cheng, Yubing Sun, Xiangke Wang
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Retraction: Enhanced adsorption of Eu(III) on mesoporous Al2O3/expanded graphite composites investigated by macroscopic and microscopic techniques

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Dalton Trans., 2020, 49,5742-5742
DOI: 10.1039/D0DT90075C, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yubing Sun, Changlun Chen, Xiaoli Tan, Dadong Shao, Jiaxing Li, Guixia Zhao, Shubin Yang, Qi Wang, Xiangke Wang
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Enhancing the energy barrier by replacing the counterions in two holmium(III)-pentagonal bipyramidal single-ion magnets

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00905A, Paper
Lei-Lei Li, Hong-Dan Su, Shuang Liu, Wen-Zhen Wang
Upon changing the employed halide ions as counterions, Ueff increases from 290 K to 320 K in two HoIII-SIMs with pentagonal-bipyramidal structures.
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Pyridylamido hafnium complexes with a silylene bridge: synthesis and olefin polymerization

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01031F, Paper
Pavel S. Kulyabin, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Jo Ann M. Canich, John R. Hagadorn
Pyridylamido hafnium complexes with a silylene bridge were synthesized, characterized with X-ray crystal structure analysis and shown to polymerize 1-hexene and propene and copolymerize ethylene and 1-octene.
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Theoretical rationalization for the equilibrium between (μ–η2:η2-peroxido)CuIICuII and bis(μ-oxido)CuIIICuIII complexes: perturbational effects from ligand frameworks

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01001D, Paper
Tsukasa Abe, Yoshihito Shiota, Shinobu Itoh, Kazunari Yoshizawa
DFT calculations are carried out to investigate the geometric effects of the supporting ligands in the relative energies of the (μ–η2:η2-peroxido)CuIICuII complex 1 and the bis(μ-oxido)CuIIICuIII complex 2.
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Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01241F, Paper
Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Two families of lanthanide(III) phospholyl borohydride complexes are reported (carbon = grey, hydrogen = white, oxygen = red, boron = yellow, phosphorus = magenta, potassium = blue, lanthanides = teal; only BH4 hydrogens are shown for clarity).
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Conductivity and mixed conductivity of a novel dense diffusion barrier and the sensing properties of limiting current oxygen sensors

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00496K, Paper
Ke Shan, Zhong-Zhou Yi, Xi-Tao Yin, Davoud Dastan, Hamid Garmestani
First-principles calculations were used to explore the effect of various Y-doping levels on the electrical conductivity of SrTiO3.
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Self-assembled gold nanoparticles and amphiphile peptides: a colorimetric probe for copper(II) ion detection

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00844C, Paper
Juliane N. B. D. Pelin, Charlotte J. C. Edwards-Gayle, Herculano Martinho, Barbara B. Gerbelli, Valeria Castelletto, Ian W. Hamley, Wendel A. Alves
We show that arginine/phenylalanine based peptides can be used to control the aggregation of gold nanoparticles in different ways. The arrangement provides a colorimetric approach to detect Cu2+ ions in water.
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Copolymerization of CHO/CO2 catalyzed by a series of aluminum amino-phenolate complexes and insights into structure–activity relationships

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00726A, Paper
Hart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. Kerton
Five aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.
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Self-assembly of mixed-valent and heterometallic metallocycles: efficient catalyst for oxidation of alcohols to aldehydes with ambient air

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01340D, Communication
Ya-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan Li
Two mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...
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Water-locking molecule-assisted fabrication of natural-inspired Mg(OH)2 for high-efficient and economical uranium capture

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00618A, Paper
Hengbin Xu, Zhenyuan Bai, Milin Zhang, Jun Wang, Yongde Yan, Min Qiu, Jiaming Chen
With the depletion of uranium terrestrial deposits, researchers have focused on the development of adsorbents to extract radioactive uranium from seawater/wastewater. However, there are still considerable challenges to manipulate this...
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Accelerating charge transfer in ultrafine NiFe-LDHs/CB interface during electrocatalyst activation process for water oxidation

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00824A, Paper
Mengke Cai, Qinglin Liu, Yiyue Zhao, Zhenyu Wang, Yinle Li, Guangqin Li
Owing to coordinating of intriguing activity and conductivity, the hybrid compositions of layered double hydroxides (LDHs) and carbon-based materials have been extensively and widely applied to evolve oxygen gas for...
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Modulation of the driving forces for adsorption on MIL-101 analogues by decoration with sulfonic acid functional groups: superior selective adsorption of hazardous anionic dyes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00978D, Paper
Ji-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan Tong
MIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.
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Temperature-dependent hysteretic two-step spin crossover in two-dimensional Hofmann-type compounds

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00866D, Paper
Jun Tao, Yue Li, Min Liu, Zi-Shuo Yao
Hofmann-type spin-crossover (SCO) frameworks attract much attention due to their predictable structures and diverse SCO behaviours. In this paper, we report two isostructural two-dimensional (2D) Hofmann-type SCO frameworks [FeII(ppe)2MII(CN)4]·3H2O (ppe...
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Color Tuning in Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) Phosphors via Cation Substitution

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01130D, Paper
Huiling Zhang, Dengwen Yuan, Xiaoyun Mi, Xiuling Liu, Jun Lin
A series of Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) phosphors were prepared via high-temperature solid-state reaction process. The X-ray diffraction and Rietveld refinements were used to verify the incorporations of...
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1,2-Insertion Reactions of Alkynes into Ge–C Bonds of Arylbromogermylene

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01223H, Paper
Tomohiro Sugahara, Arturo Espinosa Ferao, Alicia Rey, Jing-Dong Guo, Shin Aoyama, Kazunobu Igawa, Katsuhiko Tomooka, Takahiro Sasamori, Daisuke Hashizume, Shigeru Nagase, Norihiro Tokitoh
1,2-insertion reactions of alkynes into the Ge–C bonds in dibromodigermenes afford stable crystalline bromovinylgermylenes. In contrast to previously reported Lewis-base-supported vinylgermylenes, the bromovinylgermylene obtained from reaction of the bromogermylene with...
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Multicolor tunable luminescence and energy transfer of core-shell structured SiO2@Gd2O3 microspheres co-activated with Dy3+/Eu3+ under single UV excitation

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper
Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
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The role of the excited state dynamic of the antenna ligand in the Lanthanide sensitization mechanism

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper
María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
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Influence of Eu valence in the optical activity of BaTiO3 decorated with CaF2 synthesized by microwave-assisted hydrothermal method

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01321H, Paper
Tatiane Strelow Lilge, Adriano Borges Andrade, Claudiane dos Santos Bezerra, Giordano Frederico da Cunha Bispo, Zélia Soares Macedo, Mario Lucio Lúcio Moreira, Mário Ernesto Giroldo Valerio
Inorganic hybrid materials are promising applications in absorbers and photon harvesting of solar irradiation, such as DSSC cell photoanodes. Moreover, the investigation of the interaction between the photoanode constituent materials...
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Probing the limits of linker substitution in aluminum MOFs through water vapor sorption studies: Mixed-MOF instead of mixed-linker CAU-23 and MIL-160 materials

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01044H, Paper
Carsten Schlüsener, Dustin Nils Jordan, Mergime Xhinovci, Tobie J. Matemb Ma Ntep, Alexa Schmitz, Beatriz Giesen, Christoph Janiak
We report the systematic study on the possibility of forming mixed-linker MOFs spanning between the aluminum metal-organic frameworks CAU-23 and MIL-160 with their 2,5-thiophenedicarboxylate (TDC) and 2,5 furandicarboxylate (FDC) linkers,...
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MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01054E, Paper
Sankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra Jana
MnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.
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Three diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2: influences of co-substitution on the crystal structure

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01070G, Paper
Ming Wen, Cong Hu, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie Pan
We reported the synthesis, structure, characterization and first-principles calculations of diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2, and studied the influences of co-substitution on the crystal structure.
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Influence of magnetic dilution on relaxation processes in a solid solution comprising tetrahedral Co/ZnII complexes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01058H, Paper
Magdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-Fitas
Dilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.
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Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(II) template

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00466A, Paper
Manas Khatua, Bappaditya Goswami, Subhas Samanta
A Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.
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