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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Single-ion magnetism in novel Btp-based cobalt complexes of different charge

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02338B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez López
By deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Fourth wave scare: Covid-19 cases in Asia surpass 100 million, India, Japan, South Korea worst-hit

The highly contagious but less deadly BA.2 sub-variant of Omicron has pushed the figures to greater highs in recent weeks in South Korea, China and Vietnam.




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Media & Freebies: a murky connection



  • Siddhartha P Saikia

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It's all in the interpretation




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How to fight compassion fatigue

Getting over the diminished capacity to empathise with or feel compassion for others




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Confessions of an impractical person

How one ignored the imperfection of life by finding solace in the perfection of art




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A dictionary at hand

Consult it regularly to develop your own vocabulary




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Freewheeling exploration with a bicycle

The machine was a precious possession, a symbol of hard work and determination




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A lie and its deleterious effects

Lying often results in guilt, anxiety, or the fear of being caught




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A women-only conversation, but for all

Why do we descend to the misogynistic use of ‘girlish’ and ‘womanly’ as labels to demean some of the complex disciplines?




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Real is rational and rational is real

They may seem inextricably intertwined, but their relationship is a complex interplay of a myriad forces




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Foreign fascination

Exploring the dream of crossing the borders brought on by inquisitiveness and curiosity




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Enhancing radiotherapy with MRI

Bas Raaymakers describes how MRI can help target tumours with improved accuracy




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Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur

Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign




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Heavy fog affects 21 flights at Kempegowda International Airport in Devanahalli in Bengaluru

There were more than 15 delays, and six flights diverted




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Karnataka makes online applications mandatory for private aided school teacher recruitment

DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently




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AITUC celebrates 105th Foundation Day in Mysuru




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Tension erupts in Mandya over entry of Dalits into temple

Former MLA M. Srinivas took the initiative in leading the entry of Dalits into the temple. However, a small group of persons opposed the move, took away the processional deity and tore down the temple plaque and board.




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Siddaramaiah, Shivakumar term PM’s allegations of raising ₹700 cr. to fund Maharashtra polls as a ‘lie’




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Cheluvarayaswamy accuses HDK of collecting ₹1,000 cr. from steel industries to fund elections; JD(S) terms it a strategy to divert attention from ‘excise scam’

After Prime Minister Narendra Modi accused the Congress government of collecting ₹700 crore from excise sources to fund the Maharashtra elections, it was the turn of N. Cheluvarayaswamy




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B.S. Yediyurappa says he will respond to allegations of corruption after bypolls




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Medical malpractice destroys profession’s nobility, says BLDE Vice-Chancellor




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Guarantee money is deposited to beneficiaries’ bank accounts when election is around the corner, alleges B.Y. Vijayendra




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Karnataka Minister Zameer Ahmed Khan kicks up another row with ‘racist’ remark about Union Minister H.D. Kumaraswamy

The Housing Minister is already facing flak for the wakf controversy that has snowballed into a big issue in Karnataka




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Karnataka Ministers seek action against Union Minister Pralhad Joshi for ‘agent’ comment on retired high court judge Michael D’Cunha

The two Ministers told the Governor that Mr. Joshi made a deliberate attempt to politicise and taint a constitutionally sanctioned inquiry, betraying public trust in the process




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BJP MLA B.P. Yatnal walks out of event after crowd objects to political speech over mention of Waqf land row

Mr. Yatnal raised the issue of waqf during an Allammaprabhu temple event




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ANF conducts combing operations in Sringeri




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Tribals seek internal reservation, FRA implementation

A memorandum will be submitted to Chief Minister Siddaramaiah during his visit to H.D. Kote on Tuesday




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Karnataka School Examination and Assessment Board directs students from unauthorised schools not to register for SSLC exam this year




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HMT forest land denotification: Forest Department issues notice to former and current officers




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Chief Minister Siddaramaiah has no moral right to seek resignation of Prime Minister Narendra Modi, says Union Minister

Pralhad Joshi was responding to a challenge by Mr. Siddaramaiah to the PM to prove charges of corruption in Karnataka or resign.




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Department of Pre-University Education to train PU students for K-CET and NEET in Shivamogga

Training programme to be inaugurated formally in Shivamogga tomorrow




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State-level mock Parliament competition for high school and PU students in Shivamogga tomorrow




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Sandur bypolls: Ballari Deputy Commissioner appeals to voters to exercise franchise




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Allocation for development works nails BJP’s lie of resource crunch in State, says Siddaramaiah




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Preparations complete for bypolls in Shiggaon Assembly segment




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Youth wins RCU swimming championship




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Rajkumar Patil Telkur refutes allegations against KKHRACS




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Judicial Commission visits MUDA office in Mysuru

The State government constituted the Commission headed by Justice P.N. Desai to look into the alleged irregularities in the allotment of sites by the MUDA




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JD(S) demands Zameer’s resignation for his remarks against HDK




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Congress asks police to book Krishna for ‘false’ accusations against CM

KPCC spokesperson M. Lakshman files a complaint with the Devaraja Police in this regard against activist Snehamayi Krishna




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Farmers demand revocation of decades-old waqf notices




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Karnataka byelections: All set for polling today after weeks of high-decibel campaign

Though the results have little consequence in the number game for the government, the stakes are high for individual leaders




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Indigenous audibilities : music, heritage, and collections in the Americas / Amanda Minks.

New York, NY : Oxford University Press, [2024]




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The effects of COVID-19 on early childhood education [electronic resource] : research and implications / by Raquel Plotka and Ruth Guirguis.

[Bradford/] : Ethics International Press Ltd, 2024.




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Handbook of art therapy [electronic resource] / edited by Cathy A. Malchiodi.

New York : Guilford Press, 2012.




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Integrated motivational interviewing and cognitive behavioral therapy (ICBT) [electronic resource] : a practitioners guide / Joseph Hyde, Maria Torres, Win Turner, R. Lyle Cooper.

Hoboken, New Jersey : John Wiley & Sons, Inc., [2024]




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Solution-focused brief therapy with clients managing trauma [electronic resource] / Adam Froerer, Jacqui von Cziffra-Bergs, Johnny Kim, Elliott Connie.

New York, NY : Oxford University Press , 2018.