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Trinuclear Mn2+/Zn2+ based microporous coordination polymers as efficient catalysts for ipso-hydroxylation of boronic acids

Dalton Trans., 2020, 49,5454-5462
DOI: 10.1039/D0DT00794C, Paper
Sanchay J. Bora, Rima Paul, Anurag Dutta, Shyam Goswami, Ankur K. Guha, Ashim J. Thakur
Two efficient catalysts based on trinuclear Mn(II)/Zn(II) clusters were synthesized and used for ipso-hydroxylation of phenylboronic acids into the corresponding phenols with excellent yields.
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Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(I) carbonyl complex

Dalton Trans., 2020, 49,5463-5470
DOI: 10.1039/C9DT04878B, Paper
Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam
Photolysis of [Mn(C^N)(CO)4] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)3(N2)].
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Templated syntheses of heterometal tungsten–cobalt–sulfur clusters with different nuclearities

Dalton Trans., 2020, 49,5523-5530
DOI: 10.1039/D0DT00765J, Paper
Jia-Ting Guo, Xu-Dong Chen
A series of heterometal tungsten–cobalt–sulfur clusters with different nuclearities have been synthesized rationally using a chelating template.
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Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

Dalton Trans., 2020, 49,5684-5694
DOI: 10.1039/D0DT01144D, Paper
Thomas Scattolin, Claudio Santo, Nicola Demitri, Luciano Canovese, Fabiano Visentin
We have examined in depth the features of oxidative addition of (E)-1,2 ditosylethene on palladium(0) complexes bearing picolyl-N-heterocyclic carbenes.
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Two novel lead-based coordination polymers for luminescence sensing of anions, cations and small organic molecules

Dalton Trans., 2020, 49,5695-5702
DOI: 10.1039/D0DT00533A, Paper
Xue-Yan Zhao, Bing Liang, Ke-Cai Xiong, Yu-Wen Shi, Si-Lei Yang, Ting-Yu Wei, Hui Zhang, Qing-Fu Zhang, Yan-Li Gai
A novel lead-based compound is reported as a multi-responsive luminescent sensor for detecting anions, cations and small organic molecules, especially Cr2O72−, CrO42−, Fe3+ and nitrobenzene.
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Oxaliplatin and [Pt(R,R-DACH)(panobinostat-2H)] show nanomolar cytotoxicity towards diffuse intrinsic pontine glioma (DIPG)

Dalton Trans., 2020, 49,5703-5710
DOI: 10.1039/C9DT04862F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marie H. C. Boulet, Laura K. Marsh, Alison Howarth, Alice Woolman, Nicola J. Farrer
Oxaliplatin and the platinum(II) panobinostat complex (2) demonstrate nanomolar cytotoxicity towards diffuse intrinsic pontine glioma cells (DIPG); with 2 exhibiting improved solubility in comparison to panobinostat.
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Photo-reduction enables catalyst regeneration in Fenton reaction on an Fe2O3-decorated TiO2 nanotube-based photocatalyst

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00670J, Paper
Quanming Peng, Guiming Peng, Liangpeng Wu, Yaqian Chen, Bin Han, Qiucheng Su, Shijun Liu, Xinjun Li
Active Fe2+ sites of TNT(Pd)/Fe2O3 with a unique electronic structure for the Fenton reaction can be self-generated.
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A novel self-assembled-derived 1D MnO2@Co3O4 composite as a high-performance Li-ion storage anode material

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00980F, Paper
Zongtang Li, Xiao Lian, Mingzai Wu, Fangcai Zheng, Yuanhao Gao, Helin Niu
Manganese dioxide (MnO2) is a high-performance anodic material and applied widely in lithium-ion batteries (LIBs).
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Syntheses, characterization and properties of two new dodeca-niobates presenting unprecedented features

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00953A, Paper
Ting-Ting Zhang, Po-Han Lin, Gui-Yang Yu, Xiao Zhang, Xiao-Bing Cui
Two new dodeca-niobate materials, K3[Nb2O2][H7SiNb12O40]·16H2O (1) and [Cu(en)2]9[(VNb12V1.69Nb0.31O42en0.31)2]·20.69H2O (2), have been obtained and characterized by IR, UV-Vis, XRD, and single crystal X-ray diffraction analysis.
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Conductivity and mixed conductivity of a novel dense diffusion barrier and the sensing properties of limiting current oxygen sensors

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00496K, Paper
Ke Shan, Zhong-Zhou Yi, Xi-Tao Yin, Davoud Dastan, Hamid Garmestani
First-principles calculations were used to explore the effect of various Y-doping levels on the electrical conductivity of SrTiO3.
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Self-assembled gold nanoparticles and amphiphile peptides: a colorimetric probe for copper(II) ion detection

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00844C, Paper
Juliane N. B. D. Pelin, Charlotte J. C. Edwards-Gayle, Herculano Martinho, Barbara B. Gerbelli, Valeria Castelletto, Ian W. Hamley, Wendel A. Alves
We show that arginine/phenylalanine based peptides can be used to control the aggregation of gold nanoparticles in different ways. The arrangement provides a colorimetric approach to detect Cu2+ ions in water.
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Copolymerization of CHO/CO2 catalyzed by a series of aluminum amino-phenolate complexes and insights into structure–activity relationships

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00726A, Paper
Hart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. Kerton
Five aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.
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Self-assembly of mixed-valent and heterometallic metallocycles: efficient catalyst for oxidation of alcohols to aldehydes with ambient air

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01340D, Communication
Ya-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan Li
Two mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...
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Modulation of the driving forces for adsorption on MIL-101 analogues by decoration with sulfonic acid functional groups: superior selective adsorption of hazardous anionic dyes

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00978D, Paper
Ji-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan Tong
MIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.
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1,2-Insertion Reactions of Alkynes into Ge–C Bonds of Arylbromogermylene

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01223H, Paper
Tomohiro Sugahara, Arturo Espinosa Ferao, Alicia Rey, Jing-Dong Guo, Shin Aoyama, Kazunobu Igawa, Katsuhiko Tomooka, Takahiro Sasamori, Daisuke Hashizume, Shigeru Nagase, Norihiro Tokitoh
1,2-insertion reactions of alkynes into the Ge–C bonds in dibromodigermenes afford stable crystalline bromovinylgermylenes. In contrast to previously reported Lewis-base-supported vinylgermylenes, the bromovinylgermylene obtained from reaction of the bromogermylene with...
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The role of the excited state dynamic of the antenna ligand in the Lanthanide sensitization mechanism

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper
María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
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Luminescent organic dyes containing a phenanthro[9,10-D]imidazole core and [Ir(N^C)(N^N)]+ complexes based on the cyclometalating and diimine ligands of this type

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper
Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
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Influence of magnetic dilution on relaxation processes in a solid solution comprising tetrahedral Co/ZnII complexes

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01058H, Paper
Magdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-Fitas
Dilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.
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Amorphous Ni–Fe–Se hollow nanospheres electrodeposited on nickel foam as a highly active and bifunctional catalyst for alkaline water splitting

Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04755G, Paper
Xuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang Yin
The electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.
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Rapid mechanochemical synthesis of metal–organic frameworks using exogenous organic base

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01240H, Paper
Zihao Wang, Zongzhe Li, Marcus Ng, Phillip J. Milner
We describe the mechanochemical, solvent-free synthesis of metal–organic frameworks using liquid organic base for the first time.
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Selenotungstates incorporating organophosphonate ligands and metal ions: synthesis, characterization, magnetism and catalytic efficiency in Knoevenagel condensation reaction

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00444H, Paper
Jingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping Wang
Three sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...
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Luminescent lanthanide complexes with a pyridine-bis(carboxamide)-bithiophene sensitizer showing wavelength-dependent singlet oxygen generation

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01034K, Paper
Katherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-Dias
A new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.
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Amorphous Co-doped MoSex Effectively Enhances Photocatalysis in Visible Light

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01295E, Paper
Rui Feng, Rong Wu, Yuncheng Cao, Xiaolin Guo, Xu Ma
Molybdenum selenide has great potential for degradation of water pollutants,but its performance is limited by the active sites and recombination of photogenerated electron-hole pairs. In this study, amorphous Co-doped MoSex...
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Tin based organic-inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01401J, Paper
Zhenhong Wei, Xiuli You, Jiaojiao Yao
Organic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...
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Oxacalix[4]arene Derived Dual Sensing Fluorescence Probe for the Detection of As (V) and Cr (VI) Oxyanions in Aqueous Media

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00452A, Paper
Shuvankar Dey, Anshu Kumar, Pradip Mondal, Krunal M. Modi, Deepak Chopra, Vinod K. Jain
An oxacalix[4]arene-Ce (III) complex viz. L-Ce(III) has been introduced for selective detection of As (V) and Cr (VI) oxyanions in aqueous medium. Binding mode of L-Ce(III) + AsO43-/ CrO42- was...
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A molecular boron cluster-based chromophore with dual emission

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00826E, Paper
Kierstyn P. Anderson, Mary A. Waddington, Gary J. Balaich, Julia M. Stauber, Nicholas A. Bernier, Justin R. Caram, Peter I. Djurovich, Alexander M. Spokoyny
Bromination of the luminescent borane, anti-B18H22, via electrophilic substitution using AlCl3 and Br2, yields the monosubstituted derivative 4-Br-anti-B18H21 as an air-stable crystalline solid.
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Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper
Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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Heat-resistant Pb(II)-based X-ray scintillating metal-organic frameworks for sensitive dosage detection via the aggregation-induced luminescent chromophore

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication
Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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Highly cytotoxic gold(I)-phosphane dithiocarbamate complexes trigger an ER stress-dependent immune response in ovarian cancer cells

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01411G, Paper
Hai Van Le, Maria Babak, Muhammad Ali Ehsan, Mohammad Altaf , Lisa Reichert, Artem Gushchin, Wee Han Ang, Anvarhusein Isab
Ovarian cancer is a highly aggressive disease which is treated by surgery and platinum chemotherapy. However, a significant proportion of treated patients develop resistance to platinum treatment resulting in tumor...
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Sequenced cooking that really works

I went to a talk by a cookbook author who said she’d figured out a system for efficient home cooking: big pots of beans and soup, dishes that could be frozen and reheated. The concepts would have been obvious to any old-fashioned cook, and they are good, practical concepts. But her specific advice was so

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Big History Ebooks Now Available For WH & BHP Classes

Cynthia Stokes Brown wrote BIG HISTORY, SMALL WORLD to help Big History Project students and their teachers, many of whom she knew and befriended in the earliest days of big history education. David Christian's THIS FLEETING WORLD is widely used in AP World History as well as big history courses. BIG HISTORY: A BERKSHIRE ESSENTIAL is a collection of essays by

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T.S. Eliot “Got Cheese” Campaign Announced

Great Barrington, MA - COVID-19 has delayed the launch of a record-setting marketing deal expected to boost international appreciation of English and European cheeses. The image and words of the Nobel Prize winning poet T S Eliot, as well as characters from the musical Cats, will be used to promote cheese and cheese products throughout the world.

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The Origins of Berkshire Publishing’s Chinese Name, 宝库山

When I meet someone Chinese, in Beijing or New York or London, they often exclaim over our name. Publishers tell me how exactly right its meaning - “treasure mountain library” - is, especially for a press known for encyclopedias on global topics. I explain that 宝库山 was carefully crafted by a group of friends who

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Selma and the Liuzzo murder trials: the first modern civil rights convictions / by James P. Turner

Dewey Library - KF224.K7 T87 2018




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Our selfish tax laws: toward tax reform that mirrors our better selves / Anthony C. Infanti

Dewey Library - KF6289.I49 2018




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Real estate finance in a nutshell / Vada Waters Lindsey, Associate Professor of Law, Marquette University Law School

Rotch Library - KF695.Z9 L56 2018




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Practitioner's guide to project-based vouchers: a successor to the Beginner's guide / Sarah Molseed and Julie S. McGovern

Rotch Library - KF5735.M654 2018




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No property in man: slavery and antislavery at the nation's founding / Sean Wilentz

Hayden Library - KF4545.S5 W59 2018




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Separate: the story of Plessy v. Ferguson, and America's journey from slavery to segregation / Steve Luxenberg

Hayden Library - KF223.P56 L88 2019




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The essential guide to intellectual property / Aram Sinnreich

Dewey Library - K1401.S56 2019




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The curse of bigness: antitrust in the new Gilded Age / Tim Wu

Dewey Library - KF1649.W88 2018




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Authors, users, and pirates: copyright law and subjectivity / James Meese

Dewey Library - K1420.5.M44 2018




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Armed conflict and forcible displacement: individual rights under international law / edited by Elena Katselli Proukaki

Dewey Library - KZ6530.A75 2018




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Silenced victims of wartime sexual violence / Olivera Simić

Dewey Library - KZ7162.S56 2018




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Habeas data: privacy vs. the rise of surveillance tech / Cyrus Farivar

Dewey Library - KF1262.F37 2018




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Transactional intellectual property: from startups to public companies / Richard S. Gruner, professor of law, John Marshall Law School), Shubha Ghosh (Crandall Melvin Professor of Law, director, Technology Commercialization Law Program & Syracuse Inte

Dewey Library - KF2980.G78 2018




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Land use planning and development regulation law / Julian Conrad Juergensmeyer (professor and Ben F. Johnson Jr. Chair in Law, Georgia State University College of Law, adjunct professor in city and regional planning, Georgia Institute of Technology), Tho

Rotch Library - KF5698.J84 2018




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Secrecy, privacy and accountability: challenges for social research / Mike Sheaff

Online Resource




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Research methods in legal translation and interpreting: crossing methodological boundaries / edited by Łucja Biel, Jan Engberg, M. Rosario Martín Ruano, and Vilelmini Sosoni

Online Resource




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Women as constitution-makers: case studies from the new democratic era / edited by Ruth Rubio-Marín, Helen Irving

Dewey Library - K3243.W66 2019