A method for isolating 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD) solids from an isolated feed slurry formed in a TMCD process comprising TMCD, a liquid phase, and impurities by (a) treating the isolated feed slurry in a product isolation zone to produce an isolated TMCD product wet cake, a mother liquor, and impurities; wherein the product isolation zone can comprise at least one rotary pressure drum filter.

Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid using an extractive distillation column. A diluted acid stream, comprising less than 30 wt. % acetic acid, is used as the extractive agent and is fed at a point above the crude feed stream. The column yields a residue that comprises ethanol, acetic acid, and water. The diluted acid stream may be separated from the residue and returned to the extractive distillation column.

The present invention is directed to processes for the recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid using a low energy process. The crude ethanol product is separated in one or more columns. At least one of the columns is operated at a controlled pressure to enhance separation of ethanol and organics. In one embodiment, there are at least two columns that operate at controlled pressures.

A process for selective formation of ethanol from acetic acid by hydrogenating acetic acid in the presence of a catalyst comprises a first metal on an acidic support. The acidic support may comprise an acidic support material or may comprise an support having an acidic support modifier. The catalyst may be used alone to produced ethanol via hydrogenation or in combination with another catalyst. In addition, the crude ethanol product is separated to obtain ethanol.

A process is disclosed for producing ethanol comprising contacting acetic acid and hydrogen in a reactor in the presence of a catalyst comprising a binder and a mixed oxide comprising nickel and tin.

Disclosed herein are processes for alcohol production by reducing an esterification product, such as ethyl acetate. The processes comprise esterifying acetic acid and an alcohol such as ethanol to produce an esterification product. The esterification product may be recovered using an extractive separation. The esterification product is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture.

A catalyst composition for converting ethanol to higher alcohols, such as butanol, is disclosed. The catalyst composition comprises at least one alkali metal, at least a second metal and a support. The second metal is selected from the group consisting of palladium, platinum, copper, nickel, and cobalt. The support is selected from the group consisting of Al2O3, ZrO2, MgO, TiO2, zeolite, ZnO, and a mixture thereof.

A method of making alcohols involves forming of alcohol esters from liquid alkane halides and a solution of metallic salts of organic acids to produce gaseous alcohol esters for reaction with magnesium or metal hydroxides to form the alcohol and the metal salt of the organic acids. In an improvement method liquid phase alcohol esters instead of gaseous alcohol esters are produced from liquid alkane halides and a solution of metal salts of organic acids whose alkane esters are less soluble in water than that of the alkane halide and treating of the alcohol ester formed with magnesium or metal hydroxides to form the alcohol and the metal salt of the organic acids.

The present invention relates to a method for preparing menthone, starting from isopulegol, using specific homogeneous catalysts.

A process for obtaining an industrially useful 2-chloromethylbenzaldehyde-containing liquid composition at a high yield is provided. More specifically, a process for producing 2-chloromethylbenzaldehyde comprising step (A) of mixing 1-dichloromethyl-2-chloromethylbenzene and sulfuric acid having a concentration of 84.5% by weight or more; and step (B) of mixing a mixture obtained in step (A) and water is provided.

A para-methoxy protected benzaldehyde useful in preparation of treprostinil, and of formula: (Formula (1)) is prepared by subjecting to Claisen re-arrangement a substituted benzaldehyde of formula (1a): (Formula (Ia)) to form the m-hydroxy-substituted benzaldehyde of formula (1b): (Formula (Ib)) and then reacting compound (1b) with a p-methoxybenzyl (PMB) compound to form a PMB-substituted benzaldehyde of formula (1).

The present invention relates to an apparatus for coproducting iso-type reaction product and alcohol from olefin, and a method for coproducting using the apparatus, in which the hydroformylation reactor provides a sufficient reaction area due to the broad contact surface area between the olefin and the synthesis gases that are the raw materials by a distributor plate installed in the reactor, and the raw materials can be sufficiently mixed with the reaction mixture due to the circulation of the reaction mixture so that the efficiency of the production of the aldehyde is excellent; and also the hydrogenation reactor suppresses the side reaction so that the efficiency for producing aldehyde and alcohol are all increased, and also iso-type reaction product and alcohol can be efficiently co-produced.

In a process for producing phenol, cyclohexylbenzene is contacted with oxygen in the presence of an oxidation catalyst comprising a cyclic imide under oxidation conditions effective to produce a product comprising cyclohexylbenzene hydroperoxide and unreacted cyclic imide catalyst. At least a portion of the product is contacted with a cleavage catalyst under conditions effective to convert at least a portion of the cyclohexylbenzene hydroperoxide into a second product comprising further unreacted cyclic imide catalyst, phenol, and cyclohexanone. A portion of the further unreacted cyclic imide catalyst may then be removed from the second product and optionally recycled back to the oxidation step.

Disclosed herein are processes for alcohol production by reducing ethyl acetate produced by hydrogenating acetic acid in the presence of a suitable catalyst. The product of the acetic acid hydrogenation is fed directly to a decanter to separate the hydrogenation product into an aqueous phase comprising water and ethanol and an organic phase comprising ethyl acetate. The organic phase is reduced with hydrogen in the presence of a catalyst to obtain a crude reaction mixture comprising the alcohol, in particular ethanol, which may be separated from the crude reaction mixture. Thus, ethanol may be produced from acetic acid through an ethyl acetate intermediate without an esterification step. This may reduce the recycle of ethanol in the hydrogenolysis process and improve ethanol productivity.

A method for producing a phenylphosphonic acid metal salt composition, including reacting a phenylphosphonic acid compound (a) with a metal salt, metal oxide or metal hydroxide (b) that is present in an amount beyond the equivalent, the phenylphosphonic acid metal salt composition containing phenylphosphonic acid metal salt, and a surplus amount of the metal salt, the metal oxide or the surplus metal hydroxide (b). A crystal nucleating agent comprises the phenylphosphonic acid metal salt composition produced by the method.

Disclosed is a method for preparing a compound of Formula 1 wherein Q and Z are as defined in the disclosure comprising distilling water from a mixture comprising a compound of Formula 2, a compound of Formula 3, a base comprising at least one compound selected from the group consisting of alkaline earth metal hydroxides of Formula 4 wherein M is Ca, Sr or Ba, alkali metal carbonates of Formula 4a wherein M1 is Li, Na or K, 1,5-diazabicyclo[4.3.0]non-5-ene and 1,8-diazabicyclo[5.4.0]undec-7-ene, and an aprotic solvent capable of forming a low-boiling azeotrope with water. Also disclosed is a method for preparing a compound of Formula 2 comprising (1) forming a reaction mixture comprising a Grignard reagent derived from contacting a compound of Formula 5 wherein X is Cl, Br or I with magnesium metal or an alkylmagnesium halide in the presence of an ethereal solvent, and then (2) contacting the reaction mixture with a compound of Formula 6 wherein Y is OR11 or NR12R13, and R11, R12 and R13 are as defined in the disclosure. Further disclosed is a method for preparing a compound of Formula 7 wherein Q and Z are as defined in the disclosure, using a compound of Formula 1 characterized by preparing the compound of Formula 1 by the method disclosed above or using a compound of Formula 1 prepared by the method disclosed above.

A process for preparing isophorone (3,5,5-trimethyl-2-cyclohexen-1-one) is provided wherein distillation vapors from the work-up of product fractions are recycled to earlier stages of operation of the process.

An optically active bicyclic compound is efficiently produced by optical resolution using an optically active amine.

Disclosed are processes relating to the production of polyglycerol ethers of fatty alcohols, in particular, one step process using fatty alcohol and glycerine to synthesize polyglycerides of fatty alcohols will provide a 100% renewable surfactant that is cost effective efficient and CMR free. The synthetic methods mentioned in prior art uses hazardous chemicals as glycidyl ethers, epichlorohydrin that are listed as CMR and known carcinogens and hazardous to handle.

A polyether polyol based on renewable materials is obtained by the in situ production of a polyether from a hydroxyl group-containing vegetable oil, at least one alkylene oxide and a low molecular weight polyol having at least 2 hydroxyl groups. The polyol is produced by introducing the hydroxyl group-containing vegetable oil, a catalyst and an alkylene oxide to a reactor and initiating the alkoxylation reaction. After the alkoxylation reaction has begun but before the reaction has been 20% completed, the low molecular weight polyol having at least 2 hydroxyl groups is continuously introduced into the reactor. After the in situ made polyether polyol product having the desired molecular weight has been formed, the in situ made polyether polyol is removed from the reactor. These polyether polyols are particularly suitable for the production of flexible polyurethane foams.

Processes are disclosed for the conversion of a carbohydrate source to hexamethylenediamine (HMDA) and to intermediates useful for the production of hexamethylenediamine and other industrial chemicals. HMDA is produced by direct reduction of a furfural substrate to 1,6-hexanediol in the presence of hydrogen and a heterogeneous reduction catalyst comprising Pt or by indirect reduction of a furfural substrate to 1,6-hexanediol wherein 1,2,6-hexanetriol is produced by reduction of the furfural substrate in the presence of hydrogen and a catalyst comprising Pt and 1,2,6-hexanediol is then converted by hydrogenation in the presence of a catalyst comprising Pt to 1,6 hexanediol, each process then proceeding to the production of HMDA by known routes, such as amination of the 1,6 hexanediol. Catalysts useful for the direct and indirect production of 1,6-hexanediol are also disclosed.

The present invention relates to a process for heat integration in the preparation of saturated C3-C20-alcohols, in which a hydrogenation feed comprising at least one C3-C20-aldehyde is hydrogenated in the presence of a hydrogen-comprising gas in a hydrogenation zone and a discharge is taken off from the hydrogenation zone and subjected to distillation in at least one distillation column to give a fraction enriched in saturated C3-C20-alcohols.

A filtration method is disclosed for recovering purified polyether polyol comprising the steps of providing an aqueous solution of a polyether polyol containing an alkali metal catalyst residual formed from a transesterification process utilizing an alkali metal catalyst, contacting the aqueous solution with a stoichiometric excess of magnesium sulfate, magnesium sulfite or a combination thereof to form a second aqueous solution, wherein said stoichiometric excess is based on the amount of said alkali metal catalyst residual. Water is removed from the second aqueous solution at a temperature above a set limit of said polyether polyol to produce a dehydrated slurry containing a polyether polyol phase substantially free of residual alkali metal and a precipitated solid phase comprising sulfate and/or sulfite salts of the alkali metal catalyst, magnesium hydroxide, and excess magnesium sulfate and/or sulfite, wherein the particle size distribution of said precipitated solid phase is controlled to minimize the amount of particles therein that are smaller than 3 microns. The dehydrated slurry is then passed through a filtration system to separate the polyether polyol phase from the precipitated solid phase.

An improved method for recovering a purified polyether polyol comprising the steps of providing an aqueous solution of a polyether polyol containing an alkali metal catalyst residual formed from a transesterification process, contacting the aqueous solution with a stoichiometric excess of magnesium sulfate to form a second aqueous solution, removing water from said second aqueous solution at a temperature above the melt temperature of said polyether polyol to produce a dehydrated slurry containing a molten polyether polyol phase essentially free of residual alkali metal and a precipitated solid phase comprising sulfate and/or sulfite salts of the alkali metal catalyst, magnesium hydroxide, and excess magnesium sulfate and/or sulfide, passing the dehydrated slurry of through a filtration system comprising a filtration press to separate the molten polyether polyol phase from the precipitated solid phase, wherein the filtration press is treated with a filter aid that is essentially free of transition metal oxide content, separating the molten polyether polyol phase substantially free of water, residual alkali metal catalyst and transition metal contaminants from the precipitated solid phase and recovering polyether polyol from the separated polyether polyol phase.

A process for preparation of 2-phenyl ethanol by catalytic hydrogenation of styrene oxide using a catalyst consisting of Pd (II) on basic inorganic support is investigated. The present invention comprises development of new Pd based catalysts. The present method yields 2-phenyl ethanol in 98% selectivity at total conversion of styrene oxide. The present process represents an environment friendly alternative to conventionally used methods in industry and eliminates the reduction step for catalyst preparation. In the present invention the active catalyst is generated in situ during the hydrogenation of styrene oxide. In addition, Pd (II) supported catalysts do not catch fire (non pyrophoric), can be stored under ambient conditions and produce very less or no dust which makes said catalysts suitable for industrial application.

A method of removing alkalinity and salt from a nitroaromatic product downstream of water washing to remove mineral acids and alkaline washing to remove salts of organic acids, comprises washing the product stream with an acidic aqueous solution, prior to the step of removing excess organic reactant, by steam stripping or distillation. Acid removed from the stripper or column is recycled back for use in the acidic washing. The acidic washing is done instead of the neutral washing step of the prior art. It removes residual salt and decreases the level of entrained colloidal water in the nitroaromatic product.

A method for operating an internal combustion engine in which a speed-based feature of the internal combustion engine, which is correlated with an indicated mean effective pressure of the fuel, is determined during the warm-up of the internal combustion engine and an ideal fuel quantity, which is to be injected into at least one combustion chamber of the internal combustion engine during the warm-up, is ascertained therefrom.

There is provided an engine restart control device. A controller is configured to stop an engine which is adapted to generate a driving force for running a vehicle when a predetermined stop condition is met and configured to restart the engine when a predetermined restart condition is met after stopping the engine. A steering torque detector is configured to detect a steering torque of a steering wheel which is adapted to be operated by a driver. The controller includes an origin torque setting unit configured to set the steering torque detected by the steering torque detector when the predetermined stop condition is met and the engine is stopped as an origin torque. The controller restarts the engine when the steering torque detected by the steering torque detector exceeds a predetermined threshold with reference to the origin torque set by the origin torque setting unit.

Apparatus for orientating a user in a space wherein the space comprises a plurality of zones of which only certain zones constitute functional zones wherein each functional zone includes a first type device containing information relating to the position of the zone in the space and wherein the first type device is reactive to the presence of a second type device associated with the user to provide the user with the information to determine the orientation of the user in the space. A method of orientating the user within the space and guiding the user toward one or more features in the space is also disclosed.

Disclosed is a feature for a vehicle that enables taking precautionary actions in response to conditions on the road network around or ahead of the vehicle, in particular, a blind intersection along a section of road. A database that represents the road network is used to determine locations where a blind intersection is located along a section of road. Then, precautionary action data is added to the database to indicate a location at which a precautionary action is to be taken about the blind intersection located along the section of road. A precautionary action system installed in a vehicle uses this database, or a database derived therefrom, in combination with a positioning system to determine when the vehicle is at a location that corresponds to the location of a precautionary action. When the vehicle is at such a location, a precautionary action is taken by a vehicle system as the vehicle is approaching a blind intersection.

Dive computers in accordance with embodiments of the invention are disclosed that store information concerning a dive site. The stored information can be accessed during the dive to provide information concerning such things as points of interest and/or hazards. One embodiment of the invention includes a processor, memory connected to the processor, a pressure transducer connected to the processor and configured to measure depth, and a display connected to the processor. In addition, the memory contains factual information concerning a dive site, and the processor is configured to display at least a portion of the stored factual information concerning the dive site via the display.

A method of adjusting a speed of a mobile machine is provided. Image data of a location is collected where currently generated sensor data and previously generated sensor data indicate a discontinuity in sensor data. The image data is analyzed to determine if a non-motion blur score for the image data is above a threshold value. Then, a speed of the mobile machine is adjusted based on a determination that the non-motion blur score is above the threshold value.

An apparatus for estimating a travel path of a vehicle is mounted on the vehicle; and includes: an object detection device that detects an object lying ahead of the vehicle; a stationary object detection device that determines whether a detected object is a stationary object; a device that calculates an approximate straight line indicating a path of the stationary object from the temporal positional data for the stationary object projected on two-dimensional coordinates using a vehicle position as a starting point; a device that calculates a orthogonal line which passes through a midpoint in the temporal positional data for the stationary object and goes straight with respect to the approximate straight line on the two-dimensional coordinates; and a device that calculates a vehicle turning radius from an intersection point where the orthogonal line intersects with a x axis.

A method for illustrating an aircraft flight plan comprising at least one waypoint on a flight display of a flight deck of an aircraft, where the method may include displaying on the flight display of the flight deck some type of display indicia that indicates the suitability of locations for future waypoints.

Traffic information readings corresponding to a vehicle are received, the readings including at least a location. The traffic information readings are compared to information already within a map database, and are used to derive additional map information augmenting or correcting that already within the database, the additional map information subsequently being stored in the database. Additional information that is derived includes the presence of stop signs and traffic lights at intersections, the legality of turns at certain times of day, and the connectedness or non-connectedness of road segments.

A navigation system having a central device which uses a link shape compression unit to compress information of altitude changes of a road link obtained from a three-dimensional road map, and calculates a geometry parameter based on variation of energy of a vehicle travelling on the road link. An on-board terminal device estimates the vehicle's average travelling pattern by using a travel-pattern-estimation unit based on the geometry parameter calculated by the central device, a link-travelling time estimated from statistically-stored traffic information, and a link length. The on-board terminal device further calculates fuel consumption of the vehicle travelling on each road link based on the estimated travelling pattern and parameters of the vehicle by using a fuel-consumption calculation unit, and then, searches a fuel-efficient route by using the fuel consumption as a link cost. The on-board terminal device has a vehicle-type selector for selecting a type of the vehicle.

There is a provided a method for car navigating using traffic signal data. The method for car navigating is characterized of providing an optimized route for the earliest arrival to destinations by using signal system data of one or more traffic signals existing on a certain route.

A method and apparatus for determining a trajectory for a vehicle are disclosed, wherein, the method includes: identifying a starting position (p0) and a desired terminal position (P) for the vehicle; linearly approximating dynamics of the vehicle; and using the starting position (p0), desired terminal position (P), and linear approximation, determining the trajectory for the vehicle. The linear approximation can be constrained by requirements (e.g., specifications) that: (i) an acceleration applied to the vehicle at a point on the trajectory is relatively large when the acceleration acts in a direction that is substantially perpendicular to the velocity of the vehicle; and (ii) an acceleration applied to the vehicle at a point on the trajectory is relatively small when the acceleration acts in a direction that is substantially parallel to the velocity of the vehicle. The vehicle may have a curvature limit.

The invention relates to compressed data transmission in wireless data communication. Disclosed are methods and apparatuses for transporting residue of vehicle position data via a wireless network. A disclosed method for transporting residue of vehicle position data via a wireless network, includes the steps of: receiving data for updating residue encoding schema from a monitoring server; constructing a residue encoding schema based on the data, thereby producing a constructed residue encoding schema; and storing the constructed residue encoding schema such that the constructed residue encoding schema will become the current residue encoding schema; where: the constructed residue encoding schema is constructed such that each residue of the constructed residue encoding schema corresponds to a code; and the constructed residue encoding schema is constructed such that a residue having a relatively high probability of occurrence corresponds to a code of relatively short length.

An automated process uses a local positioning system to acquire location (i.e., position and orientation) data for one or more movable target objects. In cases where the target objects have the capability to move under computer control, this automated process can use the measured location data to control the position and orientation of such target objects. The system leverages the measurement and image capture capability of the local positioning system, and integrates controllable marker lights, image processing, and coordinate transformation computation to provide tracking information for vehicle location control. The resulting system enables position and orientation tracking of objects in a reference coordinate system.

A method of operation of a navigation system includes: receiving an origin and a destination; receiving a route keyword for routing between the origin and the destination; identifying a via point matching the route keyword; calculating a keyword group locale based on the via point within a group distance threshold from a keyword group center; and calculating a travel route from the origin to the destination traversing the keyword group locale for displaying on a device.

A navigation system and various methods of using the system are described herein. Search query results are refined by the system and are prioritized based at least in part upon sub-search categories selected during the searching process. Sub-searches can be represented by graphical icons displayed on the user interface.

Some embodiments provide a mapping application that provides routing information to third-party applications on a device. The mapping application receives route data that includes first and second locations. Based on the route data, the mapping application provides a set of routing applications that provide navigation information. The mapping application receives a selection of a routing application in the set of routing applications. The mapping application passes the route data to the selected routing application in order for the routing application to provide navigation information.

Provided are an apparatus and method of providing path information based on a status of a path and/or a purpose of the use of the path. A path information providing server collects environmental information from a sensing device. The path information providing server receives a path information request including a departure and a destination from a terminal device, and provides path information generated by mapping environmental data to a searched path.

An apparatus and method for determining an Absolute Location of an indoor stationary object, the method comprising: receiving a distance between an indoor stationary object and one or more predetermined spots; determining a location of stationary object relative to one of the predetermined spots; receiving an Absolute Location of one of the predetermined spots; determining an Absolute Location of the stationary object; and storing the Absolute Location of the stationary object with description information of the stationary object.

A power steering device is mounted on a vehicle and includes a variable transmission ratio mechanism, a torque applying unit, and an applied friction torque changing unit. The torque applying unit sets an applied friction torque applied to the steering wheel and performs a control of applying the applied friction torque to the steering wheel. The applied friction torque changing unit changes the applied friction torque based on the transmission ratio of the variable transmission ratio mechanism.

Various methods, apparatuses and/or articles of manufacture are provided which may be implemented to estimate a trajectory of a mobile device within an indoor environment. In some embodiments, the trajectory may be estimated without the use of any signal-based positioning information. For example, a mobile device may estimate such a trajectory based, at least in part, on one or more sensor measurements obtained at the mobile device, and further affect the estimated trajectory based, at least in part, on one or more objects identified in an electronic map of the indoor environment.

A parking assist system includes: an actuator that drives a back door of a vehicle; an opening degree control unit that controls an opening degree of the back door by controlling the actuator; a storage device that stores an allowable opening degree of the back door at a park position of the vehicle in association with the park position; and a position information acquisition unit that acquires position information of the vehicle. When a position of the vehicle corresponds to the park position stored in the storage device, the opening degree control unit limits the opening degree of the back door on the basis of the allowable opening degree of the back door, stored in the storage device in association with the park position.

A method of monitoring an engine coolant system includes modeling the total energy stored within an engine coolant. If an actual temperature of the engine coolant is below a minimum target temperature, the modeled total energy stored within the energy coolant is compared to a maximum stored energy limit to determine if sufficient energy exists within the engine coolant to heat the engine coolant to a temperature equal to or greater than the minimum target temperature. The engine coolant system fails the diagnostic check when the modeled total energy stored within the energy coolant is greater than the maximum stored energy limit, and the minimum target temperature has not been reached.

A vehicle notification sound emitting apparatus is basically provided with a first sound emitting device, a second sound emitting device and a notification sound control device. The first sound emitting device emits a first intermittent notification sound inside a cabin interior of a vehicle. The second sound emitting device emits a second intermittent notification sound outside of the cabin interior of the vehicle. The notification sound control device operates the first and second sound emitting devices to separately emit the first and second intermittent notification sounds in at least a partially overlapping pattern in response to occurrence of a vehicle condition to convey a same type of vehicle information to both inside and outside of the cabin interior of the vehicle. The notification sound control device includes a cabin interior-exterior notification sound synchronizing section that is configured to synchronize the first and second intermittent notification sounds.