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Ay-Inversion in Tagalog : Information Structure and Morphosyntax of an Austronesian Language [Electronic book] / Patrick Nuhn.

Düsseldorf : düsseldorf university press, [2021]




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The archaeology of human bones [Electronic book] / Simon Mays.

New York : Routledge, 2010.




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The archaeology of ethnicity : constructing identities in the past and present [Electronic book] / Siân Jones.

London ; New York : Routledge, 1997.




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Shear zones in granular mixtures of hard and soft particles with high and low friction

Soft Matter, 2024, 20,3118-3130
DOI: 10.1039/D4SM00100A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Aditya Pratap Singh, Vasileios Angelidakis, Thorsten Pöschel, Sudeshna Roy
Granular materials show inhomogeneous flows characterized by strain localization.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Nickel-catalyzed γ-alkylation of cyclopropyl ketones with unactivated primary alkyl chlorides: balancing reactivity and selectivity via halide exchange

RSC Adv., 2024, 14,12883-12887
DOI: 10.1039/D4RA02616K, Paper
Open Access
Zheng-Ying Wang, Shi-Zheng Liu, Cong Guo, Yi-Zheng Cheng, Qiang Li, Jianmin Dou, Dacheng Li
Nickel-catalyzed cross-electrophile coupling of cyclopropyl ketones and alkyl chlorides. High reactivity and selectivity can be achieved with sodium iodide as a cocatalyst that generates a low concentration of alkyl iodide via halide exchange.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Game Of Thrones, Handmaid's Tale lead Emmy noms

The Emmy nominations for 2018.




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DFT rationalization of the mechanism and selectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP01700E, Paper
Guowei Yan, Ji Ma, Simeng Qi, Alexander M. Kirillov, Lizi Yang, Ran Fang
The mechanism, regioselectivity, and chemoselectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols to give furan-3-carboxylate derivatives were explored by density functional theory (DFT).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Expedient (3+3)-annulation of carbonyl ylides with azaoxyallyl cations: formal access to oxa-benzo[c]azepin-3-ones

Chem. Commun., 2024, 60,13368-13371
DOI: 10.1039/D4CC04946B, Communication
Kshitiz Verma, Hemanga Bhattacharyya, Sharajit Saha, Tharmalingam Punniyamurthy
Cascade C–C/C–N bond formation of carbonyl ylides with azaoxyallyl cations generated in situ using Rh-catalysis has been accomplished in the presence of a base at room temperature.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Facile synthesis of spiro-pyrazolone-tetrahydrofurans/pyrans: ipso-cyclization of arylidene pyrazolones with haloalcohols

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00447G, Paper
Kavyashree Kuppayya Gond, Mahagundappa Rachappa Maddani
Facile synthesis of spiro-pyrazolone-tetrahydrofurans & pyrans by base-mediated cascade ipso-cyclization of haloalcohols & arylidine pyrazolones is realised. Features include brief reaction time, practicality, good yields and mild reaction conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Sharing our latest differential privacy milestones and advancements

Google is committed to investing in privacy-enhancing technologies (PETs) to ensure user data privacy, improving products like Google Home and Google Search.




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Alleviation of Cadmium-Induced Oxidative Damage through Application of Zinc Oxide Nanoparticles and Strigolactones in Solanum lycopersicum L.

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00796K, Paper
Vaseem Raja, Karanpal Singh, Sami Ullah Qadir, Jagpreet Singh, Ki-Hyun Kim
In this research, zinc oxide nanoparticles (ZnO NPs) are bio-synthesized using Mangifera indica leaf extract as a sustainable capping and stabilizing source. The spherical morphology, crystallinity, and average size (17.97...
The content of this RSS Feed (c) The Royal Society of Chemistry




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New York City bans use of TikTok on city-owned phones

Joins US federal government, majority of states in banning the social media app on security concerns




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How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power?

How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power? How Will the Prabowo Administration Shape Indonesia’s Foreign Policy as a Middle Power?

jacksonl




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Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship

Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship

jacksonl




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Clean facts on cyclones and climate change

Higher sea surface temperatures hold out the threat of more cyclones and deep depressions in the Bay of Bengal and Arabian Sea.




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Drones to emerge as a game changer in fisheries: MoS George Kurian




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Apple ships $6 billion of iPhones from India in big China shift

Apple is expanding its manufacturing network in India at a rapid clip




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Nvidia to take Intel’s spot on Dow Jones Industrial Average 




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Synthesis of 3,5-disubstituted isoxazoles by domino reductive Nef reaction/cyclization of β-nitroenones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00232F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Ehtisham Ibraheem Khan, Tomas Lighuen Cassini, Marino Petrini, Alessandro Palmieri
β-Nitroenones were converted into 3,5-disubstituted isoxazoles via a domino reaction promoted by tin(II) dichloride. The protocol efficiently works under both microwave and flow conditions.
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Dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00190G, Paper
Kai-Cheng Yang, Shi-Lu Zheng, Zhong Wen, Yu-Shan Zhang, Hai-Liang Ni, Long Chen
A HOTf or Fe(OTf)3-catalyzed dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes was developed, which represents a brand-new procedure for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones.
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Diastereoselective synthesis of functionalized spiroindolines via intramolecular ipso-iodocyclization/nucleophile addition cascade reactions of indole-tethered ynones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00112E, Paper
Debojyoti Bag, Sanghapal D. Sawant
Herein, we describe a highly diastereoselective approach for synthesizing polyfunctionalized spiroindolines from indolyl-ynones involving an ipso-iodocyclization/nucleophile addition cascade.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Copper catalyzed dehydrogenative cyclization, alkenylation towards dihydroquinolinones

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00134F, Paper
Pari Keerthana, Fazlur-Rahman Nawaz Khan
An efficient copper-catalysized one-pot sequential synthesis of alkenylated quinolinyldihydroquinolinones is reported utilizing ketones, 1,3-cyclohexanediones, and benzyl alcohols via dehydrogenative cyclisation, followed by alkenylation. This highly straightforward method provides a mild...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Generation of sulfones utilizing β-sulfinyl esters as masked aryl sulfinates under redox-neutral conditions

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00238E, Communication
Yixin Zhang, Zhu Yang, Hongjun Yang, Xuefeng Li, Lu Yang
A method for generation of SVI sulfones from β-sulfinyl esters (SIV) under transition-metal-free non-oxidative mild conditions is presented.
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A copper-catalyzed asymmetric Friedel–Crafts hydroxyalkylation of pyrazole-4,5-diones with 5-aminoisoxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00322E, Communication
Siyu Gao, Xiang Sun, Sijie Peng, Zhenggen Zha, Qi Sun, Zhiyong Wang
An asymmetric Friede-Crafts hydroxyalkylation reaction was developed under the catalysis of chiral copper complexes. A variety of pyrazolone derivatives were obtained with excellent yields and enantioselectivities.
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Rh(III)-catalysed C-H annulation of cis-stilbene acids with 2-diazo-1,3-diketones: A facile access to 6,7-dihydrobenzofuran-4(5H)-one and α-pyrone scaffolds

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00151F, Paper
Shankaraiah Nagula, Mary Sravani Galla, Nandini B. Kale, Akshay Kumawat, Darshana Bora
An efficient Rh(III)-catalysed C-H functionalization, tandem annulation of cis-stilbene acids using 2-diazo-1,3-diketones was devised. The protocol has solely afforded 6,7-dihydrobenzofuran-4(5H)-ones using alicyclic diazocarbonyls via decarbonylation and α-pyrones with aliphatic diazo...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of alkenylphosphine oxides via Tf2O promoted addition–elimination of ketones and secondary phosphine oxides

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00318G, Communication
Jiangkai Ma, Lianjie Wang, Anjiang Qiao, Zhongxian Li, Fengqian Zhao, Junliang Wu
An efficient method for the synthesis of alkenylphosphine oxides via the addition-elimination of SPOs to ketones has been developed. The reaction exhibits good yields and compatibility. Several conversions have also proven the value of this method.
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Electrochemical nickel-catalyzed cross-coupling of glycosyl thiols with preactivated phenols and ketones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00442F, Communication
Fuxin Li, Hui Liu, Wanyu Xing, Qingju Zhang, Liming Wang
Here we report an efficient electrochemical nickel-catalyzed cross-coupling reaction for the synthesis of S-glycosides from preactivated phenols and ketones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Stereoselective Synthesis of gem-Dihalopiperidines via Halo-Aza-Prins Cyclization Reaction: Access to Piperidin-4-ones and Pyridines

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00338A, Paper
Anil Kumar Saikia, Surjya Kumar Bora, Subhamoy Biswas, Bipin Kumar Behera
An efficient methodology for the synthesis of 4,4-dihalopiperidine derivatives has been developed from N-(3-halobut-3-en-1-yl)-4-methylbenzenesulfonamide and aldehyde catalyzed by In(OTf)3 in excellent yields. The reaction involves an initial formation of six...
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Photogenerated chlorine radicals activate C(sp3)–H bonds of alkylbenzenes to access quinazolinones

Org. Biomol. Chem., 2024, 22,2968-2973
DOI: 10.1039/D4OB00129J, Communication
Xin-Yao Pan, Gui-Xia Sun, Fang-Ping Huang, Wen-Jian Qin, Qing-Hu Teng, Kai Wang
An Fe-catalyzed visible-light induced condensation of alkylbenzenes with anthranilamides has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Iron-catalyzed selective construction of indole derivatives via oxidative C(sp3)–H functionalization of indolin-2-ones

Org. Biomol. Chem., 2024, 22,3073-3079
DOI: 10.1039/D4OB00133H, Paper
Wei Chen, Lang-Qi Wen, Xiao-Bing Lu, Hui Zhou
We have developed a clean and efficient iron-catalyzed C(sp3)–H functionalization of indolin-2-ones for the chemodivergent synthesis of value-added indole derivatives, including isatins, and symmetrical and non-symmetrical isoindigos.
The content of this RSS Feed (c) The Royal Society of Chemistry




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BBr3-mediated dearomative spirocyclization of biaryl ynones: facile access to spiro[5.5]dienones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00274A, Communication
Gaurav Jaiswal, Subhas Chandra Pan
BBr3 mediated dearomative spirocyclization of biaryl ynones has been reported for the direct synthesis of spiro[5.5]dienones with a tri-substituted double bond.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Exploring the mechanism of the reductive amination of acetophenones via Borch approach: the role of the acid catalyst

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00160E, Paper
João Pedro Albuquerque Souza, Amanda Krauskopf Jacobs, Leandro Piovan, Renan Borsoi Campos
The energetic viability of several mechanistic variations of the reductive amination of acetophenones via the Borch approach was reexamined through density functional theory calculations. The crucial involvement of the acid...
The content of this RSS Feed (c) The Royal Society of Chemistry




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An FeCl3-catalyzed three-component reaction for the synthesis of β-(1,2,3-triazolyl)-ketones using DMF as a one-carbon source

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00207E, Communication
Ruilin Fang, Lei Zheng, Xuyang Chen, Can Wang, Yunfeng Chen
FeCl3-catalyzed oxidative condensation of NH-1,2,3-triazoles and aryl methyl ketones and DMF has been reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Regioselective synthesis of 4-arylamino-1,2-naphthoquinones in eutectogel as a confined reaction medium using LED light

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00140K, Communication
R. Vara Prasad, Yogendra Kumar, R. Arun Kumar, Tohira Banoo, Subbiah Nagarajan
The use of a simple carbohydrate-derived eutectogel facilitating a LED-light-induced regioselective synthesis of 4-arylamino-1,2-naphthoquinones in good yields is reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Efficient synthesis of SCF3-containing 3-alkenylquinoxalinones via three-component radical cascade reaction

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00363B, Paper
Si-Yu Wang, Chu Liu, Wei Yang, Zhong-Ying Tian, Lin Yuan, Long-Yong Xie
A three-component cascade reaction of quinoxalinones, alkynes and AgSCF3 toward complete E-selective SCF3-containing 3-alkenylquinoxalinones was developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Base- and sulfur-promoted oxidative lactonization of chalcone-acetate Michael adducts: access to pyran-2-ones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00479E, Communication
Cao Nguyen Nguyen, Duc Toan Nguyen, Ha An Tran, Dinh Hung Mac, Thi Thu Tram Nguyen, Pascal Retailleau, Thanh Binh Nguyen
A cost-effective, practical, straightforward and scalable synthesis of α-pyrones via base- and sulfur-promoted annulation of phenylacetates and chalcones is reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Indonesia bans sales of Google phones days after blocking Apple's iPhone 16

Indonesia said it has banned sales of smartphones made by Alphabet's Google due to rules requiring the use of locally manufactured components




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Osteoporosis can shorten your life − here’s how to prevent fractures and keep bones healthy

The key to having healthy bones for a lifetime is to take some simple preventive measures – and the earlier, the better




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Data on how smartphones driving enterprise mobility in India




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The five best ones

Bringing you the top five watches at the 2018 version of Salon International de la Haute Horlogerie




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The phones that light up your instagram

Camera phones that will help you take your Instagram game up a notch this festival season




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The real Charlotte / E. Œ. Somerville & Martin Ross ; afterword by Malcolm Jones.

New York, NY : First Warbler Press, m [2022]




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George Lucas : a life / Brian Jay Jones.

London : Headline, 2017.




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The war lawyers : the United States, Israel, and juridical warfare / Craig Jones.

Oxford, United Kingdom : Oxford University Press, 2020.




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The medieval clergy, 800-1250 : a sourcebook / John S. Ott and Anna Trumbore Jones.

Toronto : Pontifical Institute of Mediaeval Studies, [2024]




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Critique du De mundo de Thomas White / Thomas Hobbes ; introduction, texte critique et notes par Jean Jacquot et Harold Whitmore Jones.

Paris : Librairie Philosophique J. Vrin, 1973.




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Biologist Explains How Drones Catching Whale "Snot" Helps Research

Whale research is difficult, but a conservation organization is trying to make it a bit easier with drones. WIRED's Matt Simon talks with Ocean Alliance CEO Iain Kerr about the benefits of flying the "SnotBot" into a whale's blow spout.




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What If... Time zones didn't exist? | What If

Daylight saving time means we change the clocks twice a year, and the world has over 30 different time zones. Some countries span multiple different time zones, while the likes of China and India choose to have just one time zone despite the huge differences in real time from east to west. Time influences almost every aspect of our lives – yet we barely ever stop to think about what time means exactly. Studies show the Daylight Savings Time leads to spikes in heart attacks and traffic accidents, while reduced sleep due changing times is linked to increased levels of obesity. So, why do we even bother? That's the argument of some scientists, who believe the whole world should switch to Coordinated Universal Time (UTC), which is already used in aviation and in space. In this video we ask, what if we abolished time zones (and clock changes) forever? This video was produced as part of Digital Society, a publishing partnership between WIRED and Vontobel where all content is editorially independent. Visit Vontobel Impact for more stories on how technology is shaping the future of society: https://www.vontobel.com/en-int/about-vontobel/impact/




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WIRED25 2020: Brie Larson, Van Jones, and Elijah Allan-Blitz on VR and Empathy

Brie Larson, Van Jones, and Elijah Allan-Blitz joined the WIRED25 event to discuss what divides us, and their approach with VR films to bridge those gaps.




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The Drop In with Guy Raz | Tilane Jones on Flipping the Script

Produced by WIRED Brand Lab with Dropbox | How do you not only sustain, but grow your business during the pandemic? Guy Raz and Tilane Jones, president of the distribution company ARRAY, discuss the future of work and staying flexible to meet the needs of consumers.