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The influence of hydrogen bonding on the structure of organic–inorganic hybrid catalysts and its application in the solvent-free epoxidation of α-olefins

RSC Adv., 2024, 14,12853-12863
DOI: 10.1039/D4RA01399A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hong-Bin Ju, Li-Zhi Zhang, De-Bao Li, Tao Geng, Ya-Jie Jiang, Ya-Kui Wang
Different reaction routes with the influence of hydrogen bonding and without hydrogen bonding.
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Mechanical properties and molecular adhesion exhibited by inorganic–organic composite elastomers

Polym. Chem., 2024, 15,4196-4203
DOI: 10.1039/D4PY00879K, Paper
Naoki Yamashita, Ryohei Ikura, Kenji Yamaoka, Nobu Kato, Masanao Kamei, Kentaro Ogura, Minoru Igarashi, Hideo Nakagawa, Yoshinori Takashima
Organic–inorganic composite elastomers with reversible cross-links formed by β-cyclodextrin and adamantane (Ad) were prepared. Excess Ad units improve the mixability of polydimethylsiloxane and poly(ethyl acrylate) to increase the healing ratio.
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The CF3TMS adduct of anthraquinone as a monomer for making polymers with potential as separation membranes

Polym. Chem., 2024, 15,4312-4318
DOI: 10.1039/D4PY01002G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kim Jiayi Wu, John M. Tobin, Anli Ji, Yang Shi, Chunchun Ye, Gary S. Nichol, Alessio Fuoco, Mariagiulia Longo, Johannes C. Jansen, Neil B. McKeown
The CF3TMS adduct of anthraquinone reacts with diphenyl ether via a superacid-catalysed step-growth polymerisation to give a polymer (BTFMA-DPE) with promise for making gas separation membranes.
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Reversible aminolysis: a new concept for postpolymerization modification

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00827H, Communication
Koki Kasai, Hideki Amii, Ryohei Kakuchi
Efficient yet reversible aminolysis postpolymerization modification reactions.
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Axial-phenyl Constrained Bis(imino)acenaphthene-Nickel Precatalysts Enhancing Ethylene Polymerization

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01110D, Paper
Quanchao Wang, Qiuyue Zhang, Yizhou Wang, Song Zou, Yanping Ma, Tongling Liang, Wen Hua Sun
To enhance the performance of the bis(imino)acenaphthene-nickel precatalyst, the axial phenyl group is introduced on the acenaphthenyl backbone forming five analogues, bis(aryl)imino-5-phenylacenaphthene nickel bromides (aryl: 2,6-dimethylphenyl, Ni1; 2,6-diethylphenyl, Ni2; 2,6-diisopropylphenyl,...
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Controlled therapeutic cholesterol delivery to cells for the proliferation and differentiation of keratinocytes

J. Mater. Chem. B, 2024, 12,11110-11122
DOI: 10.1039/D4TB01015A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Krzysztof Berniak, Ahmadreza Moradi, Agata Lichawska-Cieslar, Weronika Szukala, Jolanta Jura, Urszula Stachewicz
The research concept involves investigating how cholesterol endocytosis impacts cells using electrospun fibers as a carrier. We studied keratinocyte proliferation and evaluated gene expression levels for markers of early and late differentiation.
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Imaging specific proteins in living cells with small unnatural amino acid attached Raman reporters

Analyst, 2024, 149,5476-5481
DOI: 10.1039/D4AN00758A, Paper
Erli Cai, Yage Chen, Jing Zhang, Haozheng Li, Yiran Li, Shuai Yan, Zhiyong He, Quan Yuan, Ping Wang
For living HeLa cells, we report a small and minimally-invasive Raman reporter (about 2 aa and <1 kDa), which can be site-specifically introduced into proteins by genetic codon expansion combined with tetrazine ligation.
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Structural determination of fructooligosaccharides and raffinose family oligosaccharides using logically derived sequence tandem mass spectrometry

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN00872C, Paper
Chia Yen Liew, Wun-Long Li, Chi-Kung Ni
Logical procedures for structural determination of fructooligosaccharides and raffinose family oligosaccharides.
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Densification of sodium and magnesium aluminosilicate glasses at ambient temperature: structural investigations by solid-state nuclear magnetic resonance and molecular dynamics simulations

Phys. Chem. Chem. Phys., 2024, 26,27348-27362
DOI: 10.1039/D4CP02431A, Paper
Millena Logrado, Yara Hellen Firmo Gomes, Tomiki Inoue, Shingo Nakane, Yoshinari Kato, Hiroki Yamazaki, Akihiro Yamada, Hellmut Eckert
Superposition of 17O triple-quantum magic-angle spinning NMR spectra of 20MgO–20Al2O3–60SiO2 (MAS**) and 20Na2O–20Al2O3–60SiO2 (NAS**) glasses prepared at ambient pressure (AP) and pressurized and decompressed at 25 GPa at room temperature (HP(25)).
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‘Linguistic minority school students find Tamil difficult’




ino

70 p.c. of out-of-school children are from SC, ST, minorities

This includes children who have never enrolled in schools and dropouts.




ino

Dino's bestaan niet. English

Janssen, Mark, 1974- author, illustrator




ino

Too tall houses / Gianna Marino

Marino, Gianna, author, illustrator




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Catalytic applications of organic–inorganic hybrid porous materials

Chem. Commun., 2024, 60,13325-13335
DOI: 10.1039/D4CC04284K, Feature Article
Maodi Wang, Huicong Dai, Qihua Yang
Insights into the synergistic effects of different active sites of organic–inorganic hybrid porous materials for thermal- and photo-catalysis were discussed.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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Solution plasma synthesis of α-amino acids

Chem. Commun., 2024, 60,13408-13411
DOI: 10.1039/D4CC04482G, Communication
Changhua Wang, Yutong Zhang, Yuanyuan Li, Yinhe Rong, Xintong Zhang
This work uses solution plasma for easier control of amino acid synthesis, successfully producing rare serine, achieving green and low-carbon synthesis from small molecules to amino acids.
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Intramolecular cyclization of N-aryl amides for the synthesis of 3-amino oxindoles

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05259E, Communication
Haitao Yang, Yu Pan, Yijing Tian, Kaili Yu, Yifeng Bai, Yonggang Jiang, Hongbin Zhang, Guogang Deng, Xiaodong Yang
A mild and efficient strategy to synthesize pharmaceutically important 3-amino oxindoles from readily available N-aryl amides has been developed.
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Palladium catalyzed C(sp3)-H alkylation of 8-methylquinolines with aziridines: access to functionalized γ-quinolinylpropylamines

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05275G, Communication
Anita Sahoo, Tripti Paul, Shubhajit Basak, Tharmalingam Punniyamurthy
Palladium-catalyzed directed site-selective C(sp3)-H alkylation of 8-methylquinolines has been accomplished using aziridine as an alkylating source via a sequential C-H and C-N bond activation. Site selectivity, funtional group tolerance and...
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The structural, electronic and thermodynamic properties of the designed p-benzoquinone based dicationic ionic liquids: insight from DFT–GD3 and QTAIM

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00119B, Paper
Hossein Roohi, Sajedeh Habibipour, Khatereh Ghauri
In this work, physicochemical properties of the dicationic ionic liquids [BTAD][A1–8]2 ([BTAD]2+ = [p-C6O2(N3H2)2]2+ and A1–8 = [CH3CO2], [CF3CO2], [N(CN)2], [CF3SO3], [ClO4], [BF4], [NTf2] and [PF6]) were theoretically investigated.
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Design of Fe and N co-decorated biomass-derived hierarchical porous carbon frameworks with boosted oxidase-like activity for hydroquinone detection

New J. Chem., 2024, 48,7197-7204
DOI: 10.1039/D4NJ00509K, Paper
Han Zhang, Xiaodan Qi, Zhifei Wang, Lihua Jin, Yehua Shen
An Fe and N co-decorated biomass-derived porous carbon framework with boosted oxidase-like activity was prepared and applied to sensitive hydroquinone detection.
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Hydroquinone colorimetric sensing based on core–shell structured CoFe2O4@N-GQDs@CeO2 nanocomposites as oxidase mimics

New J. Chem., 2024, 48,7323-7333
DOI: 10.1039/D4NJ00284A, Paper
Xuefang Lei, Yujin Li, Peiqing Guo, Mingzhu Qiu, Rang Meng, Shaohui Li, Dongxia Zhang, Nali Chen, Xibin Zhou
The core–shell structured CoFe2O4@N-GQDs@CeO2 nanocomposites were successfully synthesized by co-precipitation method, and CeO2 was uniformly dispersed on the shell layer with the help of nitrogen-doped graphene quantum dots (N-GQDs).
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Oxazoline amino acid bioconjugates: one-pot synthesis and analysis of supramolecular interactions

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00995A, Paper
Marija Bakija, Berislav Perić, Srećko I. Kirin
Oxazoline amino acid bioconjugates were synthesized; the relative stability of a supramolecular dimer of a tris-derivative was investigated using mean absolute error values (MAE), derived from 1H NMR experiments and DFT calculations.
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The pulmonary effects of nickel-containing nanoparticles: cytotoxicity, genotoxicity, carcinogenicity, and their underlying mechanisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00929G, Critical Review
Yiqun Mo, Yue Zhang, Qunwei Zhang
This review summarized the cytotoxic, genotoxic, and carcinogenic effects of Ni-containing NPs on humans, lung cells in vitro, and rodent lungs in vivo, and the underlying mechanisms. Their extra-pulmonary effects were also briefly mentioned.
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Assessing aspects of solution-based chemical synthesis to convert waste Si solar cells into nanostructured aluminosilicate crystals

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00038B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Edita Garskaite, Math Bollen, Enock Mulenga, Mathis Warlo, Glenn Bark, Espen Olsen, Dalia Brazinskiene, Denis Sokol, Dietrich Buck, Dick Sandberg
An affordable, scalable, and easily adoptable solution-based processing route provides a potential way of converting waste Si solar cells into aluminosilicate minerals to contribute to sustainability in the solar energy value chain.
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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
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3-(3,5-Dinitrophenyl)-5-amino-1,2,4-oxadiazole: synthesis, structure and properties of a novel insensitive energetic material

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00201F, Paper
Binshan Zhao, Baolong Kuang, Mou Sun, Tingwei Wang, Chao Zhang, Meiqi Xu, Cong Li, Zujia Lu, Jian-guo Zhang
A novel heat-resistant energetic compound 3-(3,5-dinitrophenyl)-5-amino-1,2,4-oxadiazole with low mechanical sensitivity on the basis of combining dinitrobenzene and aminooxadiazole was synthesized through a simple method in this work.
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Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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Man sentenced to death for raping and murdering minor stepdaughter




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Minor’s rape: HC denies rickshaw driver’s bail




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Jasmino Corporation announces acquisition of two German firms




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Sino-Russia Arctic Relations: The View from Singapore

Sino-Russia Arctic Relations: The View from Singapore Sino-Russia Arctic Relations: The View from Singapore

jacksonl




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US Perspectives on Sino-Russian Cooperation in the Arctic and Roles for Partners

US Perspectives on Sino-Russian Cooperation in the Arctic and Roles for Partners US Perspectives on Sino-Russian Cooperation in the Arctic and Roles for Partners

jacksonl




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Synthesis of 3,5-disubstituted isoxazoles by domino reductive Nef reaction/cyclization of β-nitroenones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00232F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Ehtisham Ibraheem Khan, Tomas Lighuen Cassini, Marino Petrini, Alessandro Palmieri
β-Nitroenones were converted into 3,5-disubstituted isoxazoles via a domino reaction promoted by tin(II) dichloride. The protocol efficiently works under both microwave and flow conditions.
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Dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00190G, Paper
Kai-Cheng Yang, Shi-Lu Zheng, Zhong Wen, Yu-Shan Zhang, Hai-Liang Ni, Long Chen
A HOTf or Fe(OTf)3-catalyzed dehydrative alkynylation of 3-hydroxyisoindolinones with terminal alkynes was developed, which represents a brand-new procedure for the synthesis of 3-alkynylated 3,3-disubstituted isoindolinones.
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Copper catalyzed dehydrogenative cyclization, alkenylation towards dihydroquinolinones

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00134F, Paper
Pari Keerthana, Fazlur-Rahman Nawaz Khan
An efficient copper-catalysized one-pot sequential synthesis of alkenylated quinolinyldihydroquinolinones is reported utilizing ketones, 1,3-cyclohexanediones, and benzyl alcohols via dehydrogenative cyclisation, followed by alkenylation. This highly straightforward method provides a mild...
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HFIP-mediated C-3-alkylation of indoles and synthesis of indolo[2,3-b]quinolines & related natural products

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00414K, Paper
Auqib Rashid, Waseem I. Lone, Preeti Dogra, Showkat Rashid, Bilal A. Bhat
An expeditious metal free C-3 alkylation of indoles and its NIS-mediated deviation to indolo[2,3-b]quinolines is reported. Applications of these strategies in accessing bioactive natural products have also been demonstrated.
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A copper-catalyzed asymmetric Friedel–Crafts hydroxyalkylation of pyrazole-4,5-diones with 5-aminoisoxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00322E, Communication
Siyu Gao, Xiang Sun, Sijie Peng, Zhenggen Zha, Qi Sun, Zhiyong Wang
An asymmetric Friede-Crafts hydroxyalkylation reaction was developed under the catalysis of chiral copper complexes. A variety of pyrazolone derivatives were obtained with excellent yields and enantioselectivities.
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Synthesis of Asp-based lactam cyclic peptides using an amide-bonded diaminodiacid to prevent aspartimide formation

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00472H, Communication
Wen-Jie Li, Jun-You Chen, Hui-Xia Zhu, Yi-Ming Li, Yang Xu
A diaminodiacid (DADA) containing an amide bond can be used in Fmoc solid-phase peptide synthesis (SPPS) of an Asp-based lactam cyclic peptide with no aspartimide formation.
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Vinylogous and stereoselective domino synthesis of pyrano[2,3-c]pyrroles from alkylidene meldrum's acids

Org. Biomol. Chem., 2024, 22,2948-2952
DOI: 10.1039/D4OB00233D, Communication
Mariia Savchuk, Giang Vo-Thanh, Sylvain Oudeyer, Hélène Beucher, Jean-François Brière
An expeditious diatereoselective synthesis of pyrano[2,3-c]pyrroles thanks to a domino Vinylogous aza-Michael-Aldol-Cyclocondensation (aza-VMAC) reaction to alkylidene Meldrum's acid derivatives.
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Photogenerated chlorine radicals activate C(sp3)–H bonds of alkylbenzenes to access quinazolinones

Org. Biomol. Chem., 2024, 22,2968-2973
DOI: 10.1039/D4OB00129J, Communication
Xin-Yao Pan, Gui-Xia Sun, Fang-Ping Huang, Wen-Jian Qin, Qing-Hu Teng, Kai Wang
An Fe-catalyzed visible-light induced condensation of alkylbenzenes with anthranilamides has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electro-oxidative three-component cascade coupling of isocyanides with elemental sulfur and amines for the synthesis of 2-aminobenzothiazoles

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00432A, Paper
Peng-Fei Huang, Jia-Le Fu, Ying Peng, Jian-Hong Fan, Long-Jin Zhong, Kewen Tang, Yu Liu
2-Aminobenzothiazoles are commonly encountered in various functional compounds. Herein, we disclose an electro-oxidative three-component reaction for the effective synthesis of 2-aminobenzothiazoles under mild conditions, utilizing non-toxic and abundant elemental sulfur...
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Design, synthesis, biological evaluation and molecular docking studies of quinoline-anthranilic acid hybrids as potent anti-inflammatory drugs

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00040D, Paper
Sidra Siddique, Khalid Hussain, Naureen Shehzadi, Muhammad Arshad, Muhammad Nadeem Arshad, Sadaf Iftikhar, Farhat Saghir, Ayisha Shaukat, Muhammad Sarfraz, Nisar Ahmed
Despite the high global prevalence, rheumatoid arthritis lacks a satisfactory treatment.
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TEMPO/PhI(OAc)2 promotes the α-aminophosphinoylation of alcohols with amines and H-phosphine oxides in aqueous medium

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00302K, Communication
Qiang Huang, Xin Jin, Lvjia Wu, Jiangdong Li, Qianlu Xing, Xianheng Wang, Changkuo Zhao
The aminophosphinoylation of alcohols with amines and H-phosphine oxides provides an efficient and mild approach to access various α-aminoalkylphosphine oxides in good yields with good tolerance of functional groups using H2O as a clean solvent.
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Facile synthesis of tetrahydroquinoline containing dithiocarbamate derivatives via one-pot sequential multicomponent reaction

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00490F, Communication
SIDDHARTHA KUMAR SENAPATI, Anit Pal, Animesh Das
An efficient sequential multi-component method for the synthesis of tertrahydroquinoline containing dithiocarbamate has been developed. This reaction involved a boronic acid-catalyzed reduction of quinoline to tertrahydroquinoline, followed by nucleophilic addition...
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N-Functionalization of beta-aminophosphonates; Cytotoxic effect of the new derivatives

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00243A, Paper
György Keglevich, Petra Regina Varga, Emőke Dinnyési, Zsuzsanna Szalai, Szilvia Bősze, Rita Oláhné Szabó, Laszlo Drahos, Konstantin Karaghiosoff
Beta-Aminophosponates obtained by the Michael addition of primary amines to the double bond of diethyl vinylphosphonate proved to be suitable starting materials (amine components) in the Kabachnik–Fields reaction with formaldehyde...
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Regioselective synthesis of 4-arylamino-1,2-naphthoquinones in eutectogel as a confined reaction medium using LED light

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00140K, Communication
R. Vara Prasad, Yogendra Kumar, R. Arun Kumar, Tohira Banoo, Subbiah Nagarajan
The use of a simple carbohydrate-derived eutectogel facilitating a LED-light-induced regioselective synthesis of 4-arylamino-1,2-naphthoquinones in good yields is reported.
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Efficient synthesis of SCF3-containing 3-alkenylquinoxalinones via three-component radical cascade reaction

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00363B, Paper
Si-Yu Wang, Chu Liu, Wei Yang, Zhong-Ying Tian, Lin Yuan, Long-Yong Xie
A three-component cascade reaction of quinoxalinones, alkynes and AgSCF3 toward complete E-selective SCF3-containing 3-alkenylquinoxalinones was developed.
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Chef Agostino D’ Angelo: Pasta comes in all shapes and sizes

Visiting chef Agostino D’ Angelo takes his audience through the flavours of true Sicilian food