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Sulfonylcalix[4]arene-based Al4 clusters: three aluminum oxo clusters with different coordinated solvents for the CO2 cycloaddition reaction

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02096K, Research Article
Xiao-Jie Liu, Long-Xue Guo, Wei Xu, Ya-Wen Wang, Yuan-Hang Tian, Li-Xing Zhao, Xiao-Yu Li, Jin-Hua Li, Guo-Ming Wang
By using a macrocyclic H4BTC4A-SO2 ligand, we successfully synthesized three Al4 clusters with different solvents, which exhibit different potentials to expose metal active sites for the catalytic reaction. of cycloaddition of carbon dioxide.
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Heterointerface synergy between a 3 × 3 tunnel τ-MnO2 cathode and Mg2(OH)3Cl·4H2O for achieving long cycle-life aqueous zinc-ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02572E, Research Article
Fang Xu, Jialin Zheng, Dai-Huo Liu, Ao Wang, Zhenjiang Li, Chunyan Xu, Mengqin Song, Beinuo Zhang, Zhengyu Bai, Zhongwei Chen
The prepared of τ-MnO2–Mg2(OH)3Cl·4H2O heterostructure cathode material enhances Zn-ion diffusion, increases the proportion of Mn(IV) and suppresses structural instability, thereby improving the cycling stability of τ-MnO2.
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A novel cerium-based metal-organic framework supported Pd catalyst for semi-hydrogenation of phenylacetylene

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02225D, Research Article
Open Access
Xiangdi Zeng, Zi Wang, Meng He, Wanpeng Lu, Wenyuan Huang, Bing An, Jiangnan Li, Li Mufan, Ben Spencer, Sarah Day, Floriana Tuna, Eric J L McInnes, Martin Schroder, Sihai Yang
Phenylacetylene is a detrimental impurity in the polymerisation of styrene, capable of poisoning catalysts even at ppm levels and significantly degrading the quality of polystyrene. The semi-hydrogenation of phenylacetylene to...
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A novel extra-broadband visible-emitting garnet phosphor for efficient single-component pc-WLEDs

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01824A, Research Article
Qianyi Chen, Zhenjie Lun, Dongdan Chen, Yongsheng Sun, Puxian Xiong, Siyun Li, Shanhui Xu, Zhongmin Yang
A defect engineering strategy mediated by the structural cationic substitution is proposed and experimentally demonstrated for ultra-broadband emission in a garnet Y3Sc2Al3O12:B3+ phosphor.
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Exploring the optimal post-treatment strategy for boosting the electrochemical performances of a new bimetal–organic framework-based supercapacitor

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02314E, Research Article
Xinwen Dou, Mingyue Liu, Tian Cao, Chan Wang, Yingjie Zhang, Yuhang Jia, Qiang Ju, Zhenlan Fang
Effects of four kinds of post-treatment strategies on the structures, morphologies, and electrochemical behaviors of MOF derivatives are systematically investigated for the first time.
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Unprecedented aluminum molecular ring based-layer with tailorable optical limiting effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02507E, Research Article
Lin Geng, Di Wang, Ran-Qi Chen, San-Tai Wang, Chan Zheng, Wei-Hui Fang, Jian Zhang
This study achieved structural modulation from 0D aluminum rings to 2D MOF via a coordination-driven self-assembly strategy. Notably, the exfoliated nanosheets showed enhanced NLO properties, highlighting their potential in optical applications.
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Toward highly efficient TADF-active Cu(I), Ag(I) and Au(I) carbene complexes using symmetry-based design strategy

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01996B, Research Article
Alexander V. Artem'ev, Maxim I. Rogovoy, Ilia M. Odud, Maria P. Davydova, Marianna I. Rakhmanova, Pavel A. Petrov, Valery K. Brel, Oleg I. Artushin, Konstantin A. Brylev, Denis G. Samsonenko, Alexey S. Berezin, Dmitry E. Gorbunov, Nina P. Gritsan
Tetraphosphine-carbene Cu(I), Ag(I) and Au(I) complexes, synthesized via a symmetry-based design strategy, exhibit cyan to yellow TADF with excellent quantum yields (58–89%) and reduced lifetimes.
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Fe3O4-decorated MXene for the effective removal of 133Ba and 137Cs: synthesis, characterization, and optimization via response surface methodology (RSM)

Inorg. Chem. Front., 2024, 11,7860-7871
DOI: 10.1039/D4QI00404C, Research Article
Shalu Atri, Vipul Vilas Kusumkar, Süleyman İnan, Maros Gregor, Tomas Roch, Maria Caplovicova, Michal Galambos, Eva Viglasova, Gustav Plesch, Martin Motola, Olivier Monfort
The potential activity of Fe3O4 decorated MXenes in the removal of highly toxic 133Ba and 137Cs using a radioactive indicator method.
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A tetranuclear-cluster-based MOF with a low-polarity pore environment for efficient C2H6/C2H4 separation

Inorg. Chem. Front., 2024, 11,7947-7954
DOI: 10.1039/D4QI01685H, Research Article
Meng Feng, Jiantang Li, Xirong Wang, Jingyu Wang, Dongmei Wang, Banglin Chen
Benefitting from reticular chemistry, the newly developed MOF material ZJNU-400 establishes a low-polarity environment that enables reversed ethane adsorption and facilitates the efficient separation of C2H6/C2H4.
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Design of DyIII single-molecule magnets with molecularly installed luminescent thermometers based on bridging [PtII(CN)2(C^N)]− complexes

Inorg. Chem. Front., 2024, 11,7966-7978
DOI: 10.1039/D4QI02373K, Research Article
Pawel J. Bonarek, Mikolaj Zychowicz, Jan Rzepiela, Michal Liberka, Sebastian Baś, Jakub J. Zakrzewski, Szymon Chorazy
Dysprosium(III) single-molecule magnets are bridged within a coordination polymer by Pt(II)-cyanido metalloligands serving as their temperature sensors.
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Realizing efficient broadband near-infrared emission under blue light excitation in Sb3+-doped zero-dimensional organic tin(IV)-based metal halides via coordination structure modulation

Inorg. Chem. Front., 2024, 11,7979-7990
DOI: 10.1039/D4QI01904K, Research Article
Bao Ke, Hui Peng, Yongqi Yang, Chengzhi Yang, Shangfei Yao, Arfan Bukhtiar, Qilin Wei, Jialong Zhao, Bingsuo Zou
Here, we report a new NIR emitter of Sb3+-doped tin(IV)-based metal halides via coordination structure modulation, which can exhibit bright broadband NIR emission under blue light excitation with a PLQY of 33.2%.
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In situ growth of δ-MnO2/C fibers as a binder-free and free-standing cathode for advanced aqueous Zn-ion batteries

Inorg. Chem. Front., 2024, 11,8016-8024
DOI: 10.1039/D4QI01661K, Research Article
Yan Li, Fei Zhang, Miaomiao Wu, Yong Guo, Yuanyuan Liang, Reyihanguli Ababaikeri, Luyang Wang, Qiao Liu, Xingchao Wang
δ-MnO2 anchored in N-doped carbon fibers, derived from coal, was prepared using an electrospinning method, demonstrating enhanced performance in AZIBs.
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Rationally reconstructing the surface microstructure of a chemical bath deposited electron transport layer for efficient and stable perovskite solar cells

Inorg. Chem. Front., 2024, 11,7910-7920
DOI: 10.1039/D4QI01808G, Research Article
Xinxuan Yang, Lexin Wang, Meihan Liu, Jiahui Jin, Lili Yang, Lin Fan, Maobin Wei, Huilian Liu, Haoran Chen, Jinghai Yang, Yulei Chang, Fengyou Wang
A reconstruction strategy is designed to manipulate the surface microstructure of a CBD SnO2 ETL, yielding PSCs with a high PCE >24%.
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Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening

Inorg. Chem. Front., 2024, 11,7843-7852
DOI: 10.1039/D4QI02234C, Research Article
Chenxu Li, Abudukadi Tudi, Huanhuan Cheng, Qingyu Liu, Zhihua Yang, Shilie Pan
High-throughput screening of 222 hydroxyborates identified three as promising short-wavelength ultraviolet nonlinear optical. with phase-matching second harmonic generation capacity extending to the solar blind region (200–280 nm).
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Coordination tuning of Ni/Fe complex-based electrocatalysts for enhanced oxygen evolution

Inorg. Chem. Front., 2024, 11,8110-8122
DOI: 10.1039/D4QI01934B, Research Article
Hongbo Zhou, Xuan Hao, Jiexin Guan, Yilin Deng, Zi Wei, Yashu Liu, Guoxing Zhu
The 2,2'-bpy coordination shells surrounding the Ni/Fe active sites of NiFe(2,2'-bpy)n@CNT materials effectively boost OER catalysis.
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Critical metal recovery from spent lithium-ion batteries’ leaching solution using electrodialysis technologies: strategies and challenges

Inorg. Chem. Front., 2024, 11,7775-7792
DOI: 10.1039/D4QI01978D, Review Article
Tianshu Zhang, Yijun Qian, Changyong Zhang, Tao Qian, Chenglin Yan
This review overviews the recent advances in electrodialysis (ED) in extracting critical metals from spent battery leachate. In addition, strategies and challenges regarding ED techniques toward battery recycling are pointed out.
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Correction: BaSc2(HPO3)4(H2O)2: a new nonlinear optical phosphite exhibiting a 3D {[Sc2(HPO3)4]2−}∞ anionic framework and phase-matchable SHG effect

Inorg. Chem. Front., 2024, 11,8146-8146
DOI: 10.1039/D4QI90072C, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ru-Ling Tang, Gang-Xiang Liu, Wen-Dong Yao, Li-Nan Zhang, Wenlong Liu, Sheng-Ping Guo
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Optimizing the spin qubit performance of lanthanide-based metal–organic frameworks

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02324B, Research Article
Xiya Du, Lei Sun
Reducing the spin concentration, spin-orbit coupling strength, and ground spin state of lanthanide ions embedded in metal–organic frameworks improves their spin qubit performance.
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Stable solid-state potassium metal batteries enabled by a KB11H14·2Me3NBH3 complex electrolyte

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02372B, Research Article
Guo-guo Zhang, Pengtao Qiu, Jiaxin Kang, Zhiwei Lu, An-qi Zhu, Xiaohu Yu, Xuenian Chen
Solid-state potassium metal batteries have increasingly gained attention as promising alternatives in large-scale energy storage due to their safety and low cost. However, these batteries usually suffer from a lack...
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Naphthalene diimide-based crystalline hybrid photochromic materials: Structural types, photochromic mechanism, and applications

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02653E, Review Article
Li Li, Jian-Ge Zeng, Ning-Ning Zhang, Yu Yang-Tao, Shu-Hao Li, Yang Hua
The multifunctional stimuli-responsive photochromic materials significantly expand their application fields, including molecular switching, information storage and encryption, detection and sensing, etc. 1,4,5,8-naphthalenediimides (NDIs) have been widely used for the construction...
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Multifunctional separator modified with catalytic multishelled structural CoS2 enables a stable lithium–sulfur battery

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02340D, Research Article
Open Access
Ruyi Bi, Jilu Zhao, Mei Yang, Jiangyan Wang, Ranbo Yu, Dan Wang
A multifunctional separator modified with a multi-shelled CoS2 structure is developed to simultaneously inhibit the shuttle effect and effectively catalyze the redox reactions.
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Dual-functional Applications of Photochromic BiNbO4: Er3+ Ceramics Based on Reversible Upconversion Luminescence Modulation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02440K, Research Article
ASAD ULLAH, Imran Khan, Yangke Cun, Yue Liu, Zhiguo Song, Jianbei Qiu, Tatiana Grigorievna Cherkasova, Anjun Huang, Asif Ali Haider, Zhengwen Yang
Photochromic luminescent phosphor has attracted considerable attention owing to its excellent optical properties, which face the problem of limited applications. Herein, the reversible photochromic and photo-/thermal bleaching phenomenon of BiNbO4...
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Pentagonal-bipyramidal Dysprosium(III) complexes with two apical phosphine oxide ligands and equatorial pentadentate N3O2 Schiff-base ligands: Breakdown of the apical magnetic axiality by strong equatorial crystal field†

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02262A, Research Article
Tamara A. Bazhenova, Vyacheslav Kopotkov, Denis V. Korchagin, Elena Yureva, Michael V. Zhidkov, Alexey I Dmitriev, Ilya Yakushev, N. N. Efimov, Konstantin Andreevich Babeshkin, Vladimir Sergeevich Mironov, Eduard B. Yagubskii
A series of three new seven-coordinate pentagonal-bipyramidal (PBPY-7) Dy(III) complexes [Dy(LCH3)(Cy3PO)2]ClO4∙CH3CN (1), [Dy(L2(t-Bu))(Ph3PO)2]ClO4∙0.63C2H5OH (2), [Dy(LOCH3)(Ph3PO)2]ClO4∙2H2O (3) including various chelating pentadentate ligands with a [N3O2]2− binding node in the equatorial plane,...
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Unraveling the Correlation between Biological Effects and Halogen Substituents in Cobalt bis(dicarbollide)

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02296C, Research Article
Katarzyna Zakret-Drozdowska, Bożena Szermer-Olearnik, Waldemar Goldeman, Michalina Gos, Dawid Drozdowski, Anna Gągor, Tomasz M. Goszczyński
Over the past decade, considerable scientific attention has been given to adapting cobalt bis(dicarbollides) as innovative agents with various biomedical applications. Although the studied compounds show great potential in this...
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The use of single metal atoms-based photocatalysts for the production of ammonia through photocatalytic nitrogen fixation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02449D, Review Article
Ping Zhang, Yongchong Yu, Reyila Tuerhong, Xinyu Du, Keyi Chai, Xiaoping Su, Qiong Su, Shujuan Meng, Lijuan Han
The conventional synthetic ammonia industry is characterized by its high energy consumption, necessitating the exploration of a new environmentally sustainable method for NH3 synthesis. A prospective alternative to the Haber-Bosch...
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A miniprotein receptor electrochemical biosensor chip based on quantum dots

Lab Chip, 2024, 24,1875-1886
DOI: 10.1039/D3LC01100C, Paper
Yunong Zhao, Juan Han, Jing Huang, Qing Huang, Yanbing Tao, Ruiqin Gu, Hua-Yao Li, Yang Zhang, Houjin Zhang, Huan Liu
We developed an on-chip laboratory for biomolecule interactions and kinetics analysis based on the three-electrode and high electron mobility transistor (HEMT) chip platform.
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Multifunctional cardiac microphysiological system based on transparent ITO electrodes for simultaneous optical measurement and electrical signal monitoring

Lab Chip, 2024, 24,1903-1917
DOI: 10.1039/D3LC00908D, Paper
Zhangjie Li, Kai Niu, Chenyang Zhou, Feifan Wang, Kangyi Lu, Yijun Liu, Lian Xuan, Xiaolin Wang
We developed a multifunctional cardiac microphysiological system on transparent electrodes, enabling simultaneous electrical signal monitoring and optical observations of cardiac tissue, holding promise for applications in cardiac drug development.
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SeParate: multiway fluorescence-activated droplet sorting based on integration of serial and parallel triaging concepts

Lab Chip, 2024, 24,2107-2121
DOI: 10.1039/D3LC01075A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wannes Verbist, Jolien Breukers, Sapna Sharma, Iene Rutten, Hans Gerstmans, Lotte Coelmont, Francesco Dal Dosso, Kai Dallmeier, Jeroen Lammertyn
A novel platform, called SeParate, enabling accurate multiplex droplet sorting by integrating serial and parallel sorting principles for three model systems with increasing complexity and intra-subpopulation variation in fluorescence intensities.
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Lab on skin: real-time metabolite monitoring with polyphenol film based subdermal wearable patches

Lab Chip, 2024, 24,2039-2048
DOI: 10.1039/D4LC00073K, Paper
Open Access
Georgeta Vulpe, Guoyi Liu, Sam Oakley, Guanghao Yang, Arjun Ajith Mohan, Mark Waldron, Sanjiv Sharma
Development of wearable sensing devices for minimally invasive and real time monitoring of physiological information in ambulatory conditions.
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Droplet microfluidic system for high throughput and passive selection of bacteria producing biosurfactants

Lab Chip, 2024, 24,1947-1956
DOI: 10.1039/D3LC00656E, Paper
Open Access
Klaudia Staskiewicz, Maria Dabrowska-Zawada, Lukasz Kozon, Zofia Olszewska, Lukasz Drewniak, Tomasz S. Kaminski
Novel microfluidic technique for functional selection of biosurfactant-producing microorganisms. Single bacterial cells are encapsulated into picoliter droplets for clonal cultivation and passively sorted at high throughput by interfacial tension.
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A self-assembly and cellular migration based fabrication of high-density 3D tubular constructs of barrier forming membranes

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00006D, Paper
Seyedaydin Jalali, Ponnambalam Ravi Selvaganapathy
A scalable method for creating perfusable 3D tissue constructs using self-assembly is introduced. Unlike conventional cell injection methods, here we leverage cell migration to form tissue barriers of low permeability, mimicking in vivo environments.
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Development of a self-contained microfluidic chip and an internet-of-things-based point-of-care device for automated identification of respiratory viruses

Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC00933E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huynh Quoc Nguyen, Van Dan Nguyen, Vu Minh Phan, Tae Seok Seo
The COVID-19 pandemic greatly impacted the in vitro diagnostic market, leading to the development of new technologies such as point-of-care testing (POCT), multiplex testing, and digital health platforms.
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Screening for Urothelial Carcinoma Cells in Urine Based on Digital Holographic Flow Cytometry through Machine Learning and Deep Learning Method

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D3LC00854A, Paper
Lu Xin, Xi Xiao, Wen Xiao, Ran Peng, Hao Wang, Feng Pan
The incidence of urothelial carcinoma continue to rise annually, particularly among the elderly. Prompt diagnosis and treatment can significantly enhance patient survival and quality of life. Urine cytology remains a...
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Distance-based paper analytical device for multiplexed quantification of cytokine biomarkers using carbon dots integrated with molecularly imprinted polymer

Lab Chip, 2024, 24,2262-2271
DOI: 10.1039/D4LC00055B, Paper
Kawin Khachornsakkul, Ruben Del-Rio-Ruiz, Lita Chheang, Wenxin Zeng, Sameer Sonkusale
A carbon dots and dopamine-imprinted polymer was immobilized onto a distance-based paper channel for simultaneous detection of three cytokine biomarkers without requiring expensive reagents and instruments.
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Designing and prototyping a novel biosensor based on a volumetric bar-chart chip for urea detection

Lab Chip, 2024, 24,2298-2305
DOI: 10.1039/D3LC00730H, Paper
Mahdi Samadi Khezri, Mohammad Reza Housaindokht, Mojtaba Firouzi
A volumetric bar-chart chip (V-chip) is a microfluidic device based on distance-based quantitative measurement that visualizes analyte concentration without the need for apparatus or data processing.
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A novel ratiometric design of microfluidic paper-based analytical device for the simultaneous detection of Cu2+ and Fe3+ in drinking water using a fluorescent MOF@tetracycline nanocomposite

Lab Chip, 2024, 24,2306-2316
DOI: 10.1039/D3LC01045G, Paper
Sabah H. Al-Jaf, Sameera Sh. Mohammed Ameen, Khalid M. Omer
On-site monitoring of ions in drinking water is essential for safeguarding public health, ensuring high water quality, and preserving the ecological balance of aquatic ecosystems.
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A microfluidic-based gut-on-a-chip model containing the gut microbiota of patients with depression reveals physiological characteristics similar to depression

Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC01052J, Paper
Wenxin Wang, Yiyuan Liu, Zhikai Yao, Dengbo Chen, Yue Tang, Jingwei Cui, Jiangjiang Zhang, Hong Liu, Zikai Hao
A depression-on-gut-chip (DoGC) is prepared and enables extended co-culture of aerobic human intestinal epithelial cells and anaerobic gut microbiota, and allows direct study of interactions between human gut microbiota and depression.
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Rocking- and diffusion-based culture of tumor spheroids-on-a-chip

Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC01116J, Paper
Duomei Tian, Zheng Mao, Li Wang, Xiaochen Huang, Wei Wang, Haoyue Luo, Juan Peng, Yong Chen
Tumor spheroids are cultured in hydrogel microwells with a gravity driven medium flow underneath the membrane on-a-chip. The rocking system is pumpless, powered with a rechargeable battery, and programmable with a built-in microprocess.
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A microfluidic microalgae detection system for cellular physiological response based on object detection algorithm

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D3LC00941F, Paper
Shizheng Zhou, Tianhui Chen, Edgar S. Fu, Liuyong Shi, Teng Zhou, Hong YAN
The composition of species and the physiological status of microalgal cells serve as significant indicators for monitoring marine environments. Symbiotic with corals, Symbiodiniacea are more sensitive to the environmental response....
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Advanced sequencing-based high-throughput and long-read single-cell transcriptome analysis

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00105B, Critical Review
Shanqing Huang, Weixiong Shi, Shiyu Li, Qian Fan, Chaoyong Yang, Jiao Cao, Lingling Wu
Cells are the fundamental building blocks of living systems, exhibiting significant heterogeneity. The transcriptome connects the cellular genotype and phenotype, and profiling single-cell transcriptome is critical for uncovering distinct cell...
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A paper-based dual functional biosensor for safe and user-friendly point-of-care urine analysis

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00163J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yujia Li, Yingqi Kong, Yubing Hu, Yixuan Li, Rica Asrosa, Wenyu Zhang, Buddha Deka Boruah, Ali K. Yetisen, Andrew Davenport, Tung-Chun Lee, Bing Li
A safe, accurate, and reliable sensing platform for urinary biomarkers analysis of urinary biomarkers is clinically important for the early detection and monitoring of the progression of chronic kidney disease (CKD), as it has become one of the world's most prevalent non-communicable diseases.
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A laboratory scale fast feedback characterization loop for optimizing coated catalysts for emission control

React. Chem. Eng., 2024, 9,2868-2881
DOI: 10.1039/D4RE00168K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tim Delrieux, Shweta Sharma, Florian Maurer, Paolo Dolcet, Maximilian Lausch, Anna Zimina, Camilo Cárdenas, Patrick Lott, Maria Casapu, Thomas Lennon Sheppard, Jan-Dierk Grunwaldt
This work presents a fast and non-invasive photo-based channel analysis approach, which helps to screen and understand the effects of different coating parameters on the activity of noble metal-based oxidation catalyst coated on a ceramic cordierite.
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Closed-loop identification of enzyme kinetics applying model-based design of experiments

React. Chem. Eng., 2024, 9,2984-2993
DOI: 10.1039/D4RE00127C, Paper
Leon Hennecke, Lucas Schaare, Mirko Skiborowski, Andreas Liese
This study presents an automated reactor platform for the identification of enzyme kinetic models using model-based design of experiments on the example of the reduction of NAD+ by formate dehydrogenase from Candida boidinii.
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Bayesian-optimization-based design of highly active and stable Fe–Cu/SSZ-13 catalysts for the selective catalytic reduction of NOx with NH3

React. Chem. Eng., 2024, 9,3029-3037
DOI: 10.1039/D4RE00327F, Paper
Sanha Lim, Hwangho Lee, Hyun Sub Kim, Jun Seop Shin, Jong Min Lee, Do Heui Kim
Bayesian optimization approach facilitates an efficient optimization of multi-components catalyst for NH3-SCR reaction.
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Selective Separation of Li, Ni, Co and Mn from Model Spent Li Ion Battery Cathode by Dry Processing using Combination of Chlorination and Oxidation

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00328D, Paper
Naoto Tsubouchi, Yuuki Mochizuki
The volatilization of Li, Ni, Co, and Mn during chlorination treatment of LNO, LCO, and LMO (model materials for used LIB cathode material) was investigated with the aim of developing...
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Ammonia Decomposition over Low-loading Ruthenium Catalyst Achieved through “Adiabatic” Plasma Reactor

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00509K, Paper
Minhazur Rahman Shawon, Chinwendu Umeojiakor, Anthony Griffin, Jeffrey S. Aguinaga, Jiachun Wu, Derek Patton, Zhe Qiang, Hossein Toghiani, Yizhi Xiang
Electrified catalytic processes for ammonia (NH3) decomposition have been considered as essential technologies for distributed COx-free hydrogen production. Here we show that efficient NH3 decomposition can be achieved over low-loading...
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Agent-based modeling of stress anisotropy driven nematic ordering in growing biofilms

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01535A, Paper
Open Access
Changhao Li, Japinder Nijjer, Luyi Feng, Qiuting Zhang, Jing Yan, Sulin Zhang
Our agent-based model reveals complex spatiotemperal evolution of the morphology and internal cell ordering of Vibrio cholerae biofilms.
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Thermoresponsive oil-continuous gels based on double-interpenetrating colloidal-particle networks

Soft Matter, 2024, 20,3033-3043
DOI: 10.1039/D3SM01582C, Paper
Braulio A. Macias-Rodriguez, Roland Gouzy, Corentin Coulais, Krassimir P. Velikov
Gels of multicomponent building blocks offer promising opportunities for the development of novel soft materials with unique and useful structures and properties.
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Fabric-based jamming phase diagram for frictional granular materials

Soft Matter, 2024, 20,3175-3190
DOI: 10.1039/D3SM01277H, Paper
Yuxuan Wen, Yida Zhang
Fabric-based jamming phase diagram, where Ft and Zt are the fabric anisotropy (deviatoric invariant of the 2nd order fabric tensor) and the coordination number (mean invariant of the 2nd order fabric tensor) of the total-contact network, respectively.
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Adsorption of semiflexible wormlike polymers to a bar and their double-chain complex formation

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00188E, Paper
Open Access
A. N. Semenov, I. A. Nyrkova
The quantitative transfer matrix approach and scaling arguments in terms of trains, loops, tails and supertrains allowed us to characterize the main regimes of semiflexible chain adsorption on a bar and double-chain complex formation.
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