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Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01025A, Edge Article
Open Access
Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor Alabugin
How far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...
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Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00021C, Edge Article
Open Access
Koichiro Masuda, Shū Kobayashi
A direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.
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Near-infrared light-activated membrane fusion for cancer cell therapeutic applications

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00863J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Fujian Huang, Ruilin Duan, Zhixin Zhou, Margarita Vázquez-González, fan xia, Itamar Willner
The spatiotemporal stimulation of liposome-liposome or liposome-membrane fusion processes attracts growing interest as a means to mimic cell-cell interactions in nature and for using these processes for biomedical applications. We...
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The Role of Porphyrin Peripheral Substituents in Determining the Reactivities of Ferrous Nitrosyl Species

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01625J, Edge Article
Open Access
Sk Amanullah, Abhishek Dey
Ferrous nitrosyl {FeNO}7 species are intermediates common to the catalytic cycles of Cd1NiR and CcNiR, two heme-based nitrite reductases (NiR), and its reactivity vary dramatically in these enzymes. The former...
The content of this RSS Feed (c) The Royal Society of Chemistry




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The Endeavor of Vibration-Induced Emission (VIE) for Dynamic Emissions

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01591A, Perspective
Open Access
Zhiyun Zhang, Guangchen Sun, Wei Chen, Jianhua Su, He Tian
Organic chromophores with large Stokes shifts and dual emissions are fascinating because of their fundamental and application interests. Vibration-induced emission (VIE) refers to a tunable multiple fluorescence exhibited by saddle-shaped...
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N2Phos – an easily made, highly effective ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura cross couplings in water

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00968G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nnamdi Akporji, Ruchita R. Thakore, Margery Cortes-Clerget, Joel Andersen, Evan Landstrom, Donald H. Aue, Fabrice Gallou, Bruce H. Lipshutz
A new, biaryl phosphine-containing ligand, N2Phos, forms a 1 : 1 complex with Pd resulting in an active catalyst at the ppm level for Suzuki–Miyaura couplings in water, enabled by an aqueous micellar medium. Notably, aryl chlorides are shown to be amenable substrates.
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Electrochemical Radical Reactions of Alkyl Iodides: A Highly Efficient, Clean, Green Alternative to Tin Reagents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01694B, Edge Article
Open Access
diyuan Li, Tsz-Kan Ma, Reuben J Scott, Jonathan David Wilden
An electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Weather Warnings for Queensland - land areas. Issued by the Australian Bureau of Meteorology




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Bihar gears up to screen all returnees from abroad

The state government is gearing up to facilitate the arrival of state residents stranded abroad, including in the Middle-East, after the Centre on Thursday kicked off the evacuation exercise to bring back Indian stranded due to the Covid-19 lockdown.




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Wife dead, man held on dowry charges in Patna

A 30-year-old man was arrested in Patna after his wife was found dead at their home in Shivpuri under Shastri Nagar police station area on Thursday. The couple, Manish Kumar and Anita Devi, were marred in 2017.




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Delhi: 2nd 'shramik spl train' leaves for Bihar

The workers were ferried to the New Delhi Railway station mostly in Delhi Transport Corporation (DTC) buses, and in some cases in police vans from shelters homes run by the city government.




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Bihar youth beaten to death by girlfriend's kin

An 18-year-old youth was held captive and subsequently beaten to death by the family members of a minor girl in a case of honour killing at a village in Vaishali district early on Friday.




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NCDEX gets Sebi go-ahead for Rs 500 crore IPO

The offering comprises a fresh issue aggregating up to Rs 100 crore and an offer for sale of up to 1.44 crore shares.




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Half of FY20 IPOs hold head above water in this selloff, some remain multibaggers

Out of the 15 stocks that got listed in FY 2019-20, seven are still trading above issue prices.




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Applied learning design in an online teacher-education course / Jillian J. Downing

Downing, Jillian J., author




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Academic culture : a student's guide to studying at university / Jean Brick, Maria Herke, Deanna Wong ; editor: Laura Davies

Brick, Jean, author




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Creating environments for learning : birth to age eight / Julie Bullard, University of Montana Western

Bullard, Julie, author




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Reflective teaching in higher education / Paul Ashwin and [and 10 others]

Ashwin, Paul, 1970-




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Researching higher education : international perspectives on theory, policy and practice / edited by Jennifer M. Case and Jeroen Huisman




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Understanding the University : institution, idea, possibilities / Ronald Barnett

Barnett, Ronald, 1947- author




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Teaching and learning for the twenty-first century : educational goals, policies, and curricula from six nations / Fernando M. Reimers, Connie K. Chung, editors




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Handbook of research on teaching / edited by Drew H. Gitomer and Courtney A. Bell




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Professional development, instructional intelligence and teacher emotions : a mixed methods study of a four-year systemic change initiative / by Rebecca Ann Saunders

Saunders, Rebecca Ann, author




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The falling rate of learning and the neoliberal endgame / David J. Blacker

Blacker, David J., author




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International handbook of research on conceptual change / edited by Stella Vosniadou




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The Giroux reader / by Henry A. Giroux ; edited and introduced by Christopher G. Robbins

Giroux, Henry A., author




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The abandoned generation : democracy beyond the culture of fear / Henry A. Giroux

Giroux, Henry A




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Education and the crisis of public values : challenging the assault on teachers, students, and public education / Henry A. Giroux

Giroux, Henry A, author




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Pedagogy and the politics of hope : theory, culture, and schooling : a critical reader / Henry A. Giroux

Giroux, Henry A




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Thinking with a line (TWAL©) : teacher's guide to the interactive CD-ROM / Cathy Weisman Topal

Topal, Cathy Weisman, author




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Thinking through new literacies for primary and early years / Jayne Metcalfe [and three others] ; edited by Dr Eileen Honan

Metcalfe, Jayne, author




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Those who can, teach / Kevin Ryan, James M. Cooper

Ryan, Kevin, 1932-




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Situation models and children's reading comprehension : what role does visual imagery play? / by Maroulia Katsipis

Katsipis, Maroulia, author




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The skillful teacher : on technique, trust, and responsiveness in the classroom / Stephen D. Brookfield

Brookfield, Stephen, author




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Teaching for social justice : a Democracy and education reader / edited by William Ayers, Jean Ann Hunt, and Therese Quinn




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Transforming schools : creativity, critical reflection, communication, collaboration / Miranda Jefferson and Michael Anderson

Jefferson, Miranda




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Research methods for education in the digital age / Maggi Savin-Baden and Gemma Tombs

Savin-Baden, Maggi, 1960- author




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Research methods for pedagogy / Melanie Nind, Alicia Curtin and Kathy Hall

Nind, Melanie, author




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Teaching language in context / Beverly Derewianka, Pauline Jones

Derewianka, Beverly, 1946- author




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Geoffrey Bolton introduces 'It had better be a good one' [videorecording] : the first ten years of Murdoch University

Bolton, G. C. (Geoffrey Curgenven), 1931-2015




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Early childhood and neuroscience : theory, research and implications for practice / Mine Conkbayir

Conkbayir, Mine, author




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Peer-group mentoring for teacher development / edited by Hannu Heikkinen, Hannu Jokinen and Päivi Tynjälä




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Still learning to think thinking to learn : within the Australian curriculum : planning with a thinking focus / Michael Pohl

Pohl, Michael, author




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Teaching thinking skills in the primary years : a whole school approach / by Michael Pohl

Pohl, Michael




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Effective teaching strategies : lessons from research and practice / Roy Killen

Killen, Roy, 1947-




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Learning English as a second language in the early years : hundreds of ideas for supporting children with English as an additional language / Anita Soni & Liz Rouse

Soni, Anita, (Educational psychologist), author




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Making learning whole : how seven principles of teaching can transform education / David N. Perkins

Perkins, David N




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How colleges work : the cybernetics of academic organization and leadership / Robert Birnbaum

Birnbaum, Robert




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Creating wonder : using natural and recycled materials / Jenny Aitken, Jan Hunt, Elizabeth Roy & Bess Sajfar

Aitken, Jenny, author




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Understanding behaviour in the early years

Mathieson, Kay