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Structure determination of difficult-to-crystallize organic molecules by co-crystallization of a phosphorylated macrocycle

Org. Chem. Front., 2024, 11,6358-6366
DOI: 10.1039/D4QO01498G, Research Article
Heng Li, Zhijin Li, Juli Jiang, Chen Lin, Leyong Wang
This work reported that 37 different difficult-to-crystallize guest molecules were co-crystallized with the host macrocycle F[3]A1-[P(O)Ph]3 at room temperature, and the molecular structures of the guests could be determined by SCXRD.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Silver likely to rule at higher levels this year on supply deficit

Supply shortage forecast to increase by 17% even as industrial demand is projected to rise 9%



  • Gold & Silver

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Gold prices may rule firm if central banks continue to buy, says World Gold Council

The yellow metal outlook looks strong: Sachin Jain, Regional CEO of WGC



  • Gold & Silver

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Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02656J, Paper
Tomasz Wojnowski, Anna Ordyszewska, Hanna Halenka, Iwona Anusiewicz, Jarosław Chojnacki, Kinga Kaniewska-Laskowska, Rafał Grubba
The reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me]

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT01863J, Paper
Rodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn Pillinger
For inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Ketamine [electronic resource] : the story of modern psychiatry's most fascinating molecule / by Keith G. Rasmussen.

Washington, DC : American Psychiatric Association Publishing, [2024]




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ICC continues discussion on Champions Trophy schedule with participating nations

Meanwhile, it was not a surprise that ICC has also put on hold the prestigious ODI tournament's launch event, which was scheduled to be held in Lahore on November 11.




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Spinners call the shots in Al Barkaat-Sule Guruji semis




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‘Headguard rule was removed to prevent concussion’

Kishen Narsi is chairman of the AIBA ad hoc committee, which oversees the sport in India




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Why Are Thousands Of Aspirants Protesting Against UPPSC Over Exam Schedule?

Tensions escalated among the students after UPPSC announced a new schedule for the preliminary exams.




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Delayed Asian Games rescheduled to start in September 2023

The Olympic Council of Asia on Tuesday confirmed the delayed games would be held from September 23 to October 8




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Understanding the structure–activity relationship of additives for durable Zn metal batteries: a case study of aromatic molecules

Energy Environ. Sci., 2024, 17,8349-8359
DOI: 10.1039/D4EE03232B, Paper
Da-Qian Cai, Haiyang Cheng, Jin-Lin Yang, Huan Liu, Tao Xiao, Xin Liu, Minghua Chen, Hong Jin Fan
The Zn/electrolyte interface with parallelly adsorbed Pym molecules can efficiently suppress corrosion and HER and simultaneously accelerate Zn redox kinetics by inducing zincophilicity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Well-regulated structure-featuring giant-molecule acceptors enable long-term stability and high-performance binary organic solar cells

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03754E, Paper
Jingyu Shi, Pengfei Ding, Jintao Zhu, Zhenyu Chen, Shuangjiao Gao, Xueliang Yu, Xiaochun Liao, Quan Liu, Ziyi Ge
Through systematically selecting the numbers and positions of selenium atom of giant-molecule acceptors, the device based on PM6:GMA-SSeS yields the highest PCE of 19.37% with high VOC of 0.917 V and exhibits extended t80% lifetimes of 5600 h.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Interfacial coordination utilizing chelating ligands for operationally stable perovskite solar modules

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02803A, Paper
Bingkun Tian, Peikun Zhang, Tianjun Liu, Weicun Chu, Yuyang Long, Peng Xu, Ying Jiang, Jinping Zhang, Yajing Tang, Xiangnan Sun, Riming Nie, Xiaoming Zhao, Wanlin Guo, Zhuhua Zhang
Perovskite solar cells (PSCs) feature a higher maximum theoretical efficiency and a lower cost than silicon-based solar cells, while also offering additional advantages of being flexible and transparent. However, the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Violation of rules causes traffic bottleneck on VOC Road




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Our Hindutva is not in contrast with Shahu-Phule-Ambedkar ideology: Eknath Shinde

Maharashtra Chief Minister accuses Congress of copying its flagship popular scheme ‘Mukhyamantri Majhi Ladki Bahin Yojana’ while announcing the five guarantees in Mumbai; welfare schemes of ruling alliance benefit everyone, he says




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HUL, fintech SRO raise concerns over Trai’s new rules for transactional messages

The Telecom Regulatory Authority of India, in a consultation paper issued in September, has suggested that users will have the option to opt out of receiving transactional messages




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Human milk oligosaccharides and milk fat globule membrane reduce allergic reactions in mice through the modulation of gut microbiota and metabolic functions

Food Funct., 2024, 15,11252-11265
DOI: 10.1039/D4FO03851G, Paper
Xinzhang Chen, Shengjun Yang, Zhengtao Guo, Bailiang Li, Zhongjiang Wang, Lianzhou Jiang
Human milk oligosaccharides (HMOs) and the milk fat globule membrane (MFGM) represent novel treatments for cow's milk allergy (CMA).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Editorial. Turbulent passage ahead for climate talks

The developed world has been implicitly arguing that China and India should contribute to the climate kitty rather than receive monies from it




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Severe turbulence jolts Buenos Aires-Frankfurt Lufthansa flight, 11 injured

The Boeing 747-8 had been carrying 329 passengers and 19 crew members. The turbulence was brief and occurred in an intertropical convergence zone




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Four astronauts return to Earth after being delayed by Boeing’s capsule trouble and Hurricane Milton

Four astronauts are back on Earth after a space station mission that lasted almost eight months




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Astronomers just found complex carbon molecules in space – a step closer to deciphering the origins of life

A new study shows that complex organic molecules (with carbon and hydrogen) likely existed in the cold, dark gas cloud that gave rise to our Solar System.




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Websol Energy System Ltd. - Board Meeting Intimation for Meeting Of The Board Of Directors Of The Company Is Schedule To Be Held On 13.08.2019 To Consider, Approve And Take On Record The Unaudited Financial Results For The Quarter Ended 30.06.2019 And Any




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Rajath Finance Limited - Board Meeting Intimation for Intimation Of Board Meeting Schedule To Be Held On 14Th August, 2019 For Approval Of Unaudited Result For The Quarter Ended On 30Th June, 2019




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Cian Agro Industries & Infrastructure Ltd - Board Meeting Intimation for Meeting Of The Board Of Directors Of The Company Is Scheduled To Be Held On Tuesday, 13Th August, 2019 To Consider And Approve The Un-Audited Financial Results Of The Company For




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Cats rule Istanbul




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Preparation and application of high thermal conductivity phase change microcapsules with fluorescence characteristics based on a ZnWO4 shell

Nanoscale, 2024, 16,20331-20341
DOI: 10.1039/D4NR02691H, Paper
H. Cheng, B. Tang, H. Y. Bao, F. Shan, C. X. Lu
This method produces microcapsules that possess a high thermal rate and good UV absorption and fluorescence properties, making them suitable for use in fluorescent buildings, textiles, coatings, and other applications.
The content of this RSS Feed (c) The Royal Society of Chemistry




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An injectable fluorescent and iodinated hydrogel for preoperative localization and dual image-guided surgery of pulmonary nodules

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00035H, Paper
Open Access
Woojin Back, Jiyun Rho, Kyungsu Kim, Hwan Seok Yong, Ok Hwa Jeon, Byeong Hyeon Choi, Hyun Koo Kim, Ji-Ho Park
We report the development of an injectable hydrogel-based dual computed tomography (CT) and near-infrared (NIR) imaging marker for use in preoperative pulmonary localization and intraoperative dual-imaging of deep-seated nodules.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Workshopon empowerment of Scheduled Castes held in Anakapalle




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Visakhapatnam cybercrime police arrest four mule account holders from Nellore

A businessman from Visakhapatnam was duped of ₹16.50 lakh by cyber criminals and the bank accounts of the four arrested were used by the main accused, say police




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French politicians navigate evolving fashion rules

Women politicians in France have largely abandoned the neat designer outfits of the past in a bid to look less elitist




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Column | When the rupee ruled

From Akbar’s rupiya to the Rupay app that’s going international, tracing the adventurous run of India’s currency




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Modi Slams Congress, Says ``Shahi Parivar` Believes They Are Born To Rule India`

PM Modi attacked the opposition alliance Maha Vikas Aghadi (MVA) and accused it of being the "biggest player of corruption".




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Apple iPhone 16 sales blocked in Indonesia due to local parts rule

Apple will not be allowed to sell its iPhone 16 smartphones in Indonesia because they have not met the country’s rules on the use of locally made components




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Colours that will rule the new year

Teja Lele Desai lists out shades that will stand out this year




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Colours to rule the new year

Teja Lele Desai lists out shades that will stand out this year




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Small molecule could help modulate the microbiome 

An inhibitor of starch-digesting enzymes stunts the growth of certain gut bacteria




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Small molecule could help modulate the microbiome

An inhibitor of starch-digesting enzymes stunts the growth of certain gut bacteria




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Roy C. Tulee




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Scientists push back against Trump administration’s proposed visa rules




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Sensing molecules released from single cells without labels

Combination of microfluidics and a nanosensor achieves label-free detection of cytokines from individual cells




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Ancient organic molecules found on Mars

Curiosity rover also reports data on the red planet’s mysterious methane plumes




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Sensing molecules released from single cells without using labels

Combination of microfluidics and a nanosensor achieves label-free detection of cytokines from individual cells




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Chemists synthesize Saturn-shaped molecule

Flat, macrocyclic host captures fullerene guest with CH–π interactions




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Human enzyme makes antiviral small molecule

Naturally occurring compound inhibits replication of Zika virus in living cells




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Celgene partners with Skyhawk Therapeutics to drug RNA with small molecules

Skyhawk will receive $60 million up front to develop drug candidates that target RNA in neurological diseases




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Ocean geysers on Enceladus harbor large organic molecules

Moon is a good candidate to host extraterrestrial life, but this find isn’t proof that it does




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Human enzyme makes antiviral small molecule

Naturally occurring compound inhibits replication of Zika virus in living cells




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Reversing rules of arene chemistry

New norbornene compound overcomes ring substitution limitation