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Boosting the electrocatalytic activity of single atom iron catalysts through sulfur-doping engineering for liquid and flexible rechargeable Zn–air batteries

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00524D, Paper
Tianfang Yang, Bingcheng Ge, XuPo Liu, Zunjie Zhang, Ye Chen, Yang Liu
A practical strategy is reported to design single-Fe atom decorated S/N-doped C (Fe SAs@S/N–C) catalysts with a high Fe loading of 5.45 wt%. The prepared catalysts exhibit excellent performances for liquid and all-solid-state Zn–air batteries.
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A high-current initiated formation strategy for improved cycling stability of anode-free lithium metal batteries

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01043D, Paper
Kangning Cai, Mengtian Zhang, Geng Zhong, Guohuang Kang, Jie Biao, Chuang Li, Yanru Liu, Guangmin Zhou, Feiyu Kang, Yidan Cao
Anode-free lithium metal batteries (AFLMBs) are considered as one of the most promising candidates for next-generation high-energy-density rechargeable lithium batteries. An efficient high-current initiated formation strategy is developed for AFLMBs.
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Boosting reaction kinetics of polycrystalline phase Fe7S8/FeS2 heterostructures encapsulated in hollow carbon nanofiber for superior fast sodium storage

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01241K, Paper
Hui Cai, Fei Wang, Huiyan Feng, Zhendong Liu, Chengzhi Zhang, Anbang Lu, Xi Zhao, Qiuhong Lu, Quanbing Liu, Jun Tan
Metal sulfides have been regarded as highly competitive anode materials for fast sodium storage due to the excellent redox reversibility and comparatively great electron properties. Nevertheless, metal sulfides suffer from...
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Bio-inspired design of a self-supported bismuth microforest for high performance sodium storage

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00950A, Paper
Jia Bai, Yan Liu, Ben Pu, Qi Tang, Yongbin Wang, Ruihan Yuan, Jin Cui, Yi Yang, Xiaojia Zheng, Bin Zhou, Weiqing Yang
A self-supported bismuth microforest anode material, prepared by a simple, efficient and scalable in situ galvanic replacement approach, exhibits high performance for sodium-ion batteries.
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Tuning the ion conductivity of Zr-based metal organic framework ionogels by linker functionalization

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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA06986A, Paper
Open Access
Antonija Ferbezar, Roman Zettl, Katharina Hogrefe, Harald Fitzek, Bernhard Gadermaier, Martin Wilkening, Ilie Hanzu
Solid-state ion conductors have improved significantly in the past decade. Envisioned applications range from metal anode batteries and fuel cells to sensors and medical technologies. The choice of solid electrolytes...
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In situ construction of a double perovskite heterostructure with exsolved FeNi3 alloy nanoparticles for CO2 electrolysis in solid oxide electrolysis cells

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07820E, Paper
Xiaoyu Wang, Haibo Hu, Caiyue Xie, Yifei Wang, Haowei Li, Xifeng Ding
FeNi3 nanoparticles anchored on the (PrBa)0.95Fe1.6Ni0.4O6−δ double perovskite enhance the electrochemical performance and durability in direct CO2 electrolysis.
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Oxygen insertion at the cage center: an unconventional tuning strategy for enhancing the photocatalytic performance of atomically precise copper cluster cocatalysts

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07218E, Paper
Yun-Dong Cao, Di Yin, Ming-Liang Wang, Hong Liu, Yi Feng, Lin-Lin Fan, Cai-Li Lv, Guang-Gang Gao
This work not only confirms the long-standing prediction that the Cu8 center can accommodate an oxygen atom but also demonstrates a novel central atom regulation strategy to obtain highly active copper clusters as photocatalysts.
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Melatonin treatment as an anti-aging therapy for UV-related degradation of perovskite solar cells

By pubs.rsc.org
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01332H, Paper
Fei Liu, Agnes Valencia, Yuhua Zhu, Xiangyang Zhang, Weilu Li, Walid A. Daoud
With the ability to absorb UV light and scavenge radicals, the melatonin modified perovskite exhibits enhanced anti-aging and resistance to UV-related degradation.
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Closed pore structure engineering from ultra-micropores with the assistance of polypropylene for boosted sodium ion storage

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01375A, Paper
Xue Li, Ning Sun, Shaohong Zhang, Razium Ali Soomro, Bin Xu
Closed pore architectures with exceptional Na-storage performance have been successfully fabricated from ultra-micropores with the assistance of polypropylene.
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Data-driven discovery of carbonyl organic electrode molecules: machine learning and experiment

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00136B, Paper
Jiayi Du, Jun Guo, Qiqi Sun, Wei Liu, Tong Liu, Gang Huang, Xinbo Zhang
In this work, a universal strategy for the identification of high-performance OEMs for LIBs has been illustrated. The predicted molecule, naphthalene-1,4,5,8-tetraone, exhibits excellent electrochemical performance in terms of capacity and lifetime.
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In situ analysis of the oxygen evolution reaction on the CuO film in alkaline solution by surface interrogation scanning electrochemical microscopy: investigating active sites (CuIII) and kinetics

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00628C, Paper
Seokjun Han, Jinoh Yoo, Won Tae Choi
Surface interrogation scanning electrochemical microscopy was employed to assess the electrocatalytic activity of CuO films for the oxygen evolution reaction in an alkaline solution.
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Enhancing CO2 gasification-reforming of municipal solid waste with Ni/CeO2 and Ni/ZrO2 catalysts

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00665H, Paper
Shiyu Zhang, Yibing Peng, Mengna Wu, Qinghai Li, Yanguo Zhang, Hui Zhou
CO2 gasification-reforming facilitates CO2 utilization and yields CO-rich syngas for municipal waste management. Catalysts are essential for enhancing syngas production via catalytic tar reforming.
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Insights into the Enhanced Cycling Stability of Cobalt-Free Single-Crystal Layered Oxide Cathodes at Elevated Voltage

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Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA02135E, Paper
Tiancheng Liu, Ke Fan, Changsheng Chen, Mingxia Dong, Yanping Zhu, Gao Chen, Jiangtong Li, Zezhou Lin, Liuqing Li, Ye Zhu, Huangxu Li, Haitao Huang
Co-free single-crystal cathodes Li(NixMn1-x)O2 have been proposed as promising candidates due to remarkable thermal stability and low cost. Unfortunately, insufficient in-depth understanding on the failure mechanisms hinders the development of...
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Highly Boosted Energy Storage Performance of Few-Layered MoS2 Utilized by Improved Electrode Fabrication: Experimental and Theoretical Studies

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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01713G, Paper
Zeyad M. Abdulhamid, Abhishek C. Lokhande, Adewale Hammed Pasanaje, Daniel S Choi, Nirpendra Singh, Kyriaki Polychronopoulou, Dalaver H. Anjum
Few-layer two-dimensional (2D) molybdenum disulfide (MoS2) has great potential in designing high-performance supercapacitors due to its high theoretical specific capacity, tunable bandgap, and fascinating 2D layered structure. However, the lack...
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Amphipathic Emulsion Binder for Enhanced Performance of Lithium-Sulfur Batteries

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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01037J, Paper
Yuan He, Xulong Jing, Tianxing Lai, Dong Jiang, Chao Wan, Pavel S Postnikov, Olga Guselnikova, Lixin Xu, Xiaojun He, Yusuke Yamauchi , Biyu Jin
The application of polyvinylidene fluoride (PVDF) binder in lithium-sulfur batteries faces challenges due to inadequate adhesion, undesirable conductivities, limited lithium polysulfides absorbability, and its dependence on the use of toxic...
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Constructing vacancy-rich metal phosphates by the spatial effect of ionic oligomers for enhanced OER activity

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01706D, Paper
Yida Zhao, Xinyu He, Xiaoming Ma, Zhengxi Guo, Menghui Qi, Zhaoming Liu, Ruikang Tang
By rationally selecting ionic oligomers as building blocks, sub-nano-sized gaps can be constructed in the solid structure of catalysts. This can overcome the inherent limitations associated with vacancy formation of the traditional nucleation pathway.
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Harvesting solar energy with a Ni-MOF-based evaporator for efficient solar thermal storage and steam generation

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00203B, Paper
You Xu, Zhengyun Wang, Xianbao Wang, Zhenzhen Guo, Muhammad Sultan Irshad, Naila Arshad, Jiang Gong, Hongfang Liu, Guangfang Li
A hybrid solar evaporator comprising a Ni-based metal–organic framework material and a phase change material composite was fabricated for high performance solar-thermal energy storage and continuous solar vapor generation.
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Machine Learning Enabled Exploration of Multicomponent Metal Oxides for Catalyzing Oxygen Reduction in Alkaline Media

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Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01884B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xue Jia, Hao Li
Low-cost metal oxides have emerged as promising candidates used as electrocatalysts for oxygen reduction reaction (ORR) due to their remarkable stability under oxidizing conditions, particularly in alkaline media. Recent studies...
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Insight into piezoelectricity modulation mechanism of ZnO doped with Y ions

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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01317D, Paper
Zihan Wang, Yue Sun, Shenglong Wang, Da Xiong, Guo Tian, Longchao Huang, Boling Lan, Long Jin, Weiqing Yang, Weili Deng
ZnO is a performance-rich material due to its unique coupling of piezoelectricity and semiconductor properties. However, the intrinsic piezoelectric screening effect of ZnO weakens the electromechanical conversion efficiency and greatly...
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The Role of Mn in Boosting Wide Potential Window on Solid Solution Derived Electrodes for Aqueous Supercapacitors

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Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00979G, Paper
Ziying Shi, Enzuo Liu, Biao Chen, Junwei Sha, Lihua Qian, Zhijia Zhang, Xiaopeng Han, Wenbin Hu, Chunnian He, Naiqin Zhao, Jianli Kang
The interaction mechanism of the multi-element oxide electrodes remains a challenge, despite the fact that their synergy can not only improve the electronic structure, but also broaden the working potential...
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Enhanced surface reconstruction of V-Doped Ni3N driven by strong OH adsorption to boost 5-hydroxymethylfurfural electrooxidation for energy-saving H2 production

By pubs.rsc.org
Published On ::

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01543F, Paper
Qi Zhou, Juan Wang, Ga Jin, Huiling Liu, Cheng Wang
Coupling biomass electrooxidation with hydrogen evolution reaction (HER) provides an alternative approach for simultaneously increasing the energy efficiency of H2 production and producing high value-added chemicals. Here, a V-doped Ni3N...
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The fluorescence distinction of chiral enantiomers: a Zn coordination polymer sensor for the detection of cinchonine and cinchonidine

By pubs.rsc.org
Published On ::

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03506B, Paper
Wenping Hu, Nan Wu, Dechao Li, Yefang Yang, Shaowen Qie, Shuai Su, Ruijie Xu, Wenting Li, Ming Hu
A Zn coordination polymer was constructed to identify chiral cinchonine and cinchonidine with high sensitivity, selectivity, and reproducibility.
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Superconductivity above 30 K due to the introduction of oxygen element in CaFeAsF

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Published On ::

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03994G, Paper
Yixin Liu, Teng Wang, Zulei Xu, Da Jiang, Yi Zhao, Yanpeng Qi, Xiaoni Wang, Ming Yang, Mao Ye, Wei Peng, Gang Mu
Exploring new unconventional superconductors is of great value for both fundamental research and practical applications. It is a long-term challenge to develop and study more hole-doped superconductors in 1111 system...
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Breaking the Trade-off Between ∆EST and Oscillator Strength in Hybrid LR/SR-CT Compounds for Enhanced TADF Performance

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Published On ::

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04549A, Paper
Nikhitha R., Anirban Mondal
Achieving an ideal thermally activated delayed fluorescence (TADF) emitter requires balancing a minimal singlet-triplet energy gap (∆EST) with a considerable oscillator strength (f), which are typically mutually exclusive. By strategically...
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Multimodal anti-counterfeiting inks: modern use of an ancient pigment in synergy with a persistent phosphor

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Published On ::

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04228J, Paper
ALESSANDRO LO BIANCO, Francesco Armetta, Vitalii Boiko, Dariusz Hreniak, Maria Luisa Saladino
A multi-level luminescent, transparent and not-permanent inks for anti-counterfeiting systems and security was developed. The inks emit a radiation of different wavelength depending on the radiation used to illuminate them,...
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Dopant-free Tert-butyl Zn (II) Phthalocyanines: Impact of Substitution on Photo-Physical Properties in Their Role in Perovskite Solar Cells

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Published On ::

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04013A, Paper
Mahdi Gassara, Jose Garcés-Garcés, Luis Lezama, Javier Ortiz, Fernando Fernandez-Lazaro, Samrana Kazim, Angela Sastre-Santos, Shahzada Ahmad
We synthesized molecular hole-transporting materials (HTMs) featuring a zinc phthalocyanine (ZnPc) central core and modulated the non-perypheral position with different numbers of tert-butyl groups. The synthesized molecules were also integrated...
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The Mushroom Color Atlas: An Interactive Web Site Lets You Explore the Incredible Spectrum of Colors Created from Fungi

By www.openculture.com
Published On :: Wed, 13 Nov 2024 09:04:10 +0000

Enter the Mushroom Color Atlas, and you can discover the “beautiful and subtle colors derived from dyeing with mushrooms.” Featuring 825 colors, each associated with different types of mushrooms, the interactive atlas lets you appreciate the broad spectrum of colors latent in the fungi kingdom. The shades, tints, and hues will surprise you. Julie Beeler, […]


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A New 3D Scan, Created from 25,000 High-Resolution Images, Reveals the Remarkably Well-Preserved Wreck of Shackleton’s Endurance

By www.openculture.com
Published On :: Wed, 13 Nov 2024 10:00:16 +0000

Photos on this page courtesy of the Falklands Maritime Heritage  Few who hear the story of the Endurance could avoid reflecting on the aptness of the ship’s name. A year after setting out on the Imperial Trans-Antarctic Expedition in 1914, it got stuck in a mass of drifting ice off Antarctica. There it remained for ten months, […]


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Coimbatore District Police arrest two men for robbing Kerala jeweller of ₹54 lakh

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 19:29:30 +0530


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Kalpathy car fest: a spectacle of faith and tradition

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 20:57:49 +0530

Chariots of the Sree Visalakshi Sametha Viswanatha Swamy temple start moving through the streets


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Food prices rising due to failed policies of Modi govt., says Congress

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 21:03:46 +0530

Tomatoes, onions, and potatoes disappearing from common man’s plate, says Jairam Ramesh


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Preethi Abraham takes charge as Accountant General of Kerala

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 21:12:10 +0530


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BJP accuses Congress of releasing election manifesto during “silence” period in Jharkhand

By www.thehindu.com
Published On :: Thu, 14 Nov 2024 07:40:16 +0530

Mr. Patra claimed that the Congress wanted to give 4% reservation to the Muslim organisations and contractors in public tenders


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BJP’s win in recent polls is expression of people’s faith in govt. policies: Haryana Governor

By www.thehindu.com
Published On :: Thu, 14 Nov 2024 07:50:35 +0530


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Mamata calls for unity of hills and plains; focuses on development in north Bengal

By www.thehindu.com
Published On :: Thu, 14 Nov 2024 07:55:01 +0530

This is her first official visit to Darjeeling in two years; she did not go to the hills even during the 2024 Lok Sabha election campaigns


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Use fog safety devices to ensure punctuality and safety of trains in winters: SCR GM

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 14:13:21 +0530


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US Deputy Secretary of State Kurt Campbell to attend inaugural US India Indian Ocean Dialogue in Delhi

By www.thehindubusinessline.com
Published On :: Wed, 13 Nov 2024 10:42:54 +0530

During his visit, on November 13-14, Campbell will also participate in the Critical and Emerging Technologies (iCET) Intersessional to further expand cooperation between the United States and India on technological innovation and production


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'Any relief on bank guarantee will be provided across the sector': Scindia on Vodafone Idea request for waiver of bank guarantees for spectrum

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 17:36:01 +0530


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India IT spending to reach USD 160 billion in 2025 fueled by application and infrastructure software market growth: Gartner

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 17:38:01 +0530


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India's index of industrial production shows 3.1 per cent growth in September 2024

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 17:48:02 +0530


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Public Sector Banks records strong performance in 1st half of FY25

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 17:50:02 +0530


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FSSAI discusses various sets of compliances with e-commerce food operators

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 17:54:01 +0530


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India set to become 'major producer' of electric vehicles like China: Mark Mobius

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 18:50:02 +0530


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India could save 91,000 crore rupees on import bill through biofuel blending: Hardeep Singh Puri

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 19:04:01 +0530


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Photocatalytic 1,3-Oxyheteroarylation of Aryl Cyclopropanes with Azine N-oxides

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06723A, Edge Article
Open Access
Doyoung Kim, Hyewon Ju, Wooseok Lee, Sungwoo Hong
Cyclopropanes, valuable C3 building blocks in organic synthesis, possess high strain energy and inherent stability. We present an efficient, environmentally benign 1,3-oxyheteroarylation of aryl cyclopropanes using azine N-oxides as bifunctional...
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Guest modulating the photoactivity of a titanium-oxide cage

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04983G, Edge Article
Open Access
Dexin Wang, Yanshu Liu, Guanyun Zhang, Menghui Chu, Fangfang Gao, Guanjie Chen, Guo Wang, Chen-Ho Tung, Yifeng Wang
Ti-oxide salicylate clusters with novel biloculate cages and exchangeable guests are reported. The guests influence the physiochemical properties and photocatalytic CO2/epoxide cycloaddition activities of the complexes.
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Synthesis of highly condensed phospholes by Lewis acid-assisted dehydrogenative Mallory reaction under visible light irradiation

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05657D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ikki Kamiyoshi, Yuki Kojima, Shibo Xu, Kosuke Yasui, Yuji Nishii, Koji Hirano
A photo-promoted oxidative cyclization, that is, Mallory reaction of 2,3-diarylbenzophopholes has been developed. With an assistance of Bi(OTf)3 Lewis acid, the reaction proceeds smoothly under visible light irradiation even without...
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Providing better healthcare biggest priority: PM Modi ahead of Darbhanga AIIMS inauguration

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 16:38:02 +0530


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India's CO2 emissions account 8pc of global total, to rise by 4.6pc in 2024: Report

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 18:34:02 +0530


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Vistara's last flight from Odisha takes off for Delhi ahead of merger with Air India

By www.newkerala.com
Published On :: Wed, 13 Nov 2024 19:06:02 +0530


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