liz

A generalized model for predicting different morphologies of bacterial swarming on a porous solid surface

By pubs.rsc.org
Published On ::

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM01072H, Paper
Uttam Kumar, Pushpavanam Subramaniam
In this study, we develop a comprehensive two-phase model to analyze the dynamics of bacterial swarming on porous substrates. The two distinct phases under consideration are the cell and aqueous...
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Bevel Up : Chapter 4 - Becky & Liz / directed by: Nettie Wild ; produced by: Julie Huguet, André Picard ; production agencies: British Columbia Centre for Disease Control. Street Nurse Program (Vancouver), National Film Board of Canada (Montreal)

By darius.uleth.ca
Published On ::

Montreal : National Film Board of Canada, 2019


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Visible-light excited copper activating unactivated alkyl iodides for radical addition/cyclization to access oxindole derivatives

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, 11,6380-6384
DOI: 10.1039/D4QO01329H, Research Article
Hang Luo, Fangnian Yu, Luqing Lin
The photocopper catalyst facilitates halogen atom transfer to give unactivated alkyl radicals, which is critical for achieving radical cyclization in the absence of an exogenous photocatalyst.
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Structure determination of difficult-to-crystallize organic molecules by co-crystallization of a phosphorylated macrocycle

By pubs.rsc.org
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Org. Chem. Front., 2024, 11,6358-6366
DOI: 10.1039/D4QO01498G, Research Article
Heng Li, Zhijin Li, Juli Jiang, Chen Lin, Leyong Wang
This work reported that 37 different difficult-to-crystallize guest molecules were co-crystallized with the host macrocycle F[3]A1-[P(O)Ph]3 at room temperature, and the molecular structures of the guests could be determined by SCXRD.
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Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, 11,6319-6326
DOI: 10.1039/D4QO01368A, Research Article
Yu Lan, Peng Liu, Zekai Fang, Lili Shao, Qilong Cai, Xiaoming Wang
A variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.
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Copper(II)-catalyzed synthesis of sulfonyl-functionalized quinone-fused cyclopenta[b]indoles via four-component cascade annulation

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01560F, Research Article
Hong Xu, Jie Liao, Fei Ren, Chuan-Rong Zhou, Xiao-Zhuo Liu, Yao Xiao, Dong-Wei Hang, Fuyu Li, Bei Wang, Ji-Yu Wang
Through crucial selective radical tandem process and intramolecular nucleophilic addition, a facile copper-catalyzed four-component cascade has been realized to selectively construct novel sulfonyl-functionalized quinone-fused cyclopenta[b]indole.
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Folding of a dynamic macrocyclic system to stabilize its cation radical state

By pubs.rsc.org
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01566E, Research Article
Arnab Dutta, Krzysztof Dzieszkowski, Marco Farinone, Łukasz Orzeł, Krzysztof Kruczała, Monika Kijewska, Miłosz Pawlicki
A precisely designed π-extended system responds to different stimuli by folding the structure, which prevents overoxidation and stabilizes the cation radical.
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Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization

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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01627K, Research Article
Bo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long Zhu
We report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.
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Palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids for the synthesis of fused isoquinolinones

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01573H, Research Article
Zhaolin Quan, Yubo Duan, Zhengkai Chen
A straightforward approach for the preparation of fused isoquinolinone derivatives via palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids is described.
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PIFA-Mediated cyclization of methyl(2-(1-phenylvinyl)phenyl)sulfane for the concise, flexible, and scalable de novo synthesis of C3-arylated benzo[b]thiophenes

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01589D, Research Article
Xinya Liu, Olivier Provot, Christine Tran, Jean-Francois Soule, Abdallah Hamze
The well-decorated arylated benzo[b]thiophene scaffold is a pivotal structural motif with diverse applications in medicinal chemistry. This paper outlines a de novo synthesis of C3-arylated benzo[b]thiophenes, showcasing its flexibility and...
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Enhanced surface functionalization of 2D molybdenum/tin chalcogenide nanostructures for effective SERS detection of Escherichia coli

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35021-35034
DOI: 10.1039/D4RA05315J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zainab Ishfaq, Layla A. Almutairi, M. Yasir Ali, Salhah Hamed Alrefaee, Mohamed Abdelsabour Fahmy, Elsammani Ali Shokralla, Lamiaa G. Alharbe, Adnan Ali, Arslan Ashfaq, A. R. Abd-Elwahed
This study enhances MoS2/SnS2 nanoparticles for SERS, functionalizing them with L-cysteine. Successful detection of E. coli demonstrates their potential as cost-effective SERS substrates for real-world applications.
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An electrochemiluminescence device for visualized detection of lead in practical samples

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35232-35238
DOI: 10.1039/D4RA05742B, Paper
Open Access
Huaanzi Hu, Cheng Wang, Chen Qian, Chengqi Li, Yulin Li, Jianbin Pan, Xinye Ni
An up-response ECL imaging system is designed for visualized Pb2+ detection with high selectivity.
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N-doped carbon quantum dots for the selective detection of OCl− ions, bioimaging, and the production of Fe3O4 nanoparticles utilized in the synthesis of substituted imidazole

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35448-35459
DOI: 10.1039/D4RA06474G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Namrata Priyadarshini Hota, Sathiyanarayanan Kulathu Iyer
Nitrogen-doped quantum dots (NCQD) were synthesized by solvothermal means using o-phenylenediamine and L-tartaric acid.
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Low temperature synthesis of franklinite stabilized cefixime as a multifunctional nanoformulation

By pubs.rsc.org
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RSC Adv., 2024, 14,34156-34164
DOI: 10.1039/D4RA06435F, Paper
Open Access
Amna Munsaf, Muhammad Naeem Ahmed, Aroosa Zafar, Bilal Akram, Mahmoud A. A. Ibrahim
Cefixime, an antibiotic with low solubility, stability, bioavailability and therapeutic effectiveness, needs to be administered in larger doses for effective treatment.
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Chronological effects of oxygen on the structural transformations of polyacrylonitrile fibers during the rapid thermal stabilization process

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35560-35567
DOI: 10.1039/D4RA06327A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shiyang Li, Liang Chen, Jie Liu, Yixin Li, Jian Tang, Rongchao Jiang, Xiaoxu Wang
The effects of oxygen on the structure changes of PAN fibers during the rapid thermal stabilization are chronological, including thermal-driven dehydrogenation, oxidation and cyclization in the shorter, intermediate and longer periods, respectively.
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Synthesis and characterization of carbonyl functionalized organotellurium(IV) derivatives

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35650-35656
DOI: 10.1039/D4RA06023G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Puspendra Singh, Mariya Khan, Andrew Duthie, Ray J. Butcher
Aryltellurium trichlorides, ArTeCl3 (Ar = C6H5, Ph; 4-Me-C6H4, p-Tol; 1-C10H7, 1-Nap; 2,4,6-Me3C6H2, Mes) react under mild conditions with acetylacetone/benzoylacetone to give carbonyl functionalized organotellurium(IV) derivatives.
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Tailoring dual cross-linked polymer-ionic liquid composites by blending co-crystallizable polymers for stretchable electronics

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,36022-36030
DOI: 10.1039/D4RA05968A, Paper
Open Access
Minjun Kim, Moonsung Park, Hobin Seon, Sohyun Choi, Hee Joong Kim, Sangwon Kim
A dual cross-linked polymer-ionic liquid composite exhibits self-healing capabilities and is ideal for wearable strain sensor applications.
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Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
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Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02656J, Paper
Tomasz Wojnowski, Anna Ordyszewska, Hanna Halenka, Iwona Anusiewicz, Jarosław Chojnacki, Kinga Kaniewska-Laskowska, Rafał Grubba
The reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the...
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Two amino-functionalized metal–organic frameworks with different topologies for C2H2/C2H4 separation

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02592J, Communication
Yue Li, Mingming Xu, Hongyan Liu, Xiaokang Wang, Yutong Wang, Meng Sun, Weidong Fan, Daofeng Sun
Two amino-functionalized metal–organic frameworks (UPC-121 and UPC-122) with different topologies were obtained by regulating metal ions. Among them, UPC-122 exhibit the potential to separate C2H2/C2H4 at room temperature.
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Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction

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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02756F, Paper
Xiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing Wan
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
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The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions

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Dalton Trans., 2024, 53,18013-18020
DOI: 10.1039/D4DT02533D, Paper
Open Access
Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. Nolan
Despite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.
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Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

By pubs.rsc.org
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Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
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Reconceptualizing Mental Illness in the Viral Age [electronic resource] : Souls in the Machine / by Elliott B. Martin, Jr.

By darius.uleth.ca
Published On ::

Newcastle upon Tyne : Cambridge Scholars Publishing, 2024.


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Sustainable treatment for low ammonia nitrogen sewage wastewater in cold climates: natural polymer gel–organic synthetic polymer embedded anammox bacteria immobilized pellets

By pubs.rsc.org
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Environ. Sci.: Water Res. Technol., 2024, 10,2809-2830
DOI: 10.1039/D4EW00538D, Paper
Jun Li, Salma Tabassum, Hüseyin Altundag
Denitrification effect of the hybrid carrier-embedded anammox bacteria pellets to treat NH4+–N urban sewage wastewater at low temperature through batch and continuous tests.
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Mathematical modeling to size anaerobic stabilization ponds intended for slaughterhouse wastewater treatment – the role of temperature and hydraulic retention time

By pubs.rsc.org
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Environ. Sci.: Water Res. Technol., 2024, 10,2882-2896
DOI: 10.1039/D4EW00557K, Paper
P. E. S. Soldera, R. F. Dantas, E. Fagnani
A new mathematical model for constructing anaerobic stabilization pond treatment systems for high organic load wastewater, based on biochemical oxygen demand, temperature and hydraulic retention time, is discussed.
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Simultaneous removal of acetaminophen, sulfamethoxazole, and iohexol from real wastewater in continuous mode by an immobilized sulfur-doped Bi2O3/MnO2 photocatalyst

By pubs.rsc.org
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Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00501E, Paper
Vishal Kumar Parida, Mario Vino Lincy Gnanaguru, Suneel Kumar Srivastava, Shamik Chowdhury, Ashok Kumar Gupta
The photocatalytic potential of the Z-scheme 2S-Bi2O3/MnO2 immobilized photocatalyst for the simultaneous degradation of ACT, SMX, and IOX from MBBR-sand filter treated wastewater is studied for the first time, purely from a practical perspective.
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Dead lizard found in meal sparks agitation at Digital University Kerala; mess temporarily closed

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 21:20:30 +0530

The contractor responsible for providing food to over 200 students has claimed to have purchased the pickle from outside


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India wouldn't be fastest-growing economy if people hadn't utilized digital infrastructure: Nirmala Sitharaman

By www.thehindu.com
Published On :: Wed, 23 Oct 2024 10:32:51 +0530

Nirmala Sitharaman highlighted that providing free digital access to the public, coupled with extensive campaigns and awareness programs in local languages, helped people across the country embrace technology


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De-templated crystallization in 2D perovskites for enhanced photovoltaic efficiency

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Energy Environ. Sci., 2024, 17,8284-8292
DOI: 10.1039/D4EE03272A, Paper
Fang Zeng, Zhenhuang Su, Weiyu Kong, Feng Li, Yuhang Liang, Xingmo Zhang, Tao Wang, Lin Zhang, Yuze Lvtao, Runkai Liu, Xingyu Gao, Jun Huang, Xudong Yang, Rongkun Zheng
A de-templated crystallization strategy using a stable intermediate to promote out-of-plane crystallization of layered 2D perovskites was proposed, in favor of highly efficient and stable perovskite solar cells.
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Stabilizing doped Spiro-OMeTAD by organic molten salt for efficient and stable perovskite solar cells

By pubs.rsc.org
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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04310C, Paper
Tengfei Pan, Zhiwei Li, Biyun Ren, Wan Yang, Xueqin Ran, Yajing Li, Yutian Xu, Yue Wang, Deli Li, Yingdong Xia, Xingyu Gao, Lingfeng Chao, Yonghua Chen
Bis(trifluoromethane)sulfonimide (LiTFSI) and 4-tert-butylpyridine (TBP) have been currently suggested to be irreplaceable in classic doped 2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD) for high-performance perovskite solar cells (PSCs). However, the stability of Spiro-OMeTAD was...
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The construction of multifunctional solid electrolyte interlayers for stabilizing Li6PS5Cl-based all-solid-state lithium metal batteries

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03289F, Paper
Ya Chen, Xin Gao, Zheng Zhen, Xiao Chen, Ling Huang, Deli Zhou, Tengfei Hu, Bozhen Ren, Runjing Xu, Jiayi Chen, Xiaodong Chen, Lifeng Cui, Guoxiu Wang
The established multifunctional interlayers effectively eliminate both anode-initiated and GB-initiated dendrites and guarantee satisfactory battery performance for ASSLMBs.
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Regulating the Crystallization of Mixed-Halide Perovskites by Cation Alloying for Perovskite-Organic Tandem Solar Cells

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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03045A, Paper
Mingqian Chen, Yanxun Li, Zixin Zeng, Ming Liu, Tao Du, Xiaofeng Huang, Leyu Bi, Jiarong Wang, Wenlin Jiang, Yidan An, Sai Wing Tsang, Jun Yin, Shengfan Wu, Alex K. Y. Jen
Halide segregation and energy loss pose significant challenges for wide-bandgap perovskite solar cells, impairing their photovoltage and device stability. These issues are often exacerbated by inferior film quality and inhomogeneous...
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Interfacial coordination utilizing chelating ligands for operationally stable perovskite solar modules

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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02803A, Paper
Bingkun Tian, Peikun Zhang, Tianjun Liu, Weicun Chu, Yuyang Long, Peng Xu, Ying Jiang, Jinping Zhang, Yajing Tang, Xiangnan Sun, Riming Nie, Xiaoming Zhao, Wanlin Guo, Zhuhua Zhang
Perovskite solar cells (PSCs) feature a higher maximum theoretical efficiency and a lower cost than silicon-based solar cells, while also offering additional advantages of being flexible and transparent. However, the...
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Weaving electron-rich alkynes: a durable in situ skin for stabilizing zinc anodes

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03164D, Paper
Xin Liu, Weimian Zhang, Ying Liu, Xiaodong Li, Deyi Zhang, Kun Wang, Lifeng Liu, Changshui Huang
An electron-rich alkyne of thiophdiyne (e-TDYP) is engineered in situ onto a zinc anode to regulate the EDL properties. The synergy between the conjugated thiophene and alkyne groups of e-TDYP facilitates the desolvation and ion-capture.
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Salt Dissociation and Localized High-concentration Solvation by Interface of Fluorinated Gel and Polymer Solid Electrolyte

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04078C, Paper
Dechao Zhang, Yuxuan Liu, Dedi Li, Shimei Li, Qi Xiong, Zhaodong Huang, Shixun Wang, Hu Hong, Jiaxiong Zhu, Haiming Lyu, Chunyi Zhi
Low salt dissociation and unstable [Li(N, N-dimethylformamide (DMF))x]+ solvent structure in poly(vinylidene fluoride) (PVDF)-based solid polymer electrolyte (SPE) remarkably restricts the high throughput ion transport and interfacial stability. Here, we...
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Self-assembled porous salt crystals for solar-powered crystallization

By pubs.rsc.org
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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04741A, Paper
Jie Yu, Lenan Zhang, Jintong Gao, Wenyu Han, Ruzhu Wang, Zhenyuan Xu
Thermally localized solar evaporation has been recognized as an efficient and suitable pathway for desalination and brine treatment. However, the annoying salt crystallization inside the porous evaporator brings challenges for...
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TiO2 nanopowder and nanofilm catalysts in the disinfection and mineralization of S. aureus with solar-simulated radiation

By pubs.rsc.org
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00540B, Paper
Raed Shqier, Ahed Zyoud, Muath H. S. Helal, Heba Nassar, Raed Alkowni, Mohyeddin Assali, Shaher Zyoud, Naser Qamhieh, Abdul Razack Hajamohideen, Shadi Sawalha, Samer H. Zyoud, Hikmat S. Hilal
TiO2 films photo-catalyze S. aureus rupture and mineralization of resulting organic materials.
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Merging inline crystallization and pulsed flow operation to enable enantiospecific solid state photodecarbonylation

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00058G, Paper
Open Access
Bavo Vandekerckhove, Bart Ruttens, Bert Metten, Christian V. Stevens, Thomas S. A. Heugebaert
Photoelimination of α-chiral ketones in the solid state results in highly regio- and enantiospecific C–C bond formation. By combining inline crystallisation and pulsatile flow, the photochemistry of these slurries can now be run fully continuously.
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Development of Pickering water-in-oil emulsions using a dual stabilization of candelilla wax and acylated EGCG derivatives to enhance the survival of probiotics (Lactobacillus plantarum) powder

By pubs.rsc.org
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Food Funct., 2024, 15,11141-11157
DOI: 10.1039/D4FO01342E, Paper
Zhaojuan Shi, Jun Wu, Xingting Wang, Tongqiao Nie, Qingmei Zeng, Chuanxun Yuan, Risheng Jin
Candelilla wax reinforced the stability of Pickering W/O emulsions with a three-dimensional crystal network. The oil phase volume fraction of the emulsions showed dramatic differences in protecting probiotic viability from environmental stresses.
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Gujarat State Fertilizers & Chemicals Ltd. - Unaudited Financial Results For The 1St Quarter Ended On 30Th June, 2019

By www.thehindubusinessline.com
Published On :: Tue, 06 Aug 2019 17:39:41 +0530


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Gujarat State Fertilizers & Chemicals Ltd. - Revised- Standalone And Consolidated Unaudited Financial Results For The 1St Quarter Ended On 30Th June, 2019.

By www.thehindubusinessline.com
Published On :: Tue, 06 Aug 2019 17:47:50 +0530


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Vibrational frequencies utilized for the assessment of exchange–correlation functionals in the description of metal–adsorbate systems: C2H2 and C2H4 on transition-metal surfaces

By pubs.rsc.org
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00685B, Paper
Ray Miyazaki, Somayeh Faraji, Sergey V. Levchenko, Lucas Foppa, Matthias Scheffler
Vibrational frequencies can be utilized as a reference to assess the reliability of the exchange–correlation functionals.
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A metal-free route to substituted imidazolidines via ring-opening cyclization (ROC) of activated aziridines with N-benzylanilines: DA-COP catalyzed photo-oxidative C–H activation

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6411-6419
DOI: 10.1039/D4CY00808A, Paper
Manish Kumar, Bharat Singh, Sugandha Singh, Indresh Verma, Kamal K. Kar, Manas K. Ghorai
A metal-free, conjugated organic polymer (TPA-PQ)-catalyzed intramolecular C–H functionalization strategy for the synthesis of imidazolidines in the presence of light and O2 is reported.
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All-in-one Rh(III)-covalent organic framework for sustainable and regioselective C(sp2)–H bond functionalization

By pubs.rsc.org
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01098A, Paper
Luohe Wang, Junnan E, Xiubin Bu, Jing Zeng, Xiaobo Yang, Hua Fu, Zhen Zhao
RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp2)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
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Recyclable copper(I)-catalyzed cascade C–S and C–N bond formation between 2-iodoanilines and 2-bromobenzenethiols towards functionalized phenothiazines

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Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper
Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
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Dual defect sites at g-C3N4 synergistically induce the electron localization effect for boosting photocatalytic H2O2 production

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Catal. Sci. Technol., 2024, 14,6701-6709
DOI: 10.1039/D4CY01101E, Paper
Jingjing Jiang, Yuyao Chen, Shijian Zhou, Haoran Xie, Changlai Li, Zheng Wei, Yan Kong
Defect engineering (such as doping of non-metallic elements or vacancies) is a universally effective modification to improve the electronic structure and physical properties of g-C3N4, which has been widely applied in various photocatalytic systems.
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Study on the effect and mechanism of Ag and Bi2MoO6 modification on the CO2 photo-thermal reduction performance of g-C3N4 catalysts with localized surface plasmon resonance

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Catal. Sci. Technol., 2024, 14,6621-6640
DOI: 10.1039/D4CY00930D, Paper
Bin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen Huang
As a promising future energy material, g-C3N4 as a CO2 photo-thermal-reduction catalyst can effectively convert CO2 to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.
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Unspecific peroxygenase immobilization in 3D-printed microfluidics: towards tailor-made screening platforms

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Catal. Sci. Technol., 2024, 14,6496-6502
DOI: 10.1039/D4CY00869C, Communication
Elena Gkantzou, Theofilia Koulopoulou, Hannah Brass, David Schönauer, Anton Glieder, Selin Kara
In the context of empowering biocatalysis, an easy-to-develop, reproducible, and easy-to-scale biocatalytic system is demonstrated as a microfluidic screening platform.
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Effect of graphene electrode functionalization on machine learning-aided single nucleotide classification

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Nanoscale, 2024, 16,20202-20215
DOI: 10.1039/D4NR02274B, Paper
Mohd Rashid, Milan Kumar Jena, Sneha Mittal, Biswarup Pathak
In this study, we explored the role of functionalized entities (C, H, N, and OH) in graphene electrodes using a machine learning (ML) framework integrated with the quantum transport method to achieve precise single DNA nucleotide identification.
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