metal

New 2D layered structures with direct fluorine–metal bonds: MF(CH3COO) (M: Sr, Ba, Pb)

CrystEngComm, 2020, 22,2772-2780
DOI: 10.1039/D0CE00287A, Paper
S. Zänker, G. Scholz, M. Heise, F. Emmerling, E. Kemnitz
New coordination polymers with 2D network structures with fluorine directly coordinated to the metal ion were prepared both via mechanochemical synthesis and fluorolytic sol–gel synthesis.
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metal

Synthesis of all-silica hollow zeolites by selective demetallation

CrystEngComm, 2020, 22,2845-2848
DOI: 10.1039/D0CE00263A, Paper
Open Access
Teng Li, Frank Krumeich, Jeroen A. van Bokhoven
Exploiting the protective role of extra-framework aluminum species on the crystal rim, all-silica hollow zeolites are efficiently produced by demetallation.
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metal

Supramolecular association of M2+⋯π induced by different electrostatic properties using naphthyl substituted β-diketonate complexes (metal = Cu, Pd, Pt)

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00416B, Communication
Takumi Kusakawa, Takayuki Goto, Akiko Hori
Expanded π-conjugated coordination complexes, [M(L2)2] (M = Cu2+, Pd2+, Pt2+; L2 = dinaphthoylmethanido), were prepared and their unique electron contributions and electrophile/nucleophile characteristics were found due to the supramolecular associations.
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metal

A water-stable terbium metal-organic framework with functionalized ligands for the detection of Fe3+, Cr2O72- ions in water and picric acid in seawater

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00430H, Paper
Hai-Huan Yu, Jia-Qi Chi, Zhong-Min Su, Xiao Li, Jing Sun, Chen Zhou, Xiao-Li Hu, Qun Liu
The existence of Cr2O72- anions, excessive Fe3+ cations in water and picric acid in seawater have irreversible harm to human health and aquatic organism. Herein, a water-stable terbium metal-organic framework...
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metal

Intrinsically porous molecular building blocks for metal organic frameworks tailored by the bridging effect of counter cations

CrystEngComm, 2020, 22,2889-2894
DOI: 10.1039/D0CE00397B, Communication
Open Access
Peng Yang, Buthainah Alshankiti, Niveen M. Khashab
Intrinsically porous molecular building blocks are used for the rational design and construction of molecular-level controlled porous materials.
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metal

The different magnetic relaxation behaviors in [Fe(CN)6]3− or [Co(CN)6]3− bridged 3d–4f heterometallic compounds

CrystEngComm, 2020, 22,2998-3004
DOI: 10.1039/D0CE00039F, Paper
Ruirui Wang, Haili Wang, Juan Wang, Feifei Bai, Yue Ma, Licun Li, Qinglun Wang, Bin Zhao, Peng Cheng
For the isomorphic tetranuclear 3d–4f compounds constructed by [M(CN)6]3− linking LnIII-Schiff-base units, the diamagnetic CoIII ions in the system could suppress QTM effectively and obtain a field-induced SMMs behavior.
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metal

New pronounced progress in the synthesis of group 5 polyoxometalates

CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00315H, Highlight
Joanna Dopta, Lisa K. Mahnke, Wolfgang Bensch
This highlight summarizes new developments made in group 5 polyoxometalate science of high nuclearity clusters with focus on synthetic approaches.
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metal

Open metal site (OMS) and Lewis basic site (LBS)-functionalized copper–organic framework with high CO2 uptake performance and highly selective CO2/N2 and CO2/CH4 separation

CrystEngComm, 2020, Advance Article
DOI: 10.1039/C9CE02005E, Paper
Cheng He, Chao Hou, Yu Min Wang, Xue Yong Gong, Hong Li Jiang, Yong Bin Sun, Kun Liu, Xiao Qun Cao
A robust porous metal–organic framework with dual functionalities of open metal sites (OMSs) and O-rich Lewis basic sites (LBSs) has been designed and synthesized, and shows high CO2 uptake and excellent selectivity for CO2 over N2 and CH4.
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metal

Halogen bonded metal bis(dithiolene) 2D frameworks

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00512F, Paper
Hadi Hachem, olivier Jeannin, Marc Fourmigue, Frederic Barriere, Dominique Lorcy
Halogenated metal dithiolene complexes have been designed together with halogen bond acceptor sites in order to favor halogen bonding interactions between these electroactive architectures. For the synthesis, we explored the...
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metal

Strong stacking interactions at large horizontal displacements of tropylium and cyclooctatetraenide ligands of transition metal complexes: crystallographic and DFT study

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00501K, Paper
Dusan P Malenov, Snezana D Zaric
Cambrigde Structural Database search was performed in order to study stacking interactions of 7-membered tropylium ring and 8-membered cyclooctatetraenide (COT) ring, coordinated to transition metals via their π-electrons. The search...
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metal

Metallic glass-based nanocomposites: molecular dynamics study of properties / Sumit Sharma

Online Resource




metal

Metal fatigue: effects of small defects and nonmetallic inclusions / Yukitaka Murakami

Online Resource




metal

Science, technology and applications of metals in additive manufacturing / Bhaskar Dutta, Sudarsanam Babu, Bradley Jared

Online Resource




metal

TMS 2020 149th Annual Meeting and Exhibition Supplemental proceedings The Minerals, Metals and Materials Society, editor

Online Resource




metal

Nanostructured metal oxides for advanced applications: symposium held April 1-5, 2013, San Francisco, California, U.S.A. / editors, Alberto Vomiero, Federico Rosei, Xiao Wei Sun, Juan Roman Morante

Hayden Library - TA418.9.N35 S9665 2013




metal

Asymmetric copper-catalyzed conjugate additions of organometallic reagents in syntheses of natural compounds and pharmaceuticals

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00278J, Review Article
Denisa Vargová, Ivana Nemethova, Radovan Sebesta
Stereoselective synthesis of complex molecular structures is needed in medicine as well as in crop-protection. Copper-catalyzed 1,4-additions of organometallic reagents is a robust C-C bond formation strategy applicable in a...
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metal

Metal-free cascade reactions of aziridines with arylalkynes and aryldiazoniums: facile access to arylazopyrrolines

Org. Biomol. Chem., 2020, 18,3149-3157
DOI: 10.1039/D0OB00346H, Paper
Jing Rong, Hao Jiang, Sijing Wang, Zhenni Su, Huiyan Wang, Chuanzhou Tao
A novel and facile approach to synthesize arylazopyrroline scaffolds via metal-free cascade reactions of aziridines with arylalkynes and aryldiazoniums has been developed, providing access to a variety of 4-arylazo-2-pyrrolines in a highly concise fashion.
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metal

Recent Progress on Transition Metal-catalysed Regioselective C–H Transformations Based on Noncovalent Interactions

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00703J, Review Article
Yoichiro Kuninobu, Takeru Torigoe
Transition metal-catalysed C–H transformations are powerful tools to obtain functionalised organic molecules from simple starting materials. To control regioselectivity is one of the most important issues in C–H transformations. Since...
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metal

[ASAP] Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries

ACS Energy Letters
DOI: 10.1021/acsenergylett.0c00700




metal

Plant-Metal Interactions

Online Resource




metal

[ASAP] Analysis of the Different Metabolic Phenotypes of Metalaxyl Enantiomers in Adolescent Rat by Using <sup>1</sup>H NMR Based Urinary Metabolomics

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00011




metal

[ASAP] Particulate Matter Toxicity Is Nrf2 and Mitochondria Dependent: The Roles of Metals and Polycyclic Aromatic Hydrocarbons

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00007




metal

[ASAP] Quadruply Stranded Metallo-Supramolecular Helicate [Pd<sub>2</sub>(hextrz)<sub>4</sub>]<sup>4+</sup> Acts as a Molecular Mimic of Cytolytic Peptides

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00061




metal

Engineer Builds Instruments for One-Man Metal Band

Tristan Shone designed, prototyped, and machined his "dub machines" and uses them to rage on songs like "Terrorbird."




metal

Absurd Creatures | A Bird Impaling Its Victims Is So Metal I Can't Even Stand It

The shrike may look like a songbird but the only tunes it knows are METAL! The cute little bird kills its prey then impales them on spikes.




metal

Solar selective characteristics and local electronic bonding states of 3d transition metal oxide and metal nitride based thin film coatings / Mohammad Mahbubur Rahman

Rahman, Mohammad Mahbubur, author




metal

Transformation processes of metals in urban road dust: implications for stormwater reuse / Ayomi Jayarathne, Buddhi Wijesiri, Prasanna Egodawatta, Godwin A Ayoko, Ashantha Goonetilleke

Online Resource




metal

Ultrafast assembly of swordlike Cu3(1,3,5-benzenetricarboxylate)n metal–organic framework crystals with exposed active metal sites

Nanoscale Horiz., 2020, Advance Article
DOI: 10.1039/D0NH00171F, Communication
Heba Ahmed, Xinci Yang, Yemima Ehrnst, Ninweh N. Jeorje, Susan Marqus, Peter C. Sherrell, Ahmed El Ghazaly, Johanna Rosen, Amgad R. Rezk, Leslie Y. Yeo
A new acoustomicrofluidic method for synthesizing copper-based metal–organic frameworks is shown to yield novel large aspect ratio elongated crystal morphologies with high active metal site density on their surfaces, leading to enhanced conductivity.
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metal

Interface engineering of two-dimensional transition metal dichalcogenides towards next-generation electronic devices: recent advances and challenges

Nanoscale Horiz., 2020, 5,787-807
DOI: 10.1039/C9NH00743A, Review Article
Wugang Liao, Siwen Zhao, Feng Li, Cong Wang, Yanqi Ge, Huide Wang, Shibo Wang, Han Zhang
This review presents recent advances and challenges in the interface engineering of 2D TMDCs and emerging electronics based on TMDCs.
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metal

Metal assisted chemical etching of silicon in the gas phase: a nanofabrication platform for X-ray optics

Nanoscale Horiz., 2020, 5,869-879
DOI: 10.1039/C9NH00709A, Communication
Open Access
Lucia Romano, Matias Kagias, Joan Vila-Comamala, Konstantins Jefimovs, Li-Ting Tseng, Vitaliy A. Guzenko, Marco Stampanoni
Gas-MacEtch of Si with a Pt catalyst allows vertical etching nanostructures with an extreme aspect ratio up to 10 000 : 1.
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metal

Spatially separated bimetallic cocatalysts on hollow-structured TiO2 for photocatalytic hydrogen generation

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00042F, Research Article
Ping She, Jun-sheng Qin, Heng Rao, Buyuan Guan, Jihong Yu
A hollow-structured TiO2 decorated with spatially separated bimetallic cocatalysts (Pd@TiO2@Au) was obtained, which exhibited superior photo-induced charge separation by combining the SPR effect of Au NPs and the smaller size effect of Pd NPs.
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metal

3D-Nanosponge enabled segregation: a versatile approach for highly dispersed and high content functionalization of metal oxide species

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00115E, Research Article
Min Zhang, Yannan Yang, Yang Liu, Jianye Fu, Jingyi Lu, Yang Yang, Jinqing Jiao, Chengzhong Yu
A general 3D nanosponge enabled strategy is developed to achieve simultaneously highly dispersed and high content functionalization of metal oxide species, ebabling a liabrary of functional nanostructures with great application potential.
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metal

Intervaginal space injection of a liquid metal can prevent breast cancer invasion and better-sustain concomitant resistance

Mater. Chem. Front., 2020, 4,1397-1403
DOI: 10.1039/C9QM00753A, Research Article
Open Access
Yupeng Cao, Xiajun Hu, Qiang Zhang, Wenda Hua, Nan Hu, Yifeng Nie, Xue Xu, Yonggang Xu, Chongqing Yang, Xiaohan Zhou, Wentao Liu, Dong Han
CW invasion by the primary tumor was inhibited by ISI of an LM. DCs were activated by the LM to sustain CR.
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metal

Design and construction of bi-metal MOF-derived yolk–shell Ni2P/ZnP2 hollow microspheres for efficient electrocatalytic oxygen evolution

Mater. Chem. Front., 2020, 4,1366-1374
DOI: 10.1039/D0QM00128G, Research Article
Jinyang Zhang, Xuan Sun, Yang Liu, Linrui Hou, Changzhou Yuan
Hierarchical yolk–shell Ni2P/ZnP2 hollow microspheres are smartly synthesized, and exhibit exceptional OER performance, benefiting from their unique compositional/structural merits.
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metal

Highly-selective synthesis of trimetallic PtRuCu nanoframes as robust catalysts for the methanol oxidation reaction

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00033G, Research Article
Hai-Jing Yin, Zhi-Ping Zhang, Yu Guo, Kun Yuan, Ya-Wen Zhang
PtRuCu NFs/C exhibited much higher mass activity and specific activity than commercial Pt/C and PtRuCu NPs/C towards the MOR due to the frame nanostructures and the synergistic effect of the trimetallics.
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metal

Opportunities and critical factors of porous metal-organic frameworks for the industrial separation of light olefins

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00186D, Review Article
Tianhao Lan, Libo Li, Yang Chen, Xiaoqing Wang, Jiangfeng Yang, Jinping Li
Light olefins (ethylene, propylene, and 1,3-butadiene) are widely used as building blocks in the petrochemical industry and for the fabrication of everyday products. Developing energy cost-efficient porous materials for the...
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metal

Recent advances in nanostructured intermetallic electrocatalysts for renewable energy conversion reactions

J. Mater. Chem. A, 2020, 8,8195-8217
DOI: 10.1039/D0TA01809K, Review Article
Ho Young Kim, Sang Hoon Joo
This review summarises recent advances in the synthesis and electrocatalytic application of intermetallic nanostructures.
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metal

Screening metal-free photocatalysts from isomorphic covalent organic frameworks for the C-3 functionalization of indoles

J. Mater. Chem. A, 2020, 8,8706-8715
DOI: 10.1039/D0TA02164D, Paper
Ziping Li, Songjie Han, Chunzhi Li, Pengpeng Shao, Hong Xia, He Li, Xiong Chen, Xiao Feng, Xiaoming Liu
An excellent framework photocatalyst was screened from a series of isomorphic COFs. The photocatalytic properties of C-3 functionalization of indoles by COF-based photocatalysts were first reported.
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metal

Large energy-storage density in transition-metal oxide modified NaNbO3–Bi(Mg0.5Ti0.5)O3 lead-free ceramics through regulating the antiferroelectric phase structure

J. Mater. Chem. A, 2020, 8,8352-8359
DOI: 10.1039/D0TA02285C, Paper
Ao Tian, Ruzhong Zuo, He Qi, Min Shi
The combination of AFE phase structural regulation and breakdown strength optimization through chemical modification leads to a large energy-storage density of Wrec ∼ 5.57 J cm−3 in NN–BMT lead-free bulk ceramics.
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metal

NixRh1−x bimetallic alloy nanofibers as a pH-universal electrocatalyst for the hydrogen evolution reaction: the synthetic strategy and fascinating electroactivity

J. Mater. Chem. A, 2020, 8,8629-8637
DOI: 10.1039/D0TA02005B, Paper
Dasol Jin, Areum Yu, Youngmi Lee, Myung Hwa Kim, Chongmok Lee
NixRh1–x bimetallic alloy nanofibers synthesized by H2-reduction of NiRh2O4 exhibited outstanding pH-universal HER electrocatalytic activity with high stability.
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metal

Anderson polyoxometalate built-in covalent organic frameworks for enhancing catalytic performances

J. Mater. Chem. A, 2020, 8,8548-8553
DOI: 10.1039/D0TA02443K, Paper
Rui Ma, Naifang Liu, Ting-Ting Lin, Tianbo Zhao, Sheng-Li Huang, Guo-Yu Yang
Anderson polyoxometalate-based covalent organic frameworks exhibited the highest catalytic activity in the photodegradation of RhB and MB, as well as 100% selective oxidation of sulfides to sulfoxides.
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metal

A series of highly stable porphyrinic metal–organic frameworks based on iron–oxo chain clusters: design, synthesis and biomimetic catalysis

J. Mater. Chem. A, 2020, 8,8376-8382
DOI: 10.1039/D0TA02033H, Paper
Gang Liu, Hao Cui, Sujuan Wang, Li Zhang, Cheng-Yong Su
A facile synthesis of a series of Fe–oxo chain-based porphyrinic MOFs (namely M-PMOF-3(Fe), M = Fe, Co, Ni, Cu) has been reported.
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metal

Synthesis of metal-free lightweight materials with sequence-encoded properties

J. Mater. Chem. A, 2020, 8,8752-8760
DOI: 10.1039/D0TA03162C, Paper
Adi Azoulay, Jesús Barrio, Jonathan Tzadikov, Michael Volokh, Josep Albero, Christel Gervais, Pilar Amo-Ochoa, Hermenegildo García, Félix Zamora, Menny Shalom
A general synthesis of phosphorus–nitrogen–carbon materials with highly tunable elemental composition and spatial organization as well as structural, electronic, and thermal stability properties is reported.
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metal

Hollow PtCu Nanoparticles Encapsulated into Carbon Shell via Mild Annealing of Metal-Organic Frameworks

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01549K, Paper
Guanjun Chen, Huaqiang Shan, Yan Li, Hongwei Bao, Tingwei Hu, Long Zhang, Shuai Liu, Fei Ma
Alloying Pt with less expensive 3d transition metal to form bimetallic nanoparticles (NPs) has been proven to be an ideal strategy for synthesis of catalysts, especially in the field of...
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metal

A smart lithiophilic polymer filler in gel polymer electrolyte enables stable and dendrite-free Li metal anode

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02499F, Paper
Fei Ye, Xiu Zhang, Kaiming Liao, Qian Lu, Xiaohong Zou, Ran Ran, Wei Zhou, Yijun Zhong, Zongping Shao
A new conceptional lithiophilic polymer-filler-reinforced gel polymer electrolyte was proposed and prepared to guide uniform Li-ion flux during the Li plating/stripping process.
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metal

Bimetallic-MOF Catalyst for Efficient CO2 Photoreduction from Simulated Flue Gas to Value-added Formate

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA00205D, Paper
Shao-hong Guo, Xiang-Juan Qi, Hui-Min Zhou, Jie Zhou, Xiao-Hui Wang, Man Dong, Xue Zhao, Chun-Yi Sun, Xinlong Wang, Zhong-Min Su
Direct CO2 conversion from flue gas into high-value products is of great significance not only in relieving environmental burden but alleviating energy crisis by a low-cost and saving-energy avenue, yet...
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metal

[ASAP] A One-Pot Iodo-Cyclization/Transition Metal-Catalyzed Cross-Coupling Sequence: Synthesis of Substituted Oxazolidin-2-ones from <italic toggle="yes">N</italic>-Boc-allylamines

Organic Letters
DOI: 10.1021/acs.orglett.0c01114




metal

[ASAP] Designing Homogeneous Copper-Free Sonogashira Reaction through a Prism of Pd–Pd Transmetalation

Organic Letters
DOI: 10.1021/acs.orglett.0c01227




metal

Half-metallic materials and their properties / C.Y. Fong, J.E. Pask, L.H. Yang

Hayden Library - TA481.F66 2013




metal

Metallurgy for the non-metallurgist / edited by Arthur C. Reardon

Hayden Library - TN667.R72 2011