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Charge-induced deformation of scanning electrolyte before contact

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00147H, Paper
Liang Liu
Deformation of liquid and gel electrolytes before touching the sample in SECCM and SGECM: equilibrium does not always exist.
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Donald Trump marks second term victory with formation of inaugural committee for 2025

President-elect Donald Trump announced the formation of his inaugural committee which will organize and celebrate his inauguration on January 20, 2025. This follows Trump's victory in the 2024 US presidential election, securing his second term in the White House after a comeback from his loss to President Joe Biden in 2020.




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Erosion of rigid plastics in turbid (sandy) water: quantitative assessment for marine environments and formation of microplastics

Environ. Sci.: Processes Impacts, 2024, 26,1847-1858
DOI: 10.1039/D4EM00122B, Paper
Ali Al-Darraji, Ibukun Oluwoye, Christopher Lagat, Shuhei Tanaka, Ahmed Barifcani
Mechanical degradation (erosion) of plastics in the marine environment has been reported in many literature studies but without quantitative information. Therefore, this study quantified the erosion of some plastics in the marine environment.
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Emerging investigator series: in-depth chemical profiling of tire and artificial turf crumb rubber: aging, transformation products, and transport pathways

Environ. Sci.: Processes Impacts, 2024, 26,1703-1715
DOI: 10.1039/D4EM00326H, Paper
Open Access
Madison H. McMinn, Ximin Hu, Katherine Poisson, Phillip Berger, Paola Pimentel, Xinwen Zhang, Pranali Ashara, Ella L. Greenfield, Jessica Eig, Zhenyu Tian
Chemical profiling of artificial turf crumb rubber reveals time-based trends in transformation products and transport pathways.
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Organic aerosol formation from 222 nm germicidal light: ozone-initiated vs. non-ozone pathways

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00384E, Paper
Open Access
Matthew B. Goss, Jesse H. Kroll
Ozone production can explain most indoor air quality impacts of 222 nm germicidal ultraviolet light (GUV222). However, GUV222 causes more new particle formation than is explained by ozone chemistry.
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The West and the Word : Imagining, Formatting, and Ordering the American West in Nineteenth-Century Cultural Discourse [Electronic book] / Steffen Wöll.

München ; Wien : De Gruyter Oldenbourg, [2020]




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Urban transformations and public health in the emergent city [Electronic book] / ed. by Michael Keith, Andreza Aruska de Souza Santos.

Manchester : Manchester University Press, [2020]




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Social-Ecological Cooperative Housing : Gemeinschaftliches, transformatives Bauen und Wohnen [Electronic book] / hrsg. von id22: Institute for Creative Sustainability.

Berlin : JOVIS Verlag GmbH, [2022]




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Religiöse Erfahrung und ihre transformative Kraft : Qualitative und hermeneutische Zugänge zu einem praktisch-theologischen Grundbegriff [Electronic book] / Sabrina Müller.

Berlin ; Boston : De Gruyter, [2023]




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Politics of disinformation : the influence of fake news on the public sphere [Electronic book] / edited by Guillermo López-García, Dolors Palau-Sampio, Bella Palomo, Eva Campos-Domínguez, Pere Masip, Ramon Llull.

Hoboken, NJ : John Wiley & Sons, Inc., 2021.




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Misinformation nation : foreign news and the politics of truth in revolutionary America [Electronic book] / Jordan E. Taylor.

Baltimore : Johns Hopkins University Press, 2022.




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Just Transformations : Grassroots Struggles for Alternative Futures [Electronic book] / Iokiñe Rodríguez, Mariana Walter, Leah Temper.

London : Pluto Press, 2023.




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Health care in the information society. Vol. 2, From anarchy of transition to programme for reform [Electronic book] / David Ingram.

Cambridge : Open Book Publishers, [2023]




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Health care in the information society. Vol. 1, From adventure of ideas to anarchy of transition [Electronic book] / David Ingram.

Cambridge : Open Book Publishers, [2023]




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Economic Transformation and Income Distribution in China over Three Decades [Electronic book] / Cai Meng, Bjorn Gustafsson, John Knight.

Cambridge : Cambridge University Press, 2023.




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Digital places : living with geographic information technologies [Electronic book] / Michael R. Curry.

London ; New York : Routledge, 1998.




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Bandits in Print : "The Water Margin" and the Transformations of the Chinese Novel [Electronic book] / Scott W. Gregory.

Ithaca, NY : Cornell University Press, [2023]




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Ay-Inversion in Tagalog : Information Structure and Morphosyntax of an Austronesian Language [Electronic book] / Patrick Nuhn.

Düsseldorf : düsseldorf university press, [2021]




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What can Quantum Information Theory Offer to Quantum Chemistry?

Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00059E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Damiano Aliverti-Piuri, Kaustav Chatterjee, Lexin Ding, Ke Liao, Julia Liebert, Christian Schilling
It is the ultimate goal of this work to foster synergy between quantum chemistry and the flourishing field of quantum information theory. For this, we first translate quantum information concepts...
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Stabilization of lithium metal in concentrated electrolytes: effects of electrode potential and solid electrolyte interphase formation

Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00038B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anusha Pradhan, Shoma Nishimura, Yasuyuki Kondo, Tomoaki Kaneko, Yu Katayama, Keitaro Sodeyama, Yuki Yamada
Lithium (Li) metal negative electrodes have enticed a wide attention for high-energy-density batteries. However, its low Coulombic efficiency (CE) due to parasitic electrolyte reduction has been an alarming concern. Concentrated...
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Engineering a pyrene MOF composite photocatalyst toward the formation of carbon dioxide radical anions through regulating the charge transfer from type II to Z scheme via a chemical bond-modulated strategy

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02072C, Research Article
Xin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li Zhang
A new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.
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Ammonia and formate cosynthesis via nitrate electroreduction combined with methanol electrooxidation over nitrogen-doped carbon-encapsulated nickel iron phosphide

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02350A, Research Article
Zongyi Wang, Jiuli Chang, Zhiyong Gao
Nitrate–methanol co-electrolysis by the pairwise cathodic NO3RR and anodic MOR is a viable way to coproduce ammonia (NH3) and formate via gentle, sustainable and energy-saving “E-refining” and “E-reforming” means.
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Confining calcium oxalate crystal growth in a carbonated apatite-coated microfluidic channel to better understand the role of Randall's plaque in kidney stone formation

Lab Chip, 2024, 24,2017-2024
DOI: 10.1039/D3LC01050C, Paper
Samantha Bourg, Karol Rakotozandriny, Ivan T. Lucas, Emmanuel Letavernier, Christian Bonhomme, Florence Babonneau, Ali Abou-Hassan
The successful formation of a carbonated apatite coating inside a micrometer channel is described, which was used to investigate its role on the formation of calcium oxalate crystals in the context of kidney stones.
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A microfluidic chip for sustained oxygen gradient formation in the intestine ex vivo

Lab Chip, 2024, 24,1918-1929
DOI: 10.1039/D3LC00793F, Paper
Lauren M. Delong, Colby E. Witt, Madison Pennell, Ashley E. Ross
Here, we have developed a 3D printed microfluidic device capable of oxygen gradient formation within intestinal tissue slices ex vivo. The device is open-welled and compatible with external electrochemical recording during tissue analysis.
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Scalable electrocatalyzed formation of C–O bonds using flow reactor technology

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00438H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Michael Prieschl, David Cantillo, C. Oliver Kappe, Gabriele Laudadio
A scalable C–O bond formation via continuous-flow Ni-electrocatalysis was developed, enabling the gram-scale preparation of a key delamanid intermediate, a pharmaceutical used to treat multidrug-resistant tuberculosis.
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Conformational and static properties of tagged chains in solvents: effect of chain connectivity in solvent molecules

Soft Matter, 2024, 20,3073-3081
DOI: 10.1039/D3SM01473H, Paper
Hong-Yao Li, Bokai Zhang, Zhi-Yong Wang
The radius of gyration of tagged polymer chain: effect of chain length in solvent molecules.
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Steering droplets on substrates with plane-wave wettability patterns and deformations

Soft Matter, 2024, 20,3161-3174
DOI: 10.1039/D4SM00213J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Josua Grawitter, Holger Stark
Motivated by strategies for targeted microfluidic transport of droplets, we investigate how sessile droplets can be steered toward a preferred direction using travelling waves in substrate wettability or deformations of the substrate.
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Mechanical guidance to self-organization and pattern formation of stem cells

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00172A, Paper
Wei-Hua Zhou, Lin-Ru Qiao, She-Juan Xie, Zhuo Chang, Xu Yin, Guang-Kui Xu
We introduce a mechanical model based on the dynamic balance between cell-ECM-culture environment, and demonstrate that it can capture specific phenomena in stem cell pattern formation experiments guided by geometric constraints.
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Adsorption of semiflexible wormlike polymers to a bar and their double-chain complex formation

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00188E, Paper
Open Access
A. N. Semenov, I. A. Nyrkova
The quantitative transfer matrix approach and scaling arguments in terms of trains, loops, tails and supertrains allowed us to characterize the main regimes of semiflexible chain adsorption on a bar and double-chain complex formation.
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Deformation-dependent gel surface topography due to the elastocapillary and osmocapillary effects

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00139G, Paper
Open Access
Luochang Wang, Qihan Liu
Elastocapillary and osmocapillary effects can roughen a stretched surface although the elastic Poisson’s effect always flattens a stretched surface.
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In silico design of misfolding resistant proteins: the role of structural similarity of a competing conformational ensemble in the optimization of frustration

Soft Matter, 2024, 20,3283-3298
DOI: 10.1039/D4SM00171K, Paper
Bondeepa Saikia, Anupaul Baruah
The degree of similarity of the non-native conformations to the target plays a prominent role in designing misfolding resistant protein sequences.
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Harnessing the power of natural deep eutectic solvents (choline chloride/sucrose) and polypropylene glycol in the formation of aqueous biphasic systems and the application of these systems in drug extraction

RSC Adv., 2024, 14,12349-12359
DOI: 10.1039/D3RA07066B, Paper
Open Access
Fariba Ghaffari, Mohammed Taghi Zafarani-Moattar, Hemayat Shekaari
In recent times, there has been considerable interest in utilizing aqueous biphasic systems (ABSs) containing natural deep eutectic solvents (NADESs) for the extraction of various substances.
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Formation of H-bonding networks in the solid state structure of a trinuclear cobalt(III/II/III) complex with N2O2 donor Schiff base ligand and glutaric acid as bridging co-ligand: synthesis, structure and DFT study

RSC Adv., 2024, 14,13200-13208
DOI: 10.1039/D3RA07697K, Paper
Open Access
Sovana Maity, Sudip Bhunia, Michael G. B. Drew, Rosa M. Gomila, Antonio Frontera, Shouvik Chattopadhyay
Formation of hydrogen bonding network in a trinuclear linear mixed-valence centrosymmetric cobalt(III)–cobalt(II)–cobalt(III) complex has been analyzed using DFT calculations.
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Effect of interfacial local conformation of polymer chains on adhesion strength

Polym. Chem., 2024, 15,4425-4432
DOI: 10.1039/D4PY00951G, Paper
Open Access
Tatsuki Abe, Satoru Yamamoto, Keiji Tanaka
The aggregation states of polymer chains at solid interfaces are strongly related to their adhesion properties.
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Rapid formation of antifouling coatings via cation–π interactions

Polym. Chem., 2024, 15,4465-4473
DOI: 10.1039/D4PY00859F, Paper
Zhicheng Huang, Kaijie Zhao, Shaoyin Wei, Yingxin Hao, Qina Yu, Jingcheng Hao, Jiwei Cui, Peiyu Zhang
Antifouling coatings can be quickly prepared on various substrates through cation–π interactions between copolymers and MPNs. In addition, block copolymers exhibited superior antifouling capabilities compared to random copolymers.
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Enzymatic self-assembly of short peptides for cell spheroid formation

J. Mater. Chem. B, 2024, 12,11210-11217
DOI: 10.1039/D4TB01154F, Paper
Open Access
Jiaqi Guo, Weiyi Tan, Bing Xu
Biphenyl-capped phosphopeptides instruct cell aggregation into spheroids, with minimal effective concentrations below 10 μM. Key factors driving morphogenesis include the self-assembly ability and dynamic shapeshifting of the peptide assemblies.
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Effect of supramolecular peptide hydrogel scaffold charge on HepG2 viability and spheroid formation

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01701C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yu Xin, Cosimo Ligorio, Marie O’brien, Richard Collins, Siyuan Dong, Aline F. Miller, Alberto Saiani, Julie E. Gough
Understanding how fibre charge in self-assembling peptide hydrogel networks affect HepG2 cell fate and spheroid formation.
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A transformative experience

PARAS ARORA’S internship at Teach for India helped him become an activist.




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The efficient triplet states formation of Se-modified PDI dimers and tetramers in solvents

Phys. Chem. Chem. Phys., 2024, 26,27325-27331
DOI: 10.1039/D4CP00954A, Paper
Feijun Huang, Wenli Su, Yubo Yang, Hang Wang, Zhishan Bo, Pengfei Jing, Wenkai Zhang
The Se-modified PDI oligomers experience triplet states formation in the solvents, but there are differences in the efficiency of triplet state generation due to variations in molecular structure.
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Spintronic performance of bent zigzag phosphorene nanoribbons: effects of mechanical deformation and gate voltage

Phys. Chem. Chem. Phys., 2024, 26,27363-27370
DOI: 10.1039/D4CP03470H, Paper
Rouhollah Farghadan
This study explores how bending and gate voltage tune the spintronic properties of zigzag phosphorene nanoribbons (ZPNRs) for advanced applications.
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Oxidation of fine aluminum particles: thermally induced transformations in particle shells and kinetics of oxide nucleation

Phys. Chem. Chem. Phys., 2024, 26,27602-27616
DOI: 10.1039/D4CP03355H, Paper
Andrey V. Korshunov
A submicron aluminum particle during oxidation is a shrinking spherical segment due to the growth of a single γ-Al2O3 nucleus.
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Experimental and theoretical study of the Sn–O bond formation between atomic tin and molecular oxygen

Phys. Chem. Chem. Phys., 2024, 26,27763-27771
DOI: 10.1039/D4CP03687E, Paper
Iakov A. Medvedkov, Anatoliy A. Nikolayev, Shane J. Goettl, Zhenghai Yang, Alexander M. Mebel, Ralf I. Kaiser
In this article, we combine state-of-art electronic structure calculations and crossed beam experiments to expose the reaction dynamics of 120Sn(3Pj) + 16O2(X3Σg) → 120Sn16O(X1Σ+) + 16O(3P) reaction that involve extensive ISC.
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A Comprehensive Guide for Accurate Conformational Energies of Microsolvated Li+ Clusters with Organic Carbonates

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03487B, Paper
Arseniy A. Otlyotov, Andrey Moshchenkov, Timofey P. Rozov, Anna A. Tuma, Alexander S. Ryzhako, Yury Minenkov
Organic carbonates and their mixtures are frequently used in electrolyte solutions in lithium-ion batteries. Rationalization and tuning of the related Li+ solvation processes are rooted in the proper identification of...
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Simulation study of the conformation and dynamics of substrate-supported ring and linear polymer films

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02794A, Paper
Jianhua Huang, Hongzhu Ji, Jin Zhang, Zhunpeng Wang
Ring polymers in substrate-supported films exhibit stronger adsorbability, less deformation, and similar dynamics suppression compared to linear polymers.
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Unlocking the potential of metal ligand cooperation for enantioselective transformations

Chem. Soc. Rev., 2024, 53,3216-3223
DOI: 10.1039/D3CS00998J, Viewpoint
Open Access
Tizian-Frank Ramspoth, Johanan Kootstra, Syuzanna R. Harutyunyan
Metal–ligand cooperation, (MLC) is a versatile catalysis concept. Herein, we discuss the historical context, mechanisms, and applications, suggesting exploring MLC for enantioselective transformations beyond (de)hydrogenative processes.
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Outer-surface adduct formation and selective separation of cis-type gallated and cis-type non-gallated catechins using cucurbit[7]uril

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05035E, Communication
Open Access
Hiroyuki Tsutsumi, An Miura, Asuka Hanada, Rino Sonoda, Rie Nakashima, Tomonori Ohata, Hirohito Ikeda
The selective separation of cis-type gallated and non-gallated catechins in solution was achieved by utilizing the formation of outer-surface adducts between cis-type catechins and cucurbit[7]uril.
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Mild boroxazolidone formation and dissociation: Application toward target identification of bioactive molecules

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05370B, Communication
Toya Tabei, Kyoko Nagasawa-Goto, Yohei Saito
We successfully found that boroxazolidone can dissociate under aqueous conditions, which were applicable to a solution containing proteins. The immobilization of a newly synthesized diarylborinic acid on beads enabled the...
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Extended polyene formation by a cryptic iterative polyketide synthase from Rhodococcus

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04963B, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Panward Prasongpholchai, Sam Tucker, Charles Burgess, Robert Jenkins, Ina Wilkening, Christophe Corre, Lijiang Song, Manuela Tosin
Investigations of the workings of a newly identified iterative polyketide synthase from Rhodococcus erythropolis PR4 reveal its ability to synthesise extended polyenes.
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Bidirectional strain release in a thermosalient organic salt crystal induced by anisotropic thermal expansion and phase transformation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04764H, Communication
Priyasha Harsha, Dinabandhu Das
Two-way release of strain followed by jumping in an organic salt crystal can be attributed to the anisotropic thermal expansion by heating and phase transformation followed by shear deformation of the crystals by cooling.
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Copper nanoclusters: emerging photoredox catalysts for organic bond formations

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04774E, Feature Article
Open Access
Arunachalam Sagadevan, Kathiravan Murugesan, Osman M. Bakr, Magnus Rueping
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
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