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N-Functionalization of beta-aminophosphonates; Cytotoxic effect of the new derivatives

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00243A, Paper
György Keglevich, Petra Regina Varga, Emőke Dinnyési, Zsuzsanna Szalai, Szilvia Bősze, Rita Oláhné Szabó, Laszlo Drahos, Konstantin Karaghiosoff
Beta-Aminophosponates obtained by the Michael addition of primary amines to the double bond of diethyl vinylphosphonate proved to be suitable starting materials (amine components) in the Kabachnik–Fields reaction with formaldehyde...
The content of this RSS Feed (c) The Royal Society of Chemistry




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I Didn’t Realize How Much I Rely on GitHub Codespaces Until This week

How much do I rely on GitHub Codespaces for open source development? Super double-plus much. I can illustrate exactly how much with one short anecdote. Gulp 5 was recently released and I created several PRs across repos in the H5BP organization to update Gulp across the board. I missed one issue with the encoding of […]




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House panel tells government to ensure fertilizer availability, increase local production

Standing Committee also questions the high GST rate on components of fertilizers




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Centre announces ₹24,420 crore subsidy for summer crop fertilizers




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Henry Moore : in the light of Greece / exhibition curator, Roger Cardinal ; catalogue editorial supervision and co-ordination, Kyriakos Koutsomallis, Elizabeth Plessa.

Andros : Basil and Elise Goulandris Foundation, [2000]




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Learning support : a guide for mature students / Elizabeth Hoult.

London : SAGE Publications, 2006.




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Belize : country environmental profile : a field study / by Gary Hartshorn [and others].

Belize City, Belize : Robert Nicolait & Associates Ltd., 1984.




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Heart drum : spirit possession in the Garifuna communities of Belize / Byron Foster.

Belize : Cubola Productions, 1986.




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Readings in Belizean history. Vol. 1 / edited by John Maher, S.J.

Belize City, Belize : BISRA, 1978.




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A history of Belize : nation in the making.

Belize City, Belize : Sunshine Books, 1984




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Reuse of spent industrial graphite in batteries by green recycling and interphase functionalization

Mater. Chem. Front., 2024, 8,3653-3663
DOI: 10.1039/D4QM00438H, Research Article
Yu Jiang, Yuqing Li, Qunting Qu, Linze Lv, Jie Shao, Jing Wang, Honghe Zheng
A green, energy-saving and effective method for recycling graphite from spent Li-ion batteries and its reutilization in high-voltage dual-ion batteries are developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Channelization of cathode/electrolyte interphase to enhance the rate-capability of LiCoO2

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00748D, Research Article
Liewu Li, Zhencheng Huang, Qi Yuan, Hongbin Wang, Xuming Yang, Chufang Chen, Xiaoyu Gong, Qianqian Jiang, Jing Chen, Xiaoping Ouyang, Jionghui Wang, Liqing He, Xiangzhong Ren, Jiangtao Hu, Qianling Zhang, Jianhong Liu
The LiCoO2@ZrP2O7 cathode was fabricated employing an in situ surface coating technique, which significantly enhanced both the rate capability and structural stability of the LiCoO2 cathode.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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MoS2-functionalized chitosan hydrogel with antibacterial and antioxidant functions promotes healing of infected diabetic wounds

Mater. Chem. Front., 2024, 8,3770-3789
DOI: 10.1039/D4QM00562G, Research Article
Yingjie He, Jiahe Guo, Hua Li, Jiaxi Jiang, Jing Chen, Guichun Yang, Xiaofan Yang, Zhenbing Chen, Cuifen Lu
Construction and application of a MoS2-based injectable self-healing composite hydrogel with antibacterial and antioxidant dual functions for promoting infected diabetic wound healing.
The content of this RSS Feed (c) The Royal Society of Chemistry




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“Delocalized π-bond” guided pyramidal nanocrystal superstructures for excellent light trapping in SERS

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00576G, Research Article
Yang Shang, Bo Ren, Xiaotian Wang, Jie Lin
A 2D CuI pyramidal superstructure is self-assembled in a manner similar to a delocalized π-bond, which effectively traps light and exhibits a remarkable SERS performance.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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How AWS Nitro Reimagines the Future of Virtualization | WIRED Brand Lab

Produced by WIRED Brand Lab with AWS | When AWS realized their clients' needs for computation were outgrowing its cloud virtualization's capabilities, their engineers rebuilt it by creating custom, original silicon chips, pioneering a hybrid software and hardware model called NITRO. NITRO provides dedicated hardware, increased performance, and security at a cheaper cost to their customer base — and is programmed for evolution as the virtualization landscape continues to change.




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Tech Support - Maya Expert Answers Maya Civilization Questions From Twitter | Tech Support

Dr. Ed Barnhart, an American archaeologist, answers the internet's burning questions about the ancient Maya civilization. Why was the Maya calendar year only 260 days? Who did they sacrifice? Did they build more pyramids than the Egyptians? This Maya expert answers all these questions and much more.Dr. Ed Barnhart is the director of Maya Exploration Center https://www.mayaexploration.orgCheck out The ArchaeoEd Podcast - https://www.archaeoed.com for more content about the ancient Americas.Director: Lisandro Perez-ReyDirector of Photography: AJ YoungEditor: Christopher JonesExpert: Ed BarnhartLine Producer: Joseph BuscemiAssociate Producer: Brandon WhiteProduction Manager: Peter BrunetteCasting Producer: Nicholas SawyerCamera Operator: Lucas VilicichSound Mixer: Kari BarberProduction Assistant: Fernando BarajasPost Production Supervisor: Christian OlguinPost Production Coordinator: Ian BryantSupervising Editor: Doug LarsenAdditional Editor: Paul TaelAssistant Editor: Billy Ward




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Ov-rich γ-MnO2 enhanced electrocatalytic three-electron oxygen reduction to hydroxyl radicals for sterilization in neutral media

Nanoscale Horiz., 2024, 9,1999-2006
DOI: 10.1039/D4NH00289J, Communication
Yingnan Qin, Tongzhu Han, Ligang Chen, Kexin Yan, Jing Wang, Ning Wang, Baorong Hou
The synergistic interaction between Ov and γ-MnO2 significantly enhanced the performance of the neutral 3e ORR, exhibiting impressive sterilization capabilities.
The content of this RSS Feed (c) The Royal Society of Chemistry




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V for voltage stabilizer: The behind-the-scenes hero

In India where power supply is often erratic and fluctuates, this silent guardian protects our appliances, much like the father of a family




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Evaluation of miniaturized ultrasonic nebulization for high-efficiency sampling in characterization of silver nanoparticles by single particle inductively coupled plasma mass spectrometry

J. Anal. At. Spectrom., 2024, 39,2791-2798
DOI: 10.1039/D4JA00320A, Paper
Junhang Dong, Zhenli Zhu, Lujie Li, Pengju Xing, Shuyang Li, Lei Ouyang, Xing Liu, Wei Guo, Hongtao Zheng, Rong Qian
Miniaturized ultrasonic nebulization (MUN) provides high sampling efficiency for single particle inductive coupled plasma mass spectrometry (sp-ICPMS).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Explained | Why was former Theranos CEO Elizabeth Holmes given 11 years in prison?

Her blood-testing startup claimed to revolutionise testing by detecting hundreds of medical conditions from just a few drops of blood 




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Uptick in US Adults Social Media Usage Will Likely Normalize Post-Pandemic

When US consumers started spending more time at home in March and April, they also started using social media more, providing an unexpected boost to the platforms.

Depending on the research source, up to 51% of US adults are using social media at higher rates during the pandemic. But even though elevated social usage continued at least into May, causing us to upgrade our forecast for time spent on social networks by US social network users, we believe that when consumers eventually get back to their normal routines of school, work and social activities, the trends will moderate. We think this will start to happen later in 2020, with a more visible downward trend evident in 2021 and beyond.




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Visualizing the Social Media Universe in 2020

Social media has seeped into virtually all aspects of modern life. The vast social media universe collectively now holds 3.8 billion users, representing roughly 50% of the global population.

With an additional billion internet users projected to come online in the coming years, it’s possible that the social media universe could expand even further.

How the Networks Stack Up
To begin, let’s take a look at how social networks compare in terms of monthly active users (MAUs)—an industry metric widely used to gauge the success of these platforms.

Rank        Social Network        
#1        Facebook        
#2        WhatsApp        
#3        YouTube        
#4        Messenger        
#5        WeChat        
#6        Instagram        
#7        TikTok        
#8        QQ        
#9        Weibo        
#10        Qzone        
#11        Reddit




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A black zirconia cathode coating layer enabling facile charge diffusion and surface lattice stabilization for lithium-ion batteries

J. Mater. Chem. A, 2024, 12,30667-30675
DOI: 10.1039/D4TA05179C, Paper
Yoo Jung Choi, Sungbin Jang, Hongjun Chang, Youjin Kim, Suji Kim, Ga Yoon Kim, Juho Lee, Janghyuk Moon, Jinsoo Kim, Won-Hee Ryu
Black ZrO2−x is coated onto a Ni-rich cathode via solvent-free shearing, enhancing charge transfer, reducing gas evolution, and preventing cracking. It lowers Li-ion transfer barriers and mitigates oxygen release through strong Zr–O hybridization.
The content of this RSS Feed (c) The Royal Society of Chemistry




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An azo-receptor immobilized mesoporous honeycomb silica framework as a solid-state chromogenic sensor for capturing ultra-trace cadmium ions from environmental/industrial samples

J. Mater. Chem. A, 2024, 12,30567-30581
DOI: 10.1039/D4TA04574B, Paper
Anju P. Veedu, Balasurendran Jeyakumar, Akhila Maheswari Mohan, Satheesh Kuppusamy, Pitchaiah K. Chinaraga, Manjula Muthurathinam, C. V. S. Brahmananda Rao, Sivaraman Nagarajan, Prabhakaran Deivasigamani
A solid-state naked-eye sensor composed of a mesoporous honeycomb structured silica monolith impregnated with a DMTHBD receptor offers a simple, rapid and eco-benign approach for the selective sensing of trace Cd2+, with brilliant color transitions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rational engineering and synthesis of pyrene and thiazolo[5,4-d]thiazole-functionalized conjugated microporous polymers for efficient supercapacitor energy storage

J. Mater. Chem. A, 2024, 12,30508-30521
DOI: 10.1039/D4TA05908E, Paper
Abdul Basit, Yang-Chin Kao, Yasser A. El-Ossaily, Shiao-Wei Kuo, Mohamed Gamal Mohamed
The Py-Th-TzTz CMP was synthesized through a Schiff base reaction and exhibited a decomposition temperature (Td10) of 352 °C. In a three-electrode system, it demonstrated a specific capacitance of 652 F g−1.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Efficient hydrogen isotope separation utilizing photocatalytic capability

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA07355J, Paper
Linzhen Wu, Sifan Zeng, Weiwei Wang, Shengtai Zhang, Hongbo Li, Xiaosong Zhou
An N–O–C3N4 catalyst for catalytic hydrogen isotope separation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tech Query: What is the outlook for TVS Holdings, Gujarat State Fertilizers & Chemicals (GSFC), Ideaforge Technology and Niyogin Fintech?

We zoom in on the prospects of TVS Holdings, as also the prospects of three other stocks — Gujarat State Fertilizers & Chemicals (GSFC), Ideaforge Technology and Niyogin Fintech




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New insight into π–π interactions: realization of full color emission from blue to red under hydrostatic pressure without exogenous intramolecular charge transfer

J. Mater. Chem. C, 2024, 12,17377-17385
DOI: 10.1039/D4TC03810J, Communication
Aisen Li, Jiaqiang Wang, Changjiang Bi, Zirun Chen, Shuping Xu, Kai Wang, Jinfeng Wang, Zhen Li
A new strategy to disclose the relationship between π–π stacking without exogenous ICT and photophysical properties was propounded through the construction of smart piezochromic materials with a discrete π–π dimer and high-pressure technique.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Stabilizing perovskite quantum dot oxygen sensors through ultra-long 2 mm horizontally aligned nanopores in anodic alumina oxide templates

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03851G, Paper
Johan Iskandar, Chih-Yi Liu, Chih-Chien Lee, Kuan-Yu Ke, M. Rivaldi Ali Septian, Richie Estrada, Humaidi Humaidi, Sajal Biring, Cheng-Shane Chu, Zong-Liang Tseng, Shun-Wei Liu
Perovskite quantum dots (PQDs) offer potential for gas sensing, though stability limits use. Johan et al. enhanced PQD stability with a horizontally aligned anodic alumina oxide template, maintaining fluorescence for 3 weeks without change.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tb(III)-Functionalized MOF Hybridized Bis-crosslinked Networked Hydrogel Luminescent Films for Arginine and Dopamine Hydrochloride Sensing and Anticounterfeiting

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03444A, Paper
Jiaxuan Pan, JZ Lu, Yichen Shang, Ying Li, Bing Yan
Dopamine and arginine are both important substances in the body and are closely related to human health. Timely detection of their concentration abnormalities is of great significance for dsaevention. In...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Supramolecular gels: a versatile crystallization toolbox

Chem. Soc. Rev., 2024, 53,10604-10619
DOI: 10.1039/D4CS00271G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rafael Contreras-Montoya, Luis Álvarez de Cienfuegos, José A. Gavira, Jonathan W. Steed
Supramolecular gels are unique materials formed through the self-assembly of low molecular weight gelators (LMWGs). Their versatility has allowed the expansion of gel crystallization processes, giving a new impetus to this field.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Recent synthetic strategies for the functionalization of fused bicyclic heteroaromatics using organo-Li, -Mg and -Zn reagents

Chem. Soc. Rev., 2024, 53,11045-11099
DOI: 10.1039/D4CS00369A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Vasudevan Dhayalan, Vishal S. Dodke, Marappan Pradeep Kumar, Hatice Seher Korkmaz, Anja Hoffmann-Röder, Pitchamuthu Amaladass, Rambabu Dandela, Ragupathy Dhanusuraman, Paul Knochel
This review presents various new strategies for the functionalization of 5 and 6-membered fused heteroaromatics. These synthetic strategies enable rapid access to complex heterocyclic compounds.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Personalization Pyramid: A Framework for Designing with User Data

As a UX professional in today’s data-driven landscape, it’s increasingly likely that you’ve been asked to design a personalized digital experience, whether it’s a public website, user portal, or native application. Yet while there continues to be no shortage of marketing hype around personalization platforms, we still have very few standardized approaches for implementing personalized UX.

That’s where we come in. After completing dozens of personalization projects over the past few years, we gave ourselves a goal: could you create a holistic personalization framework specifically for UX practitioners? The Personalization Pyramid is a designer-centric model for standing up human-centered personalization programs, spanning data, segmentation, content delivery, and overall goals. By using this approach, you will be able to understand the core components of a contemporary, UX-driven personalization program (or at the very least know enough to get started). 

Growing tools for personalization: According to a Dynamic Yield survey, 39% of respondents felt support is available on-demand when a business case is made for it (up 15% from 2020).

Source: “The State of Personalization Maturity – Q4 2021” Dynamic Yield conducted its annual maturity survey across roles and sectors in the Americas (AMER), Europe and the Middle East (EMEA), and the Asia-Pacific (APAC) regions. This marks the fourth consecutive year publishing our research, which includes more than 450 responses from individuals in the C-Suite, Marketing, Merchandising, CX, Product, and IT.

Getting Started

For the sake of this article, we’ll assume you’re already familiar with the basics of digital personalization. A good overview can be found here: Website Personalization Planning. While UX projects in this area can take on many different forms, they often stem from similar starting points.      

Common scenarios for starting a personalization project:

  • Your organization or client purchased a content management system (CMS) or marketing automation platform (MAP) or related technology that supports personalization
  • The CMO, CDO, or CIO has identified personalization as a goal
  • Customer data is disjointed or ambiguous
  • You are running some isolated targeting campaigns or A/B testing
  • Stakeholders disagree on personalization approach
  • Mandate of customer privacy rules (e.g. GDPR) requires revisiting existing user targeting practices
Workshopping personalization at a conference.

Regardless of where you begin, a successful personalization program will require the same core building blocks. We’ve captured these as the “levels” on the pyramid. Whether you are a UX designer, researcher, or strategist, understanding the core components can help make your contribution successful.  

From the ground up: Soup-to-nuts personalization, without going nuts.

From top to bottom, the levels include:

  1. North Star: What larger strategic objective is driving the personalization program? 
  2. Goals: What are the specific, measurable outcomes of the program? 
  3. Touchpoints: Where will the personalized experience be served?
  4. Contexts and Campaigns: What personalization content will the user see?
  5. User Segments: What constitutes a unique, usable audience? 
  6. Actionable Data: What reliable and authoritative data is captured by our technical platform to drive personalization?  
  7. Raw Data: What wider set of data is conceivably available (already in our setting) allowing you to personalize?

We’ll go through each of these levels in turn. To help make this actionable, we created an accompanying deck of cards to illustrate specific examples from each level. We’ve found them helpful in personalization brainstorming sessions, and will include examples for you here.

Personalization pack: Deck of cards to help kickstart your personalization brainstorming.

Starting at the Top

The components of the pyramid are as follows:

North Star

A north star is what you are aiming for overall with your personalization program (big or small). The North Star defines the (one) overall mission of the personalization program. What do you wish to accomplish? North Stars cast a shadow. The bigger the star, the bigger the shadow. Example of North Starts might include: 

  1. Function: Personalize based on basic user inputs. Examples: “Raw” notifications, basic search results, system user settings and configuration options, general customization, basic optimizations
  2. Feature: Self-contained personalization componentry. Examples: “Cooked” notifications, advanced optimizations (geolocation), basic dynamic messaging, customized modules, automations, recommenders
  3. Experience: Personalized user experiences across multiple interactions and user flows. Examples: Email campaigns, landing pages, advanced messaging (i.e. C2C chat) or conversational interfaces, larger user flows and content-intensive optimizations (localization).
  4. Product: Highly differentiating personalized product experiences. Examples: Standalone, branded experiences with personalization at their core, like the “algotorial” playlists by Spotify such as Discover Weekly.

Goals

As in any good UX design, personalization can help accelerate designing with customer intentions. Goals are the tactical and measurable metrics that will prove the overall program is successful. A good place to start is with your current analytics and measurement program and metrics you can benchmark against. In some cases, new goals may be appropriate. The key thing to remember is that personalization itself is not a goal, rather it is a means to an end. Common goals include:

  • Conversion
  • Time on task
  • Net promoter score (NPS)
  • Customer satisfaction 

Touchpoints

Touchpoints are where the personalization happens. As a UX designer, this will be one of your largest areas of responsibility. The touchpoints available to you will depend on how your personalization and associated technology capabilities are instrumented, and should be rooted in improving a user’s experience at a particular point in the journey. Touchpoints can be multi-device (mobile, in-store, website) but also more granular (web banner, web pop-up etc.). Here are some examples:

Channel-level Touchpoints

  • Email: Role
  • Email: Time of open
  • In-store display (JSON endpoint)
  • Native app
  • Search

Wireframe-level Touchpoints

  • Web overlay
  • Web alert bar
  • Web banner
  • Web content block
  • Web menu

If you’re designing for web interfaces, for example, you will likely need to include personalized “zones” in your wireframes. The content for these can be presented programmatically in touchpoints based on our next step, contexts and campaigns.

Contexts and Campaigns

Once you’ve outlined some touchpoints, you can consider the actual personalized content a user will receive. Many personalization tools will refer to these as “campaigns” (so, for example, a campaign on a web banner for new visitors to the website). These will programmatically be shown at certain touchpoints to certain user segments, as defined by user data. At this stage, we find it helpful to consider two separate models: a context model and a content model. The context helps you consider the level of engagement of the user at the personalization moment, for example a user casually browsing information vs. doing a deep-dive. Think of it in terms of information retrieval behaviors. The content model can then help you determine what type of personalization to serve based on the context (for example, an “Enrich” campaign that shows related articles may be a suitable supplement to extant content).

Personalization Context Model:

  1. Browse
  2. Skim
  3. Nudge
  4. Feast

Personalization Content Model:

  1. Alert
  2. Make Easier
  3. Cross-Sell
  4. Enrich

We’ve written extensively about each of these models elsewhere, so if you’d like to read more you can check out Colin’s Personalization Content Model and Jeff’s Personalization Context Model

User Segments

User segments can be created prescriptively or adaptively, based on user research (e.g. via rules and logic tied to set user behaviors or via A/B testing). At a minimum you will likely need to consider how to treat the unknown or first-time visitor, the guest or returning visitor for whom you may have a stateful cookie (or equivalent post-cookie identifier), or the authenticated visitor who is logged in. Here are some examples from the personalization pyramid:

  • Unknown
  • Guest
  • Authenticated
  • Default
  • Referred
  • Role
  • Cohort
  • Unique ID

Actionable Data

Every organization with any digital presence has data. It’s a matter of asking what data you can ethically collect on users, its inherent reliability and value, as to how can you use it (sometimes known as “data activation.”) Fortunately, the tide is turning to first-party data: a recent study by Twilio estimates some 80% of businesses are using at least some type of first-party data to personalize the customer experience. 

Source: “The State of Personalization 2021” by Twilio. Survey respondents were n=2,700 adult consumers who have purchased something online in the past 6 months, and n=300 adult manager+ decision-makers at consumer-facing companies that provide goods and/or services online. Respondents were from the United States, United Kingdom, Australia, and New Zealand.Data was collected from April 8 to April 20, 2021.

First-party data represents multiple advantages on the UX front, including being relatively simple to collect, more likely to be accurate, and less susceptible to the “creep factor” of third-party data. So a key part of your UX strategy should be to determine what the best form of data collection is on your audiences. Here are some examples:

Figure 1.1.2: Example of a personalization maturity curve, showing progression from basic recommendations functionality to true individualization. Credit: https://kibocommerce.com/blog/kibos-personalization-maturity-chart/

There is a progression of profiling when it comes to recognizing and making decisioning about different audiences and their signals. It tends to move towards more granular constructs about smaller and smaller cohorts of users as time and confidence and data volume grow.

While some combination of implicit / explicit data is generally a prerequisite for any implementation (more commonly referred to as first party and third-party data) ML efforts are typically not cost-effective directly out of the box. This is because a strong data backbone and content repository is a prerequisite for optimization. But these approaches should be considered as part of the larger roadmap and may indeed help accelerate the organization’s overall progress. Typically at this point you will partner with key stakeholders and product owners to design a profiling model. The profiling model includes defining approach to configuring profiles, profile keys, profile cards and pattern cards. A multi-faceted approach to profiling which makes it scalable.

Pulling it Together

While the cards comprise the starting point to an inventory of sorts (we provide blanks for you to tailor your own), a set of potential levers and motivations for the style of personalization activities you aspire to deliver, they are more valuable when thought of in a grouping. 

In assembling a card “hand”, one can begin to trace the entire trajectory from leadership focus down through a strategic and tactical execution. It is also at the heart of the way both co-authors have conducted workshops in assembling a program backlog—which is a fine subject for another article.

In the meantime, what is important to note is that each colored class of card is helpful to survey in understanding the range of choices potentially at your disposal, it is threading through and making concrete decisions about for whom this decisioning will be made: where, when, and how.

Scenario A: We want to use personalization to improve customer satisfaction on the website. For unknown users, we will create a short quiz to better identify what the user has come to do. This is sometimes referred to as “badging” a user in onboarding contexts, to better characterize their present intent and context.

Lay Down Your Cards

Any sustainable personalization strategy must consider near, mid and long-term goals. Even with the leading CMS platforms like Sitecore and Adobe or the most exciting composable CMS DXP out there, there is simply no “easy button” wherein a personalization program can be stood up and immediately view meaningful results. That said, there is a common grammar to all personalization activities, just like every sentence has nouns and verbs. These cards attempt to map that territory.




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To Ignite a Personalization Practice, Run this Prepersonalization Workshop

Picture this. You’ve joined a squad at your company that’s designing new product features with an emphasis on automation or AI. Or your company has just implemented a personalization engine. Either way, you’re designing with data. Now what? When it comes to designing for personalization, there are many cautionary tales, no overnight successes, and few guides for the perplexed. 

Between the fantasy of getting it right and the fear of it going wrong—like when we encounter “persofails” in the vein of a company repeatedly imploring everyday consumers to buy additional toilet seats—the personalization gap is real. It’s an especially confounding place to be a digital professional without a map, a compass, or a plan.

For those of you venturing into personalization, there’s no Lonely Planet and few tour guides because effective personalization is so specific to each organization’s talent, technology, and market position. 

But you can ensure that your team has packed its bags sensibly.

Designing for personalization makes for strange bedfellows. A savvy art-installation satire on the challenges of humane design in the era of the algorithm. Credit: Signs of the Times, Scott Kelly and Ben Polkinghome.

There’s a DIY formula to increase your chances for success. At minimum, you’ll defuse your boss’s irrational exuberance. Before the party you’ll need to effectively prepare.

We call it prepersonalization.

Behind the music

Consider Spotify’s DJ feature, which debuted this past year.

https://www.youtube.com/watch?v=ok-aNnc0Dko

We’re used to seeing the polished final result of a personalization feature. Before the year-end award, the making-of backstory, or the behind-the-scenes victory lap, a personalized feature had to be conceived, budgeted, and prioritized. Before any personalization feature goes live in your product or service, it lives amid a backlog of worthy ideas for expressing customer experiences more dynamically.

So how do you know where to place your personalization bets? How do you design consistent interactions that won’t trip up users or—worse—breed mistrust? We’ve found that for many budgeted programs to justify their ongoing investments, they first needed one or more workshops to convene key stakeholders and internal customers of the technology. Make yours count.

​From Big Tech to fledgling startups, we’ve seen the same evolution up close with our clients. In our experiences with working on small and large personalization efforts, a program’s ultimate track record—and its ability to weather tough questions, work steadily toward shared answers, and organize its design and technology efforts—turns on how effectively these prepersonalization activities play out.

Time and again, we’ve seen effective workshops separate future success stories from unsuccessful efforts, saving countless time, resources, and collective well-being in the process.

A personalization practice involves a multiyear effort of testing and feature development. It’s not a switch-flip moment in your tech stack. It’s best managed as a backlog that often evolves through three steps: 

  1. customer experience optimization (CXO, also known as A/B testing or experimentation)
  2. always-on automations (whether rules-based or machine-generated)
  3. mature features or standalone product development (such as Spotify’s DJ experience)

This is why we created our progressive personalization framework and why we’re field-testing an accompanying deck of cards: we believe that there’s a base grammar, a set of “nouns and verbs” that your organization can use to design experiences that are customized, personalized, or automated. You won’t need these cards. But we strongly recommend that you create something similar, whether that might be digital or physical.

Set your kitchen timer

How long does it take to cook up a prepersonalization workshop? The surrounding assessment activities that we recommend including can (and often do) span weeks. For the core workshop, we recommend aiming for two to three days. Here’s a summary of our broader approach along with details on the essential first-day activities.

The full arc of the wider workshop is threefold:

  1. Kickstart: This sets the terms of engagement as you focus on the opportunity as well as the readiness and drive of your team and your leadership. .
  2. Plan your work: This is the heart of the card-based workshop activities where you specify a plan of attack and the scope of work.
  3. Work your plan: This phase is all about creating a competitive environment for team participants to individually pitch their own pilots that each contain a proof-of-concept project, its business case, and its operating model.

Give yourself at least a day, split into two large time blocks, to power through a concentrated version of those first two phases.

Kickstart: Whet your appetite

We call the first lesson the “landscape of connected experience.” It explores the personalization possibilities in your organization. A connected experience, in our parlance, is any UX requiring the orchestration of multiple systems of record on the backend. This could be a content-management system combined with a marketing-automation platform. It could be a digital-asset manager combined with a customer-data platform.

Spark conversation by naming consumer examples and business-to-business examples of connected experience interactions that you admire, find familiar, or even dislike. This should cover a representative range of personalization patterns, including automated app-based interactions (such as onboarding sequences or wizards), notifications, and recommenders. We have a catalog of these in the cards. Here’s a list of 142 different interactions to jog your thinking.

This is all about setting the table. What are the possible paths for the practice in your organization? If you want a broader view, here’s a long-form primer and a strategic framework.

Assess each example that you discuss for its complexity and the level of effort that you estimate that it would take for your team to deliver that feature (or something similar). In our cards, we divide connected experiences into five levels: functions, features, experiences, complete products, and portfolios. Size your own build here. This will help to focus the conversation on the merits of ongoing investment as well as the gap between what you deliver today and what you want to deliver in the future.

Next, have your team plot each idea on the following 2×2 grid, which lays out the four enduring arguments for a personalized experience. This is critical because it emphasizes how personalization can not only help your external customers but also affect your own ways of working. It’s also a reminder (which is why we used the word argument earlier) of the broader effort beyond these tactical interventions.

Getting intentional about the desired outcomes is an important component to a large-scale personalization program. Credit: Bucket Studio.

Each team member should vote on where they see your product or service putting its emphasis. Naturally, you can’t prioritize all of them. The intention here is to flesh out how different departments may view their own upsides to the effort, which can vary from one to the next. Documenting your desired outcomes lets you know how the team internally aligns across representatives from different departments or functional areas.

The third and final kickstart activity is about naming your personalization gap. Is your customer journey well documented? Will data and privacy compliance be too big of a challenge? Do you have content metadata needs that you have to address? (We’re pretty sure that you do: it’s just a matter of recognizing the relative size of that need and its remedy.) In our cards, we’ve noted a number of program risks, including common team dispositions. Our Detractor card, for example, lists six stakeholder behaviors that hinder progress.

Effectively collaborating and managing expectations is critical to your success. Consider the potential barriers to your future progress. Press the participants to name specific steps to overcome or mitigate those barriers in your organization. As studies have shown, personalization efforts face many common barriers.

The largest management consultancies have established practice areas in personalization, and they regularly research program risks and challenges. Credit: Boston Consulting Group.

At this point, you’ve hopefully discussed sample interactions, emphasized a key area of benefit, and flagged key gaps? Good—you’re ready to continue.

Hit that test kitchen

Next, let’s look at what you’ll need to bring your personalization recipes to life. Personalization engines, which are robust software suites for automating and expressing dynamic content, can intimidate new customers. Their capabilities are sweeping and powerful, and they present broad options for how your organization can conduct its activities. This presents the question: Where do you begin when you’re configuring a connected experience?

What’s important here is to avoid treating the installed software like it were a dream kitchen from some fantasy remodeling project (as one of our client executives memorably put it). These software engines are more like test kitchens where your team can begin devising, tasting, and refining the snacks and meals that will become a part of your personalization program’s regularly evolving menu.

Progressive personalization, a framework for designing connected experiences. Credit: Bucket Studio and Colin Eagan.

The ultimate menu of the prioritized backlog will come together over the course of the workshop. And creating “dishes” is the way that you’ll have individual team stakeholders construct personalized interactions that serve their needs or the needs of others.

The dishes will come from recipes, and those recipes have set ingredients.

In the same way that ingredients form a recipe, you can also create cards to break down a personalized interaction into its constituent parts. Credit: Bucket Studio and Colin Eagan.

Verify your ingredients

Like a good product manager, you’ll make sure—andyou’ll validate with the right stakeholders present—that you have all the ingredients on hand to cook up your desired interaction (or that you can work out what needs to be added to your pantry). These ingredients include the audience that you’re targeting, content and design elements, the context for the interaction, and your measure for how it’ll come together. 

This isn’t just about discovering requirements. Documenting your personalizations as a series of if-then statements lets the team: 

  1. compare findings toward a unified approach for developing features, not unlike when artists paint with the same palette; 
  2. specify a consistent set of interactions that users find uniform or familiar; 
  3. and develop parity across performance measurements and key performance indicators too. 

This helps you streamline your designs and your technical efforts while you deliver a shared palette of core motifs of your personalized or automated experience.

Compose your recipe

What ingredients are important to you? Think of a who-what-when-why construct

  • Who are your key audience segments or groups?
  • What kind of content will you give them, in what design elements, and under what circumstances?
  • And for which business and user benefits?

We first developed these cards and card categories five years ago. We regularly play-test their fit with conference audiences and clients. And we still encounter new possibilities. But they all follow an underlying who-what-when-why logic.

Here are three examples for a subscription-based reading app, which you can generally follow along with right to left in the cards in the accompanying photo below. 

  1. Nurture personalization: When a guest or an unknown visitor interacts with  a product title, a banner or alert bar appears that makes it easier for them to encounter a related title they may want to read, saving them time.
  2. Welcome automation: When there’s a newly registered user, an email is generated to call out the breadth of the content catalog and to make them a happier subscriber.
  3. Winback automation: Before their subscription lapses or after a recent failed renewal, a user is sent an email that gives them a promotional offer to suggest that they reconsider renewing or to remind them to renew.
A “nurture” automation may trigger a banner or alert box that promotes content that makes it easier for users to complete a common task, based on behavioral profiling of two user types. Credit: Bucket Studio.
A “welcome” automation may be triggered for any user that sends an email to help familiarize them with the breadth of a content library, and this email ideally helps them consider selecting various titles (no matter how much time they devote to reviewing the email’s content itself). Credit: Bucket Studio.
A “winback” automation may be triggered for a specific group, such as users with recently failed credit-card transactions or users at risk of churning out of active usage, that present them with a specific offer to mitigate near-future inactivity. Credit: Bucket Studio.

A useful preworkshop activity may be to think through a first draft of what these cards might be for your organization, although we’ve also found that this process sometimes flows best through cocreating the recipes themselves. Start with a set of blank cards, and begin labeling and grouping them through the design process, eventually distilling them to a refined subset of highly useful candidate cards.

You can think of the later stages of the workshop as moving from recipes toward a cookbook in focus—like a more nuanced customer-journey mapping. Individual “cooks” will pitch their recipes to the team, using a common jobs-to-be-done format so that measurability and results are baked in, and from there, the resulting collection will be prioritized for finished design and delivery to production.

Better kitchens require better architecture

Simplifying a customer experience is a complicated effort for those who are inside delivering it. Beware anyone who says otherwise. With that being said,  “Complicated problems can be hard to solve, but they are addressable with rules and recipes.”

When personalization becomes a laugh line, it’s because a team is overfitting: they aren’t designing with their best data. Like a sparse pantry, every organization has metadata debt to go along with its technical debt, and this creates a drag on personalization effectiveness. Your AI’s output quality, for example, is indeed limited by your IA. Spotify’s poster-child prowess today was unfathomable before they acquired a seemingly modest metadata startup that now powers its underlying information architecture.

You can definitely stand the heat…

Personalization technology opens a doorway into a confounding ocean of possible designs. Only a disciplined and highly collaborative approach will bring about the necessary focus and intention to succeed. So banish the dream kitchen. Instead, hit the test kitchen to save time, preserve job satisfaction and security, and safely dispense with the fanciful ideas that originate upstairs of the doers in your organization. There are meals to serve and mouths to feed.

This workshop framework gives you a fighting shot at lasting success as well as sound beginnings. Wiring up your information layer isn’t an overnight affair. But if you use the same cookbook and shared recipes, you’ll have solid footing for success. We designed these activities to make your organization’s needs concrete and clear, long before the hazards pile up.

While there are associated costs toward investing in this kind of technology and product design, your ability to size up and confront your unique situation and your digital capabilities is time well spent. Don’t squander it. The proof, as they say, is in the pudding.




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Surface functionalization, particle size and pharmaceutical co-contaminant dependent impact of nanoplastics on marine crustacean – Artemia salina.

Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript
DOI: 10.1039/D4EM00010B, Paper
Durgalakshmi Rajendran, Mahalakshmi Kamalakkannan, George Priya Doss C, Natarajan Chandrasekaran
Despite a significant amount of research on micronanoplastics (MNPs), there is still a gap in our understanding of their function as transporters of other environmental pollutants (known as the Trojan...
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Groundwater Denitrification Enhanced by Hydrogel Immobilized Iron/Solid Carbon Source: Impact on Denitrification and Substrate Release Performance

Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript
DOI: 10.1039/D3EM00444A, Paper
Wenhao Yu, Lecheng Liu, Yan Ni, Xilai Zheng
Encapsulating solid carbon source and zero-valent iron (ZVI) within hydrogel can prevent direct contact with groundwater, thereby extending the lifespan of their released active substrates. It is currently unclear whether...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hybridized local and charge transfer dendrimers with near-unity exciton utilization for enabling high-efficiency solution-processed hyperfluorescent OLEDs

Mater. Horiz., 2024, 11,1741-1751
DOI: 10.1039/D3MH01860A, Communication
Yixiao Yin, Songkun Zeng, Chen Xiao, Peng Fan, Dong Jin Shin, Ki Ju Kim, Hyewon Nam, Qian Ma, Huili Ma, Weiguo Zhu, Taekyung Kim, Jun Yeob Lee, Yafei Wang
Two dendrimers, called D-TTT-H and D-TTT-tBu, were prepared, which exhibits both hot exciton process and TADF characteristic simultaneously in solid state. The solution processable OLED showed an EQEmax of 30.88% employing D-TTT-H as a sensitizer.
The content of this RSS Feed (c) The Royal Society of Chemistry




liz

A bioactive calcium silicate nanowire-containing hydrogel for organoid formation and functionalization

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00228H, Communication
Wenping Ma, Yi Zheng, Guangzhen Yang, Hongjian Zhang, Mingxia Lu, Hongshi Ma, Chengtie Wu, Hongxu Lu
An optimized CS/GelMA composite hydrogel is designed for organoid development, which can be used as a substrate for supporting intestinal and liver organoid formation and functionalization.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




liz

Advancing Lithium-Sulfur Battery Efficiency: Utilizing a 2D/2D g-C3N4@MXene Heterostructure to Enhance Sulfur Evolution Reactions and Regulate Polysulfides in Lean Electrolyte Conditions

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00200H, Communication
Vijay Kumar, Otavio Augusto Titton Dias, Abdelaziz Gouda, Ritu Malik, Mohini M. Sain
Lithium–sulfur batteries (LSBs) show promise for achieving a high energy density of 500 Wh/kg, despite challenges such as poor cycle life and low energy efficiency due to sluggish redox kinetics...
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liz

Hierarchical surface-modification of nano-Cu toward one pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions

Mater. Horiz., 2024, 11,1957-1963
DOI: 10.1039/D3MH01921G, Communication
Zhi-Qiang Wang, ChengHua Deng, Bo Li, Hai-Qiang Luo, Peng Hao, Xiao Liu, Jian-Gong Ma, Peng Cheng
One pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions to synthesize high value-added dihydrobenzofurans are realized through the hierarchically constructed Cu–Ag nanoalloy with a MOF cover as an efficient catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




liz

Decorin in the spatial control of collagen mineralization

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02216A, Communication
Yuming Bai, Peng Wu, Qiufang Zhang, Feng Lin, Ling Hu, Zhisheng Zhang, Wenxia Huang, Yin Xiao, Qiliang Zuo
Understanding the molecular mechanism by which the periodontal ligament (PDL) is maintained un-calcified between two mineralized tissues (cementum and bone), may facilitate the functional repair and regeneration of the periodontium...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Why Does Globalization Fuel Populism? [electronic journal].




liz

The Wheels of Change: Technology Adoption, Millwrights, and Persistence in Britain's Industrialization [electronic journal].




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What drives the legalization of immigrants? Evidence from IRCA [electronic journal].




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Welfare State vs. Market Forces in a Globalization Era [electronic journal].

National Bureau of Economic Research




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Welfare State, Inequality, and Globalization: Role of International-capital-flow Direction [electronic journal].

National Bureau of Economic Research




liz

The Welfare State besides Globalization Forces [electronic journal].

National Bureau of Economic Research




liz

Wage Equalization and Regional Misallocation: Evidence from Italian and German Provinces [electronic journal].

National Bureau of Economic Research




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Utilization-Adjusted TFP Across Countries: Measurement and Implications for International Comovement [electronic journal].

National Bureau of Economic Research




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Understanding the Effects of Legalizing Undocumented Immigrants [electronic journal].