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Single-layer 2D supramolecular-organic-framework-supported polyoxometalates: efficient selective oxidation of toluene in seawater under sunlight

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04480K, Paper
Xin-Long Ni, Yan Fan, Yi Luo, Xu Luo
Performing organic reactions in water, in particular in seawater under sunlight, is a desirable objective in chemistry because both are the most abundant and cheapest resources on earth. Herein, we...
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Green dipolar aprotic solvents for the dynamic polycondensation of high-performance polyimide membranes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04279D, Paper
Open Access
E. San José, M. R. de la Viuda, F. J. Carmona, C. Soto, L. Palacio, P. Prádanos, A. Hernández, A. Tena
Guidelines for the evaluation of green solvents were revisited and integrated into a decision diagram. GVL, Cyrene™, DMC, NOP, DEC, DMI, GBL, NBP, Rhodiasolv® PolarClean, and DMSO showed the potential to substitute hazardous polar aprotic solvents.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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High Efficiency Leaching of Valuable Metals from Waste Lithium-ion ternary Batteries under Mild Conditions Using Green Deep Eutectic Solvents

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04373A, Paper
Bo Li, Zhengfu Zhang, Chengping Li, Jinsong Wang, Rundong Wan, Jiangzhao Chen, Ying Liu, Yuejing Bin, xiaoping yang, Chongjun Bao, Shaohua Ju
Recently, the production and demand for lithium-ion batteries (LIBs) has increased owing to increasing number of electric vehicles and products. This surge has considerably increased spent LIBs, leading to environmental...
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Continuous production of 1,2-pentanediol from furfuryl alcohol over highly stable bimetallic Ni–Sn alloy catalysts

Green Chem., 2024, 26,11164-11176
DOI: 10.1039/D4GC02757D, Paper
Ajaysing S. Nimbalkar, Kyung-Ryul Oh, Do-Young Hong, Byung Gyu Park, Maeum Lee, Dong Won Hwang, Ali Awad, Pravin P. Upare, Seung Ju Han, Young Kyu Hwang
A bimetallic NiSn/ZnO catalyst converts biomass-derived furfuryl alcohol into 1,2-PDO continuously, yielding 91.0% over 400 hours.
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Visible light-induced strain-release transformations of bicyclo[1.1.0]butanes

Green Chem., 2024, 26,11083-11105
DOI: 10.1039/D4GC03193H, Tutorial Review
Qing-Bao Zhang, Feng Li, Bin Pan, Shanshan Zhang, Xiang-Guo Yue, Qiang Liu
This review aims to provide an overview on the recent visible light-mediated strain-release transformations of bicyclo[1.1.0]butanes. Prospects for future development of (aza)bicyclo[1.1.0]butanes in this fascinating field are outlined.
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Thermodynamically stable synthesis of high entropy alloys and efficiently catalyzed oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under base-free conditions

Green Chem., 2024, 26,11316-11327
DOI: 10.1039/D4GC04186K, Paper
Guangqiang Lv, Shan Liu, Xiaoyan Chen, Mengxin Chen, Yanjuan Wu, Yuji Gao, Shuai Wang, Furong Tao, Jingui Wang, Liwei Niu
In a completely non-alkaline aqueous system, a high-entropy alloy catalyst composed of FeCoNiCuGaPt activates O2 and H2O molecules to form hydroxyl radicals (˙OH) and efficiently oxidizes 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.
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Correction: Continuous production of 1,2-pentanediol from furfuryl alcohol over highly stable bimetallic Ni–Sn alloy catalysts

Green Chem., 2024, 26,11364-11364
DOI: 10.1039/D4GC90117G, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ajaysing S. Nimbalkar, Kyung-Ryul Oh, Do-Young Hong, Byung Gyu Park, Maeum Lee, Dong Won Hwang, Ali Awad, Pravin P. Upare, Seung Ju Han, Young Kyu Hwang
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Augmentation of Pd-catalysed oxidative C–H/C–H carbonylation through alternating current electrosynthesis

Green Chem., 2024, 26,11177-11181
DOI: 10.1039/D4GC04569F, Paper
Haoran Li, Jiaqi Peng, Li Zeng, Linpu Zhou, Muhammad Shabbir, Feiran Xiao, Jiaxin Yuan, Hong Yi, Aiwen Lei
Unsymmetrical-waveform AC electrolysis facilitates Pd-catalysed oxidative C–H/C–H carbonylation. This methodology highlights the substantial benefits conferred by Pd-catalysed conversions in comparison to traditional DC electrolysis.
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Development of a highly efficient electrocatalytic hydrogenation and dehalogenation system using a flow cell with a Pd tube cathode

Green Chem., 2024, 26,11328-11333
DOI: 10.1039/D4GC04617J, Paper
Hiroaki Tajima, Hideki Ishii, Shinsuke Inagi, Toshio Fuchigami
A novel flow and circulation electrolytic system has been developed for the highly efficient cathodic hydrogenation of unsaturated compounds and dehalogenation of various aromatic halides.
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High-efficient green catalytic conversion for waste CS2 by non-noble metal cage-based MOFs: An access to high-valued thiazolidine-2-thione

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04541F, Paper
Wenyu Ding, Xinyu Tang, Sheng Jin, Zhao Li, Dongwei Xu, Xiaomin Kang, Zhiliang Liu
Green and effective disposal of Carbon disulfide (CS2) waste into high-valued chemicals under mild conditions is meaningful and challenging. Herein, a novel 3D cluster-based metal-organic framework (MOF) {(Me2NH2)2[Co3(µ3-O)(XN)(BDC)3]∙4DMF∙5MeOH}n (compound 1)...
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Spotlight on the media

Satirical films about the media have always been entertaining




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High Five

Readers write in with their top five list




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High five

Readers write in with their top five list movies




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High five

Readers write in thier top five favorite films




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High Five

Readers write in with their top five list




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Highfive

Readers write in with their top-five list




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High Five

Readers write in with their top five list




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High five




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High five

Readers write in their top five list




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High Five




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High Five

Readers write in with their top five list




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The piracy nightmare

A look at the losses to the film industry thanks to smartphones, camcorders and hi-tech projectors




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High five

Readers write in with their top five list




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High Five

Readers write in with their top five list




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High Five

Readers write in their top five list




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High Five

Readers send in their top five films.




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Daredevils not taking Supergiants lightly

Delhi team to stick to its horses-for-courses policy



  • Indian Premier League

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It’s all about getting the basics right: Amla



  • Indian Premier League

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Raina returns as Lions hope to roar against Knight Riders

Half of Gujarat Lions worries will be taken care of if the dazzling opening combo of Dwayne Smith and Brendon McCullum fires.



  • Indian Premier League

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Lions breeze through by 6 wickets

A Dwayne-Smith bowling special and a Suresh-Raina batting special takes Gujarat Lions up to the top of the table on points.



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It’s win or go home for Knight Riders



  • Indian Premier League

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Kolkata Knight Riders books play-offs berth



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Can Sunrisers tame the marauding Knight Riders?

Injuries to key players a concern for both teams; the winner will meet the loser of Qualifier 1 for a place in the final



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Sunrisers eliminate Knight Riders

Bowlers do the trick once again for the Hyderabad team, setting up a meeting with Lions



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Kotla assignment was my toughest: Mudgal



  • Indian Premier League

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IPL 2022 | Shreyas Iyer appointed as Kolkata Knight Riders’ new captain

Iyer has captained Delhi Capitals to their only IPL final in 2020




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Titans hold their nerve to ward off Russell onslaught

The KKR all-rounder’s four for five and a belligerent 48 go in vain after Hardik guides GT to 156



  • Indian Premier League

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CSK were not good enough to win close games: Fleming

“We suffered from catastrophic success so just trying to play the same way... is a real challenge,” said Chennai Super Kings coach Stephen Fleming after the team’s final IPL 2022 match against Rajasthan Royals



  • Indian Premier League

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Amazon pulls out of high-stakes bidding battle for IPL telecast rights

Amazon’s decision comes just two days ahead of the bidding for IPL television and digital broadcast rights



  • Indian Premier League

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IPL | After ₹48k-crore media rights deal, Ness Wadia pitches for longer seasons

Punjab Kings co-owner Ness Wadia congratulated Jay Shah and Co for delivering on an innovative media rights strategy but hoped the IPL would have more games over two halves in a calendar year



  • Indian Premier League

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What explains the BCCI bonanza on IPL media rights? 

Why has digital streaming rights garnered higher numbers in the auction? How has the league’s value improved?




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Chandrakant Pandit appointed Kolkata Knight Riders head coach

He is the first Indian to hold that position for the two-time IPL champion



  • Indian Premier League

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Data | Run-fest IPL 2023: Highest run-rate, most sixes and boundaries per game across all seasons

Rule changes and team tactics have made “power hitting” a mainstay of T20 cricket




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Dia Mirza on droughts, trolls




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‘Be yourself’: Balraj SIngh Khera

After winning the “MTV Roadies X4”, Balraj Singh Khera emphasises the need to drive away the fear of failure




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Reaching for the high notes

Singer Syed Subahan gears up for his new innings as an actor in a new film Veruli, which tackles a social issue




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The ‘Ghost Stories’ directors' roundtable: United in horror

Zoya Akhtar, Anurag Kashyap, Dibakar Banerjee and Karan Johar talk to Namrata Joshi on what scares them in film and in real life, 'sanskari ghosts' and questioning authority




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Lamborghini rolls out new Huracan Spyder at Rs 3.89 crore




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Soak in the sights

The Mercedes C-Class Cabriolet is a plush and personal driving experience that makes a strong case for convertible cars




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The right balance

While the exorbitant price of the Volkswagen GTI makes it a car you buy with your heart and not your head, here’s a look at its noteworthy features