Frances Fuller has followed up her award winning book about Lebanon, In Borrowed Houses, with a new book that helps us face a challenge each and every one of us must someday face.

Season Two Reveals Whether Adrienne's Love Life Will Bring Tricks or Treats

Acquisition Results in an Unparalleled Connected Health Experience for Individuals, Hospitals, and Healthcare Organizations Nationwide

The Complaint alleges that installation technicians were paid on a piece-rate/per task basis only and not paid an overtime premium.

Sharpe's previously published books are riveting inspirational thrillers written in honor of her daughter Kate and her husband Steve.

Gripping account of K.P. Yohannan's spiritual journey set for release April 28 as nearly half of North Americans cite COVID-19 as 'last days' warning

After almost a year of planning and consideration, "Light the Barricades" is now live in Los Angeles, CA, a project by renowned artists Candy Chang and James A. Reeves in collaboration with Annenberg Space for Photography.

Is your El Pasos home Air Conditioner blowing hot air? Professional service technicians will be able to come out and diagnose your problem and give you a fair estimate for what it will cost to get your air conditioner running again.

Lightweight, Portable and Compact the Meditation-T and the FlooringKnee-T device are affordable solutions to knee strain problems.

CSUDH moves forward with energy storage technology for green initiative

Illumitex's FarmVisionAI provides remote visualization, AI analysis, and labor management alleviating COVID-19 driven operational constraints

The nationwide tally of confirmed COVID-19 cases reached 59,662 on Saturday and the death toll rose to 1,981 with the country registering an increase of 95 deaths and 3,320 cases in 24 hours till Saturday morning, the Union Health Ministry said

The post India’s COVID-19 tally reaches 59,662, deaths near 2,000; fresh cases among repatriated Indians, paramilitary forces emerges as a major concern appeared first on Firstpost.

Andrew Liveris, the CEO of Dow Chemical, discusses the 120-year-old company’s ambitious sustainability agenda. He says an environmentally driven business model is good for the earth—and the bottom line. Liveris is one of the CEOs contributing to Harvard Business Review’s Future Economy Project, in which leaders detail their company’s efforts to adapt to and mitigate climate change.

Digitally determined businesses are those that have the bigger picture in mind and plan a roadmap towards advanced changes with a view of the entire business.

Tower and Infrastructure Providers Association (TAIPA) Director-General T R Dua said that during the lockdown period so far, telecom tower-related work was primarily focused on operation and maintenance activities and carrying out essential repairs and upgrades.

Stallion Spotlight offers stud farm representatives a chance to address breeders and answer questions as they finalize their mating decisions for the 2020 breeding season. In this edition, Tom Hamm, director of stallion seasons at Three Chimneys, talks about Funtastic, a Grade 1 winner whose first foals are arriving in 2020. Funtastic Gr. or ro. h., […]

The post Stallion Spotlight: Tom Hamm Of Three Chimneys On Funtastic appeared first on Horse Racing News | Paulick Report.

The Jockey Club board of stewards today announced that it has adopted a final rule limiting the annual breeding of individual stallions. The rule reflects The Jockey Club's goal to preserve the health of the Thoroughbred breed for the long term and will apply prospectively to stallions born in 2020 or later. Effective today, The […]

The post The Jockey Club Officially Adopts Rule Limiting Stallion Book Size To 140 Mares appeared first on Horse Racing News | Paulick Report.

Stallion Spotlight offers stud farm representatives a chance to address breeders and answer questions as they finalize their mating decisions for the 2020 breeding season. In this edition, Claiborne Farm president Walker Hancock and stallion seasons and bloodstock manager Bernie Sams discuss First Samurai, the sire of Grade 1 winners Lea, Justin Phillip, and Executiveprivilege. First […]

The post Stallion Spotlight: Claiborne Farm’s Walker Hancock And Bernie Sams On First Samurai appeared first on Horse Racing News | Paulick Report.

Baltimore Police say multiple people were shot, at least one dead, at two cookouts on Edmondson Ave near North Warwick Ave on Sunday evening.

Listen to Scott Wykoff's WBAL NewsRadio 1090 interview with Mike Pons of Country Life Farm as Md's top new stallion settles into his stall at Md's oldest continuous operating Thoroughbred breeding farm & birthplace of Cigar.

Multiple graded stakes winner Call Paul, formerly trained by Jason Servis, had to be euthanized on Wednesday morning at Belmont Park. The Daily Racing Form reports that the colt suffered catastrophic injuries to his left hind leg during a workout over the training track. The 4-year-old Pennsylvania-bred son of Friesan Fire was breezing for the fourth […]

The post Former Jason Servis Trainee Call Paul Fatally Injured During Belmont Workout appeared first on Horse Racing News | Paulick Report.

Grand Canyon National Park recently completed installation of new interpretive and orientation exhibits at the Grand Canyon Visitor Center located near Mather Point on the South Rim. https://www.nps.gov/grca/learn/news/2012-04-23_exhibits.htm

On March 29, 2018, the National Park Service (NPS) will begin installing one test well and two monitoring wells next to Bright Angel Creek near Phantom Ranch. https://www.nps.gov/grca/learn/news/test-wells.htm

Grand Canyon National Park will begin installing five water test wells within the inner canyon at Phantom Ranch next week. The construction will begin Oct. 28 and is expected to conclude on Dec. 5, 2019. https://www.nps.gov/grca/learn/news/grand-canyon-national-park-installs-new-test-wells-2019-10-24.htm

Did you do it? Did you download? Did you trust the federal government enough to let them trace your extended interactions with your phone?

A dropline menu using a totally NEW method that requires NO hacks and works in all browsers. Also allows tabbing.

BLACKENED/Q PRIME rockers METALLICA and drummer LARS ULRICH have reached out to fans with  a message of encouragement on the band’s new SIRIUSXM  MANDATORY METALLICA … more

The following is a guest post by Austin Gunter of WPEngine.com. If you’re looking to boost performance for a content-heavy WordPress installation, adding a cache like Varnish is a great way to boost your site’s performance. NB - This is an advanced topic, and only relevant if you have full control over your server (e.g. you're on a VPS). It does not apply to regular webhosting.

Background CEDAR RAPIDS — After a bitter battle between residents and one of the city’s major employers — Cargill — with the city of Cedar Rapids in the middle, in...

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Background

CEDAR RAPIDS — After a bitter battle between residents and one of the city’s major employers — Cargill — with the city of Cedar Rapids in the middle, in December, the Cedar Rapids City Council approved a $6.5 million, 12-track, 200-car rail yard located between the Rompot neighborhood and Prairie Park Fishery.

Cargill wanted to buy and put the rail yard on a 28-acre city-owned site on Stewart Road SE. Construction required rezoning the land to industrial use and a change to the city’s future land use map — putting city officials in the spotlight.

The rail yard was needed for more supply chain stability and to protect jobs at the corn-milling plant, at 1710 16th St. SE and not far from the rail yard site, company officials said. Cargill officials planned to submit final paperwork within a month of the vote, begin construction in early spring and have the rail yard operating by the end of the year.

A lot and nothing.

Before construction was to begin, the city required Cargill to provide a third-party appraisal of the land. The city had provided an initial value of $83,200, which Cargill agreed to match. However, the value of the land has been in question as nearby properties ranged from $20,000 to $30,000 an acre, which was far greater than the $3,000 per acre value the city used.

City officials say the appraisal has not been submitted, nor has Cargill sought the required permits before construction can begin.

This delay began well before disruptions from the coronavirus pandemic and after lawsuits were filed to block the rail yard.

Rompot resident and state Sen. Rob Hogg, who is a lawyer, filed two lawsuits against the City Council — one each challenging the rezoning vote and the vote to change the future land use map. Numerous neighbors and others in opposition to the rail yard have joined the lawsuit, which Hogg supported.

Meanwhile, Cargill intervened on behalf of the city. At this point, sides still are arguing whether to expand the record to include additional evidence. Dates for a hearing have not been set.

So, the status of the contentious rail yard and a timeline for construction remains in limbo.

“We don’t have anything new to share at this point regarding work and timelines specific to the development of the rail yard,” Kelly Sheehan, a spokeswoman for Cargill, said in late April.

Applying the equivariant moving frames method, we construct convergent normal forms for real-analytic 5-dimensional totally nondegenerate CR submanifolds of C^4. These CR manifolds are divided into several biholomorphically inequivalent subclasses, each of which has its own complete normal form. Moreover it is shown that, biholomorphically, Beloshapka's cubic model is the unique member of this class with the maximum possible dimension seven of the corresponding algebra of infinitesimal CR automorphisms. Our results are also useful in the study of biholomorphic equivalence problem between CR manifolds, in question.

You’re out of a job. You’ve been stuck inside for weeks.…

The invention concerns a new process for the preparation of crystalline form of agomelatine from a solution of agomelatine in a solvent, characterized in that the agomelatine is crystallized by instantaneous precipitation from said solution, at a temperature equal to or below −10° C.

Disclosed are oil-extended olefin block copolymer compositions with microcrystalline wax. The microcrystalline wax reduces oil-bleed while maintaining composition softness.

This invention relates to a process for polymerizing ethylene comprising contacting ethylene and optional comonomers with a catalyst system comprising an activator and a transition metal compound represented by the formula: ##STR1## Wherein R1 and R2 are independently hydrogen or a group having up to 100 carbon atoms, Cp1 is a bulky ligand; Cp2 is a bulky ligand or a heteroatom optionally bound to a C1 to C50 hydrocarbyl group, n is the valence state of the transition metal, Tm is a Group 3 to 10 metal, and each X is independently an anionic leaving group.

Metallocene compounds having two fluorenyl ligands bridged with a single silicon or germanium atom, said atom having two substituent groups containing a total of at least four carbon atoms, are useful as catalyst components for the polymerization of olefins. Particularly, it is possible to prepare high molecular weight atactic polypropylene with improved yields with respect to the known catalysts.

A metallocene compound is provided wherein to a transition metal compound is bonded a multidentate compound wherein a substituted cycloalkadienyl ring CA1 having therein a heteroaromatic group Ra containing an oxygen, sulfur or nitrogen atom on a cycloalkadienyl ring, preferably the five-membered ring thereof, and an unsubstituted or substituted cycloalkadienyl group CA2 or --(R1)N--, --O--, --S-- or --(R1)P--, preferably CA2, more preferably a substituted cycloalkadienyl group identical with CA1 are bonded through a divalent linking group. The metallocene compound is suitable as a principal ingredient of a catalyst for the polymerization of olefins, particularly achieving a very high effect in making the molecular weight of a polypropylene higher.

A number of process steps are provided that can be combined to produce bridged cyclopentadienyl-fluorenyl metallocenes. The process steps include production of a cyclopentadiene compound from dicyclopentadiene; production and recovery of a fulvene compound using the cyclopentadiene compound; production of a raw metallocene product using the fulvene compound; and recovery of the pure metallocene from the raw product.

A process for obtaining silicon-bridged metallocene compounds comprising the following steps: a) reacting, at a temperature of between −10° C. and 70° C., the starting ligand with about 2 molar equivalents of an alkylating agent;b) after the reaction has been completed, adding at least 2 molar equivalents of an alkylating agent that can be also different from the first one; andc) reacting, at a temperature of between −10° C. and 70° C., the product obtained from step b) with at least 1 molar equivalent of a compound of formula ML's, wherein M is a transition metal; s is an integer corresponding to the oxidation state of the metal; and L' is an halogen atom selected from chlorine, bromine and iodine.

This invention relates to processes for the production of organometallic compounds represented by the formula M(L)3 wherein M is a Group VIII metal, e.g., ruthenium, and L is the same or different and represents a substituted or unsubstituted amidinato group or a substituted or unsubstituted amidinato-like group, which process comprises (i) reacting a substituted or unsubstituted metal source compound, e.g., ruthenium (II) compound, with a substituted or unsubstituted amidinate or amidinate-like compound in the presence of a solvent and under reaction conditions sufficient to produce a reaction mixture comprising said organometallic compound, e.g., ruthenium (III) compound, and (ii) separating said organometallic compound from said reaction mixture. The organometallic compounds are useful in semiconductor applications as chemical vapor or atomic layer deposition precursors for film depositions.

A method for preparing fuel components from crude tall oil. Feedstock containing tall oil including unsaturated fatty acids is introduced to a catalytic hydrodeoxygenation to convert unsaturated fatty acids, rosin acids and sterols to fuel components. Crude tall oil is purified in a purification by washing the crude tall oil with washing liquid and separating the purified crude tall oil from the washing liquid. The purified crude tall oil is introduced directly to the catalytic hydrodeoxygenation as a purified crude tall oil feedstock. An additional feedstock may be supplied to the catalytic hydrodeoxygenation.

Device for forming, on a nanowire made of a semiconductor, an alloy of this semiconductor with a metal or metalloid by bringing this nanowire into contact with electrically conductive metal or metalloid probes and Joule heating the nanowire at the points of contact with the probes so as to form an alloy such as a silicide. Application to the production of controlled-channel-length metal-silicide transistors.

The present invention relates to 1,4-diethynylbenzene derivatives having substituents in the 2,3-position (cf. formula I, Claims), to the use thereof for high-frequency components, to liquid-crystalline media comprising the compounds, and to high-frequency components, in particular antennae, especially for the gigahertz range, comprising these media. The liquid-crystalline media serve, for example, for the phase shifting of microwaves for tuneable ‘phased-array’ antennae.

Methods of increasing the solubility of a base in supercritical carbon dioxide include forming a complex of a Lewis acid and the base, and dissolving the complex in supercritical carbon dioxide. The Lewis acid is soluble in supercritical carbon dioxide, and the base is substantially insoluble in supercritical carbon dioxide. Methods for increasing the solubility of water in supercritical carbon dioxide include dissolving an acid or a base in supercritical carbon dioxide to form a solution and dissolving water in the solution. The acid or the base is formulated to interact with water to solubilize the water in the supercritical carbon dioxide. Some compositions include supercritical carbon dioxide, a hydrolysable metallic compound, and at least one of an acid and a base. Some compositions include an alkoxide and at least one of an acid and a base.

A method for isolating 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD) solids from an isolated feed slurry formed in a TMCD process comprising TMCD, a liquid phase, and impurities by (a) treating the isolated feed slurry in a product isolation zone to produce an isolated TMCD product wet cake, a mother liquor, and impurities; wherein the product isolation zone can comprise at least one rotary pressure drum filter.

The present invention relates to processes for preparing 3-methylsulfonylpropionitrile. The processes provide a good yield and a good purity of the final product and provide a controllable reaction. The present invention also relates to a crystalline form of 3-methylsulfonylpropionitrile having X-ray diffraction peaks at 13.9±0.1, 19.2±0.1, 20.0±0.1, 22.5±0.1, 23.2±0.1, 25.7±0.1, 28.1±0.1, 29.9±0.1, and 30.6±0.1 degrees 2θ, and wherein the most intense peak is the peak at 13.9±0.1 degrees 2θ.

A carbonylation process for making acetic acid using a metallic co-catalyst composition, effective as a rhodium stabilizer and/or rate promoter, at molar ratios of metal/rhodium of about 0.5 to 40. The process includes reacting methanol with carbon monoxide in the presence of a rhodium-based catalytic metal complex with about 1 to 20 weight percent methyl iodide, less than about 8 weight % water and about 0.5 to about 30 weight percent methyl acetate. The crude acetic acid is flashed and further purified.

A process to prepared bridged bis(indenyl)ligands, comprising the step of reacting a 2-indenylpinacolyl borane compound with a bromosubstituted compound in the presence of a Pd catalyst and a base to form the corresponding bridged bis(indenyl) ligand. The process may further comprise the step of reacting a 2-bromo indene compound with pinacolborane in the presence of a Pd catalyst and a base to form the corresponding 2-indenylpinacolylborane compound. These bridged bis(indenyl)ligands may suitably be used in the preparation of metallocene complexes, such as 2,2'-bis(2-indenyl)biphenyl ZrCl2 and 1,2-bis(2-indenyl)benzene ZrCl2. These metallocene complexes may be used for the polymerization, optionally in the presence of a cocatalyst, of one or more α-olefins, preferably for the polymerization of ethylene.