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Depressing charge recombination in hybrid perovskites by introducing a dynamic electron/energy relay couple towards enhanced photocatalytic hydrogen production

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03864A, Paper
Jiaqi Liu, Yuxin Xie, Yongxin Jiao, Hefeng Zhang, Junhui Wang, Yuying Gao, Xu Zong
Extraordinary photocatalytic hydrogen evolution is achieved on methylammonium lead iodide perovskites by introducing a dynamic Cu/(CuI2)− couple as the electron/energy relay station and the Pt co-catalyst as the charge/energy-releasing promotor.
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Hydrogel electrolytes with an electron/ion dual regulation mechanism for highly reversible flexible zinc batteries

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Energy Environ. Sci., 2024, 17,8570-8581
DOI: 10.1039/D4EE03067B, Paper
Fusheng Luo, Song Yang, Qing Wu, Yue Li, Jinlong Zhang, Yanhui Zhang, Jun Huang, Haibo Xie, Yiwang Chen
The unique electron/ion dual regulation mechanism is established in the well-designed hydrogel electrolyte by integrating polyacrylamide network and carboxylated multi-walled carbon nanotubes for high performance flexible ZIBs.
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Naphtho[1,2-c:5,6-c']bis([1,2,3]thiadiazole) enables the design of efficient halogen-free polymer donors and fabrication of organic solar cells with >19% efficiency

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Energy Environ. Sci., 2024, 17,8593-8608
DOI: 10.1039/D4EE02414A, Paper
Tao Jia, Yongmin Luo, Yulong Hai, Tao Lin, Xudong Qin, Ruijie Ma, Kezhou Fan, Aleksandr A. Sergeev, Top Archie Dela Peña, Yao Li, Mingjie Li, Kam Sing Wong, Gang Li, Jiaying Wu, Shengjian Liu, Fei Huang
Fusion and isomerization strategies are used to develop an electron-withdrawing motif naphtho[1,2-d:5,6-d']bis([1,2,3]thiadiazole) (iNT) and a halogen-free polymer donor achieving an efficiency of 19.1%.
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A techno-economic study of photovoltaic-solid oxide electrolysis cell coupled magnesium hydride-based hydrogen storage and transportation toward large-scale applications of green hydrogen

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Published On ::

Energy Environ. Sci., 2024, 17,8429-8456
DOI: 10.1039/D4EE04224G, Analysis
Xusheng Wang, Longfei Shao, Shouyi Hu, Zi Li, Hangzuo Guo, Jiaqi Zhang, Yingyan Zhao, Xi Lin, Binjian Nie, Zhigang Hu, Jianxin Zou
Integrating PV-SOEC for hydrogen production with MgH2-based storage and transportation holds significant potential in advancing the hydrogen supply chain.
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Weakened hydrogen bond connectivity promotes interfacial mass transfer for industrial level scalable biomass electrooxidation

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Energy Environ. Sci., 2024, 17,8801-8809
DOI: 10.1039/D4EE03482A, Paper
Zhaohui Yang, Lan Chen, Yijun Yin, Chenyang Wei, Zhimin Xue, Tiancheng Mu
The inhomogeneous valence distribution due to in the intrinsic electric field of a material can weaken the interfacial H-bonding connectivity under the bias potential, which promotes the mass transfer of HMF during the HMF electrooxidation reaction.
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Achieving high performance triboelectric nanogenerators simultaneously with high-voltage and high-charge energy cycle

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Energy Environ. Sci., 2024, 17,8734-8744
DOI: 10.1039/D4EE02447H, Paper
Open Access
Yikui Gao, Jiaqi Liu, Linglin Zhou, Lixia He, Di Liu, Peiyuan Yang, Bingzhe Jin, Zhong Lin Wang, Jie Wang
This work achieves a high-voltage and high-charge energy cycle for TENGs, as well as lossless energy transmission between TENGs and PMCs.
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An octave box inspired energy regularization triboelectric nanogenerator for highly efficient wave energy harvesting

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Energy Environ. Sci., 2024, 17,8829-8837
DOI: 10.1039/D4EE02969K, Paper
Yuanchao Ren, Zizhuo Wang, Jie Chen, Fei Wu, Hengyu Guo
Inspired by the mechanical transmission structure of octave boxes, this work proposes a novel energy regularization triboelectric nanogenerator to effectively convert chaotic wave energy into stable electric output.
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Anti-Freezing Hydrogel Electrolyte with Regulated Hydrogen Bond Network Enables High-Rate and Long Cycling Zinc Batteries

By pubs.rsc.org
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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02772H, Paper
Shaojie Guo, Mengyu Yan, DongMing Xu, Pan He, Kaijian Yan, Jiexin Zhu, Yongkun Yu, Zeya Peng, Yanzhu Luo, Feifei Cao
Zinc-based batteries, utilizing hydrogel electrolytes, present significant promise as power sources for next-generation flexible devices due to their stretchable nature and enhanced safety features. Nonetheless, the current hydrogel electrolytes require...
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Mass transport effects in gas-phase selective hydrogenation of 1,3-butadiene over supported Pd

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00039K, Paper
Open Access
Oscar E. Brandt Corstius, M. Kikkert, S. T. Roberts, E. J. Doskocil, J. E. S. van der Hoeven, P. E. de Jongh
The performance of selective hydrogenation reactions is affected by mass transfer limitations, induced by higher local metal loading and larger catalyst grain size.
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Palladium particle-catalyzed selective butadiene hydrogenation: effect of covalent organic framework modification

By pubs.rsc.org
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React. Chem. Eng., 2024, 9,950-958
DOI: 10.1039/D3RE00606A, Paper
Xianming Li, Yi Wang, Qiao Yuan, Xintai Chen, Xiaoling Mou, Xiangen Song, Li Yan, Ronghe Lin, Yunjie Ding
Deposition of a covalent organic framework on palladium nanoparticles induces geometric and electronic effects on the metal species and improves their selective performance in 1,3-butadiene hydrogenation.
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Machine-learning assisted optimisation during heterogeneous photocatalytic degradation utilising a static mixer under continuous flow

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React. Chem. Eng., 2024, 9,872-882
DOI: 10.1039/D3RE00570D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas M. Kohl, Yan Zuo, Benjamin W. Muir, Christian H. Hornung, Anastasios Polyzos, Yutong Zhu, Xingdong Wang, David L. J. Alexander
Machine-learning assisted optimisation of a continuous photodegradation reaction, using a TiO2 coated catalytic static mixer successfully accounting for catalyst degradation.
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From microkinetic model to process: understanding the role of the boron nitride surface and gas phase chemistry in the oxidative dehydrogenation of propane

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React. Chem. Eng., 2024, 9,795-802
DOI: 10.1039/D3RE00600J, Paper
Unni Kurumbail, William P. McDermott, Edgard A. Lebrón-Rodríguez, Ive Hermans
In the oxidative dehydrogenation of propane over boron nitride, propylene selectivity is lost due to unselective gas-phase chemistry.
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Biomass-based graphene aerogel for the removal of emerging pollutants from wastewater

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React. Chem. Eng., 2024, 9,753-776
DOI: 10.1039/D3RE00526G, Review Article
Vijayendra Kumar Tripathi, Manish Shrivastava, Jaya Dwivedi, Raju Kumar Gupta, Lokesh Kumar Jangir, Kumud Malika Tripathi
This review article provides a detailed overview of the synthesis techniques of biomass-based graphene aerogels and highlights the influence of fabrication parameters on the performance of the resulting aerogels for wastewater treatment applications.
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At-line monitoring of hydrogen peroxide released from its photocatalytic and continuous synthesis

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React. Chem. Eng., 2024, 9,777-781
DOI: 10.1039/D3RE00659J, Communication
Open Access
Anders Ø. Tjell, Lars-Erik Meyer, Barbara Jud, Selin Kara, Torsten Mayr
Photocatalytic synthesis of H2O2 in a continuous operation set-up using nitrogen-doped carbon nanodots (N-CNDs) and simultaneous determination of generated H2O2.
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Digital Pareto-front mapping of homogeneous catalytic reactions

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React. Chem. Eng., 2024, 9,787-794
DOI: 10.1039/D3RE00673E, Communication
Open Access
Negin Orouji, Jeffrey A. Bennett, Sina Sadeghi, Milad Abolhasani
We present a digital framework for rapid multi-objective reaction space exploration and optimization of homogeneous catalytic reactions through autonomous experimentation and Bayesian optimization.
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Selective hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan over Ni–Ga intermetallic catalysts and its kinetic studies

By pubs.rsc.org
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00129J, Paper
Weixiao Sun, Fuzeyu Zhong, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang
5-Hydroxymethylfurfural (HMF) has been listed as the “TOP 14” most important biomass-derived platform molecules, which can be converted into 2,5-bis(hydroxymethyl)furan (BHF) via selective hydrogenation of the carbonyl group on HMF.
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Novel TPMS carbon-based monolithic catalysts by three-dimensional printing for enhancement of nitrobenzene hydrogenation reaction

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00049H, Paper
Haoyang Wang, Haoran Tian, Qi Zhang, Li Zhang
Preparation of periodic curved surface, structured, carbon-based catalysts using a 3D printing method achieved good results in the hydrogenation of nitrobenzene to aniline in a packed-bed micro-reactor.
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Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
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Hydrogenolysis of furfuryl alcohol over CuCeMgAl mixed metal oxide catalysts derived from layered double hydroxides

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00070F, Paper
Zhihui Wang, Wenbo Li, Xinyao Fu, Chen Zhang, Wei Zhang, Long Huang, Cuiqing Li
LDH-derived CuCeMgAl mixed metal oxide catalysts were synthesized. Ce addition promoted Cu dispersion and improved catalyst basicity, resulting in high activity in furfuryl alcohol hydrogenolysis and high selectivity toward 1,2-pentanediol.
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Generation of nitrogen by means of electrochemical oxygen depletion

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00104D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dominik Sachse, Basil Noha Chelachottil, Andreas Glüsen, Martin Müller, Uwe Rau, Ralf Peters
Electrochemical oxygen reduction enables a high depletion of the oxygen content with very high Faraday efficiency at the same time.
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Create SECI-like entity for efficient long-term procurement of green hydrogen: TERI

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 19:35:48 +0530

The policy think tank also recommends creating an SPV for each industrial segment for development of pilot plants


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Summer–autumn tea promotes adipocyte browning and thermogenesis in association with gut microbiota regulation in high-fat diet-fed mice

By pubs.rsc.org
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Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03826F, Paper
Chengcheng Yang, Luyao Liu, Yao Du, Lu Zhao, Lu Liu, Xingbin Yang, Yan Zhao
This study revealed for the first time the anti-obesity effect of summer–autumn tea aqueous extract (SATE) and its underlying mechanism.
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Aspartate restrains thermogenesis by inhibiting the AMPK pathway in adipose tissues

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Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03614J, Paper
Shengjun Dong, Mengxin Jiang, Qinglei Sun, Junqing Xu, Lei Zhang, Lei Han, Yan-na Li, Zhengtong Zhou, Yingjiang Xu
We evaluated the potential effects of aspartate on brown adipose tissue function.
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Impact of pH on the fabrication of egg white reinforced soy protein composite microgels for gastrointestinal delivery purposes

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Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03997A, Paper
Feng Liu, Yi Liu, Suyun Zhang, Gang Liu, Christos Ritzoulis, Yue Zhang
Protein molecules such as soy protein isolate (SPI) and egg white (EW) are highly promising materials for developing hydrogels (especially micro/nanogels) for the encapsulation, protection and controlled release of bioactive substances.
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Aronia melanocarpa extract extends the lifespan and health-span of Caenorhabditis elegans via mitogen-activated protein kinase 1

By pubs.rsc.org
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Food Funct., 2024, 15,11020-11035
DOI: 10.1039/D4FO02479F, Paper
Huan Zhang, Zhigang Zhu, Wenjing Wei, Zekun Liu, Huiji Zhou, Yueling Gong, Xinlei Yan, Jun Du, Houkai Li, Liang Chen, Lili Sheng
Aronia melanocarpa (AM) was shown to promote the lifespan and health-span of C. elegans via the PMK-1 pathway, highlighting the potential of AM as a dietary supplement for delaying aging.
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Donald Trump names Elon Musk, Vivek Ramaswamy to lead newly formed Department of Government Efficiency (DOGE)

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 07:47:06 +0530

The U.S. President elect said their work would conclude by July 4, 2026, adding that a smaller and more efficient government would be a "gift" to the country on the 250th anniversary of the signing of the Declaration of Independence.


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Hydrogenation of sulfoxides to sulfides mediated by incomplete cubane-type Mo3S4 clusters: synthetic applications and mechanistic insights

By pubs.rsc.org
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00987H, Paper
Juanjo Mateu-Campos, María Gutiérrez-Blanco, Eva Guillamón, Vicent S. Safont, Rosa Llusar
Air-stable diamino Mo3S4 clusters are efficient catalysts for the late-stage functionalization of drugs and other valuable products containing sulfide moieties.
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Enhanced catalytic performance of single-atom Cu on Mo2C toward CO2/CO hydrogenation to methanol: a first-principles study

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00703D, Paper
Open Access
Anna Vidal-López, Estefanía Díaz López, Aleix Comas-Vives
First-principles calculations show the crucial role of the Cu/Mo2COx interface in enabling low-energy pathways for CO2/CO hydrogenation to methanol via successive heterolytic H2 cleavages.
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Accelerated design of nickel-cobalt based catalysts for CO2 hydrogenation with human-in-the-loop active machine learning

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6307-6320
DOI: 10.1039/D4CY00873A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yasemen Kuddusi, Maarten R. Dobbelaere, Kevin M. Van Geem, Andreas Züttel
The effect of catalyst synthesis and reaction conditions on catalytic activity were accurately predicted with an interpretable data-driven strategy. The method is demonstrated for CO2 methanation and is extendable to other catalytic processes.
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Sulfonic acid-modified MOFs as heterogeneous bifunctional catalysts for ethylene oligomerization at room temperature without cocatalysts

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Catal. Sci. Technol., 2024, 14,6270-6277
DOI: 10.1039/D4CY00502C, Paper
Yao Ning, Yuqi Yang, Dongming Shan, Shuxing Mei, Yibai Yan, Linjie Ding, Ying Zhang
Ethylene oligomerization plays an important role in industrial production.
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Multiscale modelling of CO2 hydrogenation of TiO2-supported Ni8 clusters: on the influence of anatase and rutile polymorphs

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6393-6410
DOI: 10.1039/D4CY00586D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lulu Chen, Ying-Ying Ye, Rozemarijn D. E. Krösschell, Emiel J. M. Hensen, Ivo A. W. Filot
The selection of TiO2 phase, whether anatase or rutile, for supporting small Ni clusters significantly influences the activity and selectivity in CO2 hydrogenation to methane.
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Hydrolysis of ammonia borane for green hydrogen production over a Pd/C3N4 nanocatalyst synthesized by electron beam irradiation

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6338-6350
DOI: 10.1039/D4CY00761A, Paper
Manish Shingole, Seemita Banerjee, Priyanka Ruz, Asheesh Kumar, Pratibha Sharma, V. Sudarsan
Room temperature hydrolysis of ammonia borane in presence of electron beam irradiated Pd-C3N4 catalyst.
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Photocatalytic dehydrogenative C(sp2)–P coupling reaction between dibenzo[b,f][1,4]oxazepanes and phosphine oxides

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication
Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
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The effect of separation distance on hydrogen spillover in Os promoted Co@HCS catalysts

By pubs.rsc.org
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00758A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tshepo Molefe, Roy Peter Forbes, Neil John Coville
Decreasing the carbon shell thickness increased the reducibility of Co3O4. The reducibility of Co3O4 was further achieved by adding an Os promoter outside of the sphere showing that H spillover was favoured over H2 diffusion/Co reduction by carbon.
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Identification of Ni3Fe alloy as a candidate catalyst for quinoline selective hydrogenation with computations

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01076K, Paper
Zhaochun He, Yonghua Liu, Tao Wang
We computationally identified Ni3Fe as a promising catalyst for the quinoline (QL) selective hydrogenation to 1,2,3,4-tetrahydroquinoline (py-THQL) using density functional theory calculations and microkinetic modeling.
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One-pot synthesis of 1,4-butanediol via the deep hydrogenation of maleic anhydride over Cu–xMo/SiO2 catalysts

By pubs.rsc.org
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01006J, Paper
Kai Cui, Jiaming Yang, Yuli Jing, Junwen Chen, Chen Zhao, Peng Wu, Xiaohong Li
A Cu–0.03Mo/SiO2 catalyst realized the one-pot deep hydrogenation of maleic anhydride to 1,4-butanediol at 200 °C, under 5 MPa of hydrogen pressure with 100% conversion and 88.3% selectivity, one of the highest values for this target reaction.
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Investigation on heterogeneous Rh Catalysts for the Hydroformylation of 1,3-Butadiene to adipic aldehyde

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00745J, Paper
Lijin Gan, Zekun Liu, Lei Feng, Yi Duan, Guangyuan Xu, Si Chen, Huan Yan
Adipic aldehyde, as a precursor for polymers, has significant industrial applications, where the hydroformylation of 1,3-butadiene is a promising routine to fabricate adipic aldehyde. However, the heterogeneous hydroformylation of 1,3-butadiene...
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The O2-stable [FeFe]-hydrogenase CbA5H reveals high resilience against organic solvents

By pubs.rsc.org
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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01018C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Martin Gerbaulet, Anja Hemschemeier, Thomas Happe
CbA5H from Clostridium beijerinckii is an oxygen-stable [FeFe]-hydrogenase. Here we report that CbA5H is stable in high concentrations of acetone and acetonitrile and also withstands intermediate concentrations of DMSO, ethanol and methanol.
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1D Zn(II)/2D Cu(I) halogen pyridyl coordination polymers. Band gap engineering by DFT for predicting more efficient photocatalysts in water treatment

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6573-6583
DOI: 10.1039/D4CY00969J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
The study utilizes density functional theory to enhance the design and efficiency of coordination polymers for sustainable photocatalytic applications.
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Heterogeneous oxidative upcycling of polystyrene plastics to benzoic acid under air conditions

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6584-6591
DOI: 10.1039/D4CY00970C, Paper
Chengyang Sun, Yong Guo, Xiaohui Liu, Yanqin Wang
A heterogeneous oxidative upcycling strategy converting polystyrene (PS) waste into benzoic acid.
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Switching of selectivity from benzaldehyde to benzoic acid using MIL-100(V) as a heterogeneous catalyst in aerobic oxidation of benzyl alcohol

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6524-6536
DOI: 10.1039/D4CY00832D, Paper
Open Access
Duygu Hacıefendioğlu, Ali Tuncel
MIL-100(V) used as a heterogeneous catalyst for tunable selective oxidation of benzyl alcohol to benzaldehyde or benzoic acid by changing only the reaction temperature.
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Synergistic promotion of oxygen vacancy and Lewis acidity of Nb2O5 on the preferential hydroxymethyl hydrogenolysis of 5-hydroxymethylfurfural catalyzed by single atom Pt

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, 14,6550-6560
DOI: 10.1039/D4CY00559G, Paper
Ting-Hao Liu, Shuai Fu, Jin-Tao Gou, Yin-Sheng Zhang, Chang-Wei Hu, Hua-Qing Yang
Over Pt1/Nb2O5, oxygen vacancy increases the catalytic activity, while the strong Lewis acidity of Nb2O5 selectively promotes the hydrogenolysis of the –CH2OH group rather than the hydrogenation of the –CHO group.
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In situ preparation and performance of iron-based electro-magnetic synergistic electrochemical nitrogen fixation catalysts

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Catal. Sci. Technol., 2024, 14,6592-6599
DOI: 10.1039/D4CY01008F, Paper
Kaidi Chen, Run Deng, Chen Zhao, Qikun Zhang
An iron-based catalyst was prepared in situ in FeSO4 solution by electrochemical technology to catalyze the reduction of N2 to NH3. It was found that the applied magnetic field can significantly increase the current density.
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Heteroatom-doped carbon nanomaterials as potential heterogeneous Fenton reaction catalysts

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6662-6669
DOI: 10.1039/D4CY00248B, Paper
Haobin Tan, Xiuli Hou, Chen Zhou, Shengbo Wang, Qiang Liu, Zhenhui Xu, Peng Zhang
A volcano relationship between the catalytic activity and the adsorption energies of reaction intermediates was found for the H2O2 dissociation on heteroatom-doped carbon nanomaterials.
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Boron–pyridine nitrogen cooperative catalytic conversion of carbon dioxide and epoxides to cyclic carbonates

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Published On ::

Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper
Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO2 with epoxides.
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Correction: 1D Zn(II)/2D Cu(I) halogen pyridyl coordination polymers. Band gap engineering by DFT for predicting more efficient photocatalysts in water treatment

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Catal. Sci. Technol., 2024, 14,6720-6720
DOI: 10.1039/D4CY90084G, Correction
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Andrea García-Hernán, Fernando Aguilar-Galindo, Oscar Castillo, Pilar Amo-Ochoa
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Phenol Hydroxyl-Modified Imine-Based Covalent organic framework for enhanced solar-driven generation of H2O2 via Hydrogen Bonds

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Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01096E, Paper
Lang Chen, Song Qin, Jiahui Hang, Bo Chen, Jinyang Kang, yang zhao, Shan-Yong Chen, Yongdong Jin, Hongjian Yan, Yuanhua Wang, Xia Chuanqin
Photosynthesis of H2O2 have been considered an eco-friendly strategy. However, the concentration of H2O2 in reported studies is far from industrial requirement. Herein, we present a strategy by employing phenolic...
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Material design of biodegradable primary batteries: boosting operating voltage by substituting the hydrogen evolution reaction at the cathode

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Nanoscale, 2024, 16,20027-20036
DOI: 10.1039/D4NR03321C, Minireview
Shunsuke Yamada, Takashi Honda
This review highlights recent progress in increasing the operating voltage of biodegradable primary batteries by suppressing or substituting the hydrogen evolution reaction at the cathode with alternative redox reaction.
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Nanoscopic visualization of microgel-immobilized cytochrome P450 enzymes and their local activity

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Nanoscale, 2024, 16,20194-20201
DOI: 10.1039/D4NR03435J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lukas Schubert, Chiara Nenninger, Maximilian Nöth, Thomke Belthle, Robert Dirk de Lange, Andrij Pich, Ulrich Schwaneberg, Dominik Wöll
The distribution and local catalytic activity of Cytochrome P450 enzymes immobilized in microgels by electrostatic interaction has been determined with a combination of in situ super-resolution fluorescence microscopy experiments.
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Active site engineering of intermetallic nanoparticles by the vapour–solid synthesis: carbon black supported nickel tellurides for hydrogen evolution

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Nanoscale, 2024, 16,20168-20181
DOI: 10.1039/D4NR03397C, Paper
Open Access
Daniel Garstenauer, Patrick Guggenberger, Ondřej Zobač, Franz Jirsa, Klaus W. Richter
The intermetallic phases Ni3Te2, NiTe, NiTe2−x & NiTe2 were synthesized as carbon-black supported nanoparticles using the vapour–solid synthesis approach and were characterized for their performance in electrocatalytic hydrogen evolution.
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