oge Emulsifying mechanisms of phospholipids in high-pressure homogenization of perfluorocarbon nanoemulsions By pubs.rsc.org Published On :: Soft Matter, 2024, 20,8373-8384DOI: 10.1039/D4SM00828F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Larissa J. Lubitz, Harden Rieger, Gero LeneweitAn optimized PFC/W emulsion contains 1 mM lipid per 1% (v/v) dispersed phase for an emulsifying monolayer; higher ratios result in triple layers. Low viscosity ratios ηD/ηC ≤ 5 and low PFC volume fractions lead to smaller monodisperse droplets.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge pH and glucose dual-responsive phenylboronic acid hydrogels for smart insulin delivery By pubs.rsc.org Published On :: Soft Matter, 2024, Advance ArticleDOI: 10.1039/D4SM01004C, PaperKeke Yang, Hou Bo, Dewei Ma, Mingwei Peng, Qinglong Liu, Ziwen Heng, Zhongwei Gu, Xuhan Liu, Siyuan ChenPhenylboronic acid (PBA) is a widely exploited glucose-sensitive element for constructing glucose-responsive hydrogels to enable smart insulin delivery.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Hydrogel-based 3D fabrication of multiple replicas with varying sizes and materials from a single template via iterative shrinking By pubs.rsc.org Published On :: Soft Matter, 2024, Accepted ManuscriptDOI: 10.1039/D4SM00835A, PaperEunseok Heo, Hye Been Koo, Jun Chang Yang, In Cho, Hyun-Hee Lee, Yong-Jin Yoon, Steve Park, Jae-Byum Chang3D printing technologies have been widely used for the rapid prototyping of 3D structures, but their application in a broader context has been hampered by their low printing throughput. For...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Mechanical properties soft hydrogels: assessment by scanning ion-conductance microscopy and atomic force microscopy By pubs.rsc.org Published On :: Soft Matter, 2024, Accepted ManuscriptDOI: 10.1039/D4SM00966E, PaperTatiana Tikhonova, Yuri M. Efremov, Vasilii Kolmogorov, Aleksei Iakovlev, Nikolay Sysoev, Peter S. Timashev, Victor Fadeev, Alexander Tivtikyan, Sergey Salikhov, Petr Gorelkin, Yuri Korchev, Alexandr Erofeev, Evgeny ShirshinThe growing interest in biomimetic hydrogels is due to their successful applications in tissue engineering, 3D cell culturing and drug delivery. Major characteristics of hydrogels include swelling, porosity, degradation rate,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Reversible pH-responsive supramolecular aggregates from viologen based amphiphiles – A molecular design perspective By pubs.rsc.org Published On :: Soft Matter, 2024, Accepted ManuscriptDOI: 10.1039/D4SM00695J, PaperRedhills L. Narendran, Archita PatnaikpH responsive self-assembled supramolecular systems in water hold tremendous promise spanning across the various realms of science and technology. Herein, we report the design and synthesis of benzyl viologen (BV)...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Usability and Security; Better Together By 24ways.org Published On :: Sun, 22 Dec 2019 12:00:00 +0000 Divya Sasidharan calls into question the trade-offs often made between security and usability. Does a secure interface by necessity need to be hard to use? Or is it the choice we make based on years of habit? Snow has fallen, snow on snow. Security is often synonymous with poor usability. We assume that in order for something to be secure, it needs to by default appear impenetrable to disincentivize potential bad actors. While this premise is true in many instances like in the security of a bank, it relies on a fundamental assumption: that there is no room for choice. With the option to choose, a user almost inevitably picks a more usable system or adapts how they interact with it regardless of how insecure it may be. In the context of the web, passwords are a prime example of such behavior. Though passwords were implemented as a way to drastically reduce the risk of attack, they proved to be marginally effective. In the name of convenience, complex, more secure passwords were shirked in favor of easy to remember ones, and passwords were liberally reused across accounts. This example clearly illustrates that usability and security are not mutually exclusive. Rather, security depends on usability, and it is imperative to get user buy-in in order to properly secure our applications. Security and Usability; a tale of broken trust At its core, security is about fostering trust. In addition to protecting user accounts from malicious attacks, security protocols provide users with the peace of mind that their accounts and personal information is safe. Ironically, that peace of mind is incumbent on users using the security protocols in the first place, which further relies on them accepting that security is needed. With the increased frequency of cyber security threats and data breaches over the last couple of years, users have grown to be less trusting of security experts and their measures. Security experts have equally become less trusting of users, and see them as the “the weakest link in the chain”. This has led to more cumbersome security practices such as mandatory 2FA and constant re-login flows which bottlenecks users from accomplishing essential tasks. Because of this break down in trust, there is a natural inclination to shortcut security altogether. Build a culture of trust not fear Building trust among users requires empowering them to believe that their individual actions have a larger impact on the security of the overall organization. If a user understands that their behavior can put critical resources of an organization at risk, they will more likely behave with security in mind. For this to work, nuance is key. Deeming that every resource needs a similarly high number of checks and balances diminishes how users perceive security and adds unnecessary bottlenecks to user workflows. In order to lay the foundation for good security, it’s worth noting that risk analysis is the bedrock of security design. Instead of blindly implementing standard security measures recommended by the experts, a better approach is to tailor security protocols to meet specific use cases and adapt as much as possible to user workflows. Here are some examples of how to do just that: Risk based authentication Risk based authentication is a powerful way to perform a holistic assessment of the threats facing an organization. Risks occur at the intersection of vulnerability and threat. A high risk account is vulnerable and faces the very real threat of a potential breach. Generally, risk based authentication is about calculating a risk score associated with accounts and determining the proper approach to securing it. It takes into account a combination of the likelihood that that risk will materialize and the impact on the organization should the risk come to pass. With this system, an organization can easily adapt access to resources depending on how critical they are to the business; for instance, internal documentation may not warrant 2FA, while accessing business and financial records may. Dynamically adaptive auth Similar to risk based auth, dynamically adaptive auth adjusts to the current situation. Security can be strengthened and slackened as warranted, depending on how risky the access point is. A user accessing an account from a trusted device in a known location may be deemed low risk and therefore not in need of extra security layers. Likewise, a user exhibiting predictive patterns of use should be granted quick and easy access to resources. The ability to adapt authentication based on the most recent security profile of a user significantly improves the experience by reducing unnecessary friction. Conclusion Historically, security failed to take the user experience into account, putting the onus of securing accounts solely on users. Considering the fate of password security, we can neither rely on users nor stringent security mechanisms to keep our accounts safe. Instead, we should aim for security measures that give users the freedom to bypass them as needed while still protecting our accounts from attack. The fate of secure systems lies in the understanding that security is a process that must constantly adapt to face the shifting landscape of user behavior and potential threats. About the author Divya is a web developer who is passionate about open source and the web. She is currently a developer experience engineer at Netlify, and believes that there is a better workflow for building and deploying sites that doesn’t require a server—ask her about the JAMstack. You will most likely find her in the sunniest spot in the room with a cup of tea in hand. More articles by Divya Full Article UX security
oge Editorial. E-commerce bogey, again By www.thehindubusinessline.com Published On :: Fri, 23 Aug 2024 20:16:42 +0530 Clarity on regulatory, policy environment needed Full Article Editorial
oge Youth from Anantapur invited for We are Together International Prize of Russia By www.thehindu.com Published On :: Tue, 12 Nov 2024 15:37:31 +0530 The prize is +awarded annually to citizens and organizations regardless of their country of residence, nationality, gender Full Article Andhra Pradesh
oge The great prime number race [electronic resource] / Roger Plymen. By darius.uleth.ca Published On :: Providence, Rhode Island : American Mathematical Society, [2020] Full Article
oge Multi-step chirality transfer and racemization kinetics of pillar [5]arenes by tuning the halogen substituents on the rims By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01799D, Research ArticleLizhi Fang, Xiaowen Guan, Yanling Shen, Dayang Zhou, Long Chen, Xiaochuan Chen, Wanhua Wu, Leyong Wang, Cheng YangHalogen-substituted pillar[5]arenes exhibited hindered hydroquinone subunit flipping, enabling enantioseparation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01382D, Research ArticleAjay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha MoorthyAn IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01698J, Research ArticleHeng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen XuThe first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01767F, Research ArticleGui-Xiang Zhou, Cheng HouThis study reveals a mechanism in which a ruthenium complex catalyst improves catalytic efficiency and lowers the energy barrier in the dehydrogenation of benzyl alcohol by dynamically switching ligand sites.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Photocatalytic arylation/alkylation of olefins/alkynes via halogen-atom transfer mediated by NHC-BH3 By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01562B, Research ArticleXinhan Li, Yao Zhong, Fengsong Tan, Yusong Fei, Xiaohan Zhao, Jianbin Xu, Baomin FanA versatile method for radical reductive cross-coupling of iodides and activated olefins under mild conditions, facilitated by NHC-BH3 through photocatalysis, was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01638F, Research ArticleAijun Zhang, Miao-Miao Li, Lei Guo, Huaixiang Yang, Jiefei Guo, Da Xu, Wei DingA highly efficient allylic radical mono- and diphosphinylation of alkenes with secondary phosphine oxides is developed, via visible-light-induced cobaloxime catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge 18F-labelling of nitrogen-containing aryl boronates – anti-cancer drug melflufen as a case study By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6411-6417DOI: 10.1039/D4QO01594K, Research Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kevin Bajerke, Fredrik Lehmann, Gunnar Antoni, Kálmán J. SzabóThis study addresses the 18F-labelling of nitrogen-containing arenes via copper-mediated radiofluorination (CMRF). In this case study, derivatives/fragments of the anti-cancer drug melflufen were targeted.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Charge Transfer Complex Enabled Mechanochemical Synthesis of Chalcogenoacetylenes via Alkynyl Radicals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01827C, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fang Tan, Chang-Zhen Fang, Bing-Sheng Qiu, He Sheng, Yong-Liang Tu, Xiang-Yu ChenMechanochemistry has become an appealing strategy to enable numerous organic transformations. While significant advances have been achieved, the radical coupling reaction under mechanochemical conditions is still in its infancy. In...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Nickel-catalyzed reductive 1,2-alkylarylation of alkenes via a 1,5-hydrogen atom transfer (HAT) cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01875C, Research ArticleXi Chen, Qiang Wang, Xiao-Ping Gong, Rui-Qiang Jiao, Xue-Yuan Liu, Yong-Min LiangA nickel-catalyzed 1,2-alkylarylation of alkenes has been developed, leveraging amidyl radical-triggered 1,5-HAT with electrophiles as functionalizing reagents.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Influence of hydrogen bonds and π-π stacking on the self-assembly of aryldipyrrolidones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01577K, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pedro Ximenis, Llorenç Rubert, Heike Ehmann, Bartolome SoberatsWe report on the self-assembly behaviour in solution and solid-state of two newly designed bisdendronized aryldipyrrolidones (BDP and NDP) dyes with two free N-H at the lactam positions. Interestingly, while...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01641F, Research ArticlePeng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai LiAn FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35163-35171DOI: 10.1039/D4RA06595F, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng HuangGraphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Synthesis of F127-GA@ZnO nanogel as a cisplatin drug delivery pH-sensitive system By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35005-35020DOI: 10.1039/D4RA06514J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nguyen Ngoc Son, Vu Minh Thanh, Nguyen Thi HuongIn this study, a novel drug delivery system based on zinc oxide nanoparticles (ZnO NPs) was developed for the enhanced delivery of cisplatin (CPT) to improve cancer treatment.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Enhanced surface functionalization of 2D molybdenum/tin chalcogenide nanostructures for effective SERS detection of Escherichia coli By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35021-35034DOI: 10.1039/D4RA05315J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zainab Ishfaq, Layla A. Almutairi, M. Yasir Ali, Salhah Hamed Alrefaee, Mohamed Abdelsabour Fahmy, Elsammani Ali Shokralla, Lamiaa G. Alharbe, Adnan Ali, Arslan Ashfaq, A. R. Abd-ElwahedThis study enhances MoS2/SnS2 nanoparticles for SERS, functionalizing them with L-cysteine. Successful detection of E. coli demonstrates their potential as cost-effective SERS substrates for real-world applications.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Correction: Sustainable polymeric adsorbents for adsorption-based water remediation and pathogen deactivation: a review By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35104-35104DOI: 10.1039/D4RA90129K, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Huda Alkhaldi, Sarah Alharthi, Salha Alharthi, Hind A. AlGhamdi, Yasmeen M. AlZahrani, Safwat A. Mahmoud, Lamiaa Galal Amin, Nora Hamad Al-Shaalan, Waleed E. Boraie, Mohamed S. Attia, Samera Ali Al-Gahtany, Nadiah Aldaleeli, Mohamed Mohamady Ghobashy, A. I. Sharshir, Mohamed Madani, Reem Darwesh, Sana F. AbazaThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Macroporous chitosan/alginate hydrogels crosslinked with genipin accumulate and retain glioblastoma cancer cells By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35286-35304DOI: 10.1039/D4RA06197G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lauriane Parès, Sahar Naasri, Lisa Delattre, Hélène Therriault, Benoît Liberelle, Gregory De Crescenzo, Marc-Antoine Lauzon, Nathalie Faucheux, Benoit Paquette, Nick VirgilioThis work demonstrates how macroporous hydrogels can be prepared with porous polylactide molds, and homogeneous solutions of sodium alginate and chitosan crosslinked with genipin, in order to accumulate glioblastoma cancer cells.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Advanced oxidative degradation of monoethanolamine in water using ultraviolet light and hydrogen peroxide By pubs.rsc.org Published On :: RSC Adv., 2024, 14,33223-33232DOI: 10.1039/D4RA05590J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Atif Khan, Saima Yasin, Hamayoun Mahmood, Shabana Afzal, Tanveer IqbalDevelopment of an eco-friendly and commercially feasible method for monoethanolamine (MEA) degradation in aqueous phase using ultraviolet/hydrogen peroxide (UV/H2O2) advanced oxidation process (AOP).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Advances in quinoxaline derivatives: synthetic routes and antiviral efficacy against respiratory pathogens By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35400-35423DOI: 10.1039/D4RA04292A, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Fateme Dehnavi, Malihe Akhavan, Ahmadreza Bekhradnia3D lung visualization showing COVID-19 infection areas alongside respiratory pathogens. The antiviral drug structure and comparison of healthy vs. infected lungs demonstrate how the drug could restore lung health.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Zeolitic imidazolate framework-67 in chitosan-grafted hydrogel as an effective catalyst for peroxymonosulfate activation to degrade antibiotics and dyes By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35628-35637DOI: 10.1039/D4RA06537A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Atipong Nachaichot, Kunlarat Phonlakan, Supinya Nijpanich, Soraya Pornsuwan, Surangkhana BudsombatZeolitic imidazolate framework-67 (ZIF-67) was synthesized in situ in the hydrogel of chitosan-grafted poly(acrylic acid) (chitosan-g-PAA) to activate peroxymonosulfate (PMS) and degrade tetracycline (TC).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge LCST/UCST behavior of polysaccharides for hydrogel fabrication By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35754-35768DOI: 10.1039/D4RA06240J, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Seo Hyung Moon, Sol Ji Park, Ye Won Lee, Yun Jung YangThis review discusses the classification, mechanisms, characteristics, and recent advancements of thermo-responsive polysaccharides in biomedical applications.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge In silico molecular docking and ADMET prediction of biogenic zinc oxide nanoparticles: characterization, and in vitro antimicrobial and photocatalytic activity By pubs.rsc.org Published On :: RSC Adv., 2024, 14,36209-36225DOI: 10.1039/D4RA06890D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hajara Akhter, Susmita Sarker Ritu, Shahariar Siddique, Fariha Chowdhury, Rehnuma Tasmiyah Chowdhury, Samina Akhter, Mahmuda HakimA facile green route to synthesize zinc oxide nanoparticles using watermelon rind extract with antimicrobial and photocatalytic potential.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Paris Paralympics: Yogesh Kathuniya bags second consecutive silver in men's discus throw F-56 event By www.thehindu.com Published On :: Mon, 02 Sep 2024 15:00:48 +0530 The 27-year-old hurled the discus to the podium-clinching distance in his very first attempt to add to the silver he won in the Tokyo Paralympics three years ago. Full Article Olympics
oge US and India can work together on mental health, says US Surgeon General Vivek Murthy By www.thehindubusinessline.com Published On :: Sun, 13 Oct 2024 10:10:09 +0530 US Surgeon General Murthy says it is time to prioritise and accelerate the work on mental health, because the consequences have been too high Full Article World
oge India-Germany sign multiple MoUs on green hydrogen, technology & trade By www.thehindubusinessline.com Published On :: Fri, 25 Oct 2024 21:15:46 +0530 Prime Minister Narendra Modi meeting with German Chancellor Olaf Scholz follows signing of multiple treaties, agreements on Mutual Legal Assistance Treaty in Criminal Matters and Indo-German Green Hydrogen Road Map Full Article National
oge ISL | Goa finally gets it act together in big win over Bengaluru By www.thehindu.com Published On :: Sun, 03 Nov 2024 20:51:47 +0530 Full Article Football
oge Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR) By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02217C, PaperBijoy Ghosh, Sahtaz Ahmed, Ashwini K. PhukanComprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge The mechanism of Mo-nitrogenase: from N2 capture to first release of NH3 By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02606C, PaperIan DanceI describe how nitrogenase catalyses N2 → HNNH → HNNH2 → NH3 + NH and how the calculated dynamics explain recent kinetics data.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02645D, PaperKetan Maru, Sarita Kalla, Ritambhara JangirThe study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02958E, PaperJanak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika KhullarThe development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge The Bonding Situations in Ruthenium Chalcogenonitrosyl Compounds: A Physical Reasoning By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02680B, PaperRichard Fragnani Cardoso, Vinícius Acir Glitz, Renato Luis Tame Parreira, Giovanni Finoto Caramori, Luis Henrique Silveira LacerdaThis research presents, for the first time, a comprehensive and rigorous investigation of ruthenium(II) chalcogenonitrosyl bonding situations in two sets of coordination compounds: [Ru(NE)Cl2(L_{OEt})] (1a-4a) and [Ru(NE)Cl2(L_{OEt})]- (1b-4b), where E...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02131B, PaperGuo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming RenFour multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02825B, CommunicationMeysam Kakavand, Anna Kozakiewicz, Abdollah NeshatTo develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17918-17933DOI: 10.1039/D4DT02542C, PaperKrishnendu M. Nair, Pavithra Shankar, Selvaraju ThangaveluElectrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02703E, PaperVilakkathala U. Krishnapriya, Cherumuttathu H. SureshDinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Sustainable treatment for low ammonia nitrogen sewage wastewater in cold climates: natural polymer gel–organic synthetic polymer embedded anammox bacteria immobilized pellets By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, 10,2809-2830DOI: 10.1039/D4EW00538D, PaperJun Li, Salma Tabassum, Hüseyin AltundagDenitrification effect of the hybrid carrier-embedded anammox bacteria pellets to treat NH4+–N urban sewage wastewater at low temperature through batch and continuous tests.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Separation behavior of hydrogen isotopes via water pervaporation using proton conductive membranes By pubs.rsc.org Published On :: Environ. Sci.: Water Res. Technol., 2024, 10,2787-2795DOI: 10.1039/D4EW00330F, PaperChan Woo Park, Sung-Wook Kim, Hyung-Ju Kim, Euna Jeong, In-Ho YoonHydrogen isotope fractionation during water pervaporation through proton conductive membranes is primarily driven by H+/D+ transport, achieving a maximum H/D separation factor of 1.086.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Tata Projects sees green hydrogen, green ammonia, pump storage hydro as pillars of growth By www.thehindu.com Published On :: Sat, 19 Oct 2024 16:54:45 +0530 “Sustainability is a critical element for us and we see in this sustainability journey, a lot of opportunities will open up in new sectors,” said Vinayak Pai, MD & CEO, Tata Projects in an interview Full Article Industry
oge Electrocatalytic nitrogen cycle: mechanism, materials, and momentum By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Advance ArticleDOI: 10.1039/D4EE03156C, Review ArticleLaiquan Li, Linyuan Xu, Hanyun Wang, Haohong Wei, Cheng Tang, Guisheng Li, Yuhai Dou, Hua Kun Liu, Shi Xue DouAs a self-sustaining cycle, the electrocatalytic nitrogen cycle represents an avenue for rectifying the nitrogen imbalance and for synthesizing value-added chemicals, thereby contributing to a sustainable and carbon-neutral society.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Regulating local chemical softness of the collector to homogenize Li deposition for anode-free Li-metal batteries By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Advance ArticleDOI: 10.1039/D4EE03673E, PaperJiaming Zhu, Cong Kang, Xiangjun Xiao, Ya Mao, Ying Luo, Yuheng Wang, Quansheng Zhang, Yulin Ma, Chunyu Du, Shuaifeng Lou, Fanpeng Kong, Jingying Xie, Geping YinA heterogeneous collector featuring hard-base sites and soft-acid sites is proposed, which significantly reduces nucleation and growth barriers, with no dendrite formation. This finding offers a pathway to rationally design highly efficient collectors for AFLMBs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Customized structures of hydrogen-bonded organic frameworks towards photocatalysis By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Advance ArticleDOI: 10.1039/D4EE03766A, Review ArticleChengdi Ma, Liyang Qin, Tianhua Zhou, Jian ZhangThis review provides a comprehensive analysis of the unique structural characteristics of HOFs and their diverse functional properties, while further exploring the potential of HOFs in the field of photocatalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
oge Market optimization and technoeconomic analysis of hydrogen-electricity coproduction systems By pubs.rsc.org Published On :: Energy Environ. Sci., 2024, Advance ArticleDOI: 10.1039/D4EE02394C, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniel J. Laky, Nicole P. Cortes, John C. Eslick, Alexander A. Noring, Naresh Susarla, Chinedu Okoli, Miguel A. Zamarripa, Douglas A. Allan, John H. Brewer, Arun K. S. Iyengar, Maojian Wang, Anthony P. Burgard, David C. Miller, Alexander W. DowlingWe present an optimization framework to analyze emerging power systems technologies that coproduce power and alternative fuels. Emerging solid oxide-based systems have the potential to enable a reliable, efficient transition to cleaner energy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article