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Rapid in situ growth of high-entropy oxide nanoparticles with reversible spinel structures for efficient Li storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA08101J, Paper
Open Access
Siyu Zhu, Wei Nong, Lim Jun Ji Nicholas, Xun Cao, Peilin Zhang, Yu Lu, Mingzhen Xiu, Kang Huang, Gang Wu, Shuo-Wang Yang, Junsheng Wu, Zheng Liu, Madhavi Srinivasan, Kedar Hippalgaonkar, Yizhong Huang
Using laser radiation, high-entropy nanoparticles were rapidly fabricated on conductive carbon. The high-entropy nanomaterials with reversible spinel structures exhibit better cycling and rate performances in LIBs.
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From scrap metal to highly efficient electrodes: harnessing the nanotextured surface of swarf for effective utilisation of Pt and Co for hydrogen production

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00711E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Madasamy Thangamuthu, Emerson C. Kohlrausch, Ming Li, Alistair Speidel, Adam T. Clare, Richard Plummer, Paul Geary, James W. Murray, Andrei N. Khlobystov, Jesum Alves Fernandes
Atomically deposited Pt and Co on nano-grooves result in active and stable electrocatalysts for hydrogen evolution and oxygen evolution reactions.
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Design of Interfacial Dual Schottky Junctions to Modulate Charge Transfer for Enhanced Piezo-assisted Photocatalytic Degradation RhB Performances

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00619D, Paper
Xiaoqi Jiang, Shengdong Sun, Yuqiao Wang, Lebing Zhao, Fangzhi Huang, Shikuo Li
Regulating charge transfer is a great challenge to improving the efficiency of piezoelectric photocatalytic reactions. Herein, sandwich-like Bi2WO6@Ag/MXene nanoflower spheres (BWO@Ag/MXene) with piezoelectric/plasma dual characteristics were synthesized by a facile...
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A new versatile crystalline sponge for organic structural analysis without the need of activation

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA07946E, Paper
Jin chang Liu, Weiping Huang, Yuxin Tian, Wei Xu, Wen-Cai Ye, Ren-Wang Jiang
Crystalline sponges made “crystallography without crystals” and received current attentions, but were difficult to apply directly because of the tedious activation procedures. It was important to prepare crystalline sponges that...
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Investigating the Lithium Plating Triggering Criterion for Graphite Electrode

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00244J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiani Li, Lubing Wang, Jun Xu
Lithium plating is considered an undesirable side reaction due to its potential to induce capacity fade and pose safety concerns in Li-ion batteries. The timely detection of lithium plating onset...
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Oxygen vacancy-induced efficient hydrogen spillover in Ni17W3/WO3−x/MoO3−x for a superior pH-universal hydrogen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00729H, Paper
Open Access
Yiqing Sun, Yiwei Bao, Di Yin, Xiuming Bu, Yuxuan Zhang, Kaihang Yue, Xiaoshuang Qi, Ziyan Cai, Yongqiang Li, Xiulan Hu, Johnny C. Ho, Xianying Wang
By regulating the oxygen vacancy in the WO3−x/MoO3−x support synergistically, the active phase transition can be accomplished at low voltage, resulting in fast intermediate hydrogen uptake/transfer/desorption kinetics on the prepared catalyst surface and interface.
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Engineering electronic band structure of ternary thermoelectric nanocatalysts for highly efficient detection of hydrogen sulfide

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00438H, Paper
Hongyuan Shang, Xiaofei Zhang, Aiping Zhang, Jinwen Du, Ruiping Zhang
This study rationally designs a ternary thermoelectric nanocatalyst PtTeCu nanorod for the accurate detection of hydrogen sulfide in biomedical applications.
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Origin of sputter damage during transparent conductive oxide deposition for semitransparent perovskite solar cells

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA06654A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Qing Yang, Weiyuan Duan, Alexander Eberst, Benjamin Klingebiel, Yueming Wang, Ashish Kulkarni, Andreas Lambertz, Karsten Bittkau, Yongqiang Zhang, Svetlana Vitusevich, Uwe Rau, Thomas Kirchartz, Kaining Ding
The origin of sputter damage during transparent conductive oxide deposition is ion bombardment rather than plasma radiation. Ion bombardment increased recombination, whereas plasma radiation reduced recombination.
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Atomically Dispersed Ru Sites on MOF-derived NC-ZnO for Efficient Oxygen Evolution Reaction in Acid Media

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00586D, Paper
Sagar Varangane, Ragunath Madhu, Saad Mehmood, Bhavya Jaksani, Vidha Bhasin, Moses Abraham Abraham Bokinala, Ammavasi Nagaraj, Chandra Shobha Vennapoosa, Venkata Subba Reddy Basireddy, Subrata Kundu, Ujjwal Pal
Developing acid-stable oxygen evolution/reduction reaction (OER/ORR) electrocatalysts is essential for high-performance water splitting. Still, the slow kinetics of the ORR and OER during the discharge and charge processes seriously impede...
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Heteroatom-doped Graphene for Marvellous Hydrogen Storage: Unveiling Recent Advances and Future Pathways

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00717D, Review Article
Shankar Ghotia, Tripti Rimza, Shiv Singh, Neeraj Dwivedi, Avanish Kumar Srivastava, Pradip Kumar
Hydrogen energy and storage are gaining significant attention due to their potential to address various energy and environmental challenges. Storage of hydrogen in a solid–state media is an area of...
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Scalable preparation of flexible heterogeneous graphene oxide structures for high performance wet power generation

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01819B, Paper
Yu Gao, Xiaoming Cai, Yuzhou Zhao, Wentian Huang, Jian Lv, Jie Wang, Zhenliang Hao, Huiming Liang, Honglin Tan, Jinming Cai
Moisture-driven energy generation (MEG) has attracted great attention in recent years, and the interaction of functionalized nanomaterials with water offers the possibility of MEG. However, current MEG devices require specific...
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Bi-intercalated vanadium pentoxide synthesized via hydrogen peroxide-induced phase transition for highly stable cathode in aqueous zinc ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07984H, Paper
Jian-an Chen, Xuejun Hou, Xueli Wang, Chunxia Wang, Jiawei Wen, Yongjie Bu, Guoyong Huang, Tiantian Cao, Shengming Xu
Operating principle of aqueous zinc-ion batteries (ZIBs).
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Structure–property–performance relationship of vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00736K, Review Article
Reza Abazari, Soheila Sanati, Ashok Kumar Nanjundan, Qiyou Wang, Deepak P. Dubal, Min Liu
The current review discusses on vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications along with the potential future advancements in these fields.
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Dioxygen atom co-doping g-C3N4 for boosted photoreduction activity of CO2 and mechanistic investigation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00156G, Paper
Zhang Jiang, Mingnv Guo, Zhongqing Yang, Ruiming Fang, Ziqi Wang, Jingyu Ran
Visible-light photocatalytic reduction of carbon dioxide with the help of photocatalysts has become an important means to mitigate the greenhouse effect.
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Metal–support interaction triggered d–p orbital hybridization for efficient electrocatalytic semi-hydrogenation of alkynes

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01240B, Paper
Qiong Wan, Jiaxun Zhang, Xuan Liu, Huizhi Li, Abdullah, Taotao Ren, Qiyuan Liu, Yongheng Xu, Jia Liu, Jicheng Liu, Bingqing Yao, Yiyun Fang, Xinzhe Li, Chi He
Atomic restructuring in Pd/Fe2O3 catalysts weakens Pd binding to chemisorbed 4-aminophenylacetylene and hydrogen intermediates, boosting conversion and selectivity in 4-aminophenylacetylene semi-hydrogenation, surpassing Pd/C and other catalysts.
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Regulating Pt-Covalent Triazine Frameworks Schottky Junction by Tailor-Made Nitrogen Sites towards Efficient Photocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00618F, Paper
Chao Li, Lijiang Guan, Jin Zhang, Cheng Cheng, Zhaoqi Guo, Zhihong Tian, Li-Ming Yang, Shangbin Jin
Covalent triazine frameworks (CTFs) of designable nitrogen-rich structures, which can form Schottky Junction with Pt nanoparticles, have been extensively studied in photocatalysis. However, how to tune the interaction inside the...
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Deciphering cycling voltage-dependent failures of O3-layered cathode for sodium ion battery

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07967H, Paper
Xuejiao Zhao, Lihan Zhang, Xiaoqi Wang, Jinhui Li, Lin Zhang, Di Liu, Rui Yang, Xu Jin, Manling Sui, Pengfei Yan
Interfacial degradations dominate the performance decay of O3-layered cathode during low-voltage cycling; high voltage cycling induced bulk failures cause rapid performance decay due to transition metal cation migration.
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Boosting the electrocatalytic activity of single atom iron catalysts through sulfur-doping engineering for liquid and flexible rechargeable Zn–air batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00524D, Paper
Tianfang Yang, Bingcheng Ge, XuPo Liu, Zunjie Zhang, Ye Chen, Yang Liu
A practical strategy is reported to design single-Fe atom decorated S/N-doped C (Fe SAs@S/N–C) catalysts with a high Fe loading of 5.45 wt%. The prepared catalysts exhibit excellent performances for liquid and all-solid-state Zn–air batteries.
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A full metal-free flexible ammonium-ion battery with biodegradable hydrogel electrolyte

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00249K, Paper
Abhishek Paudel, Ajalynn N. Crum, Ying Wang
In this work, a full flexible metal-free battery is developed using a QSS hydrogel electrolyte sandwiched between a PANI anode and PPy cathode enabling the battery to operate and maintain its performance while bent or twisted.
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Boosting reaction kinetics of polycrystalline phase Fe7S8/FeS2 heterostructures encapsulated in hollow carbon nanofiber for superior fast sodium storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01241K, Paper
Hui Cai, Fei Wang, Huiyan Feng, Zhendong Liu, Chengzhi Zhang, Anbang Lu, Xi Zhao, Qiuhong Lu, Quanbing Liu, Jun Tan
Metal sulfides have been regarded as highly competitive anode materials for fast sodium storage due to the excellent redox reversibility and comparatively great electron properties. Nevertheless, metal sulfides suffer from...
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Bio-inspired design of a self-supported bismuth microforest for high performance sodium storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00950A, Paper
Jia Bai, Yan Liu, Ben Pu, Qi Tang, Yongbin Wang, Ruihan Yuan, Jin Cui, Yi Yang, Xiaojia Zheng, Bin Zhou, Weiqing Yang
A self-supported bismuth microforest anode material, prepared by a simple, efficient and scalable in situ galvanic replacement approach, exhibits high performance for sodium-ion batteries.
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Tuning the ion conductivity of Zr-based metal organic framework ionogels by linker functionalization

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA06986A, Paper
Open Access
Antonija Ferbezar, Roman Zettl, Katharina Hogrefe, Harald Fitzek, Bernhard Gadermaier, Martin Wilkening, Ilie Hanzu
Solid-state ion conductors have improved significantly in the past decade. Envisioned applications range from metal anode batteries and fuel cells to sensors and medical technologies. The choice of solid electrolytes...
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Efficient photocatalytic hydrogen evolution based on Z-scheme 2D OV-LaVO4/Mo-doped SV-ZnIn2S4 heterojunctions

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00754A, Paper
Wei Guan, Lin Zhang, Peng Wang, Ying Wang, Haoyu Wang, Xingchen Dong, Liyan Yu, Zhixing Gan, Lifeng Dong, Lina Sui
The purposeful design and construction of two-dimensional (2D) semiconductor heterojunctions offers a promising avenue for achieving efficient photocatalytic activity. However, the challenge of enabling efficient charge migration at the interface...
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Oxygen insertion at the cage center: an unconventional tuning strategy for enhancing the photocatalytic performance of atomically precise copper cluster cocatalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07218E, Paper
Yun-Dong Cao, Di Yin, Ming-Liang Wang, Hong Liu, Yi Feng, Lin-Lin Fan, Cai-Li Lv, Guang-Gang Gao
This work not only confirms the long-standing prediction that the Cu8 center can accommodate an oxygen atom but also demonstrates a novel central atom regulation strategy to obtain highly active copper clusters as photocatalysts.
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Closed pore structure engineering from ultra-micropores with the assistance of polypropylene for boosted sodium ion storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01375A, Paper
Xue Li, Ning Sun, Shaohong Zhang, Razium Ali Soomro, Bin Xu
Closed pore architectures with exceptional Na-storage performance have been successfully fabricated from ultra-micropores with the assistance of polypropylene.
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NiFeCo–OH/NiTe nanoarrays with amorphous/crystalline interfaces for highly efficient oxygen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00772G, Paper
Jing Liu, Da Liu, Xiaoxiao Yan, Peifang Guo, Hongbin Xu, Peng Chen, Renbing Wu
One-dimensional heterostructured NiFeCo–OH/NiTe nanorod arrays with amorphous/crystalline interfaces have been rationally synthesized, exhibiting an excellent OER electrocatalytic performance.
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In situ analysis of the oxygen evolution reaction on the CuO film in alkaline solution by surface interrogation scanning electrochemical microscopy: investigating active sites (CuIII) and kinetics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00628C, Paper
Seokjun Han, Jinoh Yoo, Won Tae Choi
Surface interrogation scanning electrochemical microscopy was employed to assess the electrocatalytic activity of CuO films for the oxygen evolution reaction in an alkaline solution.
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Configuration-entropy effects on BiFeO3–BaTiO3 relaxor ferroelectric ceramics for high-density energy storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00921E, Paper
Open Access
Rhys Montecillo, Cheng-Sao Chen, Kuei-Chih Feng, R. R. Chien, Pin-Yi Chen, Chi-Shun Tu
A high-configuration entropy results in the formation of grain boundaries and nanoclusters, which act as barriers for enhancing breakdown strength and energy-storage capability.
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Insights into the Enhanced Cycling Stability of Cobalt-Free Single-Crystal Layered Oxide Cathodes at Elevated Voltage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA02135E, Paper
Tiancheng Liu, Ke Fan, Changsheng Chen, Mingxia Dong, Yanping Zhu, Gao Chen, Jiangtong Li, Zezhou Lin, Liuqing Li, Ye Zhu, Huangxu Li, Haitao Huang
Co-free single-crystal cathodes Li(NixMn1-x)O2 have been proposed as promising candidates due to remarkable thermal stability and low cost. Unfortunately, insufficient in-depth understanding on the failure mechanisms hinders the development of...
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Highly Boosted Energy Storage Performance of Few-Layered MoS2 Utilized by Improved Electrode Fabrication: Experimental and Theoretical Studies

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01713G, Paper
Zeyad M. Abdulhamid, Abhishek C. Lokhande, Adewale Hammed Pasanaje, Daniel S Choi, Nirpendra Singh, Kyriaki Polychronopoulou, Dalaver H. Anjum
Few-layer two-dimensional (2D) molybdenum disulfide (MoS2) has great potential in designing high-performance supercapacitors due to its high theoretical specific capacity, tunable bandgap, and fascinating 2D layered structure. However, the lack...
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Enhanced Hydrogen Production by Assisted Biomass Gasification Using Lithium Manganate as Bifunctional Material

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00224E, Paper
Open Access
Carlos Hernández-Fontes, Nan Wang, Nayeli Gómez-Garduño, Heriberto Pfeiffer
The rising energy demand, among other economic and technological factors, increases the greenhouse gas emissions. Therefore, it is crucial to develop technologies to produce clean energy, such as hydrogen (H2)...
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Green solvents in battery recycling: status and challenges

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07905H, Review Article
Wenyuan Qiao, Ren Zhang, Yikai Wen, Xinyi Wang, Zheng Wang, Guoqiang Tang, Minghao Liu, Hyokyeong Kang, Zafar Said, Jang-Yeon Hwang, Changhui Liu
A green solvent hybrid system will bring about sustainable development in the battery industry by efficiently and environmentally friendly recycling of valuable resources contained in waste batteries.
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Harvesting solar energy with a Ni-MOF-based evaporator for efficient solar thermal storage and steam generation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00203B, Paper
You Xu, Zhengyun Wang, Xianbao Wang, Zhenzhen Guo, Muhammad Sultan Irshad, Naila Arshad, Jiang Gong, Hongfang Liu, Guangfang Li
A hybrid solar evaporator comprising a Ni-based metal–organic framework material and a phase change material composite was fabricated for high performance solar-thermal energy storage and continuous solar vapor generation.
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Machine Learning Enabled Exploration of Multicomponent Metal Oxides for Catalyzing Oxygen Reduction in Alkaline Media

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01884B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xue Jia, Hao Li
Low-cost metal oxides have emerged as promising candidates used as electrocatalysts for oxygen reduction reaction (ORR) due to their remarkable stability under oxidizing conditions, particularly in alkaline media. Recent studies...
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Toward record high Zn2+ storage in carbon electrodes via pore confinement engineering

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01191K, Paper
Xiubo Zhang, Chang Yu, Yuanyang Xie, Jinhe Yu, Yingbin Liu, Yi Yang, Jianjian Wang, Shuqin Lan, Siyi Hou, Kunlun Liu, Jieshan Qiu
The effective specific surface area is proposed and well correlated with Zn2+ storage, guiding maximum Zn2+ storage within carbon. Multiple in situ spectroscopy techniques clarify the co-adsorption mechanism of hydrated Zn2+, SO42−, and H+.
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Dak Prescott underwent season-ending surgery Wednesday

Cowboys quarterback Dak Prescott underwent successful surgery in New York on Wednesday, Clarence Hill of alldlls.com reports.




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Superconductivity above 30 K due to the introduction of oxygen element in CaFeAsF

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03994G, Paper
Yixin Liu, Teng Wang, Zulei Xu, Da Jiang, Yi Zhao, Yanpeng Qi, Xiaoni Wang, Ming Yang, Mao Ye, Wei Peng, Gang Mu
Exploring new unconventional superconductors is of great value for both fundamental research and practical applications. It is a long-term challenge to develop and study more hole-doped superconductors in 1111 system...
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Stronger Polar Ferromagnetism and Narrower Optical Band Gaps in Two-Dimensional Hybrid Copper Perovskites Induced by Bromine-Substitution

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03532A, Paper
Ceng Han, Jason Allan McNulty, Alasdair Bradford, Alexandra Slawin, Stephen Lee, Philip Lightfoot
Two-dimensional (2D) organic–inorganic hybrid perovskites are attracting great interest due to their structural tunability and rich functional characteristics. Here, we report a series 2D layered hybrid copper (II) halide perovskites...
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A New 3D Scan, Created from 25,000 High-Resolution Images, Reveals the Remarkably Well-Preserved Wreck of Shackleton’s Endurance

Photos on this page courtesy of the Falklands Maritime Heritage  Few who hear the story of the Endurance could avoid reflecting on the aptness of the ship’s name. A year after setting out on the Imperial Trans-Antarctic Expedition in 1914, it got stuck in a mass of drifting ice off Antarctica. There it remained for ten months, […]




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Preethi Abraham takes charge as Accountant General of Kerala




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Pilgrims visiting Sabarimala to get nowcast from Nov. 15

Hygrometers to measure humidity and thermometers will be installed on the shrine premises soon to provide weather services to pilgrims, says IMD Director




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Govt. charges BRS with hatching conspiracies to stall development projects for political gains

Dy CM says involvement of BRS leader in Lagacharla incident exposes the party’s intentions




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EU, Belgium, Denmark and Germany envoys visit Adani's Khavda, Mundra businesses, Gautam Adani says It was a privilege




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Vegetable prices sky-rocket in October, food inflation at 10.87%, CPI at 6.21 %




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Centre to deliberate on plans to achieve 500 GW green energy target by 2030




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India's infrastructure push to be among largest in 21st century: KPMG




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Coal import for blending purposes in power generation declines by 8.5% during April-Sept 2024




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Air India completes merger with Vistara




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Guest modulating the photoactivity of a titanium-oxide cage

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04983G, Edge Article
Open Access
Dexin Wang, Yanshu Liu, Guanyun Zhang, Menghui Chu, Fangfang Gao, Guanjie Chen, Guo Wang, Chen-Ho Tung, Yifeng Wang
Ti-oxide salicylate clusters with novel biloculate cages and exchangeable guests are reported. The guests influence the physiochemical properties and photocatalytic CO2/epoxide cycloaddition activities of the complexes.
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Phase transition induced hydrogen activation for enhanced furfural reductive amination over CoCu bimetallic catalyst

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05885B, Edge Article
Open Access
Yilin Wei, Zixu Ma, Beibei Liu, Jialin Yang, Dan Wu, Yongsheng Zhang, Yuexing Zhang, Charles Chunbao Xu, Renfeng Nie
The synthesis of primary amines from renewable biomass and its derivatives through reductive amination has garnered significant attention. How to construct efficient non-noble-metal catalysts that enable low-temperature catalysis still remains...
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