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The direct decomposition of NO into N2 and O2 over copper doped Ba3Y4O9

Catal. Sci. Technol., 2020, 10,2513-2522
DOI: 10.1039/D0CY00194E, Paper
Siman Fang, Atsushi Takagaki, Motonori Watanabe, Tatsumi Ishihara
Both NO decomposition activity and long-term stability increase significantly after the introduction of Cu into Ba3Y4O9.
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Single-step benzene hydroxylation by cobalt(II) catalysts via a cobalt(III)-hydroperoxo intermediate

Catal. Sci. Technol., 2020, 10,2540-2548
DOI: 10.1039/C9CY02601K, Paper
Karunanithi Anandababu, Sethuraman Muthuramalingam, Marappan Velusamy, Ramasamy Mayilmurugan
Cobalt(II) complexes reported as efficient and selective catalysts for single-step phenol formation from benzene using H2O2. The catalysis proceeds likely via cobalt(III)-hydroperoxo species.
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New findings and current controversies in the reaction of ruthenium red and ammonium cerium(IV) nitrate: focus on the precipitated compound

Catal. Sci. Technol., 2020, 10,2491-2502
DOI: 10.1039/C9CY02499A, Paper
Bahram Sarvi, Seyedeh Maedeh Hosseini, Bahareh Deljoo, Abdelhamid El-Sawy, Alireza Shirazi Amin, Mark Aindow, Steven L. Suib, Mohammad Mahdi Najafpour
During water-oxidation reaction in the presence of RuR and CAN, a heterogeneous nano-sized Ru-Ce compound is detected, which is formed by the interaction of [(NH3)5RuORu(NH3)4ORu(NH3)5],6+/7+ nitrate ions, and the products of the reduction of CAN.
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Direct synthesis of hydrogen peroxide without the use of acids or halide promoters in dissolution

Catal. Sci. Technol., 2020, 10,2333-2336
DOI: 10.1039/D0CY00416B, Communication
Open Access
G. Blanco-Brieva, F. Desmedt, P. Miquel, J. M. Campos-Martin, J. L. G. Fierro
We show the first catalyst family able to produce hydrogen peroxide at concentrations higher than 5 wt% in the absence of any promoter or stabilizing agent in dissolution.
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Effects of Ni loading on the physicochemical properties of NiOx/CeO2 catalysts and catalytic activity for NO reduction by CO

Catal. Sci. Technol., 2020, 10,2359-2368
DOI: 10.1039/C9CY02619C, Paper
Shuhao Zhang, Jaeha Lee, Do Heui Kim, Taejin Kim
The NO reduction by CO reaction was investigated using NiOx/CeO2 catalysts with different Ni loadings. Surface NiOx controls the catalytic activity which was related to the molecular structure and reducibility of the catalysts.
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Facile sulfolane-modified resins for enhanced dimethoxymethane carbonylation

Catal. Sci. Technol., 2020, 10,2561-2572
DOI: 10.1039/D0CY00201A, Paper
Jie Yao, Lei Shi, Wenjie Deng, Jiaqi Fan, Yan Wang, Weizhe Gao, Dongxi Zhang, Wenliang Zhu, Zhongmin Liu
A simple resin modification method for 50 h DMM carbonylation with a high STY of 3.15 mmolMMAc (gcat h)−1 and 100% MMAc selectivity.
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Construction of heterostructure based on hierarchical Bi2MoO6 and g-C3N4 with ease for impressive performance in photoelectrocatalytic water splitting and supercapacitor

Catal. Sci. Technol., 2020, 10,2427-2442
DOI: 10.1039/D0CY00211A, Paper
C. Murugan, M. Karnan, M. Sathish, A. Pandikumar
This work demonstrates the formation of g-C3N4/Bi2MoO6 heterostructure for water splitting and supercapacitor; which shows highest PEC efficiency and symmetric device delivered a energy density and power density of 47 W h kg−1 and 4.5 kW kg−1.
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Highly-efficient Ru/Al–SBA-15 catalysts with strong Lewis acid sites for the water-assisted hydrogenation of p-phthalic acid

Catal. Sci. Technol., 2020, 10,2443-2451
DOI: 10.1039/D0CY00047G, Paper
Cong Mao, Jingwei Zheng, Babasaheb M. Matsagar, Ranjith Kumar Kankala, Tansir Ahamad, Yucheng Yang, Kevin C.-W. Wu, Xueqin Zhang
A Ru/Al–SBA-15 catalyst with excess Lewis acid sites displayed excellent efficiency (100%), high cis-isomer selectivity (84%), and exceptional stability towards hydrogenation of p-phthalic acid in water.
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Carbon deposits during catalytic combustion of toluene on Pd–Pt-based catalysts

Catal. Sci. Technol., 2020, 10,2452-2461
DOI: 10.1039/D0CY00101E, Paper
Yu Yang, Gang Wang, Peng Zheng, Falu Dang, Jiannian Han
Carbon is easily deposited on a catalyst during the catalytic combustion of toluene, resulting in catalyst deactivation.
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Gold-catalyzed domino cyclization enabling construction of diverse fused azaspiro tetracyclic scaffolds: a cascade catalysis mechanism due to a substrate and counterion

Catal. Sci. Technol., 2020, 10,2415-2426
DOI: 10.1039/D0CY00120A, Paper
Yunhe Li, Xiang Zhao
The detailed mechanism and origins of gold-catalyzed domino cyclization to diverse fused azaspiro tetracyclic scaffolds by cooperative dual catalysis and cascade catalysis are systematically studied.
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Integrated adsorption and photocatalytic degradation of VOCs using a TiO2/diatomite composite: effects of relative humidity and reaction atmosphere

Catal. Sci. Technol., 2020, 10,2378-2388
DOI: 10.1039/D0CY00168F, Paper
Guangxin Zhang, Arman Peyravi, Zaher Hashisho, Zhiming Sun, Yangyu Liu, Shuilin Zheng, Lexuan Zhong
The optimal relative humidity condition for VOC degradation is related to the length of the carbon chain of VOCs.
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Carbon nanotube-supported Cu-based catalysts for oxidative carbonylation of methanol to methyl carbonate: effect of nanotube pore size

Catal. Sci. Technol., 2020, 10,2615-2626
DOI: 10.1039/C9CY02407G, Paper
Dan Zhao, Guoqiang Zhang, Lifei Yan, Lingqi Kong, Huayan Zheng, Jie Mi, Zhong Li
The inner diameter of CNTs significantly affected the location, dispersion, autoreduction and stability of Cu species and thus the catalytic activity and stability for oxidative carbonylation of methanol to dimethyl carbonate.
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Aerobic oxidation of 1,6-hexanediol to adipic acid over Au-based catalysts: the role of basic supports

Catal. Sci. Technol., 2020, 10,2644-2651
DOI: 10.1039/D0CY00183J, Paper
Open Access
Noemi Capece, Achraf Sadier, Camila Palombo Ferraz, Joëlle Thuriot-Roukos, Mariusz Pietrowski, Michał Zieliński, Sébastien Paul, Fabrizio Cavani, Robert Wojcieszak
1,6-Hexanediol is a relevant building blocks that could be obtained from biomass and transformed under base free conditions into adipic acid used for polymer synthesis.
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
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Enhanced oxygen evolution catalysis by aluminium-doped cobalt phosphide through in situ surface area increase

Catal. Sci. Technol., 2020, 10,2398-2406
DOI: 10.1039/D0CY00123F, Paper
Timothy E. Rosser, Juliana P. S. Sousa, Yasmine Ziouani, Oleksandr Bondarchuk, Dmitri Y. Petrovykh, Xian-Kui Wei, Jo J. L. Humphrey, Marc Heggen, Yury V. Kolen'ko, Andrew J. Wain
Al-doping of cobalt phosphide oxygen evolution catalysts results in enhanced performance which, based on in situ and operando analysis, is shown to result from a surface area increase associated with modified oxidation behaviour.
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Synthesis and molecular structure of model silica-supported tungsten oxide catalysts for oxidative coupling of methane (OCM)

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00289E, Paper
Daniyal Kiani, Sagar Sourav, Israel E. Wachs, Jonas Baltrusaitis
Catalysts with only dispersed phase Na–WO4 sites where Na/W < 2 are slightly less active but significantly more C2 selective than the traditional Na2WO4/SiO2 catalysts that contain a crystalline phase where Na/W = 2.
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Outstanding Reviewers for Catalysis Science & Technology in 2019

Catal. Sci. Technol., 2020, 10,2328-2328
DOI: 10.1039/D0CY90032J, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Catalysis Science & Technology in 2019, as selected by the editorial team for their significant contribution to the journal.
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Development of BiOI as an effective photocatalyst for oxygen evolution reaction under simulated solar irradiation

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00266F, Paper
Tzu-Hsin Chen, Masaaki Yoshida, Shun Tsunekawa, Jia-Hao Wu, Kun-Yi Andrew Lin, Chechia Hu
In this study, crystalline BiOI powders were prepared for photocatalytic O2 evolution in the presence of NaIO3 as the electron mediator.
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Mechanistic insights into the oxidation of copper(I) species during NH3–SCR over Cu-CHA zeolites: A DFT study

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00379D, Paper
Chong Liu, Hiroe Kubota, Takashi Toyao, Zen Maeno, Ken-ichi Shimizu
Selective catalytic reduction of nitrogen oxides using ammonia (NH3–SCR) over Cu-exchanged zeolites proceeds via reduction of Cu(II) to Cu(I) and subsequent reoxidation of Cu(I) to Cu(II). Although the mechanism of...
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Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and developing trend

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00400F, Perspective
Hongen Cao, Rongrong Qian, Lei Yu
Recent progresses of the selenium-catalyzed oxidation of alkenes are summarized at the mechanism level. It may be beneficial for designing novel selenium-containing catalysts and alkene oxidation protocols for the next phase of studies.
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An in situ grown lanthanum sulfide/molybdenum sulfide hybrid catalyst for electrochemical hydrogen evolution

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00425A, Paper
Xinran Ding, Tao Yang, Wenxian Wei, Yihui Wang, Kai Xu, Zizheng Zhu, Hong Zhao, Tingting Yu, Dongen Zhang
An La2S3–MoS2 catalyst with expanded interlayer spacing and engineered nano-interfaces was facilely synthesized, demonstrating enhanced catalytic activity for electrochemical hydrogen evolution.
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Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
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MOFs based on 1D structural sub-domains with Brønsted acid and redox active sites as effective bi-functional catalysts

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00235F, Paper
José María Moreno, Alexandra Velty, Urbano Díaz
Low-dimensional MOF-type catalysts containing Brønsted acid and redox active sites, based on assembled 1D organic–inorganic nanoribbons, for one-pot two-step reactions.
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Insights into isothiourea-catalyzed asymmetric [3 + 3] annulation of α,β-unsaturated aryl esters with 2-acylbenzazoles:Mechani-sm, origin of stereoselectivity and switchable chemoselectivity

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00295J, Paper
Congcong Wang, Shi-Jun Li, Qiao-Chu Zhang, Donghui Wei, Lina Ding
Recently, isothiourea-catalyzed asymmetric [3 + 3] annulation reactions of α,β-unsaturated aryl esters with 2-acylbenzothiazole (or 2-acylbenzoxazole) were reported with switchable chemoselectivity to form either dihydropyridone or dihydropyrone, but predicting the...
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Two-way desorption coupling to enhance the conversion of syngas into aromatics by MnO/H-ZSM-5

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00275E, Paper
Syed Zulfiqar Ali Gilani, Le Lu, Muhammad Tahir Arslan, Babar Ali, Qi Wang, Fei Wei
We herein report a composite catalyst containing partially reducible and highly active manganese oxide and nano-size H-ZSM-5 with short b-axis, prepared for the direct conversion of syngas into aromatics.
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Pt-Ligand single-atom catalysts: tuning activity by oxide support defect density

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02594D, Paper
Xuemei Zhou, Linxiao Chen, George E. Sterbinsky, Debangshu Mukherjee, Raymond R. Unocic, Steven L. Tait
Metal–ligand coordination stabilizes single atom Pt on pristine and defective TiO2 supports to impact local coordination and catalytic hydrosilylation activity.
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Facile synthesis of oxygen-deficient nano-TiO2 coordinated by acetate ligands for enhanced visible-light photocatalytic performance

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00592D, Paper
Shaohua Pang, Yunfei Lu, Lin Cheng, Juming Liu, Huiyan Ma, Jucai Yang, Qiancheng Zhang
To date, various methods have been adopted to enhance the visible-light photocatalytic activity of nano-TiO2. However, a more facile and moderate method is still highly desirable. In this work, a...
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CO activation and methanation mechanism on hexagonal close-packed Co catalysts: effect of functionals, carbon deposition and surface structure

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00499E, Paper
Hai-Yan Su, Changlin Yu, Jin-Xun Liu, Yonghui Zhao, Xiufang Ma, Jie Luo, Chenghua Sun, Wei-Xue Li, Keju Sun
Regardless of the functionals used and the presence of graphitic carbon, the CO methanation rate on Co(0001) is mainly controlled by CHO decomposition.
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Bifunctional rhenium-copper nanostructures for intensified and stable ethanol synthesis via hydrogenation of dimethyl oxalate

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00579G, Communication
Zhongnan Du, Meng Chen, Xuepeng Wang, Xingkun Chen, Xiaolin Mou, Yuan Tan, Wenshao Yang, Chuanqi Huang, Hejun Zhu, Ronghe Lin, Yunjie Ding
Decorating small copper nanoparticles with isolated and/or clusted oxophilic rhenium species enables the first low-copper catalytic technology for intensified and stable ethanol production under mild conditions in dimethyl oxalate hydrogenation....
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Synthesis of vinyl chloride monomer by acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00512F, Paper
Ming Cai, Haiyang Zhang, Baochang Man, Jian Li, Linfeng Li, Yanqin Li, Dongyang Xie, Renpan Deng, Jinli Zhang
With the implementation of Minamata Convention and the urgent demand for green, and efficient mercury-free catalysts, the carbon-supported IPr-(Ru)/AC catalyst was synthesized and assessed for its successful application in acetylene...
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Impact of edge structures on interfacial interactions and efficient visible-light photocatalytic activity of metal–semiconductor hybrid 2D materials

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00420K, Paper
Open Access
Deobrat Singh, Pritam Kumar Panda, Nabil Khossossi, Yogendra Kumar Mishra, Abdelmajid Ainane, Rajeev Ahuja
The present work systematically investigates the structural, electronic, and optical properties of MoS2/Si2BN heterostructures based on first-principles calculations.
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Homogeneous vs. Heterogeneous: Mechanistic Insights into Iron Group Metal-Catalyzed Reductions from Poisoning Experiments

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00644K, Minireview
Axel Jacobi von Wangelin, Sebastian Sandl, Dominik Gärtner
Iron group metal catalysts constitute a promising alternative to well-established noble metal catalysts in reduction reactions. However, the development of effective 3d metal catalysts has largely been hampered by their...
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Site-specific catalytic activities to facilitate solvent-free aerobic oxidation of cyclohexylamine to cyclohexanone oxime over highly efficient Nb-modified SBA-15 catalysts

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00479K, Paper
Wei Ding, Haoyu Peng, Wenzhou Zhong, Liqiu Mao, Dulin Yin
The development of highly active and selective heterogeneous catalysts for efficient oxidation of cyclohexylamine to cyclohexanone oxime is a challenge associated with the highly sensitive nitrogen center of cyclohexylamine.
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Photocatalytic asymmetric epoxidation of trans-stilbene with manganese–porphyrin/graphene-oxide nanocomposite and molecular oxygen: axial ligand effect

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00441C, Paper
Elahe Ahadi, Hassan Hosseini-Monfared, Alex Spieß, Christoph Janiak
An efficient, visible light-driven manganese–porphyrin photocatalyst was developed for the asymmetric epoxidation of trans-stilbene by molecular oxygen under mild conditions.
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Does the structure of CuZn hydroxycarbonate precursors affect the intrinsic hydrogenolysis activity of CuZn catalysts?

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00143K, Paper
Violetta Pospelova, Jaroslav Aubrecht, Kateřina Pacultová, Miloslav Lhotka, Oleg Kikhtyanin, David Kubička
A comparative study of the properties and activity of catalysts derived from single-phase CuZn precursors to elucidate the effect of the precursor structure on the catalyst activity in DMA hydrogenolysis and to examine replacement of CuCr catalysts.
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Photoswitchable catalysis using organometallic complexes

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00431F, Minireview
Zoraida Freixa
Photoswitchable catalysis using organometallic complexes: a ligand design perspective.
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Synthesis of FeCo-N@N-doped carbon oxygen reduction catalysts via microwave-assisted ammoxidation

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00376J, Paper
Hung-Chih Kuo, Shou-Heng Liu, Yan-Gu Lin, Chao-Lung Chiang, Dan CW Tsang
A core-shell structured FeCo-N@N-doped carbon derived from biomass wastes (sugarcane and palm kernel shell) is facilely prepared by hydrothermal carbonization and NH3 microwave ammoxidation method. The fabricated carbons are thoroughly...
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Interfacial Effect of Co4S3-Co9S8 Nanoparticles Hosted onto rGO Sheets Derived from Molecular Precursor Pyrolysis on Enhancing Electrochemical Behaviour†

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00564A, Paper
Mengmeng He, Linchao Zhu, Yanyan Liu, Hao Wen, Yunxia Hu, Baojun Li
The reasonable design and synthesis of Co-based compound with superior electrochemical activity and durability have aroused tremendous research interests. Herein, a simple molecular precursor pyrolysis strategy is proposed to fabricate...
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Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00551G, Paper
Arif Ali, Chen Zhao
The selective and high-yield production of α-olefins by alcohol dehydration is challenging because the isomerization and polymerization olefin products are more thermodynamically stable. In this study, we prepared a physical...
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Shapoorji Pallonji group subsidiary announces plan to list Eureka Forbes

Forbes & Company, a Shapoorji Pallonji group firm on Tuesday announced plans to list its subsidiary Eureka Forbes to unlock value for shareholders. The company's board has authorised the management to evaluate any such scheme in this regard, Forbes & Company said in a regulatory filing. "The Board of Directors of the company has authorised the management...to evaluate a scheme of arrangement and/or other appropriate mechanisms to enable an eventual listing of Eureka Forbes with an intention to unlock value in the hands of all the shareholders of the company," it said. These may also include listing, dilution/sale or combination thereof of Eureka Forbes, it added. Eureka Forbes is a wholly-owned subsidiary of Forbes & Company. "The Board will consider the above (schemes) when the relevant proposals are placed before it in the near future, but in principle has approved supporting the endeavours of the management in this regard," it said. It operates in water purifier, air ...




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UTI MF files draft papers for IPO; issue size likely to be up to Rs 4000 cr

The issue size is expected to be Rs 3,000-4,000 crore, valuing the AMC at Rs 10,000-11,000 crore




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Antony Waste extends IPO closing to March 16, cites exceptional volatility

Antony Waste IPO comprises of Rs 35 crore of fresh fund raising and Rs 171 crore of secondary share sale




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Guwahati girl tests Covid positive after death




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Fewer ‘other deaths’ in Kol since lockdown began

The lockdown, meant to tackle the novel coronavirus, has resulted in a 20% dip in deaths in Kolkata, if one doesn’t factor in Covid-19 deaths.




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'Death Cap' mushrooms kill six in Meghalaya

The poisonous mushrooms that killed six people at a remote village in Meghalaya's West Jaintia Hills district have been identified as Amanita phalloides, commonly known as the 'Death Cap', a senior official said on Saturday.




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Border worlds / written and illustrated by Don Simpson ; with an afterword by Stephen R. Bissette

Hayden Library - PN6727.S525 B67 2017




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Body music / Julie Maroh

Barker Library - PN6747.M36 C6713 2017




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The 7 deadly sins / written by Tze Chun; drawn by Artyom Trakhanov; and colored by Giulia Brusco

Barker Library - PN6728.A17 2018




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Women's manga in Asia and beyond: uniting different cultures and identities / Fusami Ogi, Rebecca Suter, Kazumi Nagaike, John A. Lent, editors

Rotch Library - PN6714.W664 2019




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Infidel / writer, Pornsak Pichetshote ; artist, Aaron Campbell ; colorist & editor, José Villarrubia ; letterer & designer, Jeff Powell ; introduction by Tananarive Due ; afterword by Jeff Lemire

Barker Library - PN6727.P534 I53 2018