si

A solvent-free, self-emulsified and heat-responsive polyester coating enables chemically-recyclable and fire-safe PET foam

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04531A, Paper
Bei-Bei Zhang, Li-Xia Fan, Lin Chen, Xiu-Li Wang, Yu-Zhong Wang
This work implements a state-of-the-art strategy to simultaneously achieve use performance and future recycling, which will greatly benefit the green sustainable circular economy for wind turbine blades.
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si

Does enzymatic catalysis lead to more sustainable chemicals production? A life cycle sustainability assessment of isopropyl palmitate

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04514A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pieter Nachtergaele, Ozan Kocak, Yblin Roman Escobar, Jordy Motte, Dries Gabriels, Leopold Mottet, Jo Dewulf
A methodology is presented for assessing the life cycle sustainability of enzymatic catalysis for chemicals production. For IPP, lower environmental impacts, but higher costs and social risks were found for switching to enzymatic catalysis.
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si

Flow electrosynthesis of phosphinamides and phosphoramidates through P–N coupling

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04450A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tribani Boruah, Ren Ishizeki, Alberto Roldan, Rebecca L. Melen, Thomas Wirth
A robust flow electrochemical method for P–N and P–O oxidative coupling under mild conditions has been developed. Cyclic voltammetry (CV) was employed to investigate the redox behaviour of reactants.
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si

The Effects of Polyolefin Structure and Source on Pyrolysis-Derived Plastic Oil Composition

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04029E, Paper
Jiayang Wu, Zhen Jiang, Victor S Cecon, Greg W. Curtzwiler, George W. Huber, Keith L. Vorst, Manos Mavrikakis
Seven types of plastics were pyrolyzed in a fluidized bed reactor: post-consumer recycled (PCR) high-density polyethylene (HDPE), PCR polypropylene (PP), virgin resins of varying molecular weights of HDPE, virgin resins...
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si

Continuous-flow Synthesis of Cyclic Carbonates with Polymer-supported Imidazolium-based Ionic Liquid (Im-PSIL) Catalysts

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04499A, Communication
Open Access
Zhibo Yu, Haruro Ishitani, Shu Kobayashi
Carbon dioxide (CO2), a major greenhouse gas emitted through human activities, represents a valuable carbon source for chemical production. However, maximizing its efficiency requires novel methods for CO2 conversion that...
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si

Green synthesis of N-sulfonyl amidine using a CuI-incorporated CoFe2O4 nano-catalyst in aqueous medium

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04033C, Paper
Samrat Charaimuria, Prodeep Phukan
A magnetically separable nanocatalyst has been developed by the incorporation of CuI on the functionalized surface of cobalt ferrite nanoparticles for the synthesis of N-sulfonyl amidines in aqueous medium at ambient temperature.
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si

Engineering high-valence nickel sites in Ni3S2/Ni3Se2 architectures enabling urea-assisted hydrogen evolution reactions

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04318A, Paper
Taotao Ai, Miaomiao Bai, Weiwei Bao, Jie Han, Xueling Wei, Xiangyu Zou, Jungang Hou, Lizhai Zhang, Zhifeng Deng, Yuxin Zhang
Bifunctional Ni3S2@Ni3Se2 electrocatalysts were constructed for urea-assisted hydrogen evolution. In the HER/UOR two-electrode system, the heterogeneous interface modulates the electronic structure and thus improves the catalytic performance.
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si

Engineering in situ: N-doped porous carbon-confined FeF3 for efficient lithium storage

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04097J, Paper
Open Access
Jinlong Hu, Weijun Xu, Lingzhi Zhang
Achieving N-doped porous carbon-confined FeF3 with enhanced lithium storage performance via an innovative in situ engineering approach.
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si

In silico modeling enables greener analytical and preparative chromatographic methods

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04300F, Paper
Troy T. Handlovic, Daipayan Roy, Muhammad Qamar Farooq, Gabriel Mazzi Leme, Kevin Crossley, Imad A. Haidar Ahmad
Environmental impact of chromatographic separation at both analytical and preparative scale can be significantly reduced using In Silico Modeling.
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si

Single-layer 2D supramolecular-organic-framework-supported polyoxometalates: efficient selective oxidation of toluene in seawater under sunlight

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04480K, Paper
Xin-Long Ni, Yan Fan, Yi Luo, Xu Luo
Performing organic reactions in water, in particular in seawater under sunlight, is a desirable objective in chemistry because both are the most abundant and cheapest resources on earth. Herein, we...
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si

Single cobalt atom catalysis for the construction of quinazolines and quinazolinones via the aerobic dehydrocyclization of ethanol

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04928D, Paper
Xueping Zhang, Kai Xu, Yi Zhuang, Shihao Yuan, Yamei Lin, Guo-Ping Lu
It is still a significant and challenging for the synthesis of N-heterocycles through the aerobic dehydrocyclization of ethanol since ethanol is the largest renewable small molecule feedstock but with high...
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si

Biological production and simulated moving bed purification of streptothricin F from food waste digestate

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04026K, Paper
Xiaofang Zhou, Peiyi Li, Yuchen Sun, Zeyang Zhang, Chuanyi Yao, Qingbiao Li, Yuanpeng Wang
Globally, a significant amount of food waste is generated annually, representing a considerable potential resource.
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si

Crystalline/amorphous c-NiMo/a-NiMoOx nanoarrays for urea-assisted energy-saving H2 production in alkaline seawater

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05042H, Paper
Dongxue Guo, Yi Ping, Chuanjiao Wang, Changan Hou, Danhong Wang
Electrocatalytic seawater splitting is regarded as the most effective method for producing green hydrogen (H2), but it faces issues of high energy consumption and harmful chlorine evolution side reactions. Replacing...
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si

N–N atropisomer synthesis via electrolyte- and base-free electrochemical cobalt-catalysed C–H annulation

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04390A, Communication
Jiating Cai, Linzai Li, Chuitian Wang, Shi Qin, Yuanyuan Li, Si-Yan Liao, Shengdong Wang, Hui Gao, Zhi Zhou, Yugang Huang, Wei Yi, Zhongyi Zeng
An exogenous electrolyte- and base-free electrochemical cobalt-catalysed atroposelective C–H annulation has been established to construct N–N axially chiral isoquinolinones in excellent enantioselectivities and good yields.
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si

Photo-driven reduction/cyclization of nitroarenes via electron donor–acceptor complexes: a novel method for the acquisition of N-heterocycles

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04082A, Communication
Bin Sun, Chun Lv, Xiaohui Zhuang, Yan Xu, Haijing Song, Jiayin Wang, Zhaokang Zhang, Jiayang Wang, Can Jin
An EDA complex-based method for the reduction/cyclization of nitroarenes to obtain N-heterocycles with H2O as a clean by-product is presented.
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si

Active Hydrogen Tuning by Copper-Cobalt Bimetal Catalysts for Boosting Ammonia Electrosynthesis from Simulated Waster Water

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04120H, Paper
Chunqi Yang, Chang Liu, Jingwen Zhuang, Ziyan Yang, Aiping Chen, Yuhang Li, Chunzhong Li
Electrochemical nitrate reduction reaction (NO3RR) represents a promising approach to balance the nitrogen cycle, converting environmental pollutant NO3− to valuable ammonia (NH3). However, the whole reaction involves complex protons-coupled electron...
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si

High Efficiency Leaching of Valuable Metals from Waste Lithium-ion ternary Batteries under Mild Conditions Using Green Deep Eutectic Solvents

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04373A, Paper
Bo Li, Zhengfu Zhang, Chengping Li, Jinsong Wang, Rundong Wan, Jiangzhao Chen, Ying Liu, Yuejing Bin, xiaoping yang, Chongjun Bao, Shaohua Ju
Recently, the production and demand for lithium-ion batteries (LIBs) has increased owing to increasing number of electric vehicles and products. This surge has considerably increased spent LIBs, leading to environmental...
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si

Production of propyl 4-hydroxybenzoate via selective hydrogenolysis of lignin catalyzed by Ni/MFI-ns

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05260A, Paper
Lixia Li, Yinan Rao, Menghao Jiang, Jinxing Long
Selective conversion of lignin macromolecules into aromatic monomers is of great significance but remains a great challenge. Here, we present a metallic Ni supported on hierarchical multilamellar MFI nanosheets (MFI-ns)...
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si

Catalyst free PET and PEF polyesters using a new traceless oxalate chain extender

Green Chem., 2024, 26,11182-11195
DOI: 10.1039/D4GC02791D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kevin van der Maas, Daniel H. Weinland, Robert-Jan van Putten, Bing Wang, Gert-Jan M. Gruter
When producing PET the metal catalyst (typically Sb) remains in the polymer. This raises concerns as our food and the air we breathe is contaminated with PET microplastics. Here we report the production of metal-free PET using a small amount of DGO.
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si

Toward safer and more sustainable by design biocatalytic amide-bond coupling

Green Chem., 2024, 26,11147-11163
DOI: 10.1039/D4GC03665D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Elisabeth Söderberg, Kerstin von Borries, Ulf Norinder, Mark Petchey, Ganapathy Ranjani, Swapnil Chavan, Hanna Holmquist, Magnus Johansson, Ian Cotgreave, Martin A. Hayes, Peter Fantke, Per-Olof Syrén
We describe an exploratory approach to a concept of safer and more sustainable by design in biocatalytic amide bond synthesis.
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si

A spatially integrated electrochemical–thermal tandem reaction for continuous mild synthesis of propylene oxide

Green Chem., 2024, 26,11206-11215
DOI: 10.1039/D4GC03455D, Paper
Yuefeng Qiu, Peng Jiang, Wenkai Ye, Jiahao Hu, Bin Zhang, Tuo Ji, Liwen Mu, Xin Feng, Xiaohua Lu, Jiahua Zhu
A spatially integrated electrochemical–thermal tandem reaction generates propylene oxide at 1 atm using hydrogen, oxygen, and propylene as feedstock.
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si

Regulatable selective synthesis of benzofurans and coumarins from aryl propargyl ethers via an electrochemical tandem cyclization reaction

Green Chem., 2024, 26,11216-11221
DOI: 10.1039/D4GC03842H, Paper
Zhaoyue Feng, Xueyi Guan, Haiyang Ma, Yingsibing Fan, Ping Liu, Peipei Sun
A divergent protocol for the selective synthesis of benzofuran-2-carboxaldehydes and 3-organoselenyl-2H-coumarins from propargylic aryl ethers in the presence of dialkyl(aryl) diselenides under electrochemical reaction conditions was established.
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si

Photocatalytic acylation of lysine screened using a microfluidic-based chemical robotic system

Green Chem., 2024, 26,11238-11248
DOI: 10.1039/D4GC03562C, Paper
Zhanfeng Hou, Chuan Wan, Heming Jiang, Yuena Wang, Yun Xing, Jinpeng Wang, Zhihong Liu, Xiaochun Guo, Yuhao An, Wei Han, Rui Wang, Xinhao Zhang, Feng Yin, Zigang Li
In our work, we contribute to the photoredox catalytic lysine acylation in proteins and peptides. The optimal reaction conditions were obtained using a high-throughput microfluidic-based chemical robotic system and GPR model.
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si

Catalytic synthesis of renewable lubricant base oils with methyl oleate and aromatics

Green Chem., 2024, 26,11249-11258
DOI: 10.1039/D4GC03448A, Paper
Binbin Zhou, Nan Wang, Sibao Liu, Guozhu Liu
Aromatic-ester and cyclo-branched alkane renewable lubricant base oils were produced from methyl oleate and biomass-derived aromatics by alkylation and alkylation followed by hydrodeoxygenation (HDO).
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si

Visible light-induced strain-release transformations of bicyclo[1.1.0]butanes

Green Chem., 2024, 26,11083-11105
DOI: 10.1039/D4GC03193H, Tutorial Review
Qing-Bao Zhang, Feng Li, Bin Pan, Shanshan Zhang, Xiang-Guo Yue, Qiang Liu
This review aims to provide an overview on the recent visible light-mediated strain-release transformations of bicyclo[1.1.0]butanes. Prospects for future development of (aza)bicyclo[1.1.0]butanes in this fascinating field are outlined.
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si

Selective electrosynthesis of aldehydes at industrially relevant current densities via tandem electrochemical–chemical catalysis

Green Chem., 2024, 26,11290-11302
DOI: 10.1039/D4GC04536J, Paper
Ting Lin, Menglu Cai, Huijie Chen, Yiming Mo
A closed-loop tandem electrochemical–chemical catalysis system for aldehyde synthesis was developed, demonstrating a viable approach for the electrosynthesis of valuable intermediates under practical current densities with minimal waste electrolyte.
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si

Production of nanochitins via a shell biorefinery process for self-assembly applications as photonic films and Pickering emulsions

Green Chem., 2024, 26,11222-11237
DOI: 10.1039/D4GC02680B, Paper
Open Access
Xuhai Zhu, Fuyan Peng, Hui Li, Rongjun Lin, Rui Lu, Fang Lu
A simple, environmentally friendly, and flexible shell biorefinery process for integrated utilization of all NCh products in high-value applications, such as photonic films and Pickering emulsions.
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si

Substrate-controlled regioselective hydrophosphorylation of allenes to enable photocatalytic synthesis of alkenylphosphoryl compounds

Green Chem., 2024, 26,11272-11279
DOI: 10.1039/D4GC03588G, Paper
Tian-Ming Yang, Xin-Lu Fan, Wei Shi, Xuefei Zhao, Xu-Hong Hu
A visible-light-induced hydrophosphorylation of allenes with H-phosphine oxides is demonstrated to give a diverse range of alkenylphosphoryl compounds in a highly stereoselective and regioselective manner.
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si

Thermodynamically stable synthesis of high entropy alloys and efficiently catalyzed oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under base-free conditions

Green Chem., 2024, 26,11316-11327
DOI: 10.1039/D4GC04186K, Paper
Guangqiang Lv, Shan Liu, Xiaoyan Chen, Mengxin Chen, Yanjuan Wu, Yuji Gao, Shuai Wang, Furong Tao, Jingui Wang, Liwei Niu
In a completely non-alkaline aqueous system, a high-entropy alloy catalyst composed of FeCoNiCuGaPt activates O2 and H2O molecules to form hydroxyl radicals (˙OH) and efficiently oxidizes 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.
The content of this RSS Feed (c) The Royal Society of Chemistry




si

Effect of a phase transfer catalyst structure on the alkaline hydrolysis of poly(ethylene terephthalate)

Green Chem., 2024, 26,11125-11131
DOI: 10.1039/D4GC05070C, Communication
Open Access
Lee B. Anderson, Conall Molloy, Lorenzo Pedrini, Ian L. Martin, Stephen J. Connon
The evaluation of a library of phase transfer catalysts in the alkaline hydrolysis of polyethylene terephthalate revealed the key interplay between catalyst structure/properties and the reaction conditions.
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si

Augmentation of Pd-catalysed oxidative C–H/C–H carbonylation through alternating current electrosynthesis

Green Chem., 2024, 26,11177-11181
DOI: 10.1039/D4GC04569F, Paper
Haoran Li, Jiaqi Peng, Li Zeng, Linpu Zhou, Muhammad Shabbir, Feiran Xiao, Jiaxin Yuan, Hong Yi, Aiwen Lei
Unsymmetrical-waveform AC electrolysis facilitates Pd-catalysed oxidative C–H/C–H carbonylation. This methodology highlights the substantial benefits conferred by Pd-catalysed conversions in comparison to traditional DC electrolysis.
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si

A green and sustainable multi-enzyme cascade for the biosynthesis of 1,3-propanediamine from crude glycerol in vitro

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03777D, Paper
Daocheng Liao, Shiming Tang, Ying Lin, Suiping Zheng
This paper designs a novel multi-enzyme cascade reaction capable of efficiently synthesizing 1,3-propanediamine from glycerol in vitro.
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si

Development of a highly efficient electrocatalytic hydrogenation and dehalogenation system using a flow cell with a Pd tube cathode

Green Chem., 2024, 26,11328-11333
DOI: 10.1039/D4GC04617J, Paper
Hiroaki Tajima, Hideki Ishii, Shinsuke Inagi, Toshio Fuchigami
A novel flow and circulation electrolytic system has been developed for the highly efficient cathodic hydrogenation of unsaturated compounds and dehalogenation of various aromatic halides.
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si

Economic and environmental sustainability of bio-based HMF production and recovery from lignocellulosic biomass

Green Chem., 2024, 26,11340-11350
DOI: 10.1039/D4GC04270K, Paper
Yuyao Jia, Shraddha Maitra, Lavanya Kudli, Jeremy S. Guest, Vijay Singh
Transforming waste stream of biorefinery into high-value bioproducts.
The content of this RSS Feed (c) The Royal Society of Chemistry




si

Formaldehyde dehydrogenase SzFaldDH: an indispensable bridge for relaying CO2 bioactivation and conversion

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03745F, Communication
Boxia Guo, Xiuling Ji, Yaju Xue, Yuhong Huang
A novel formaldehyde dehydrogenase with outstanding reductive activity and kinetic properties was discovered for CO2 bioactivation and conversion.
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si

Review of carbon-based catalysts for electrochemical nitrate reduction and green ammonia synthesis

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04640D, Tutorial Review
Guanting Liao, Richard L. Smith Jr., Haixin Guo, Xinhua Qi
This work aims to review the latest developments in carbon-based electrocatalysts applied in electrocatalytic nitrate reduction, including pure carbon materials, heteroatom doping or metal-bonding catalysts, and carbon substrate-supported composites.
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si

Utilize rather than create: transforming phthalonitrile resin into N-rich hierarchical porous carbon for supercapacitor materials

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04103H, Paper
Yi Li, Qiancheng Liu, Qian Zhang, Xiaoxiao Li, Yang Yang, Pan Wang, Kui Li, Ying Li, Fei Zhong, Qi Liu, Yun Zheng, Xulin Yang, Peng Zhao
The “utilize rather than create” strategy employs the reaction product (RPH) as the precursor and the by-product (KCl) as the template for the synthesis of N-rich hierarchical porous carbon for high performance supercapacitor materials.
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si

Bio-derived solvent-based automated dispersive liquid–liquid microextraction for pretreatment of diamide insecticides in environmental water samples

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04467C, Paper
Jin Liu, Yuxin Wang, Rui Song, Yukun Yang, Li Li, Xu Jing
The automatic dispersive liquid–liquid microextraction based on bio-derived solvents achieved great environmental greenness, high-throughput operation, and low human error compared to the present sample pretreatment methods for diamide insecticides.
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si

EtOH-mediated cascade C(sp3)–H alkylation via aromatization-driven [1,6]-hydride transfer: green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indoles

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04534C, Paper
Yao-Bin Shen, Qian-Hao Zhuang, Xiao-Lin Wang, Xiao-De An, Bin Qiu, Tiesheng Shi, Jian Xiao
Unprecedented EtOH-mediated cascade C(sp3)–H alkylation reactions of 4-dialkylamino-indole-3-carbaldehydes have been realized for the green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indole derivatives.
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si

CO2 switchable solvents for sustainable dissolution, modification, and processing of cellulose materials: a critical review

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04032E, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Peter McNeice, Ben L. Feringa
CO2 switchable solvents provide a convenient and environmental method to dissolve and process cellulose.
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si

High-efficient green catalytic conversion for waste CS2 by non-noble metal cage-based MOFs: An access to high-valued thiazolidine-2-thione

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04541F, Paper
Wenyu Ding, Xinyu Tang, Sheng Jin, Zhao Li, Dongwei Xu, Xiaomin Kang, Zhiliang Liu
Green and effective disposal of Carbon disulfide (CS2) waste into high-valued chemicals under mild conditions is meaningful and challenging. Herein, a novel 3D cluster-based metal-organic framework (MOF) {(Me2NH2)2[Co3(µ3-O)(XN)(BDC)3]∙4DMF∙5MeOH}n (compound 1)...
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si

Mechanoenzymatic Hydrolysis of Cotton to Cellulose Nanocrystals

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05113K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sandra Kaabel, Inge Schlapp-Hackl, Eero Kontturi, Mauri A. Kostiainen
Solid-state mechanoenzymatic approaches for the production of cellulose nanocrystals from cotton were examined using three commercially available cellulase systems from Trichoderma reesei, Aspergillus niger and a Cellic CTec2 cellulase blend....
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Electron-mediator-free efficient photocatalytic regeneration of coenzyme NAD(P)H via direct electron transfer using ultrathin Bi2MoO6 nanosheets

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC05207B, Paper
Yao Chai, Zirui Pang, Heng Jiang, Chi Chung Tsoi, Liang Wan, Yu Du, Huaping Jia, Yujiao Zhu, Detao Liu, Fengjia Xie, Guangya Zhou, Xuming Zhang
The direct electron transfer mechanism of single-layer Bi2MoO6 ultrathin nanosheets promotes the efficient regeneration of photocatalytic coenzyme NAD(P)H.
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si

Kalasi Vunte Kaladu Sukham (1961)

Always open to challenges, NTR proved his worth as an actor and also brought certain glamour to the otherwise deglamourised role.




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It’s all about getting the basics right: Amla



  • Indian Premier League

si

Kings wilt in a massive chase under pressure

Kohli and Gayle send the visitors on a leather hunt in a match reduced to 15-overs-a-side by rain.



  • Indian Premier League

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Kotla assignment was my toughest: Mudgal



  • Indian Premier League

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Great to be part of my hero Sanju’s team in the IPL: Basith



  • Indian Premier League

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Data | Run-fest IPL 2023: Highest run-rate, most sixes and boundaries per game across all seasons

Rule changes and team tactics have made “power hitting” a mainstay of T20 cricket




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We have to put our best foot forward and be sensible: Lara

On the pitch, Sunrisers Hyderabad head coach Brian Lara said that there was nothing negative to be said about it. “It would not be one-sided, it has been pretty fair so far,” he said.