Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01483D, Communication

Xuefeng Zou, Qin Hu, Hengxiu Yang, Feng Chen, Bin Xiang, Xinyue Liang, Qibing Wu, Hujun Shen
Here we report an ultra-effective, reliable pathway to reduce GO into graphene by an about 4-seconds flame-assisted microwave process. A holey graphene with a C/O atom ratio of 31.1, a...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00866D, Paper

Jun Tao, Yue Li, Min Liu, Zi-Shuo Yao
Hofmann-type spin-crossover (SCO) frameworks attract much attention due to their predictable structures and diverse SCO behaviours. In this paper, we report two isostructural two-dimensional (2D) Hofmann-type SCO frameworks [FeII(ppe)2MII(CN)4]·3H2O (ppe...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper

Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper

María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01321H, Paper

Tatiane Strelow Lilge, Adriano Borges Andrade, Claudiane dos Santos Bezerra, Giordano Frederico da Cunha Bispo, Zélia Soares Macedo, Mario Lucio Lúcio Moreira, Mário Ernesto Giroldo Valerio
Inorganic hybrid materials are promising applications in absorbers and photon harvesting of solar irradiation, such as DSSC cell photoanodes. Moreover, the investigation of the interaction between the photoanode constituent materials...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01054E, Paper

Sankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra Jana
MnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01058H, Paper

Magdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-Fitas
Dilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00863J, Frontier

Papri Sutar, Tapas Kumar Maji
In this article, we reviewed recent advances in coordination-driven polymeric gels and highlighted their design and applications in various fields.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00033G, Paper

Xiao-Quan Zhu, Wen-Hai Cao, Shao-Dong Su, Xin-Tao Wu, Tian-Lu Sheng
The SMM behavior weakens until its disappearance with the substituent changing from Br, H to OMe in the quinonoid-bridged dicobalt compounds [(N₄Co)₂LX](ClO₄)₂, (X = H, Cl, Br, and OMe).
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04755G, Paper

Xuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang Yin
The electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01227K, Communication

Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka
A triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01240H, Paper

Zihao Wang, Zongzhe Li, Marcus Ng, Phillip J. Milner
We describe the mechanochemical, solvent-free synthesis of metal–organic frameworks using liquid organic base for the first time.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01510E, Paper

Nikita V. Shvydkiy, Egor A. Dlin, Klimentiy V. Ivanov, Anastasiya G. Buyanovskaya, Yulia V. Nelyubina, Dmitry S. Perekalin
The reaction of NiBr₂ with 3-hexyne provides new access to various cyclobutadiene nickel complexes.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00444H, Paper

Jingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping Wang
Three sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01034K, Paper

Katherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-Dias
A new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01295E, Paper

Rui Feng, Rong Wu, Yuncheng Cao, Xiaolin Guo, Xu Ma
Molybdenum selenide has great potential for degradation of water pollutants，but its performance is limited by the active sites and recombination of photogenerated electron-hole pairs. In this study, amorphous Co-doped MoSex...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01401J, Paper

Zhenhong Wei, Xiuli You, Jiaojiao Yao
Organic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00452A, Paper

Shuvankar Dey, Anshu Kumar, Pradip Mondal, Krunal M. Modi, Deepak Chopra, Vinod K. Jain
An oxacalix[4]arene-Ce (III) complex viz. L-Ce(III) has been introduced for selective detection of As (V) and Cr (VI) oxyanions in aqueous medium. Binding mode of L-Ce(III) + AsO₄^3-/ CrO₄^2- was...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00826E, Paper

Kierstyn P. Anderson, Mary A. Waddington, Gary J. Balaich, Julia M. Stauber, Nicholas A. Bernier, Justin R. Caram, Peter I. Djurovich, Alexander M. Spokoyny
Bromination of the luminescent borane, anti-B₁₈H₂₂, via electrophilic substitution using AlCl₃ and Br₂, yields the monosubstituted derivative 4-Br-anti-B₁₈H₂₁ as an air-stable crystalline solid.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00168F, Paper

Daniel Baecker, Benjamin N. Ma, Jessica Sagasser, Lukas Schultz, Carina Hörschläger, Maria Weinreich, Lucy Steiner, Brigitte Kircher, Ronald Gust
Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) were synthesized and characterized as necroptosis and ferroptosis inducers using the acute myeloid leukemia cell line HL-60.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper

Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication

Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04501E, Paper

Catiúcia Rodrigues Marcelino Oliveira Matos, Henrique Silva Jr, Dayenny D’Amato, Guilherme Guedes, Glaucio Braga Ferreira, Odivaldo Cambraia Alves, Filipe Barra de Almeida, Sergio Pinheiro, Acácio Souza, Flavio Garcia, Célia Machado Ronconi
The Cu(II) heptanuclear complex (Cu7atac) was synthesised using the hydrated amino acid ligand 2-(5-amino-1H-1,2,4-triazol-3-yl)acetic acid (Hatac.H2O). Single crystal X-ray diffraction analysis revealed a μ3-hydroxo bridged Cu(II) heptanuclear complex, consisting of...
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01063D, Paper

Fabiano S Santos, Carolina H. da Silveira, Fabio Souza Nunes, Daniele Ferreira, Henrique Victória, Klaus Krambrock, Otávio Augusto Chaves, Fabiano Severo Rodembusch, Bernardo Almeida Iglesias
New isomeric tetra-cationic porphyrins containing peripheral [Pd(bpy)Cl]+ units attached at pyridyl substituents were synthetized and fully characterized. The porphyrins present an intense Soret band located in the blue spectral region...
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00848F, Paper

Mikaela M. Pyrch, Jennifer L. Bjorklund, James M. Williams, Daniel L. Parr IV, Sara E. Mason, Johna Leddy, Tori Z. Forbes
Crystallization of neptunyl(V) tetrachlorides over neptunyl(VI) species occurs simultaneously with charge assisted hydrogen bonding in our solid state materials, which we explored by DFT calculations, cyclic voltammograms, and Raman spectroscopy.
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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00990C, Paper

An-Qi Xue, Yang-Yu Liu, Jia-Xin Li, Yan Zhang, Yin-Shan Meng, Wen-Hua Zhu, Yi-Quan Zhang, Hao-Ling Sun, Fei Wang, Guan-Xia Qiu, Lu-Yu Liang, Xiang Wang, Song Gao
Differential magnetic properties were observed for triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compound.
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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01084G, Communication

Thines Kanagasundaram, Carsten Sven Kramer, Eszter Boros, Klaus Kopka
Radiolabelled fluorescent dyes are decisive for bimodal imaging and currently in demand for scintigraphic and optical imaging. This powerful method allows the combination of nuclear imaging (e.g. SPECT-imaging) and optical...
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