mi Shiv Kumar vs Office Of The Chief Minister Delhi on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (offline) RTI application dated 31.05.2023 seeking the following information: Page 1 of 3 "1- द ल सरकार के SC/ST DEPARTMENT 2018,2019,2020,2021,2022 तक कतना फ ड पछले चार साल म कतनी योजनाओंपर खच कया है उसक" पण ू जानकार द जाये 2- द ल सरकार ने 2014 से 2022 तक अपने व'ापन पर कतना फ ड द ल व ् द ल से बाहार खच कया है उसक" जानकार द जाये 3- द ल के मु+यमं ,ी ने JANUARY 2014 से 2023 JANUARY तक द ल से बाहार के दोरो पर कतना फ ड खच कया है उसक" जानकार द जाये 4- द ल सरकार ने पछले 8 साल म वधायक. को गाडी खर दने के 0लए कतना फ ड दया है उसक" जानकार द जाये" Full Article
mi R S Bhati vs Office Of The Chief Minister Delhi on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (offline) RTI application dated 06.02.2023 seeking the following information: Page 1 of 7 " नवेदन यह है क नेह वहार वाड मु तफाबाद वधान सभा म कर ब चार वष पहले सीवर क" लाईन डाल गई थी और अब सीवर क" लाइन से घर-घर तक सीवर कने*शन का काम चल रहा है । सीवर लाइन के -.येक मैन होल म घर0 म कने*शन करने के 1लए चार चीनी के पाइप लगाए गए थे। इ3ह ं पाइप0 म घर0 के कने*शन जोड़ने थे। ले कन उन चीनी पाइप0 से कने*शन नह ं 8दए जा रहे ह9 और म9ने होलो म कने*शन दे ने के 1लए नये सरु ाख करके पाईप लगाये जा रहे ह9 और नये सरु ाख0 क" मर;मत भी नह ं क" जा रह है और जो पहले से ह -.येक मैन होलो म चार पाईप लगाये गये ह9। उन पाईप0 से 1स वर ओवर=लो होने पर पानी अ3दर ह अ3दर मकान0 क" नींव म जाएगा। और कने*शन के 1लये अब नये पाईप डाले जा रहे ह9 वह रोड से एक से डेढ़ फुट गहराई पर ह9 और जो मकान नीचे पड़ गए ह9 उनका 1सवरे ज का पानी म9न होल म नह जायेगा। और मैन होल म जो नए सरु ाख कये गये है उनसे मैनहोल बहुत कमजोर हो गये है अतः Aीमान जी से नवेदन है क R.T.I Act न;न1लBखत सच ू ना दे ने क" कृEया करे । Full Article
mi Manish Agarwal vs Military Engineer Services on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (online) RTI application dated 24.04.2023 seeking the following information: Querry is in reference to Chief Engineer Central Command. Index No 5-28 -Central Command. For renewal of Security Deposit of FDR wherein many letters were sent for sending to bank FDRs for renewal. However, no reply has been received. Letters dated 08.08.2022, No 4501-244 dated 08.08.2022, letter No 4501-245 dated 06.10.2022, dated 15.11.2022 & dated 20.12.2022 & letter No 4501-248 datet25.01.2023, and 20.03.2023. FDR bearing No.7 15474 Folio 127180-98 dt.25.9-98 for Rs.60,000.00, (Maturity Date :3-7-2001 FDR bearing No.715475 Follo 127198/98) dated 23.9.98 for Rs.60,000.00. Full Article
mi Trump îl nominalizează pe veteranul și prezentatorul Fox News, Pete Hegseth, pentru funcția de secretar al apărării By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:24:11 +0000 Președintele ales Donald Trump a surprins observatorii politici marți seară prin nominalizarea prezentatorului Fox News, Pete Hegseth, pentru funcția de secretar al apărării. „Pete și-a petrecut întreaga viață ca un războinic pentru trupele noastre și pentru țară,” a declarat Trump într-un comunicat. „Pete este dur, inteligent și un adevărat susținător al politicii America First. Cu ... The post Trump îl nominalizează pe veteranul și prezentatorul Fox News, Pete Hegseth, pentru funcția de secretar al apărării appeared first on Forbes Romania. Full Article Actualitate Afaceri
mi Florin Talpeș: grupul Bitdefender a avut venituri nete de peste 391 mil. dolari și profit operațional de 85 mil. dolari în 2023, cele mai mari din istorie By www.forbes.ro Published On :: Wed, 13 Nov 2024 16:55:16 +0000 Grupul Bitdefender, cea mai importantă companie din domeniul tehnologiei cu sediul central în România, a înregistrat venituri nete de 391,9 milioane de dolari, în creștere cu 16% comparativ cu anul anterior, și un profit operațional ajustat (EBITDA) de 85 de milioane de dolari, cu 21,7% mai mare decât în 2022. Florin Talpeș, CEO și cofondator ... The post Florin Talpeș: grupul Bitdefender a avut venituri nete de peste 391 mil. dolari și profit operațional de 85 mil. dolari în 2023, cele mai mari din istorie appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii Tech
mi 'Priyanka Chopra was out...': Arjun Kapoor talks about his terrific chemistry with Ranveer Singh in Gunday By www.dnaindia.com Published On :: Wed, 13 Nov 2024 16:22:00 GMT Talking about Priyanka Chopra, Arjun admitted that she was already a big star when they made the film. Full Article Entertainment
mi Chennai Rains: IMD predicts heavy showers for 2 days in Tamil Nadu; Are schools, colleges closed today? By www.dnaindia.com Published On :: Thu, 14 Nov 2024 02:35:00 GMT The city experienced heavy rainfall on Wednesday night, and the IMD bulletin indicates that several isolated areas of the capital are expected to see heavy downpours on Thursday. Full Article India
mi Meet Vivek Ramaswamy, Harvard-Yale graduate, son of immigrants, now part of Donald Trump's cabinet, his net worth is... By www.dnaindia.com Published On :: Thu, 14 Nov 2024 01:55:00 GMT Born in the US to Indian immigrant parents, Ramaswamy gained wealth through his biotech company Full Article World
mi Synthesis of 10B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and 10BF3 By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00176A, Research ArticleWeihua Qiu, Jide Zhu, Rencai Tao, Kai Yang, Qiuling SongHerein we present a practical approach for preparing 10B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and 10BF3 (the primary source of boron-10) in the presence of chlorosilane.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Synthesis of multisubstituted carbazol-4-amines from tetrahydrocarbazol-4-one oximes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00386A, Research ArticleJiahua Wang, Dandan Gao, Aanuoluwapo O. Oyejobi, Na Ji, Xiang-Ying Tang, Long WangA sequential synthetic method toward 1,3-disubstituted carbazol-4-amines is reported and an interesting C–S metathesis process is disclosed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi DBU-catalyzed substitution-controlled synthesis of oxa[3.3.1] bridged ring and naphthylamine derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00012A, Research ArticleShiyu Xu, Zhihui Sun, Pengyutian Liu, Yuanlin Wei, Fan Sun, Man Zhao, Ying Wang, Ming Zhang, Guofeng Li, Hong LiangA switchable cascade cyclization reaction of ortho-alkynyl arylketones with amines has been developed, where the different reaction pathways are controlled by the substituent on the α-carbon of in-situ-generated ortho-alkynyl arylaldimines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Regio- and stereo-selective synthesis of β-phenylthio enamides via intramolecular 1,2-thiol migration By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D3QO02078A, Research ArticleYunqing Zhuang, Jin Zhang, Kai Yang, Gehua Bi, Xin Huang, Weimin ZhangAn efficient and novel method for the direct synthesis of β-phenylthio enamides via intramolecular 1,2-thiol migration has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Vaska's complex–PMHS combination enabled mild and chemoselective reduction of sulfoxides to sulfides with low catalyst loading By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00312H, Research ArticleFang-Fang Xu, Zhong-Lei Ruan, Pei-Qiang HuangWe report a highly efficient, versatile, and chemoselective method for the catalytic reduction of sulfoxides to sulfides under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium/cobalt co-catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00305E, Research ArticleChen He, Zhiyong Song, Wei Yao, Rui Lin, Yuanhong MaHerein, we report a decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium and cobalt co-catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Electrochemically dehydrogenative C(sp2)–H/S–H cross-coupling: efficient synthesis of ortho-aminophenyl thioglycoside derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00171K, Research ArticleLi-Yan Hu, Li Zhu, Shen-Yuan Zhang, Yu-Xin Guo, Yuan Li, Jie Zhu, Lei WuA method has been reported for synthesizing aryl thioglycosides through direct electrocatalytic dehydrogenative C(sp2)–H/S–H cross-coupling.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Iodine-catalyzed intermolecular 1,2-thio (seleno)amination of alkenes with 1,2,3-triazoles and disulfides (diselenides) in air By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00246F, Research ArticleJian Ji, Xuwen Chen, Zongjing Hu, Cong Guan, Jinhua Liu, Yaqi Deng, Shunying LiuIodine-catalyzed 1,2-thio (seleno)amination of alkenes via direct N- and C-centered radical cross-coupling was established to elicit highly regioselective β-triazolized thioalkyl compounds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Electrochemical switching in mechanically interlocked molecules (MIMs) By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00061G, Review ArticleAyush Bhadani, Murugavel KathiresanMechanically interlocked molecules (MIMs) which include rotaxanes and catenanes are formed by the mechanical linking of two or more components and has the ability to switch between different states in the presence of an external stimuli.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Three-component Friedel–Crafts-type difunctionalization of ynamides with (hetero)arenes and iodine(III) electrophile By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00489B, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jun Kikuchi, Toya Nagata, Shingo Ito, Naohiko YoshikaiA three-component Friedel–Crafts type difunctionalization of ynamides with an iodine(III) electrophile and electron-rich (hetero)arenes has been developed, enabling regio- and stereoselective synthesis of densely functionalized enamides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Correction: Stereodivergent and enantioselective total syntheses of isochaetominines A–C and four pairs of isochaetominine C enantiomers: a six-step approach By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO90034K, Correction Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Zhong-Yi Mao, Hui Geng, Tian-Tian Zhang, Yuan-Ping Ruan, Jian-Liang Ye, Pei-Qiang HuangTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Sulfamide instead of urea in Biginelli reaction: from black box to reality By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2155-2160DOI: 10.1039/D3QO01926H, Research ArticleAlexander Yu. Lyapunov, Andriy V. Tarnovskiy, Sergey Yu. Boron, Eduard B. Rusanov, Galyna P. Grabchuk, Dmytro M. Volochnyuk, Serhiy V. RyabukhinThe scope and limitations of the classical Biginelli reaction have been expanded to principally novel substrates: sulfamide and its monosubstituted analogues.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Unprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2344-2350DOI: 10.1039/D3QO01955A, Research ArticleLinge Huai, Li Zhang, Zhentao Wang, Yewen FangN → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized via the reaction of N-vinylimides with alkyl radicals derived from alkyl silicates.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Dynamic kinetic resolution of α-F-β-ketone amides (esters) via Ir/f-diaphos-catalyzed asymmetric hydrogenation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2201-2207DOI: 10.1039/D4QO00125G, Research ArticlePengtao Yang, Dingguo Song, Lingxin Chen, Xianghua Zhao, Yirui Chen, Feiyang Shen, Fei Ling, Weihui ZhongHighly reactive and highly stereoselective asymmetric hydrogenation of α-F-β-ketone amides (esters) via Ir/f-diaphos-catalyzed dynamic kinetic resolution is reported.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Synthesis of enantiopure 1,2,3-triazolylidene-type mesoionic carbene (MIC) conjugate acids featuring a rigid bicyclic scaffold By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2178-2181DOI: 10.1039/D4QO00269E, Research ArticleVojtěch Dočekal, Mohand Melaimi, Simona Petrželová, Jan Veselý, Xiaoyu Yan, Guy BertrandChiral NHCs have found numerous applications as ligands for transition metals and in their own right for asymmetric catalysis. We report a synthetic route from L-malic acid to enantiopure 1,2,3-triazoliums with the chiral center in a fused ring.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Rhodium-catalyzed C–C bond alkenylation and arylation of α-branched N-sulfonyl amines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2182-2188DOI: 10.1039/D3QO02140H, Research ArticleLun Xu, Yucheng Liu, Hang Shi, Lun LiIn this work, we described a rhodium-catalyzed C–C bond cleavage of α-branched amines via β-carbon elimination, then formed a five-membered rhodacycle intermediate, which can be captured by styrene(alkenylation) or silane(arylation).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Selective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2313-2318DOI: 10.1039/D4QO00116H, Research ArticleZhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong XueThe selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Electron donor–acceptor complex photoactivation for deaminative alkynylation, alkenylation and allenylation: a comprehensive study By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2231-2240DOI: 10.1039/D4QO00177J, Research ArticleRomain Lapierre, Lina Truong, Matthieu Hedouin, Hassan Oulyadi, Bruno Schiavi, Alexandre Jean, Philippe Jubault, Thomas PoissonHerein, we disclose our study toward photoinduced deaminative alkynylation, alkenylation and allenylation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Frustrated Lewis pair chemistry of alkynes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2375-2396DOI: 10.1039/D4QO00217B, Review ArticleJing Guo, Maying Yan, Douglas W. StephanThis review is focused on the chemistry of frustrated Lewis pairs (FLPs) with alkynes and surveys the range of stoichiometric and catalytic reactions enabled by this concept.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Regioselective electrochemical cascade C–H sulfonylation–bromination of indolizines to access difunctionalized indolizines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2306-2312DOI: 10.1039/D4QO00035H, Research ArticleWenxuan Jiang, Xiang Liu, Chuanying Zhu, Meiyi Chen, Weidan Li, Hua CaoRegioselective electrochemical C–H sulfonylation–bromination between indolizines, sodium sulfinates, and KBr has been established in an undivided cell, in which KBr serves as both the brominating agent and electrolyte.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Electrochemical remote C(sp3)–H thiocyanation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2283-2288DOI: 10.1039/D4QO00032C, Research ArticleXinyu Pang, Hui He, Xiangrui Meng, Linbao Zhang, Shaofei Ni, Ming Li, Weisi GuoAn electrochemical thiocyanation of distal C(sp3)–H bonds based on amidyl radical-mediated 1,5-HAT has been developed. The transformation is highly site-selective and compatible with primary, secondary, and tertiary sulfonamides, and bioactive derivatives.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2326-2331DOI: 10.1039/D4QO00064A, Research ArticleTing-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping DengAn efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Catalytic intermolecular hydrofunctionalizations of ynamides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2351-2374DOI: 10.1039/D4QO00301B, Review ArticleYing-Ying Zhao, Yu-Jing Jia, Yan-Cheng HuThis review carefully summarizes the advances achieved in catalytic hydrofunctionalization of ynamides and is categorized by the bond formation type including C−C, C−X, C−O, C−N, C−S, C−P, C−Si, and C−Ge bonds.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Contributors to the Organic Chemistry Frontiers Emerging Investigator Series 2022–2023 By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2149-2154DOI: 10.1039/D4QO90025A, ProfileThis profile article showcases researchers who have contributed an article to the Organic Chemistry Frontiers Emerging Investigator Series.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Selective deletion of one carbon atom from C60 through benzylamine mediated reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00449C, Research ArticleYaqiong Wang, Yiran Wu, Yuming Yu, Jie Su, Yi Qiu, Liangbing GanBenzylamine selectively adds to one of the two carbonyl groups on the 9-membered orifice to form an N,O-aminal moiety. Subsequent oxidation and hydrogen atom transfer lead to a decarboxylation process and formation of a nor [59]fullerene derivative.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00351A, Research ArticleFei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng ZhuLovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Visible-light Induced [1, 3]-Brook Rearrangements of α-Ketoacylsilanes and Its Subsequent Trapping in a Tandem Annulation with 1, 3, 5-Triazinanes and Azomethine Imines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00463A, Research ArticleZhong Zhang, Sirui Wu, Yuqiao Zhou, Bao-Lin Li, Siyue Xiao, Xiaohu Zhao, Zhipeng YuAn unusual visible light-induced [1, 3]-Brook rearrangement of α-ketoacylsilanes for cascade cyclization with 1,3,5-triazinanes and C,N-cyclic azomethine imines has been developed under catalyst-free and mild reaction conditions. The strategy offers...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Concise synthesis of succinimide-fused densely 1,3-cyclohexadienes via Co-catalyzed [2+2+2] cycloaddition of 1,6-diynes and maleimides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00435C, Research ArticleJinhui Cai, Kaili Cen, Ziyi Zhai, Yuan Liu, Jiahao Wei, Mixia Ouyang, Guojun He, Shuyu Huang, Feng ZhaoHerein, we report a new route towards succinimide-fused densely 1,3-cyclohexadienes through the reaction of 1,6-diynes with electron-deficient alkenes under cobalt catalysis. This method shown high efficiency, wide substrate scope, good...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi NBN/BNB-doped phenalenyl homo- and heterodyads: structural uniformity but optoelectronic diversity By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00468J, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alexander S. Scholz, Thomas Froitzheim, Michael Bolte, Hans-Wolfram Lerner, Jan-M. Mewes, Matthias WagnerPhenylene-bridged homo- and heterodyads of NBN- and BNB-phenalenyls were synthesized. The heterodyads show ambipolar redox character and aggregation-induced emission in the solid state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Base- and metal-free visible-light driven site-selective α-C(sp3)–H functionalization reaction of glycine derivatives with hydroxamic acid derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00425F, Research ArticleShiyun He, Hongying Fan, Xue Zhang, Meiling Ye, Jian Chen, Jinyu Hou, Tianle Huang, Li Guo, Guanghui Lv, Yong WuA visible-light-mediated radical–radical cross-coupling reaction between hydroxamic acid and N-phenyl glycine derivatives under base and metal free conditions is reported. A series of unnatural amino acids and peptides were obtained in good to excellent yields with good chemo-selectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi A retro-Mannich mediated transformation of Morita–Baylis–Hillman ketones to saturated imidazo[1,2-a]pyridines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00352G, Research ArticleSachin Sharma, Ajit Kumar Jha, Srinivasan EaswarTwo fruits felled with one stone! – a proof of mechanism and a synthetic method that delivers a privileged heterocyclic motif.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00317A, Research ArticleGuohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin YinAmine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Photochemical [2 + 2 + 1] annulation of 2-vinyloxy arylalkynes with bromomalonates via energy transfer By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00249K, Research ArticleShuo Tang, Jiupeng Liu, Min Zhang, Dan Wang, Yong Wang, Jingjing Zhao, Pan LiA transition-metal-free, oxidant-free and base-free photochemical [2 + 2 + 1] radical annulation of 2-vinyloxy arylalkynes with bromomalonates has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Expedient deaminative phosphorylation and sulfonylation of benzylic tertiary amines enabled by difluorocarbene By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00412D, Research ArticleChengbo Li, Yu Guo, Jianke Su, Xinyuan Hu, Qingqing Xuan, Qiuling SongA deaminative functionalization of aliphatic tertiary amines via the cleavage of C(sp3)–N bonds under transition metal-free conditions was disclosed, which goes through SN2 reaction with various phosphorus and sulfur nucleophiles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Diverting the Mannich reaction to access 2,2-disubstituted indolin-3-ones by merging 1,2-aryl migration and copper-catalyzed aerobic oxidation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00481G, Research ArticleJia-Chen Xiang, Yu-Die Wang, Peng Yuan, Hui-Min Zhu, Tong Lei, An-Xin Wu, Zhixin LiaoThree typical substrates for the Mannich reaction, p-anisidine, aldehyde, and a nucleophile, did not afford the predictable linear Mannich base under an aerobic copper oxidation condition, but rendering a 2,2-disubstituted indolin-3-one product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Integrating continuous flow reaction and work-up: chiral amine resolution, separation and purification using a novel coalescing filter system By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Accepted ManuscriptDOI: 10.1039/D4RE00442F, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Bethan May Rowley, Lisa Alice Thompson, Luke Power, James Daglish, Emma Parks, James Birbeck, Stephen P Marsden, Nikil Kapur, John BlackerTo maximize the benefits of a continuous flow reaction, a continuous work-up is also needed. Herein, we present a process design and novel equipment for a continuous amine resolution reaction,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Contribution of an instructional module incorporating PhET simulations to Rwandan students' knowledge of chemical reactions, acids, and bases through social interactions By pubs.rsc.org Published On :: Chem. Educ. Res. Pract., 2024, Advance ArticleDOI: 10.1039/D4RP00105B, PaperJean-Baptiste Ndagijimana, Jeannette Musengimana, Henriette Mushimiyimana, Evode Mukama, Olivier Habimana, Paulin Manirakiza, Jean Claude Dushimimana, Jean Pierre Alpha Munyaruhengeri, Samia Khan, Elizabeth LakinTo cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
mi Germany opens doors to skilled Indians amid global visa cuts By www.thehindu.com Published On :: Thu, 14 Nov 2024 08:00:00 +0530 The number of skilled Indian workers in Germany has increased to 1.3 lakh from 23,000 a decade ago Full Article Data
mi IIT Kharagpur-led study says tropical rainforests could survive global warming By www.thehindu.com Published On :: Thu, 14 Nov 2024 08:04:06 +0530 The study, published online in the Elsevier journal, was conducted on records of rainforests in sediments from Gujarat’s Vastan coal mines deposited in coastal lagoons around 56 million years ago Full Article Science
mi CPI(M) Kerala secretary M.V. Govindan backs E.P. Jayarajan amid autobiography controversy By www.thehindu.com Published On :: Wed, 13 Nov 2024 13:19:33 +0530 Govindan says CPI(M) does not require members to seek prior permission to write a book, though he emphasised that consultation with the party should occur before publication Full Article Kerala
mi Centre releases ₹266.8 crore under 15th Finance Commission grants for rural local bodies in Kerala By www.thehindu.com Published On :: Wed, 13 Nov 2024 15:53:26 +0530 Allocation represents second instalment of untied grants for 2024-25, and is meant for all eligible district panchayats, block panchayats and gram panchayats in Kerala Full Article Kerala
mi Swami AI chatbot to improve Sabarimala pilgrimage experience By www.thehindu.com Published On :: Wed, 13 Nov 2024 19:26:18 +0530 Full Article Kerala
