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Structural phase transition drives outright photoluminescence quenching and dielectric duple bistable switching

Inorg. Chem. Front., 2024, 11,2290-2299
DOI: 10.1039/D4QI00303A, Research Article
Open Access
Zhi-Jie Wang, Ming-Jing Shen, Zhi-Peng Rao, Pei-Zhi Huang, Meng-Meng Lun, Bo-Wen Deng, Jun-Yi Li, Chang-Feng Wang, Hai-Feng Lu, Da-Wei Fu, Yi Zhang
(TECA)PbBr3 and (TEBA)PbBr3 have a wide range of photoluminescence signals and undergo coupling of the structural phase transition and photoluminescence quenching.
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sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds

Inorg. Chem. Front., 2024, 11,2312-2318
DOI: 10.1039/D4QI00178H, Research Article
Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, Wen-Xiong Zhang
The reaction of rare-earth azametallacyclopentadienes with terminal alkynes provides rare-earth metallacycles with cumulated double bonds in three steps: alkynyl C–H bond activation, sp2–sp cross-carbanion coupling and subsequent isomerization.
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Electrodeposited Superaerophobic Nickel Catalyst on Pencil-Drawn Paper: A Novel Approach for Highly Efficient and Stable Hydrogen Evolution

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00101J, Research Article
Qian Sun, Xiaoyu Hao, Tianyi Zhang, Zelin Ma, Kui Hu, Ming Yang, Xiaolei Huang, Xuqing Liu
Electrocatalytic water splitting stands at the forefront of advancing renewable energy technologies. A critical challenge in this realm is the detrimental effect of gas bubble adhesion on electrode surfaces, which...
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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00386A, Research Article
Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
Two multifunctional fibrate-Pt(IV) prodrugs, 1 and 3, bearing lipid-modulating agents, exhibited impressive anticancer activity by triggering ferroptosis and apoptosis.
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Indian rice exports get delayed at ports as Customs officials hold up consignments

Exporters say they incur $70/tonne additional costs; Customs officials playing safe to verify if shipments are white or parboiled rice




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Crude oil up on fears of supply disruption

Market players feel that there could be escalation in tension in West Asia following the recent developments in the region




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Your cuppa to cost more as coffee roasters set to hike prices

Auction prices have more than doubled since the beginning of the year as domestic prices tail global trend




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Shift toward EVs could disrupt global oil market: International Energy Agency report

As China's rapid switch to electricity plays a significant role in disrupting the oil market, oil companies find they can sell more of their product to India




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Fuel price update: Jet fuel sees 3.3% hike; commercial LPG rates rise by ₹62

In contrast, domestic LPG rates remain unchanged at ₹803 for a 14.2-kg cylinder




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Growing up in the times of air pollution

High levels of pollution put children at the risk of getting viral/pneumonia infections 




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No turning back on the biotech super highway

Industry experts call for support to firms pursuing cutting-edge technologies as they forge ahead 




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Dial M for mental health support and ring-in resilience

From workplace woes to societal pressures, it’s time mental health became a priority




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UPL recognised as top patent applicant in agro-chemical research

This recognition comes from the Global Innovation Index (GII) 2024, which annually ranks the world’s economies based on their innovation capabilities




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3F Oil Palm partners Karnataka horticulture department to support growers

The company said this partnership will provide farmers with access to advanced agricultural technologies, training programs, and essential resources to enhance productivity and support Karnataka’s growing horticultural sector




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Stubble burning incidents drop by a half, but UP, Rajasthan have higher cases

Data also show that Uttar Pradesh had 17 per cent rise in number of stubble burning incidents at 1,288 against 1,102 year-ago and Rajasthan 9 per cent up at 1,072 from 982.




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Fertilizer sales hold steady as imports fall, production up 2% in H1

Government controls fertilizer sales, imports drop significantly, concerns raised over availability and pricing impacting farmers and production targets




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Dhanuka Agritech Q2 net up 15.5% at ₹117.52 cr on higher sales

“The sowing season has been strong, with substantial acreage in key crops as we anticipated. The forecast of a normal monsoon has supported a robust demand trajectory” said Mahendra Kumar Dhanuka




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Two-day NAARM meet on sustainable agri start-ups from November 12

A-Idea is a technology business incubator promoted by the NAARM




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UPL’s Q2 net losses widen to ₹443 crore on pricing impact

The company reported a net loss of Rs ₹443 crore for the September quarter against a loss of Rs ₹189 crore in the same period last year




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Indian crop input firms upbeat on rabi season prospects on higher reservoir levels, soil moisture

Sector witnessing good demand for commodity and speciality fertilizers




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Airlines, insurance companies may relook at disruption cover

Over the last seven days nearly 100 flights operated by Indian carriers have received bomb threats posted on social media resulting in flight disruptions, diversions and scrambling of fighter jets




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Air India steps up technology focus, eyes higher direct channel sales




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GMR group raises ₹6,300 crore to refinance promoter entity debt

GMR group will use the proceeds to refinance all external debt of GMR Enterprise Private Limited, the promoter of GMR Airports Limited




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InterGlobe Aviation likely to slip into red on higher costs, weak rupee

Emkay Global Research estimates InterGlobe Aviation’s second quarter loss at ₹780 crore largely driven by foreign exchange loss




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Pawfect buddies: Mumbai Airport revives emotional support dog program at Terminal 2

MIAL is the only Indian airport offering such a service, features nine trained dogs including a Golden Retriever, a Maltese, a rescued Husky, Shih Tzu, Lhasa Apso, and Labrador




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Direct flights open up new overseas destinations, Indian arrivals rise in double digits

While revenge travel fueled post-Covid 19 pandemic travel recovery, easier visa norms and increased air connectivity are boosting demand




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Adani Ports Q2 PAT up 39%, revenue up 6.3%

Adani Ports said in a statement it was well positioned to hit the upper end of the FY25 EBITDA guidance range of ₹17,000-18,000 crore




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New terminal operating system and bunching of ships disrupt truck movements at Kattupalli and Ennore container terminals

While the issue with the of TOS has been addressedsorted out, the trailers are still facing delays in the scanning centre




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India gears up to expand carbon-efficient coastal shipping services

Coastal Shipping Bill moots identifying newer routes for movement of additional cargo




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IRCTC Q2 net profit up 4.5%, interim dividend announced

Revenue from operations during the period under review stood at Rs ₹1064 crore, up 7.3 per cent y-o-y




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Curtains for Jet Airways as Supreme Court orders liquidation

A three member bench of the apex court invoked its powers under Article 142 of the constitution and directed the liquidation of the grounded airline.




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Recaro to commence India sourcing to support mega orders; IndiGo among major clients

Recaro, the global aircraft seat manufacturer, has bagged mega orders from India-based airlines, including IndiGo




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Air India sets up war room for a smooth merger with Vistara

Vistara chief commercial officer Deepak Rajawat named AI Express CFO in a management rejig, Vistara CEO Vinod Kannan will continue to hold the role of chief integration officer




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3 coaches of Secunderabad-Shalimar Superfast Express derail near Howrah

"The weekly special train derailed at Nalpur, about 40 km from Kolkata, no casualties or injuries have been reported so far"




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India could benefit from re-orientation of global supply chain away from China after Trump's victory: Report

The report highlighted the Trump’s plans include imposing a 60 per cent tariff on imports from China, as well as additional tariffs ranging from 10 per cent to 20 per cent on imports from other countries




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Odisha start-up launches fully made-in-India, autonomous logistics drone service

Air Orca is fully designed, developed and manufactured in India by Odisha-based start-up Bon V Aero and is equipped to serve as a first responder in post-disaster scenarios




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Adani Kattupalli port continues to face operational challenges

Only one container ship to be berthed between November 11 and 14




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Airtel rolls out Covid support initiative for medium, small size companies

Businesses will be able to set up a cloud communication platform with a Covid SOS feature




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India's Mylab to ramp up Covid-19 test production to 100 mln units per week

Antigent tests said to produce more false negatives




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Infosys beats market estimates; profit up 12%, raises guidance

It raised guidance to 19.5-20 per cent growth compared to the 16.5-17.5 per cent growth it had indicated earlier




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TCS net profit up 12.3% at ₹9,769 crore; revenue up 16.3%

From a pipeline perspective, the company crossed a total contract value of $7.6 billion this quarter




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An interesting line-up of kritis

Padma Sugavanam’s information on songs lent an edge.




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No break for the ‘Breakup Song’ singer

Jonita Gandhi has a lot on her plate, from recording for movies to performing live gigs, but she looks forward to a time when she can write her own music




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Deliberations on dhrupad

Arijit Mahalanabis’s workshop dealt with order and presentation in Hindustani music.




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Villupaattu exponent Subbu Arumugam no more

A native of Tirunelveli, Subbu Arumugam was brought to Chennai by the late comedian N.S. Krishnan to popularise Gandhiji’s life story; he was conferred with Padma Shri in 2021




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Ludo platform Zupee hits record 100 million users, 6.6 billion gameplays




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Ludo platform Zupee hits record 100 million users, 6.6 billion gameplays




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Centre directs officials to speed up resolution of industrial disputes cases