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Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00351A, Research Article
Fei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng Zhu
Lovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.
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A retro-Mannich mediated transformation of Morita–Baylis–Hillman ketones to saturated imidazo[1,2-a]pyridines

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00352G, Research Article
Sachin Sharma, Ajit Kumar Jha, Srinivasan Easwar
Two fruits felled with one stone! – a proof of mechanism and a synthetic method that delivers a privileged heterocyclic motif.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00317A, Research Article
Guohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin Yin
Amine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.
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Photochemical [2 + 2 + 1] annulation of 2-vinyloxy arylalkynes with bromomalonates via energy transfer

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00249K, Research Article
Shuo Tang, Jiupeng Liu, Min Zhang, Dan Wang, Yong Wang, Jingjing Zhao, Pan Li
A transition-metal-free, oxidant-free and base-free photochemical [2 + 2 + 1] radical annulation of 2-vinyloxy arylalkynes with bromomalonates has been developed.
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Synthesis of oxindole fused 1,3-oxazepanes via hydride transfer initiated ring expansion of pyrrolidine

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00474D, Research Article
Peng He, Zongkang Wang, Qiongwen Kang, Nana Fei, Chengyu Wang, Yanzhong Li
An efficient B(C6F5)3 catalyzed protocol for the synthesis of oxindole fused 1,3-oxazepanes from pyrrolidine substituted aryl alkynones has been developed.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Design of Interfacial Dual Schottky Junctions to Modulate Charge Transfer for Enhanced Piezo-assisted Photocatalytic Degradation RhB Performances

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00619D, Paper
Xiaoqi Jiang, Shengdong Sun, Yuqiao Wang, Lebing Zhao, Fangzhi Huang, Shikuo Li
Regulating charge transfer is a great challenge to improving the efficiency of piezoelectric photocatalytic reactions. Herein, sandwich-like Bi2WO6@Ag/MXene nanoflower spheres (BWO@Ag/MXene) with piezoelectric/plasma dual characteristics were synthesized by a facile...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Revolutionary SAMs: transforming inverted perovskite solar cells

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00962B, Highlight
Hongshi Li, ShunChang Liu
Revolutionary self-assembled monolayers, represented by xPACz, have propelled the rapid improvement in the performance of inverted perovskite solar cells.
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Fluorophore branching boosted photo-induced energy transfer in UiO-66 for ultrasensitive and instant hydrazine sensing

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01549E, Paper
Ying Luo, Da Lei, Maohua Li, Yuansheng Ge, Jiguang Li, Baiyi Zu, Jun Yao, Xincun Dou
Metal organic frameworks (MOFs) have made great progress in the field of fluorescent sensing; however, whether the electronic structure and recognized sites can be adjusted by external functionalization still remains challenging.
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Superconductivity above 30 K due to the introduction of oxygen element in CaFeAsF

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03994G, Paper
Yixin Liu, Teng Wang, Zulei Xu, Da Jiang, Yi Zhao, Yanpeng Qi, Xiaoni Wang, Ming Yang, Mao Ye, Wei Peng, Gang Mu
Exploring new unconventional superconductors is of great value for both fundamental research and practical applications. It is a long-term challenge to develop and study more hole-doped superconductors in 1111 system...
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BRSV and AISF demand thorough probe into RGUKT student’s death




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Akashteer: Transforming India's air defence with cutting-edge technology




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Stachydrine, a pyrrole alkaloid with promising therapeutic potential against metabolic syndrome and associated organ dysfunction

RSC Med. Chem., 2024, 15,3652-3673
DOI: 10.1039/D4MD00425F, Review Article
Semim Akhtar Ahmed, Prasenjit Manna, Jagat Chandra Borah
Metabolic syndrome is a multifaceted condition marked by interconnected risk factors, significantly increasing the risk of serious diseases like cardiovascular disease, type 2 diabetes, and stroke.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Karnataka High Court dismisses Union Bank of India’s petition seeking transfer of Valmiki corporation case to CBI

‘Banking Regulations Act does not empower banks to seek transfer of probe into criminal cases registered by States to agency of its choice’




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Flexys partners with 10x Banking to accelerate digital transformation

Flexys has announced its partnership with cloud-native core...




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SF: we have been repeatedly impressed by how resourceful GLS is in the European market

GLS and SF, China's largest integrated logistics service provider, are excited to announce a bilateral network partnership.




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DHL Express Italy: we want to help companies in their mobility transformation

DHL is opening the first Centre of Excellence for electric mobility on the European mainland in Pozzuolo Martesana (near Milan), Italy, to advance the new electric age.




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Austrian Post: The new handhelds are an important building block for [our] digital transformation

Österreichische Post AG has rolled out over 11,000 handhelds from February to July 2024.




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FAU Engineers Win NSF Grant to Develop One-of-a-Kind School of AI Bio-Robotic Fish

A school of bio-robotic fish with advanced sensors will create a versatile network capable of maneuvers and station-keeping beyond current vehicles both in shallow coastal areas and in deep ocean environments.




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Transforming lives in Mozambique

God is working to transform lives in Mozambique through the efforts of the local OM team.




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Transformation through football

It started with one ball and grew to become a garden.




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Discipled, equipped and transformed

A young woman's life is transformed by the love of Jesus shared and displayed through Tabitha Skills Training in Zambia.




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Greek woman journeys to Transform

A Greek woman embarks on a lonely journey to the Transform 2013 conference in Rome, a journey that began when she accepted Christ at 19.




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When God calls your name – Transform Greece

After attending Transform 2014 and going on the Greece outreach, a young South African man returns to Greece eight months later to stay.




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Training leads to transformation

An OM training conference equips a local pastor with tools to transform his Sunday service for Syrian refugees.




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Transform: Reaching across borders

Tim and Sophie, an Australian couple with OM in Paris, experienced life in North Africa, and its many different needs and difficulties, through Transform 2012.




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An unexpected call at Transform

How God called Andrea from Italy to leave his comfort zone during the Transform conference and his experience with OM Lifehope in the UK.




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Transform outreach casts vision for trafficking ministry

Participating in a Transform outreach to trafficked women gave OMer Erika Tello the vision of founding the OM Italy anti-trafficking ministry.




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Cycling to Transform

Cyclists with the Ride to Transform initiative rode 830 kilometres (about 515 miles) through Italy to raise funds for Transform relief projects around the Mediterranean.




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Transforming the Mediterranean

Around 340 people participated in the Transform 2013 mission conference in Rome before spreading across the Mediterranean on 29 outreaches.




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Artists transform conversations into creativity

Artists participating in the Incarnate training and discipleship programme of OM Arts in Italy are inspired by conversations with locals.




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Transform 2016: A refugee’s prayer - An insight into short-term refugee ministry

Meeting Christian refugees praying for European governments made a deep impression on a Transform participant. For another, the term ‘refugee’ got a whole new meaning.




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Transform 2016: Pilgrim walk in Spain

Walking the thousand year old pilgrim route to Santiago de Compostela gave the Transform team many opportunities to share the Gospel




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Transform 2016: Refugee

Participants witnessed God at work through the Transform conference in Spain followed by outreach teams to the Mediterranean region and beyond.




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Honeymooners at Transform

Newlyweds Sam & Lena joined Transform as part of their honeymoon, because they wanted to honour God from the very start of their life together.




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Transform 2018 - VIBRANT

The OM Transform team experienced God at work during the conference and outreach day. The local churches were an added blessing, as was the cycling team sent out to pray for least reached towns.




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Transfer of power will be so smooth, Trump tells Biden at Oval Office

Returning to Washington, Trump meets with Biden in the Oval Office




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World Bank oks $750-M PH digital transformation program

The World Bank (WB) has approved a new $750-million development policy loan aimed at helping the Philippine government ramp up its digital transformation efforts, marking its second financial aid of this type to a country where the internet economy has seen rapid expansion. The multilateral lender said on Wednesday that its second digital transformation package […]...

Keep on reading: World Bank oks $750-M PH digital transformation program




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Biden highlights 'peaceful transfer of power' as he hosts president-elect...


Biden highlights 'peaceful transfer of power' as he hosts president-elect...


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Why agents are the next step in transforming your business with gen AI

The rise of generative AI (gen AI) and ChatGPT has brought large language models (LLMs) to the forefront of technological innovation. Unlike traditional AI, these LLMs can process and generate language in a way that mimics human reasoning. Businesses are leveraging this technology in various ways, including content generation, customer service interactions, and document summarization. Gen AI offers businesses a chance to streamline operations and improve efficiency. However, LLMs are not universally…




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New IBM Centre To Help In Digital Transformation

Software giant IBM on Thursday announced the launch of a new state-of-the-art IBM centre in Mumbai that will help clients accelerate their digital transformation journey across industries, with a focus on banking and financial services organisations.




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Transforming Dharavi: How The Fadnavis-Shinde Government Is Rebuilding Mumbai’s Heart

There was a time when the name Dharavi would paint a concerning picture. Today there is hope, there are aspirations. Dharavi Redevelopment Project (DRP) is poised to be one of the most transformative urban renewal projects in India. It promises to




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Government college teachers on deputation seek transfers ahead of counselling




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Wikipedia: Constantine the Great - Roman Emperor from 306 A.D. to 337 A.D. - The foremost general of his time, Constantine defeated the emperors Maxentius and Licinius during civil wars - He also fought successfully against the Franks, Alamanni, Visigoths

Religious policy: Constantine is perhaps best known for being the first Christian Roman emperor; his reign was certainly a turning point for the Church. In February 313, Constantine met with Licinius in Milan where they developed the Edict of Milan. The edict stated that Christians should be allowed to follow the faith of their choosing. This removed penalties for professing Christianity (under which many had been martyred in previous persecutions of Christians) and returned confiscated Church property. The edict protected from religious persecution not only Christians but all religions, allowing anyone to worship whichever deity they chose. A similar edict had been issued in 311 by Galerius, then senior emperor of the Tetrarchy; Galerius' edict granted Christians the right to practice their religion but did not restore any property to them. The Edict of Milan included several clauses which stated that all confiscated churches would be returned as well as other provisions for previously persecuted Christians. ... Constantine did not patronize Christianity alone, however. After gaining victory in the Battle of the Milvian Bridge (312), a triumphal arch-the Arch of Constantine-was built (315) to celebrate it; the arch is decorated with images of Victoria and sacrifices to gods like Apollo, Diana, and Hercules, but contains no Christian symbolism. In 321, Constantine instructed that Christians and non-Christians should be united in observing the venerable day of the sun, referencing the esoteric eastern sun-worship which Aurelian had helped introduce, and his coinage still carried the symbols of the sun cult until 324. Even after the pagan gods had disappeared from the coinage, Christian symbols appeared only as Constantine's personal attributes: the chi rho between his hands or on his labarum, but never on the coin itself. Even when Constantine dedicated the new capital of Constantinople, which became the seat of Byzantine Christianity for a millennium, he did so wearing the Apollonian sun-rayed Diadem. -- The reign of Constantine established a precedent for the position of the emperor as having some influence within the religious discussions going on within the Catholic Church of that time, e.g., the dispute over Arianism. Constantine himself disliked the risks to societal stability that religious disputes and controversies brought with them, preferring where possible to establish an orthodoxy. The emperor saw it as his duty to ensure that God was properly worshiped in his empire, and that what proper worship consisted would be determined by the Church. In 316, Constantine acted as a judge in a North African dispute concerning the validity of Donatism. After deciding against the Donatists, Constantine led an army of Christians against the Donatist Christians. More significantly, in 325 he summoned the Council of Nicaea, effectively the first Ecumenical Council (unless the Council of Jerusalem is so classified). Nicaea was dealt mostly with Arianism. Constantine also enforced the prohibition of the First Council of Nicaea against celebrating the Lord's Supper on the day before the Jewish Passover (14th of Nisan) (see Quartodecimanism and Easter controversy). Constantine made new laws regarding the Jews. They were forbidden to own Christian slaves or to circumcise their slaves.



  • Christian Church History Study
  • 2. 313 A.D. to 1521 A.D. - Revised Rome and the Holy Roman Empire

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Cimaware Software Releases AccessFIX 5.00 - Fifth Generation MS Access Repair Software

-- MADRID, Spain, May 24th, 2006 -- Cimaware Software (www.cimaware.com) continues to update AccessFIX after the complete overhaul of its MS Office repair Software with the release of AccessFIX version 5.00.




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Find Your SFF Tribe On Mastodon

How to find the people who are talking about speculative fiction and books on the Fediverse.




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Video: Big Fall River Bass! #fishing #bassfishing #fishingvideo

New video by playak: Big Fall River Bass! #fishing #bassfishing #fishingvideo




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Video: Best Fishing Lures! #fishing #bassfishing #fishingvideo

New video by playak: Best Fishing Lures! #fishing #bassfishing #fishingvideo




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Filmgeschäftsführung / Finanzbuchhaltung (m/w/d)

Coproduction Office/Essential Filmproduktion GmbH ist ein internationale Firma (Deutschland, Frankreich, Großbritannien, Dänemark), die mutige und preisgekrönte Filme produziert und vertreibt. Produzent und Gründer Philippe Bober hat bis heute zweiunddreißig Filme von innovativen Regisseuren wie Roy Andersson, Jessica Hausner, Ruben Östlund, Carlos Reygadas uvm. produziert. Zu den zahlreichen gewonnen Preisen gehören u.a. die Goldene Palme 2022 für Ruben Östlunds TRIANGLE OF SADNESS oder der Goldene Löwe… | Coproduction Office – Berlin




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Digital Marketer Launches Client-Focused Website Transformation For Bryan Texas Sewing Specialty Dealer

Premier Stitching, a sewing specialty dealer in Bryan Texas, needed a new website and sewing specialty focus that was achieved by the Marketing Heroes Team to better highlight the dealer's dedicated services for clients seeking all types of sewing, quilting, and embroidery machine purchases as well as maintenance work in the greater Brazos Valley area.




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Statista is transforming the data research experience with the introduction of Research AI

Hamburg, Germany – May 14, 2024. Statista, a global leader in data and market analysis, proudly announces the official launch of its new generative AI product, Research AI. Research AI marks a milestone in data research, aimed at helping businesses make informed decisions based on verified, curated and proprietary data from Statista.