ira

Virat Starts Practice At Perth. Fans Climb Trees, Bring Ladders To Watch Him

There has been a lot of fanfare around star India batter Virat Kohli ahead of the Test series against Australia starting November 22.




ira

Vivek Ramaswamy's Old Speech Goes Viral Ahead Of 'DOGE' Appointment

The viral video features young Vivek Ramaswamy, then an 18-year-old student at St Xavier High School, reflecting on his journey through high school.




ira

"Dirty And Dangerous, But...": Foreigner's Video Praising Delhi Goes Viral

An Irish-Persian vlogger's Instagram post about living in Delhi is going viral on social media. In his post, Sean Hammond shared a long caption detailing his experience living in the city.




ira

Senate urged to work on anti-online piracy bill

As the Senate continues to take action on the Site Blocking Bill, a consumer group again called on the chamber to pass the measure to protect the creative industry and ensure the digital security of Filipinos.





ira

Marco Jansen nearly pulls off a miracle, but Proteas fall short against India




ira

Moira Dela Torre, Denise Julia lead new November releases

Moira Dela Torre’s third studio album and Denise Julia’s sophomore EP dominate November music releases     Slowly but surely, Mariah Carey and Jose Mari Chan have eased their way into radio waves and mall playlists. But before the holiday classics completely take over this December, check out these upcoming and newly-released November drops. The month’s best and latest will surely be a high point for the year in music—from Moira Dela Torre’s first album in three years to Denise Julia’s sure-hit sophomore EP. READ: What makes Filipinos start celebrating Christmas as early as September? “I’m Okay” – Moira Dela […]...

Keep on reading: Moira Dela Torre, Denise Julia lead new November releases




ira

UN nuclear chief heads to Iran for crucial talks

Tehran, Iran — International Atomic Energy Agency chief Rafael Grossi is set to visit Tehran on Wednesday for crucial talks on Iran's nuclear program, warning just ahead of his trip that room for maneuver is narrowing. His visit comes only two days after the defense minister of Iran's nemesis Israel warned the Islamic republic was "more exposed than ever to strikes on its nuclear facilities". Israel has long accused Iran of seeking to acquire nuclear weapons, a claim Tehran denies. The two countries have traded missile strikes this year, as tensions soar over Israel's war with Iran's allies, Hamas in Gaza and Hezbollah in Lebanon. The strikes have brought to the surface their years-long shadow war and fueled fears of a wider Middle East conflict. "The margins for maneuver are beginning to shrink," Grossi said in an interview with AFP ahead of his visit, adding that "it is imperative to find ways to reach diplomatic solutions". While the IAEA is allowed to carry out inspections in Iran, Grossi stressed the need for "more visibility" into Iran's nuclear program, given its scale and ambition. "They have a lot of nuclear materials that could be used eventually to make a nuclear weapon, the IAEA chief told CNN on Tuesday, adding: "They do not have a nuclear weapon at this point."  Trump's warning Grossi's trip comes after Donald Trump -- who pulled out of a hard-won nuclear deal with Iran negotiated under Barack Obama -- was voted back into the White House. Trump said last week that he was not seeking to harm Iran and instead wanted its people to have "a very successful country", while insisting "they can't have a nuclear weapon". In 2015, major world powers including the United States reached an agreement with Iran on its nuclear program after 21 months of talks. The text provided for an easing of international sanctions on Iran in exchange for guarantees that it would not seek nuclear weapons. But Trump withdrew from the agreement in 2018 before re-imposing US sanctions on Iran. A year later, Iran started to gradually roll back its commitments to the nuclear deal, which only allowed Tehran to enrich uranium to 3.65 percent purity. The IAEA says Iran has considerably increased its reserves of enriched uranium to 60 percent, close to the 90 percent needed to develop an atomic bomb. It is against this backdrop that Grossi is schedule to visit Iran for the first time since May. In a statement, the IAEA said it would hold "high-level meetings with the Iranian government" and conduct "technical discussions on all aspects". Cameras unplugged Iranian President Masoud Pezeshkian, who came to office in July with hopes of improving ties with the West and having sanctions lifted, favors a revival of the nuclear deal. But all efforts to get the nuclear agreement off life support have so far failed. The IAEA chief has repeatedly called for more cooperation from Iran. In recent years, Tehran has decreased its interaction with the UN agency by deactivating surveillance devices needed to monitor the nuclear program and effectively barring its inspectors. The foundations of Iran's nuclear program date back to the late 1950s, when the United States signed a civil cooperation agreement with Iran's then Shah Mohammad Reza Pahlavi. In 1970, Iran ratified the Non-Proliferation Treaty, which requires signatory states to declare and place their nuclear materials under the IAEA control. But with Iran threatening to hit back at Israel for its latest missile strikes, some lawmakers in the Islamic republic have called on the government to revise its nuclear doctrine to pursue nuclear weapons. The parliamentarians called on supreme leader Ayatollah Ali Khamenei, who wields ultimate authority in Iran, to reconsider his long-standing religious edict or fatwa banning nuclear weapons. The Islamic republic has maintained its policy against acquiring nuclear weapons, insisting its nuclear activities were entirely peaceful.          




ira

US military says it hit Iran-backed group in Syria

American forces on Tuesday carried out strikes against targets linked to an Iran-backed group in Syria, the U.S. military said, with a war monitor saying the attacks killed five fighters. The raids were in response to a rocket attack on U.S. troops in the country, the U.S. Central Command (CENTCOM) said. The strikes targeted the group's "weapons storage and logistics headquarters facility... in response to a rocket attack on U.S. personnel," CENTCOM said in a post on social media that did not identify the group by name. "There was no damage to U.S. facilities and no injuries to US or partner forces during the attack," CENTCOM added. The Syrian Observatory for Human Rights war monitor said "five pro-Iranian fighters were killed and others injured, after American jets targeted" one of their bases in the city of Albukamal, in Syria's eastern Deir Ezzor province. The previous day, U.S. forces bombed nine targets associated with Iran-backed groups in response to recent drone and rocket attacks, according to the Pentagon. The Observatory said those strikes killed four members of groups loyal to Iran. The U.S. military has around 900 troops in Syria and 2,500 in Iraq as part of the international coalition that was established in 2014 to help combat the Islamic State jihadist group. Since war broke out in the Gaza Strip after Hamas attacked Israel on October 7, 2023, pro-Iran groups have repeatedly targeted US forces in Iraq and Syria in response to Washington's support for Israel. The United States has on multiple occasions responded to such attacks with strikes on Iran-backed groups.




ira

Iran hangs man 'for second time' after previous execution halted

Iran hanged a 26-year-old man for a second time Wednesday months after a previous execution was halted half a minute in, an NGO said. Ahmad Alizadeh was arrested in October 2018 on a murder charge, which he denied, and was sentenced to death, Norway-based Iran Human Rights (IHR), which tracks executions in Iran, said in a statement. His death sentence was carried out on April 27 in Ghezel Hesar prison in Karaj outside Tehran. But just 28 seconds into the hanging he was brought down from the gallows when the victim's family suddenly shouted "forgiveness." His "lifeless" body was successfully resuscitated and the execution was halted, IHR said. Under Iran's sharia law, a victim's family can ask for blood money to spare the life of the perpetrator or also decide to forgive. However, in many cases the family of the condemned person cannot afford the sum set and the execution goes ahead, according to activists. Alizadeh remained under the threat of the death penalty in the absence of any deal with the victim's family for blood money. He was executed again in the Ghezel Hesar prison on Wednesday morning, IHR said. "Ahmad Alizadeh, a talented student, was hanged for the second time on charges of murder, which he denied and claimed he confessed to under torture," said IHR director Mahmood Amiry-Moghaddam, denouncing the "execution machine of the Iranian regime." Activists accuse Iran of using the death penalty to instill fear throughout society, particularly in the wake of 2022-2023 nationwide protests which shook the Islamic authorities. According to IHR, 2024 is seeing a new surge in executions, with at least 166 executions recorded in October alone, the highest number recorded in a single month since the group began documenting executions in 2007. Activists including Amnesty International say Iran carries out more annual executions than any country other than China, for which no reliable figures are available.




ira

Iran ready for possible oil export curbs after Trump election

Dubai, United Arab Emirates — Iran has made plans to sustain its oil production and exports and is ready for possible oil restrictions from a Trump administration in the U.S., Oil Minister Mohsen Paknejad said on Wednesday, according to the oil ministry's news website Shana.  In 2018, then-U.S. President Donald Trump withdrew from a 2015 nuclear pact with Iran and re-imposed sanctions that hurt Iran's oil sector, with production dropping to 2.1 million barrels per day, or bpd, during his presidency.  "Required measures have been taken. I will not go into detail but our colleagues within the oil sector have taken measures to deal with the restrictions that will occur and there is no reason to be concerned," Paknejad said.  In recent years, Iranian oil production has rebounded to around 3.2 million barrels per day according to the Organization of the Petroleum Exporting Countries, of which Iran is a member.  Iranian oil exports have climbed this year to near multi-year highs of 1.7 million bpd despite U.S. sanctions.   Chinese refiners buy most of its supply. Beijing says it doesn't recognize unilateral U.S. sanctions.  




ira

US court overturns 1983 Beirut bombing victims' $1.68B judgment against Iran bank

new york — A U.S. appeals court on Wednesday threw out a $1.68 billion judgment against Iran's central bank that had been won by family members of troops killed and injured in the 1983 bombing of the U.S. Marine Corps barracks in Beirut.  The 2nd U.S. Circuit Court of Appeals in Manhattan said a lower court judge should have addressed questions of state law before ruling against Bank Markazi and Luxembourg intermediary Clearstream Banking, a unit of Deutsche Boerse.  In a 3-0 decision, the panel also rejected a claim that a 2019 federal law designed to make it easier to seize Iranian assets held outside the United States waived Bank Markazi's sovereign immunity.  That law "neither abrogates Bank Markazi's jurisdictional immunity nor provides an independent grant of subject matter jurisdiction," Circuit Judge Robert Sack wrote.    The court returned the case to U.S. District Loretta Preska, in Manhattan to address state law questions in the 11-year-old case, and whether the case can proceed in Bank Markazi's absence.  Bombing victims sought to hold Iran liable for providing material support for the October 23, 1983, suicide attack that killed 241 U.S. service members, by seizing bond proceeds held by Clearstream in a blocked account on Bank Markazi's behalf.  Bank Markazi claimed immunity under the Foreign Sovereign Immunities Act, which generally shields foreign governments from liability in U.S. courts.  Lawyers for the plaintiffs did not immediately respond to requests for comment. Bank Markazi's and Clearstream's lawyers did not immediately respond to similar requests.  Iran, other U.S.-designated sponsors of terrorism, and banks accused of providing services to terrorists face thousands of claims in U.S. courts by victims and their families. It is often difficult for these claimants to collect judgments.  In the Bank Markazi case, the plaintiffs sued in 2013 to partially satisfy a $2.65 billion default judgment they had won against Iran in 2007.  Another judge dismissed the case in 2015, but the 2nd Circuit Court revived it in 2017.  Then in 2020, the U.S. Supreme Court ordered a fresh review in light of the 2019 law, which then-President Donald Trump signed as part of the National Defense Authorization Act.  The plaintiffs have said they hold more than $4 billion of judgments against Iran and have been unable to collect for decades.  The case is Peterson et al v. Bank Markazi et al, 2nd U.S. Circuit Court of Appeals, No. 15-690. 




ira

UN nuclear chief in Iran to 'reach diplomatic solutions'

Tehran, Iran — International Atomic Energy Agency chief Rafael Grossi was to hold talks with top Iranian officials Thursday on Tehran's nuclear program, a week after Donald Trump's re-election as US president. During his first term in the White House from 2017 to 2021, Trump was the architect of a policy called "maximum pressure," which levied against Tehran biting sanctions that had been lifted through a landmark nuclear agreement in 2015. Grossi, who is the director general of the UN agency, arrived at Tehran airport on Wednesday evening and was greeted by Behrouz Kamalvandi, the spokesman for the Atomic Energy Organization of Iran (AEOI). Grossi is set to meet Thursday in Tehran with AEOI chief Mohammad Eslami as well as Foreign Minister Abbas Araghchi, who was chief negotiator in the nuclear talks between Tehran and the major powers that resulted in the 2015 deal formally called the Joint Comprehensive Plan of Action. The deal, reached after 21 months of negotiations between Iran and world powers, gave Tehran sanctions relief in exchange for curbs on its nuclear program to guarantee that it could not develop a nuclear weapon -- something it has always denied wanting to do. Three years later, then-president Trump unilaterally withdrew the United States from the agreement and reimposed heavy sanctions against Iran. Search for solutions A year later, Iran started to gradually roll back its commitments to the nuclear deal, which only allowed Tehran to enrich uranium to 3.65% purity. The IAEA says Iran has considerably increased its reserves of enriched uranium to 60%, close to the 90% needed to develop an atomic bomb. The head of the IAEA "will do what he can to prevent the situation going from bad to worse" given the significant differences between Tehran and Western capitals, analyst Ali Vaez, an Iran expert for the Crisis Group, a U.S.-based think tank, told AFP. "The one who left the agreement was not Iran, it was America," Iran's government spokeswoman Fatemeh Mohajerani said on Wednesday. "Mr. Trump once tried the path of maximum pressure and saw that this path did not work." Grossi's visit comes only two days after the defense minister of Iran's arch enemy Israel warned that the Islamic republic was "more exposed than ever to strikes on its nuclear facilities." The two countries have exchanged missile fire in recent months in a context of high tensions in the Middle East due to the war waged by Israel in the Gaza Strip against Hamas and in Lebanon against Hezbollah, two militant groups allied with Iran. Trump's return to the White House in January also raises fears of rising tensions between Iran and his country. "The margins for maneuver are beginning to shrink," Grossi warned in an interview with AFP on Tuesday, adding that "it is imperative to find ways to reach diplomatic solutions." Religious decree Grossi has said that while Iran does not have any nuclear weapons at this moment in time, it does have plenty of nuclear materials that could be used eventually to make a weapon. Iranian President Masoud Pezeshkian, who came to office in July with hopes of improving ties with the West and having sanctions lifted, favors a revival of the nuclear deal. But all efforts to get the nuclear agreement off life support have so far failed. The IAEA chief has repeatedly called for more cooperation from Iran. In recent years, Tehran has decreased its interaction with the UN agency by deactivating surveillance devices needed to monitor the nuclear program and effectively barring its inspectors. The foundations of Iran's nuclear program date back to the late 1950s, when the United States signed a civil cooperation agreement with Iran's then-Shah Mohammad Reza Pahlavi. In 1970, Iran ratified the Non-Proliferation Treaty (NPT), which requires signatory states to declare and place their nuclear materials under the IAEA control. But with Iran threatening to hit back at Israel for its latest missile strikes, some lawmakers in the Islamic republic have called on the government to revise its nuclear doctrine to pursue nuclear weapons. The parliamentarians called on supreme leader Ayatollah Ali Khamenei, who wields ultimate authority in Iran, to reconsider his long-standing religious edict or fatwa banning nuclear weapons. The Islamic republic has maintained its policy against acquiring nuclear weapons, insisting its nuclear activities are entirely peaceful.




ira

Miranda Cosgrove drops exciting news for 'iCarly' fans

Miranda Cosgrove surprised 'iCarly' fans with a surprise updateMiranda Cosgrave revealed good news for the iCarly fans.In a conversation with Natalie Morales on The Talk, the Nickelodeon star teased a potential new project in the iCarly universe to give fans the closure they yearned for following...




ira

Eve Hewson reacts to fans recreating viral dance moves

Eve Hewson expressed she is hesitant to reprise her role for a potential new season. Eve Hewson, Irish actress, has finally voiced her opinion on the famous dance montage from the hit Netflix show The Perfect Couple. In her Byrdie cover story, the 33-year-old revealed that the cast was...




ira

Iranian bank cards now usable in Russia as nations bypass sanctions


Connecting Iran's Shetab interbank network to the Russian system enabled collaboration, reducing reliance on the global SWIFT network, which has excluded Iranian banks since 2018.




ira

UN nuclear chief in Iran in search of ‘diplomatic solutions’

Iran’s Atomic Energy Organisation spokesman Behrouz Kamalvandi (right) meets Rafael Mariano Grossi, Director General of the International Atomic Energy Agency, upon his arrival in Tehran, on Wednesday.—AFP

TEHRAN: International Atomic Energy Agency chief Rafael Grossi arrived in Iran on Wednesday for discussions on Tehran’s nuclear programme, a week after Donald Trump’s election as the new US president.

Grossi, who is the director general of the UN agency, was greeted on Wednesday evening at the airport by Behrouz Kamalvandi, the spokesman for the Atomic Energy Organisation of Iran or AEOI.

Grossi is set to meet on Thursday in Tehran with AEOI chief Mohammad Eslami as well as Foreign Minister Abbas Araghchi, who was chief negotiator in the nuclear talks between Tehran and the major powers that resulted in the 2015 deal formally called the Joint Comprehensive Plan of Action or JCPOA.

The deal, reached after 21 months of negotiations between Iran and world powers, gave Tehran sanctions relief in exchange for curbs on its nuclear programme to guarantee that it could not develop a nuclear weapon — something it has always denied wanting to do. Three years later, then-president Trump unilaterally withdrew the United States from the agreement and reimposed heavy sanctions against Iran.

European powers pushing for resolution against Iran at IAEA

‘Comprehensive report’

European powers are pushing for a new resolution against Iran by the UN atomic watchdog’s board to pressure Tehran over its poor cooperation, diplomats say.

Such resolutions risk further diplomatic tension with Iran. The resolution would task the IAEA with issuing a so-called “comprehensive report” on Iran’s nuclear activities in addition to its regular quarterly ones, which would describe in more detail and put further focus on problem areas like Iran’s continued failure to explain uranium traces found at undeclared sites.

The aim is to force Iran back to the negotiating table to agree new restrictions on its nuclear activities in exchange for sanctions relief.

“Our concerns about Iranian nuclear activity are well known. It feels a natural point to be asking the IAEA for a thorough report. That then provides a basis to deal with Iranian behaviour,” a European diplomat said, one of five who said France, Britain and Germany are pushing for a resolution.

The United States has not been the driving force behind the resolution but is still expected to back it, as happened with the last resolution against Iran in June, diplomats said. The European powers seeking a resolution, known as the “E3”, are discussing the draft with the outgoing US administration.

Published in Dawn, November 14th, 2024




ira

TikTok Virality Nets Joker 2 Survivor Lady Gaga a Spot in Wednesday



Mama Monster joining the cast of Netflix's Wednesday just makes sense.




ira

'BlueAnon' Conspiracy Theories Explode After Liberals Lose

Some Democrats are not prepared to accept Vice President Kamala Harris' election loss as legitimate






ira

European powers pushing for resolution against Iran at IAEA, diplomats say

PARIS/VIENNA — European powers are pushing for a new resolution against Iran by the United Nations atomic watchdog's board next week to pressure Tehran over its poor co-operation, as the world awaits the return of US President-elect Donald Trump, diplomats say. Such resolutions risk further diplomatic tension with Iran. It has retaliated to previous ones and other criticism at the International Atomic Energy Agency's 35-nation Board of Governors by stepping up its nuclear activities and barring top IAEA inspectors, heightening Western concerns about its aims. The resolution would task the IAEA with issuing a so-called "comprehensive report" on Iran's nuclear activities in addition to its regular quarterly ones, which would describe in more detail and put further focus on problem areas like Iran's continued failure to explain uranium traces found at undeclared sites.




ira

Activist takes own life in protest at Iranian regime

Kianoosh Sanjari was an outspoken critic of Iran's leaders and had demanded the release of political prisoners.




ira

Sheraton Jumeirah Beach Resort Unveils a New Era of Modern Comfort with a Stunning Transformation

Sheraton Jumeirah Beach Resort is proud to announce its relaunch following an extensive revitalization, redefining the guest experience at this iconic destination. As the first hotel built in the Jumeirah Beach Residence (JBR) area, Sheraton Jumeirah Beach Resort has set the standard for excellence in hospitality for over two decades. This transformation ushers in a new era, blending modern design, amenities, and cutting-edge technology while preserving the resort’s rich history and cherished legacy. The reinvention of the Resort is driven by the vision of bringing people together through shared moments and spaces. The newly reimagined rooms and suites offer a sophisticated fusion of modern design and natural textures, with a color palette inspired by the serene beachfront setting. All rooms have been thoughtfully equipped to cater to the diverse needs of today’s travellers with the latest technologies, providing guests with a seamless blend of comfort and innovation. The bathrooms to...




ira

Heavy rains hit Tamil Nadu: Health department predicts spike in viral infections and fevers

As the heavy rainfall continues to batter several districts of Tamil Nadu, the State Health Department has issued a public advisory warning of a potential surge in viral infections. These include dengue, influenza, and other fever-related illnesses.




ira

Laapataa Ladies renamed as Lost Ladies: Aamir Khan, Kiran Rao host special screening amid Oscars campaign in NY

On November 12, a new poster for the film was revealed, accompanied by a caption that read, "Official entry: India. Best International Feature Film - 97th Academy Awards."




ira

Neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition to access C–N axially chiral indoles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00042K, Research Article
Xuan Zhang, Qi Teng, Yanru Ren, Baitong Wei, Chen-Ho Tung, Zhenghu Xu
A Rh-catalyzed neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition of 1,6-diynes and ynamides to generate C–N axially chiral indole derivatives has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ira

Chiral guanidine catalyzed cyclization reactions of 1,3-enynes for lactone synthesis: switchable H-bond catalysis

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00374H, Research Article
Yongyan Zhang, Lichao Ning, Tianxin Zhu, Zheng Xie, Shunxi Dong, Xiaoming Feng, Xiaohua Liu
Cyclization and 1,4-conjugate addition/cyclization between 2-activated 1,3-enynes and azlactones were achieved with chiral guanidine-amides for enol-type activation to yield a range of δ-lactone derivatives.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ira

Organocatalytic formal [4 + 2] cycloaddition of o-quinone-methyl derivatives and 2-isocyanatomalonate diesters for the construction of chroman derivatives with adjacent quaternary chiral centers

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00141A, Research Article
Tong Xiong, Yi-Zhao Xu, Yao Wang, You-Cai Xiao, Fen-Er Chen
An asymmetric organocatalytic formal [4 + 2] cycloaddition/annulation cascade of ortho-quinone methides with 2-isocyanatomalonate diesters has been reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ira

Stereodivergent synthesis of chiral spiropyrazolones through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes: unusual solvent effects on the enantioselectivity

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00358F, Research Article
Shan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui Shao
Chiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ira

Spiro-centre substitution effects in the intramolecular spin–spin interactions of spirobiacridine diradicals

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00419A, Research Article
Open Access
Shinichi Ogawa, Takuya Kanetomo, Masaya Enomoto
Spirodiradicals with the Si and Ge spiro atoms exhibit a S = 1 state. The magnetic interaction in the Si derivative was found to be lower than that in the Ge derivative, implying a negative effect on σ*(Si–Cα)–π* hyperconjugation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ira

Stereoselective skeletal modification of tryptanthrins to install chiral piperidine-2-ones enabled by Brønsted acid catalysis

Org. Chem. Front., 2024, 11,2171-2177
DOI: 10.1039/D3QO02029K, Research Article
Rong Zeng, Xiang Zhang, Yuan-Yuan Lei, Zhuo-Zhuo Zhang, Min Jiang, Qing-Zhu Li, Jun-Long Li, Bo Han
An asymmetric formal [4 + 2] cyclisation between azlactones and aza-dienes derived from simple tryptanthrins has been developed. With this established protocol, yielding a series of novel piperidine-2-one-fused tryptanthrins with up to >99 : 1 er under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




ira

Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines

Org. Chem. Front., 2024, 11,2326-2331
DOI: 10.1039/D4QO00064A, Research Article
Ting-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng
An efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




ira

Integrating continuous flow reaction and work-up: chiral amine resolution, separation and purification using a novel coalescing filter system

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00442F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bethan May Rowley, Lisa Alice Thompson, Luke Power, James Daglish, Emma Parks, James Birbeck, Stephen P Marsden, Nikil Kapur, John Blacker
To maximize the benefits of a continuous flow reaction, a continuous work-up is also needed. Herein, we present a process design and novel equipment for a continuous amine resolution reaction,...
The content of this RSS Feed (c) The Royal Society of Chemistry




ira

KHTC looking to resume boating in Anayirankal dam

Agency, in an affidavit submitted in the Kerala High Court, outlines plans to make boating facility more eco-friendly




ira

Rahul Gandhi's video promoting Wayanad as tourist destination goes viral




ira

Bosa addresses viral Mayfield play from 49ers' win over Bucs

49ers defensive end Nick Bosa explained his side of a viral play with Buccaneers quarterback Baker Mayfield during San Francisco's 23-20 win over Tampa Bay on Sunday at Raymond James Stadium.




ira

The fluorescence distinction of chiral enantiomers: a Zn coordination polymer sensor for the detection of cinchonine and cinchonidine

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03506B, Paper
Wenping Hu, Nan Wu, Dechao Li, Yefang Yang, Shaowen Qie, Shuai Su, Ruijie Xu, Wenting Li, Ming Hu
A Zn coordination polymer was constructed to identify chiral cinchonine and cinchonidine with high sensitivity, selectivity, and reproducibility.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




ira

Govt. charges BRS with hatching conspiracies to stall development projects for political gains

Dy CM says involvement of BRS leader in Lagacharla incident exposes the party’s intentions




ira

Iran executes in public a serial rapist convicted in dozens of cases

Iran’s state media say authorities have executed in public a man convicted of raping dozens of women over two decades




ira

Andhra Pradesh Budget reflects aspirations of all sections of people, say legislators

It has given impetus to the developmental goals outlined in the NDA’s election manifesto, say MLAs on the first day of discussion




ira

Jairam Tiger Mahto stands in the way in tough battle for NDA and INDIA blocs in Jharkhand

Known for raising local issues, the 30-year-old leader hails from Kurmi (Mahtos) community that comprise 22% of the total population, the largest chunk after tribals and plays a decisive role in at least 30 seats




ira

Private college lecturer arrested for sexual assault on job aspirant in Coimbatore




ira

UPPSC aspirants protest continues for third day over exam format 

The job aspirants protest multiple shifts and score normalisation in exams, demanding a fair and unified testing process




ira

Ganababu, Chiranjeevi Rao appointed Whips in Legislative Assembly and Council respectively




ira

Surgeon Vice Admiral visits Eastern Naval Command




ira

Supreme Court could have aligned AMU with aspirational India. It did not




ira

Art 370 won't be restored even if Indira returns: Shah

Union Home Minister Amit Shah on Wednesday asserted that Article 370, which granted special status to Jammu and Kashmir, will not be restored even if Congress stalwart and late PM Indira Gandhi comes down from heaven.




ira

WATCH: Bride shares heartbreaking moment as only 5 guests attend her wedding reception, video goes viral

A bride shares her heartbreak after only five guests showed up to her wedding reception despite receiving 40 RSVPs.




ira

Ameesha Patel sparks dating rumours with 'darling' Nirvaan Birla after their Dubai photo goes viral, gets trolled for...

Ameesha Patel was age shamed after her intimate picture with businessman Nirvaan Birla went viral on social media. While Ameesha is 49 years old, Nirvaan is 30.