excited

Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
The content of this RSS Feed (c) The Royal Society of Chemistry




excited

Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline

Dalton Trans., 2024, 53,17934-17947
DOI: 10.1039/D4DT01996B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara Machura
The impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.
The content of this RSS Feed (c) The Royal Society of Chemistry




excited

Praggnanandhaa excited to take on World No. 1 Carlsen

On current form, D Gukesh is the favourite to win the World Chess Championship title against his Chinese opponent, Ding Liren, believes Indian teenage Grandmaster R Praggnanandhaa.




excited

Young and excited

Penang, Malaysia :: A group of youngsters come to Logos Hope for a three day youth camp.




excited

High-dynamic-range transmission-mode detection of synchrotron radiation using X-ray excited optical luminescence in diamond

Enhancement of X-ray excited optical luminescence in a 100 µm-thick diamond plate by introduction of defect states via electron beam irradiation and subsequent high-temperature annealing is demonstrated. The resulting X-ray transmission-mode scintillator features a linear response to incident photon flux in the range 7.6 × 108 to 1.26 × 1012 photons s−1 mm−2 for hard X-rays (15.9 keV) using exposure times from 0.01 to 5 s. These characteristics enable a real-time transmission-mode imaging of X-ray photon flux density without disruption of X-ray instrument operation.




excited

Zeeman quantum beats of helium Rydberg states excited by synchrotron radiation

Quantum beats in fluorescence decay from Zeeman-split magnetic sublevels have been measured for helium Rydberg states excited by synchrotron radiation. The Zeeman quantum beats observed in this prototypical case were fitted with an equation from a theoretical formulation. It is proposed that Zeeman quantum beat measurement can be a useful way to simply evaluate the polarization characteristics of extreme ultraviolet light.




excited

BleepingComputer is excited to announce tomorrow's launch of our redesigned site




excited

Mountain lovers, don't get excited yet about EPA ruling on MTR

New EPA ruling on infilling valleys may limit future mountaintop mining permits, but it's only the first step in a long process to stop the 'Appalachian Apocaly



  • Research & Innovations

excited

10 TV shows that have us excited for February

From animals and architecture to treasures and wild weather, these are the shows we’ll be watching this month.



  • Arts & Culture

excited

These 2 Kickstarter campaigns will get kids excited about science

From atoms to stardust, these books get kids familiar with some of science's most fascinating terms and concepts.




excited

Kevin Costner's oil filtration tech gets BP 'excited'

Company says latest tests prove the machines can make a difference in Gulf cleanup efforts.



  • Arts & Culture

excited

Goldstream Incorporated Excited to be Sponsoring Boxing Event

CEO of Goldstream Incorporated Dan Coolican was delighted to announce that the Nottingham-based outsourced sales and marketing firm will be one of the official sponsors of the Selby 10th Anniversary Show.




excited

Rockstar Capital Excited to Announce Their First Two Day Apartment Investor Networking and Educational Event with Guest Speaker Tarek El Moussa

Rockstar Capital Helps Educate Potential Investors on The Intricacies of Real Estate Investment And Gives Investors A Space To Meet And Educate One Another




excited

The Douglas Company is Excited to Announce the Completion of Construction on YourLife Memory Care Community

A new 61,760 square-foot, two-story memory care community located in Coconut Creek, Florida.




excited

‘Excited To Come Back’: Hall Of Famer Prado Back In The Saddle Saturday

Six weeks since he last rode, Hall of Fame jockey Edgar Prado is ready to return to action with three mounts on Saturday's 12-race program at Gulfstream Park. Prado, who turns 53 June 12, is named on 3-year-old gelding Mountain Tree in Race 1, 3-year-old filly By His Grace in Race 3 and 3-year-old colt […]

The post ‘Excited To Come Back’: Hall Of Famer Prado Back In The Saddle Saturday appeared first on Horse Racing News | Paulick Report.




excited

12-Year-Old Kamali Tucker Excited For Ag Show

Each year when the Ag Show rolls around Kamali Tucker is filled with excitement, as the 12-year-old likes meeting up with friends and checking out the exhibits and other entertainment, but for this passionate equestrian the real joy is in competing in horse jumping. The Bermuda High School [BHS] student admits the atmosphere at the […]

(Click to read the full article)




excited

UCLA gymnastics coach excited about future after coronavirus disrupts season

First-year UCLA gymnastics coach Chris Waller knew the Bruins would face challenges, but he's pleased with what the team accomplished.




excited

Shola Ameobi reveals Newcastle staff are 'excited by the noises' around £300m takeover



Newcastle are closing in on a £300m takeover which could see the club transformed into a major player.




excited

Commissioner excited for first OD in Cincy

Major League Baseball Commissioner Rob Manfred has never been to an Opening Day in Cincinnati. Manfred is excited to experience one for himself, now that he has the honor of being the grand marshal of the 100th Findlay Market Opening Day Parade on March 28.




excited

'Good Morning Football': Sophomore QBs we're excited to see in 2020

The "Good Morning Football" crew discusses which sophomore QBs and their offensive weapons they're most excited to see play in 2020.




excited

Equipped, excited and encouraged

Young people in Bangladesh learn to combine sport with their love for God, and one programme participant explains his enthusiasm for the experience.




excited

Five Reasons I'm Excited About Mixed-Signal Verification in 2015

Key Findings: Many more design teams will be reaching the mixed-signal methodology tipping point in 2015. That means you need to have a (verification) plan, and measure and execute against it.

As 2014 draws to a close, it is time to look ahead to the coming years and make a plan. While the macro view of the chip design world shows that is has been a mixed-signal world for a long time, it is has been primarily the digital teams that have rapidly evolved design and verification practices over the past decade. Well, I claim that is about to change. 2015 will be a watershed year for many more design teams because of the following factors:

  • 85% of designs are mixed signal, and it is going to stay that way (there is no turning back)
  • Advanced node drives new techniques, but they will be applied on all nodes
  • Equilibrium of mixed-signal designs being challenged, complexity raises risk level
  • Tipping point signs are evident and pervasive, things are going to change
  • The convergence of “big A” and “big D” demands true mixed-signal practices

Reason 1: Mixed-signal is dominant

To begin the examination of what is going to change and why, let’s start with what is not changing. IBS reports that mixed signal accounts for over 85% of chip design starts in 2014, and that percentage will rise, and hold steady at 85% in the coming years. It is a mixed-signal world and there is no turning back!

 

Figure 1. IBS: Mixed-signal design starts as percent of total

The foundational nature of mixed-signal designs in the semiconductor industry is well established. The reason it is exciting is that a stable foundation provides a platform for driving change. (It’s hard to drive on crumbling infrastructure.  If you’re from California, you know what I mean, between the potholes on the highways and the earthquakes and everything.)

Reason 2: Innovation in many directions, mostly mixed-signal applications

While the challenges being felt at the advanced nodes, such as double patterning and adoption of FinFET devices, have slowed some from following onto to nodes past 28nm, innovation has just turned in different directions. Applications for Internet of Things, automotive, and medical all have strong mixed-signal elements in their semiconductor content value proposition. What is critical to recognize is that many of the design techniques that were initially driven by advanced-node programs have merit across the spectrum of active semiconductor process technologies. For example, digitally controlled, calibrated, and compensated analog IP, along with power-reducing mutli-supply domains, power shut-off, and state retention are being applied in many programs on “legacy” nodes.

Another graph from IBS shows that the design starts at 45nm and below will continue to grow at a healthy pace.  The data also shows that nodes from 65nm and larger will continue to comprise a strong majority of the overall starts. 


Figure 2.  IBS: Design starts per process node

TSMC made a comprehensive announcement in September related to “wearables” and the Internet of Things. From their press release:

TSMC’s ultra-low power process lineup expands from the existing 0.18-micron extremely low leakage (0.18eLL) and 90-nanometer ultra low leakage (90uLL) nodes, and 16-nanometer FinFET technology, to new offerings of 55-nanometer ultra-low power (55ULP), 40ULP and 28ULP, which support processing speeds of up to 1.2GHz. The wide spectrum of ultra-low power processes from 0.18-micron to 16-nanometer FinFET is ideally suited for a variety of smart and power-efficient applications in the IoT and wearable device markets. Radio frequency and embedded Flash memory capabilities are also available in 0.18um to 40nm ultra-low power technologies, enabling system level integration for smaller form factors as well as facilitating wireless connections among IoT products.

Compared with their previous low-power generations, TSMC’s ultra-low power processes can further reduce operating voltages by 20% to 30% to lower both active power and standby power consumption and enable significant increases in battery life—by 2X to 10X—when much smaller batteries are demanded in IoT/wearable applications.

The focus on power is quite evident and this means that all of the power management and reduction techniques used in advanced node designs will be coming to legacy nodes soon.

Integration and miniaturization are being pursued from the system-level in, as well as from the process side. Techniques for power reduction and system energy efficiency are central to innovations under way.  For mixed-signal program teams, this means there is an added dimension of complexity in the verification task. If this dimension is not methodologically addressed, the level of risk adds a new dimension as well.

Reason 3: Trends are pushing the limits of established design practices

Risk is the bane of every engineer, but without risk there is no progress. And, sometimes the amount of risk is not something that can be controlled. Figure 3 shows some of the forces at work that cause design teams to undertake more risk than they would ideally like. With price and form factor as primary value elements in many growing markets, integration of analog front-end (AFE) with digital processing is becoming commonplace.  

 

Figure 3.  Trends pushing mixed-signal out of equilibrium

The move to the sweet spot of manufacturing at 28nm enables more integration, while providing excellent power and performance parameters with the best cost per transistor. Variation becomes great and harder to control. For analog design, this means more digital assistance for calibration and compensation. For greatest flexibility and resiliency, many will opt for embedding a microcontroller to perform the analog control functions in software. Finally, the first wave of leaders have already crossed the methodology bridge into true mixed-signal design and verification; those who do not follow are destined to fall farther behind.

Reason 4: The tipping point accelerants are catching fire

The factors cited in Reason 3 all have a technical grounding that serves to create pain in the chip-development process. The more factors that are present, the harder it is to ignore the pain and get the treatment relief  afforded by adopting known best practices for truly mixed-signal design (versus divide and conquer along analog and digital lines design).

In the past design performance was measured in MHz with simple static timing and power analysis. Design flows were conveniently partitioned, literally and figuratively, along analog and digital boundaries. Today, however, there are gigahertz digital signals that interact at the package and board level in analog-like ways. New, dynamic power analysis methods enabled by advanced library characterization must be melded into new design flows. These flows comprehend the growing amount of feedback between analog and digital functions that are becoming so interlocked as to be inseparable. This interlock necessitates design flows that include metrics-driven and software-driven testbenches, cross fabric analysis, electrically aware design, and database interoperability across analog and digital design environments.


Figure 4.  Tipping point indicators

Energy efficiency is a universal driver at this point.  Be it cost of ownership in the data center or battery life in a cell phone or wearable device, using less power creates more value in end products. However, layering multiple energy management and optimization techniques on top of complex mixed-signal designs adds yet more complexity demanding adoption of “modern” mixed-signal design practices.

Reason 5: Convergence of analog and digital design

Divide and conquer is always a powerful tool for complexity management.  However, as the number of interactions across the divide increase, the sub-optimality of those frontiers becomes more evident. Convergence is the name of the game.  Just as analog and digital elements of chips are converging, so will the industry practices associated with dealing with the converged world.


Figure 5. Convergence drivers

Truly mixed-signal design is a discipline that unites the analog and digital domains. That means that there is a common/shared data set (versus forcing a single cockpit or user model on everyone). 

In verification the modern saying is “start with the end in mind”. That means creating a formal approach to the plan of what will be test, how it will be tested, and metrics for success of the tests. Organizing the mechanics of testbench development using the Unified Verification Methodology (UVM) has proven benefits. The mixed-signal elements of SoC verification are not exempted from those benefits.

Competition is growing more fierce in the world for semiconductor design teams. Not being equipped with the best-known practices creates a competitive deficit that is hard to overcome with just hard work. As the landscape of IC content drives to a more energy-efficient mixed-signal nature, the mounting risk posed by old methodologies may cause causalities in the coming year. Better to move forward with haste and create a position of strength from which differentiation and excellence in execution can be forged.

Summary

2015 is going to be a banner year for mixed-signal design and verification methodologies. Those that have forged ahead are in a position of execution advantage. Those that have not will be scrambling to catch up, but with the benefits of following a path that has been proven by many market leaders.



  • uvm
  • mixed signal design
  • Metric-Driven-Verification
  • Mixed Signal Verification
  • MDV-UVM-MS

excited

University students more anxious than excited about starting careers due to Covid-19, study finds

University students have told how they are more anxious than excited about starting their careers after graduation amid the coronavirus pandemic.




excited

Zoo otters juggle because they're excited about food, scientists say

Zoo otters juggle stones when they are hungry because they may be excited about food, scientists believe.




excited

Tight end Hunter Henry excited to see what Chargers can do on offense

Chargers tight end Hunter Henry will miss Philip Rivers. But he's eager to see what the team can do with a different offense.




excited

Deepika & Ranbir May Reunite For Sanjay Leela Bhansali's ‘Baiju Bawra’ & We’re Already Excited




excited

Markets are getting too excited about the oil price rally too soon, analysts warn

Lack of storage space for crude globally remains a massive problem, and will keep a ceiling on oil prices for the near future.




excited

Excited Elephants Run To Greet New Rescued Baby Elephant

This video is from 2017 but it just makes us feel so warm and happy that we had to let it surface once more! 

The video is only a bit over a minute but filled with a lot of emotions, excitement, and love, that you can just feel. 

Elephants are truly remarkable animals, so intelligent and gentle, you can just tell they have a big heart. 




excited

Damian Hurley excited about 2020 after a 'challenging' 2019

The model, 17, looked back on his woes and highlights from the year by sharing a series of snaps to Instagram on Tuesday, which saw him pose beside his mother Elizabeth, 54, and friends.




excited

Lacey Turner reveals she couldn't get 'excited' about her pregnancy after two previous miscarriages

EastEnders star Lacey Turner has admitted she couldn't allow herself to get excited about her pregnancy before giving birth to daughter Dusty, seven months.




excited

Commons Speaker John Bercow gets very excited as he cheers on Roger Federer at Wimbledon

House of Commons speaker John Bercow made a second appearance at Wimbledon in just four days to watch Roger Federer - while wearing a T-shirt with the star's logo on it.




excited

Timo Werner is 'having English lessons' and 'excited about playing in the Premier League'

RB Leipzig striker Timo Werner looks to be edging closer to a move to the Premier League with reports claiming the Chelsea and Liverpool target has started taking English lessons.




excited

Nick Jonas tells Ellen he's 'so excited about' getting a seat on The Voice for its 18th season

The Dallas native, who is married to actress Priyanka Chopra, 37, will work alongside fellow musicians Kelly Clarkson, 37, John Legend, 40, and Blake Shelton, 43, on the network show.




excited

Emma Willis, Rochelle Humes and Rylan lead the excited celebrities at Spice Girls Wembley show

The trio joined the likes of Sam Smith, Emma Stone, Haim, Lily Collins, Jaime Winstone, Judge Rinder and Greg Rutherford at the sell-out event.




excited

Nicola Sturgeon was 'overexcited' as Jo Swinson lost seat

Ms Sturgeon was filmed reacting to the Dunbartonshire East result while doing interviews at the Glasgow count, but has faced fierce criticism over her behaviour.




excited

'This is England's Gun XV. I can't wait to see it fire': Woodward excited for Ireland warm-up game

SIR CLIVE WOODWARD: It is exactly the team I would have picked for a must-win game at the tournament. This is the first time he has put his full strength side out in these warm-up games.




excited

Four-year-old is VERY excited to receive four bottles of MUSTARD for Christmas

Annmarie Lent from Florida says her four-year-old daughter Paislee will eat mustard on everything. On Christmas, she gave her a wrapped box with four bottles of Great Value mustard inside.




excited

Amy Childs is 'very excited' about her new boyfriend

Amy Childs is reportedly 'very excited' about her new boyfriend, who she is isolating with in lockdown.




excited

Becky James: I'm so excited to get back to full training... there have been times during past 12 months when I thought it would never happen

BECKY JAMES - ROAD TO RIO: I never thought I’d be so excited about training, but having been in Manchester for the last couple of months following a year on the sidelines, it feels so good to be back.




excited

Orlando Bloom is excited to start a family with fiancee Katy Perry

The actor, 42, revealed to The Mirror he's looking forward to having a child with his fiancee, who considers herself a child at heart. Orlando and Katy became engaged on Valentine's Day 2019.




excited

England coach Silverwood excited by form of Morgan following his U-turn after winning the World Cup

RICHARD GIBSON IN JOHANNESBURG: England entered the Twenty20 series in South Africa intent on taking the first step on the road to more global silverware.




excited

'We're very, very excited': Dua Lipa gushes over Gigi Hadid confirming her pregnancy with Zayn Malik

The singer, 24, who is dating Gigi's brother Anwar, 20, spoke about the happy news after the model confirmed she is five months pregnant with her first child.




excited

Dua Lipa poses braless in a tight white tank top after revealing she's excited to become an 'auntie'

With her tresses scraped up into a stunted ponytail, the singer, 24, who is dating Gigi's brother Anwar, 20, wore minimal make-up and sunglasses atop her head for the snaps shared to Instagram




excited

Adam Sandler says he's 'never excited for romantic scenes' as Jennifer Aniston calls him good kisser

Most recently, Sandler starred as Aniston's husband in the Netflix comedy Murder Mystery. Before that, they starred together in the 2011 romantic comedy Just Go With It.




excited

Manchester United fans get excited about Odion Ighalo's trademark 'scoop' trick after sealing move

The Nigeria striker, 30, sealed a dramatic deadline day loan move to United from Shanghai Shenhua as boss Ole Gunnar Solskjaer's search for a striker went down to the wire.




excited

Odion Ighalo excited at prospect of a Bruno Fernandes and Paul Pogba partnership at United

Ighalo is one of many United stars to have benefited from the arrival of Fernandes. The Portuguese has taken to life at United and has triggered a sense of optimism among fans.




excited

Gwen Stefani says she's excited to 'hang out at work' with 'best friend' Blake Shelton on The Voice

Stefani appeared on seasons 7, 9, and 12 of The Voice and famously struck up a romance with fellow judge Blake Shelton following the end of both their marriages.




excited

New mother Amy Schumer is 'very excited' to return to TV in 10-episode Hulu comedy series Love, Beth

The 38-year-old Emmy winner has signed on to create, direct, write, executive produce, and star in the scripted show, which starts streaming late 2020




excited

Pregnant Jenna Dewan's daughter is 'excited' about new baby

The 38-year-old actress also boasted about the 'unspoken chemistry' with her beau Steve Kazee as she praised her partner for their relationship.




excited

Danielle Lloyd joins her excited sons in clapping for the NHS

In a video shared with her 558,000 followers, she showed her appreciation with her sons Archie, nine, Harry, eight, six and Ronnie, two, from her Birmingham home