lec

Self-supported FeCoNiCuP high-entropy alloy nanosheet arrays for efficient glycerol oxidation and hydrogen evolution in seawater electrolytes

Green Chem., 2024, 26,10921-10928
DOI: 10.1039/D4GC02517B, Paper
Leyang Song, Chaoqun Ma, Peidong Shi, Xiaojuan Zhu, Kaiyu Qu, Lijie Zhu, Qipeng Lu, An-Liang Wang
Self-supported FeCoNiCuP high entropy alloy nanosheet arrays electrocatalyst was developed for highly efficient glycerol oxidation to formate and hydrogen evolution in seawater electrolytes.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Research progress on photocatalytic, electrocatalytic and photoelectrocatalytic selective oxidation of 5-hydroxymethylfurfural

Green Chem., 2024, 26,10739-10773
DOI: 10.1039/D4GC03597F, Critical Review
Yang An, Tao Lei, Weiyi Jiang, Huan Pang
This paper summarizes the latest research progress in selective photocatalytic, electrocatalytic, and photoelectrocatalytic oxidation of HMF, along with the reaction mechanisms, advantages, and challenges faced during selective HMF oxidation.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Electroreductive deoxygenative carboxylation of alkyl oxalates with CO2

Green Chem., 2024, 26,10811-10817
DOI: 10.1039/D4GC03452J, Communication
Yong Yuan, Hangfei Jiang, Ya-Nan Zhang, Yuyan Tao, Xincong Liu, Congde Huo
An electroreductive deoxygenative carboxylation of alkyl oxalates with CO2 is demonstrated.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Electrochemistry-enabled Rh-catalyzed regioselective [4 + 1] and [4 + 2] cycloaddition of benzoic acid with alkynyl esters/amides

Green Chem., 2024, 26,10996-11002
DOI: 10.1039/D4GC03753G, Paper
Wei-Jung Chiu, Chung-Ming Sun
The reaction of benzoic acids with alkynyl esters/amides in the presence of a Rh-catalyst and AcOH as an additive to give phthalides by [4 + 1] annulation. In contrast, the additive NaOAc exclusively affords isocoumarins through the [4 + 2] pathway.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Electroreductive deuteration of N-propynylamides to enamides

Green Chem., 2024, 26,10975-10981
DOI: 10.1039/D4GC03790A, Paper
Qiansong Gao, Mingchun Wang, Lianyou Zheng, Lingling Shi, Cheng Wu, He Li, Jinbao Xiang
A migratory reductive deuteration of terminal alkynes to access enamides with more than 3 deuteriums incorporated per molecule was realized.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Visible light-driven α-sulfonylation of ketone-derived silyl enol ethers via an electron donor–acceptor complex

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04554H, Paper
Barakha Saxena, Roshan I. Patel, Anuj Sharma
We herein describe a versatile electron donor–acceptor complex (EDA) mediated α-sulfonylation of ketone-derived silyl enol ethers using thiosulfonates (acceptor) with DABCO (donor) under visible light irradiation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Flow electrosynthesis of phosphinamides and phosphoramidates through P–N coupling

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04450A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tribani Boruah, Ren Ishizeki, Alberto Roldan, Rebecca L. Melen, Thomas Wirth
A robust flow electrochemical method for P–N and P–O oxidative coupling under mild conditions has been developed. Cyclic voltammetry (CV) was employed to investigate the redox behaviour of reactants.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Advancing green chemistry in environmental monitoring: the role of electropolymerized molecularly imprinted polymer-based electrochemical sensors

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03250K, Tutorial Review
Christopher Mwanza, Wei-Zhi Zhang, Kalulu Mulenga, Shou-Nian Ding
Molecularly imprinted polymers (MIPs) are synthetic materials designed to mimic the natural “lock and key” mechanism observed in biomolecular systems, such as the interactions between antibodies and antigens.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Single-layer 2D supramolecular-organic-framework-supported polyoxometalates: efficient selective oxidation of toluene in seawater under sunlight

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04480K, Paper
Xin-Long Ni, Yan Fan, Yi Luo, Xu Luo
Performing organic reactions in water, in particular in seawater under sunlight, is a desirable objective in chemistry because both are the most abundant and cheapest resources on earth. Herein, we...
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

(B,P,Co,Fe)-Ni Modified on Nanowood for Boosting Seawater Urea Electro-Oxidation

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05156D, Paper
Hongjiao Chen, Kewei Zhang, Yanzhi Xia, Jian Li, Bin Hui
Coupling urea oxidation reaction (UOR) and hydrogen evolution reaction (HER) in seawater is desirable to produce sustainable and green hydrogen due to the reduced energy consumption. However, developing high-performance UOR/HER...
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

N–N atropisomer synthesis via electrolyte- and base-free electrochemical cobalt-catalysed C–H annulation

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04390A, Communication
Jiating Cai, Linzai Li, Chuitian Wang, Shi Qin, Yuanyuan Li, Si-Yan Liao, Shengdong Wang, Hui Gao, Zhi Zhou, Yugang Huang, Wei Yi, Zhongyi Zeng
An exogenous electrolyte- and base-free electrochemical cobalt-catalysed atroposelective C–H annulation has been established to construct N–N axially chiral isoquinolinones in excellent enantioselectivities and good yields.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Photo-driven reduction/cyclization of nitroarenes via electron donor–acceptor complexes: a novel method for the acquisition of N-heterocycles

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04082A, Communication
Bin Sun, Chun Lv, Xiaohui Zhuang, Yan Xu, Haijing Song, Jiayin Wang, Zhaokang Zhang, Jiayang Wang, Can Jin
An EDA complex-based method for the reduction/cyclization of nitroarenes to obtain N-heterocycles with H2O as a clean by-product is presented.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Active Hydrogen Tuning by Copper-Cobalt Bimetal Catalysts for Boosting Ammonia Electrosynthesis from Simulated Waster Water

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04120H, Paper
Chunqi Yang, Chang Liu, Jingwen Zhuang, Ziyan Yang, Aiping Chen, Yuhang Li, Chunzhong Li
Electrochemical nitrate reduction reaction (NO3RR) represents a promising approach to balance the nitrogen cycle, converting environmental pollutant NO3− to valuable ammonia (NH3). However, the whole reaction involves complex protons-coupled electron...
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Production of propyl 4-hydroxybenzoate via selective hydrogenolysis of lignin catalyzed by Ni/MFI-ns

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05260A, Paper
Lixia Li, Yinan Rao, Menghao Jiang, Jinxing Long
Selective conversion of lignin macromolecules into aromatic monomers is of great significance but remains a great challenge. Here, we present a metallic Ni supported on hierarchical multilamellar MFI nanosheets (MFI-ns)...
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

A spatially integrated electrochemical–thermal tandem reaction for continuous mild synthesis of propylene oxide

Green Chem., 2024, 26,11206-11215
DOI: 10.1039/D4GC03455D, Paper
Yuefeng Qiu, Peng Jiang, Wenkai Ye, Jiahao Hu, Bin Zhang, Tuo Ji, Liwen Mu, Xin Feng, Xiaohua Lu, Jiahua Zhu
A spatially integrated electrochemical–thermal tandem reaction generates propylene oxide at 1 atm using hydrogen, oxygen, and propylene as feedstock.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Regulatable selective synthesis of benzofurans and coumarins from aryl propargyl ethers via an electrochemical tandem cyclization reaction

Green Chem., 2024, 26,11216-11221
DOI: 10.1039/D4GC03842H, Paper
Zhaoyue Feng, Xueyi Guan, Haiyang Ma, Yingsibing Fan, Ping Liu, Peipei Sun
A divergent protocol for the selective synthesis of benzofuran-2-carboxaldehydes and 3-organoselenyl-2H-coumarins from propargylic aryl ethers in the presence of dialkyl(aryl) diselenides under electrochemical reaction conditions was established.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Selective electrosynthesis of aldehydes at industrially relevant current densities via tandem electrochemical–chemical catalysis

Green Chem., 2024, 26,11290-11302
DOI: 10.1039/D4GC04536J, Paper
Ting Lin, Menglu Cai, Huijie Chen, Yiming Mo
A closed-loop tandem electrochemical–chemical catalysis system for aldehyde synthesis was developed, demonstrating a viable approach for the electrosynthesis of valuable intermediates under practical current densities with minimal waste electrolyte.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Catalytic C–N bond formation strategies for green amination of biomass-derived molecules

Green Chem., 2024, 26,11019-11060
DOI: 10.1039/D4GC03182B, Critical Review
Yan Zhong, Feng Liu, Jingsha Li, Chunxian Guo
Recent advances in the amination of biomass-derived molecules to generate valuable nitrogenous chemicals by employing thermocatalysis, electrocatalysis and photocatalysis strategies are reviewed.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Comparative techno-economic and life cycle assessment of electrocatalytic processes for lignin valorization

Green Chem., 2024, 26,11303-11315
DOI: 10.1039/D4GC01963F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zahra Ebrahimpourboura, Manish Mosalpuri, Cheng Yang, Aditya Ponukumati, Corey Stephenson, Marcus Foston, Mark Mba Wright
This study explores the potential of using electrochemical (EC) methods for valorizing lignin, a lignocellulosic biomass cell wall component, into biofuels and high-value compounds.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Substrate-controlled regioselective hydrophosphorylation of allenes to enable photocatalytic synthesis of alkenylphosphoryl compounds

Green Chem., 2024, 26,11272-11279
DOI: 10.1039/D4GC03588G, Paper
Tian-Ming Yang, Xin-Lu Fan, Wei Shi, Xuefei Zhao, Xu-Hong Hu
A visible-light-induced hydrophosphorylation of allenes with H-phosphine oxides is demonstrated to give a diverse range of alkenylphosphoryl compounds in a highly stereoselective and regioselective manner.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

A paired alkaline electrolyzer for furfural oxidation and hydrogen evolution over noble metal-free NiFe/Ni and Co/MXene catalysts

Green Chem., 2024, 26,11351-11363
DOI: 10.1039/D4GC04447A, Paper
Open Access
Xiaopeng Liu, Mohammad Albloushi, Michael Galvin, Connor W. Schroeder, Yue Wu, Wenzhen Li
A paired alkaline electrolyzer with non-noble metal catalysts was developed, demonstrating higher performances of furfural oxidation on NiFe/Ni foam at the anode and hydrogen evolution on Co/MXene at the cathode under practical current densities.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Augmentation of Pd-catalysed oxidative C–H/C–H carbonylation through alternating current electrosynthesis

Green Chem., 2024, 26,11177-11181
DOI: 10.1039/D4GC04569F, Paper
Haoran Li, Jiaqi Peng, Li Zeng, Linpu Zhou, Muhammad Shabbir, Feiran Xiao, Jiaxin Yuan, Hong Yi, Aiwen Lei
Unsymmetrical-waveform AC electrolysis facilitates Pd-catalysed oxidative C–H/C–H carbonylation. This methodology highlights the substantial benefits conferred by Pd-catalysed conversions in comparison to traditional DC electrolysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Reusable Co-catalysts for general and selective α-alkylation of nitriles with alcohols

Green Chem., 2024, 26,11140-11146
DOI: 10.1039/D3GC04436J, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhuang Ma, Zechen Wu, Carsten Kreyenschulte, Stephan Bartling, Henrik Lund, Matthias Beller, Rajenahally V. Jagadeesh
A general cobalt-catalyzed α-alkylation of nitriles with alcohols is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Development of a highly efficient electrocatalytic hydrogenation and dehalogenation system using a flow cell with a Pd tube cathode

Green Chem., 2024, 26,11328-11333
DOI: 10.1039/D4GC04617J, Paper
Hiroaki Tajima, Hideki Ishii, Shinsuke Inagi, Toshio Fuchigami
A novel flow and circulation electrolytic system has been developed for the highly efficient cathodic hydrogenation of unsaturated compounds and dehalogenation of various aromatic halides.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Review of carbon-based catalysts for electrochemical nitrate reduction and green ammonia synthesis

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04640D, Tutorial Review
Guanting Liao, Richard L. Smith Jr., Haixin Guo, Xinhua Qi
This work aims to review the latest developments in carbon-based electrocatalysts applied in electrocatalytic nitrate reduction, including pure carbon materials, heteroatom doping or metal-bonding catalysts, and carbon substrate-supported composites.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

1D/3D hierarchical carbon skeleton confined NiFe nanoparticles with optimized three-phase interfaces as tri-functional electrocatalysts

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04466E, Paper
Yuqing Chen, Binyang Liu, Xuesong Liu, Jiahui Ye, Kuan Deng, Chengjie Wu, Qiang Niu, Tao Yang, Wen Tian, Junyi Ji
Multilevel 1D/3D CNTs/carbon spheres with hydrophilicity can promote the infiltration of an electrolyte into the interior and guide bubble diffusion, thus constructing an optimal gas–solid–liquid interface to enhance the electrocatalytic process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Electron-mediator-free efficient photocatalytic regeneration of coenzyme NAD(P)H via direct electron transfer using ultrathin Bi2MoO6 nanosheets

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC05207B, Paper
Yao Chai, Zirui Pang, Heng Jiang, Chi Chung Tsoi, Liang Wan, Yu Du, Huaping Jia, Yujiao Zhu, Detao Liu, Fengjia Xie, Guangya Zhou, Xuming Zhang
The direct electron transfer mechanism of single-layer Bi2MoO6 ultrathin nanosheets promotes the efficient regeneration of photocatalytic coenzyme NAD(P)H.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




lec

Innovations... and collections

Only a professional approach can extend the careers of new-age directors and producers




lec

Amazon pulls out of high-stakes bidding battle for IPL telecast rights

Amazon’s decision comes just two days ahead of the bidding for IPL television and digital broadcast rights



  • Indian Premier League

lec

‘Better batteries will drive electric car spread’




lec

Will Mahindra's fully-electric Verito be a gamechanger?

The electric car, which has been under wraps for few years, is expected to churn out about 40 bhp and will come with a range of 100 km.




lec

Tata confirms the all-electric Tiago hatchback




lec

Meet IAS officer, aka 'Collector Bro', who cracked UPSC exam in 2007, now suspended due to...

He was serving as Special Secretary in the Agricultural Department in Kerala government until his suspension on Monday.




lec

DNA TV Show: Uddhav Thackeray's helicopter checked by poll authorities in Latur ahead of Maharashtra elections

Shiv Sena (UBT) posted a video of the poll authorities' act on its X handle.




lec

Assembly elections 2024: Voting for first phase begins in Jharkhand

Polling for the first phase of Jharkhand assembly elections, bypolls in 33 assembly seats across 11 states and the Wayanad Parliamentary seat in Kerala began today, i.e., November 13.




lec

Maharashtra Assembly elections: Human-leopard conflict to be a raging issue in 4 seats of Pune district




lec

Maharashtra Assembly elections: NCP fields MLA Sunil Tingre from Vadgaonsheri despite opposition from local BJP unit




lec

Elections and issues: In fight for survival, warring units of farm unions come together to protect their core votes




lec

Maharashtra Assembly elections: Jarange keeps candidates names under wraps




lec

Elections and issues: As soyabean prices drop, will procurement of this key cash crop help Mahayuti in Maharashtra?




lec

Pune district: Seats that saw close contests in last elections




lec

Maharashtra Assembly Polls: Pune seats that have changed hands every time in the last three elections?




lec

Autorickshaw prepaid booth at Pune railway station may face closure due to election code of conduct




lec

Maharashtra Assembly elections: Deadline to withdraw nomination ends, 3 Pune Congress rebels refuse to pull out




lec

Maharashtra Assembly polls: Liquor, gold and cash worth Rs 16.34 crore seized since announcement of polls, says Pune collector




lec

Diwali break over, parties dive into campaign trail ahead of Maharashtra Assembly elections




lec

Maharashtra Assembly elections: ‘VBA focusing on giving voice to youth with no family ties to politics,’ says Anjali Maydeo Ambedkar




lec

Pune Assembly segments that voted differently in 2019 Lok Sabha, Assembly elections




lec

Who is Shameebha Patil, the lone transgender candidate in Maharashtra Assembly elections?




lec

Maharashtra Assembly polls: In Solapur City Central, 79-year-old Adam Master takes on ally Congress in Shinde bastion in his last election