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[ASAP] Quantifying the Electronic and Steric Properties of 1,3-Imidazole-Based Mesoionic Carbenes (iMICs)

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Published On :: Mon, 09 Mar 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00045


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[ASAP] Evaluation of the Electrocatalytic Reduction of Carbon Dioxide using Rhenium and Ruthenium Bipyridine Catalysts Bearing Pendant Amines in the Secondary Coordination Sphere

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Published On :: Tue, 10 Mar 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.9b00815


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[ASAP] Synthesis and Reactivity of (NHC)Au<sup>I</sup>–Mercaptopyridine Complexes

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Published On :: Tue, 31 Mar 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00118


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[ASAP] Electrochemical CO<sub>2</sub> Reduction — The Effect of Chalcogenide Exchange in Ni-Isocyclam Complexes

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Published On :: Wed, 15 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00129


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[ASAP] (Isonitrile)platinum(II) Complexes of an Amido Bis(N-heterocyclic carbene) Pincer Ligand

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Published On :: Mon, 20 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00065


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[ASAP] S<sub>N</sub>2 and E2 Branching of Main-Group-Metal Alkyl Intermediates in Alkane CH Oxidation: Mechanistic Investigation Using Isotopically Labeled Main-Group-Metal Alkyls

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Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00120


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[ASAP] Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based <italic toggle="yes">N</italic>^<italic toggle="yes">N</italic><sup><italic tog

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Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00161


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[ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities

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Published On :: Sun, 26 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00091


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[ASAP] Sila-Peterson Reaction of Cyclic Silanides

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Published On :: Tue, 28 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00106


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[ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

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Published On :: Wed, 29 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00049


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[ASAP] Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe<sub>2</sub>(?<sup>4</sup>-cod)]: <italic toggle="yes">cis</italic>- versus <italic toggle="yes">trans</italic>-[

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Published On :: Thu, 30 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00188


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[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

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Published On :: Fri, 01 May 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00150


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[ASAP] Heteroleptic ß-Ketoiminate Magnesium Catalysts for the Ring-Opening Polymerization of Lactide

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Published On :: Mon, 04 May 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00168


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[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

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Published On :: Mon, 04 May 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00122


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[ASAP] C5 Metalation of Imidazole-Based Monothiolates en Route to Selenothiolates

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Published On :: Tue, 05 May 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00201


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[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

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Published On :: Fri, 08 May 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00066


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Covid-19 medical staff to get addl compensation

By timesofindia.indiatimes.com
Published On :: Fri, 08 May 2020 17:44:55 IST

The Amdavad Municipal Corporation (AMC) has decided to give additional financial compensation to health and paramedical staff of AMC and private designated Covid-19 hospitals who contact coronavirus infection on duty.


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Gujarat's Covid-19 tally 7,403; death toll 449

By timesofindia.indiatimes.com
Published On :: Fri, 08 May 2020 22:37:07 IST

With as many as 390 more people testing coronavirus positive since previous night, the total number of Covid-19 cases in Gujarat reached 7,403 on Friday, a health official said.


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Ahd Covid-19 waste peaked to 8,422kg in 1 day

By timesofindia.indiatimes.com
Published On :: Sat, 09 May 2020 07:10:18 IST

On March 24, when the lockdown was imposed, the total biomedical Covid waste incinerated in Ahmedabad that day was 82kg. The waste was mainly from the initial admissions at SVP Hospital,


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Parents away, cops celebrate kid's birthday

By ahmedabadmirror.indiatimes.com
Published On :: Sat, 09 May 2020 13:35:10 IST

(This story originally appeared in AhmedabadMirror on May 9, 2020)


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Simplifying levulinic acid conversion towards a sustainable biomass valorisation

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Published On ::

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04306C, Paper
Chiara Defilippi, Daily Rodríguez-Padrón, Rafael Luque, Cristina Giordano
In the range of biomass valorisation, hydroconversion of levulinic acid (one of the products of the hydrolysis of lignocellulosic biomass) was tested for the first time using nanosized Ni3N and Ni0 catalysts, with very promising results alongside high stability.
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One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00428F, Paper
Song Li, Long Yan, Qiying Liu, Jianguo Liu, Qiyu Liu, Wei Fan, Xuelai Zhao, Xinghua Zhang, Chenguang Wang, Longlong Ma, Qi Zhang
One-pot hydrodeoxygenation of δ-furfurylidenelevulinic acid over Pd/C combined with phosphotungstic acid through successive hydrogenolysis and HDO of furans and lactones.
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Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01082K, Critical Review
Rengui Weng, Zhihao Yu, Jian Xiong, Xuebin Lu
Levulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...
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Sustainable synthesis of cobalt and cobalt oxide nanoparticles and their catalytic and biomedical applications

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00885K, Critical Review
Siavash Iravani, Rajender S. Varma
Recent advances and essential challenges as well as catalytic and biomedical applications of cobalt oxide and cobalt nanoparticles are highlighted.
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Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source

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Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04275J, Communication
Xiao Shu, Yuan-Yuan Jiang, Lei Kang, Luo Yang
A novel Ni-catayzed hydrocyanation of various alkenes to provide aliphatic nitriles is developed by generating hydrocyanic acid in situ from safe and readily available formamide.
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Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00853B, Paper
Diego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge Aburto
A series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...
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Aqueous miscible organic layered double hydroxides as catalyst precursors for biodiesel synthesis

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Published On ::

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00571A, Paper
Chunping Chen, Maxwell Greenwood, Jean-Charles Buffet, Dermot O'Hare
Surface area and basicity density dependence of base-catalysed transesterification of sunflower oil by potassium salt prepared AMO-layered double hydroxides.
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New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
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Synthesis of amorphous Geobacter-manganese oxide biohybrid as efficient water oxidation catalysts

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Published On ::

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04353E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shafeer Kalathil, Krishna Katuri, Pascal Saikaly
The development of low cost and efficient oxygen evolution reaction (OER) catalyst has paramount importance to meet future sustainable energy demand. Nature’s photosynthetic machinery deploy manganese-based complex in photosystem II...
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A Strategy for The Assembly of Glypromate® and Structure-Related Analogues by Tandem Sequential Peptide Coupling

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00143K, Paper
Ivo E Sampaio-Dias, Luís Pinto da Silva, Sandra G Silva, Xerardo Garcia-Mera, José Enrique Rodriguez-Borges
This work describes an improved and greener methodology in solution-phase synthesis for the preparation of Glypromate® (glycyl-L-prolyl-L-glutamic acid, GPE), a potent neuropeptide with applications in neurodegenerative conditions such as Huntington's,...
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Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment

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Published On ::

Green Chem., 2020, 22,2443-2458
DOI: 10.1039/C9GC02088H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts, Stefaan M. A. De Wildeman
We studied the solvent-free hydrogenation of levulinic acid to γ-valerolactone with the Shvo catalyst involving comparative catalysis, DFT, and LCA.
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Novel insights into biomass delignification with acidic deep eutectic solvents: a mechanistic study of β-O-4 ether bond cleavage and the role of the halide counterion in the catalytic performance

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Published On ::

Green Chem., 2020, 22,2474-2487
DOI: 10.1039/C9GC02569C, Paper
André M. da Costa Lopes, José R. B. Gomes, João A. P. Coutinho, Armando J. D. Silvestre
The potentiality of acidic deep eutectic solvents for β-O-4 ether bond cleavage is herein demonstrated from a mechanistic point of view.
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Efficient base-free oxidation of monosaccharide into sugar acid under mild conditions using hierarchical porous carbon supported gold catalysts

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Green Chem., 2020, 22,2588-2597
DOI: 10.1039/C9GC04333K, Paper
Xintong Meng, Zengyong Li, Di Li, Yiming Huang, Jiaojiao Ma, Chuanfu Liu, Xinwen Peng
The highly selective synthesis of D-xylonic acid and D-gluconic acid from monosaccharide catalyzed by Au/NC-3 under base-free aerobic oxidation conditions.
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Direct C(sp3)–H acyloxylation of indolin-3-ones with carboxylic acids catalysed by KI

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Green Chem., 2020, 22,2354-2358
DOI: 10.1039/C9GC04446A, Communication
Yong-Long Zhao, Yong-Qin Tang, Xing-Hai Fei, Fen-Fen Yang, Zhuo-Xian Cao, Dong-Zhu Duan, Qing-Jie Zhao, Yuan-Yong Yang, Meng Zhou, Bin He
The first KI-catalyzed direct acyloxylation of indolin-3-ones with carboxylic acids has been developed using 30% aq. H2O2 as a green oxidant at room temperature. Moreover, mechanism studies indicated that a radical oxidation process may be involved for this transformation.
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Synthesis of bioderived polycarbonates with adjustable molecular weights catalyzed by phenolic-derived ionic liquids

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Green Chem., 2020, 22,2488-2497
DOI: 10.1039/D0GC00493F, Paper
Wei Qian, Lei Liu, Zengliang Zhang, Qian Su, Weizhen Zhao, Weiguo Cheng, Li Dong, Zifeng Yang, Ruibing Bai, Fei Xu, Yanqiang Zhang, Suojiang Zhang
Phenolic ionic liquid structure can be designed readily to control the molecular weight of isosorbide-derived polycarbonates.
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A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

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Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
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Hierarchically porous covalent organic frameworks assembled in ionic liquids for highly effective catalysis of C–C coupling reactions

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Green Chem., 2020, 22,2605-2612
DOI: 10.1039/D0GC00223B, Paper
Jikuan Qiu, Huiyong Wang, Yuling Zhao, Pengxin Guan, Zhiyong Li, Hucheng Zhang, Hongshuai Gao, Suojiang Zhang, Jianji Wang
A simple and environmentally benign strategy was reported for the synthesis of hierarchically porous COFs in ionic liquids, and the obtained materials show highly effective catalytic performance for C–C bond formation reactions.
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Reusable, homogeneous water soluble photoredox catalyzed oxidative dehydrogenation of N-heterocycles in a biphasic system: application to the synthesis of biologically active natural products

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Green Chem., 2020, 22,2575-2587
DOI: 10.1039/D0GC00569J, Paper
S. Srinath, R. Abinaya, Arun Prasanth, M. Mariappan, R. Sridhar, B. Baskar
Herein, a simple and efficient method for the oxidative dehydrogenation (ODH) of tetrahydro-β-carbolines, indolines and (iso)quinolines is described using a reusable, homogeneous cobalt-phthalocyanine photoredox catalyst in a biphasic medium.
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Iridium-catalyzed orthogonal and regioselective synthesis of triazole disulfides in aqueous media under mild conditions

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Green Chem., 2020, 22,2394-2398
DOI: 10.1039/D0GC00555J, Communication
Ming Li, Nan Zheng, Junhao Li, Yubin Zheng, Wangze Song
Triazole disulfides were prepared in water or biological media under mild conditions by orthogonal and regioselective Ir-catalyzed reactions.
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Using dialkyl amide via forming hydrophobic deep eutectic solvents to separate citric acid from fermentation broth

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Published On ::

Green Chem., 2020, 22,2526-2533
DOI: 10.1039/C9GC04401A, Paper
Lijuan Liu, Qifeng Wei, Yong Zhou, Xiulian Ren
The separation of citric acids was realized by utilizing hydrophobic deep eutectic solvents (DESs), which were formed by using N,N-dibutylacetamide as a hydrogen acceptor and citric acid as the hydrogen bond.
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Double-metal cyanide as an acid and hydrogenation catalyst for the highly selective ring-rearrangement of biomass-derived furfuryl alcohol to cyclopentenone compounds

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Green Chem., 2020, 22,2549-2557
DOI: 10.1039/C9GC04432A, Paper
Xiang Li, Qiang Deng, Lian Yu, Rui Gao, Zhikun Tong, Chenxi Lu, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Herein, novel green synthetic routes to 4-hydroxy-2-cyclopentenone (HCP) and 2-cyclopentenone (CPE) from biomass-derived furfuryl alcohol via double-metal cyanide catalysis are proposed.
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Introducing deep eutectic solvents as flux boosting and surface cleaning agents for thin film composite polyamide membranes

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Green Chem., 2020, 22,2381-2387
DOI: 10.1039/D0GC00762E, Communication
Nidhi Maalige R., Sweedal A. Dsouza, Matheus M. Pereira, Veerababu Polisetti, Dibyendu Mondal, Sanna Kotrappanavar Nataraj
This study introduced DESs as versatile and multi-tasking agents to modify the surface roughness and wettability of a TFC-PA membrane to boost the permeate flux rate and they also proved to be cleaning agents for organically fouled TFC-PA membranes.
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Scalable synthesis of hydroxymethyl alkylfuranoates as stable 2,5-furandicarboxylic acid precursors

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Green Chem., 2020, 22,2399-2402
DOI: 10.1039/D0GC00770F, Communication
Martin Jæger Pedersen, Arminas Jurys, Christian Marcus Pedersen
Hydroxymethyl furanoic acid and its derivatives have been synthesized in high yields and purity from gluconolactone.
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Visible Light-Induced Aerobic Oxidation of Diarylalkynes to -Diketones Catalyzed by Copper-superoxo at Room Temperature

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Published On ::

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00975J, Communication
Vaibhav Pramod Charpe, Arunachalam Sagadevan, Kuo Chu Hwang
We have developed the visible light induced simple copper(II) chloride catalyzed the oxidation of diarylacetylenes to -diketones by molecular oxygen at room temperature. The in-situ generated copper(II)-superoxo complex is a...
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Bio-based benzoxazine surfactant from amino acid

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00218F, Paper
Zheng Wang, Shu Yao, Kun Song, Xinjian Gong, Sujuan Zhang, Sheng Gao, Zaijun Lu
A novel bio-based benzoxazine (Ca-g) surfactant was synthesized via a Mannich reaction using renewable glycine and cardanol as raw materials. The structure of Ca-g was characterized by NMR, FT-IR, and...
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Computer-aided Nanotoxicology: Risk Assessment of Metal Oxide Nanoparticles via nano-QSAR

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Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00933D, Paper
Jiakai Cao, Yong Pan, Yanting Jiang, Ronghua Qi, Beilei Yuan, Zhenhua Jia, Juncheng Jiang, Qingsheng Wang
Since the applications of nanomaterials have been expanded to serve as a therapeutic methodology, the cytotoxicity accompanying with the nanomaterials drew lots of attention during the therapeutic process. It is...
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Visible-light-promoted oxidative desulphurisation: a strategy for the preparation of unsymmetrical ureas from isothiocyanates and amines using molecular oxygen

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Published On ::

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00070A, Paper
Ziyu Gan, Guoqing Li, Qiuli Yan, Weiseng Deng, Yuan-Ye Jiang, Daoshan Yang
A green and efficient visible-light promoted oxidative desulphurisation protocol has been proposed for the construction of unsymmetrical ureas under mild conditions with broad substrate scope and good functional group tolerance.
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Boron-doped CuO nanobundles for electroreduction of carbon dioxide to ethylene

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00730G, Communication
Qiang Wan, Jianling Zhang, Bingxing Zhang, Dongxing Tan, Lei Yao, Lirong Zheng, Fanyu Zhang, Lifei Liu, Xiuyan Cheng, Buxing Han
Herein, we synthesize B-doped CuO nanobundles for electrocatalytic CO2 reduction. Ethylene is the only multi-carbon product and a maximum ethylene faradaic efficiency (FE) of 58.4% can be achieved at −1.1 V (versus the reversible hydrogen electrode).
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Degradation of poly(ethylene terephthalate) catalyzed by metal-free choline-based ionic liquids

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00327A, Paper
Yachan Liu, Xiaoqian Yao, Haoyu Yao, Qing Zhou, Jiayu Xin, Xingmei Lu, Suojiang Zhang
Glycolysis of PET is a prospective way for degradation of PET to its monomer bis(hydroxyethyl)terephthalate (BHET) which can be polymerized again to form new qualified PET materials, and hence provides possibilities for a permanent loop recycling.
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Highly efficient bioconversion of flavonoid glycosides from citrus-processing wastes in solvent-buffer systems

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Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00669F, Paper
Yucong Zou, Xuan Xin, Haixia Xu, Hongwei Yuan, Xiaofeng Li, Yigang Yu, Guanglei Zhao
The present study demonstrates that whole-cell catalysis is a good choice to hydrolyze citrus flavonoid glycosides and their derivatives.
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