ph Upconversion nanoparticles incorporated with three-dimensional graphene composites for electrochemical sensing of baicalin from natural plants By pubs.rsc.org Published On :: RSC Adv., 2024, 14,36084-36092DOI: 10.1039/D4RA06540A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Na Zhang, Yilin Wu, Tian Liang, Yongxiang Su, Xusheng Xie, Tianren Zhang, Hongyan Wang, Keying Zhang, Rongli JiangThe fabrication of UCNP-3DG and its application in electrochemical detection of Bn in natural plant samples.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Bisphenol A (BPA) toxicity assessment and insights into current remediation strategies By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35128-35162DOI: 10.1039/D4RA05628K, Review Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joshua O. Ighalo, Setyo Budi Kurniawan, Banlambhabok Khongthaw, Junaidah Buhari, P. K. Chauhan, Jordana Georgin, Dison Stracke Pfingsten FrancoTo mitigate the toxic effects of BPA, there is a need to utilize hybrid remediation strategies for its removal from the aqueous environment.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph In silico molecular docking and ADMET prediction of biogenic zinc oxide nanoparticles: characterization, and in vitro antimicrobial and photocatalytic activity By pubs.rsc.org Published On :: RSC Adv., 2024, 14,36209-36225DOI: 10.1039/D4RA06890D, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hajara Akhter, Susmita Sarker Ritu, Shahariar Siddique, Fariha Chowdhury, Rehnuma Tasmiyah Chowdhury, Samina Akhter, Mahmuda HakimA facile green route to synthesize zinc oxide nanoparticles using watermelon rind extract with antimicrobial and photocatalytic potential.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Porous CaMnO3-promoted g-C3N4 as an effective photocatalyst for tetracycline degradation By pubs.rsc.org Published On :: RSC Adv., 2024, 14,36181-36192DOI: 10.1039/D4RA06407K, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Bo Zhang, Chaoqi Li, Shasha Liu, Lixuan Zhuang, Weiqi Zhang, Limei Huang, Zhenzhen Jia, Dongdong Chen, Xiang LiNon-expensive CaMnO3 perovskite oxide can assist in developing efficient g-C3N4-based photocatalysts aimed at removing antibiotics from wastewater.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Developing Ni0.5Zn0.5Fe2O4 ferrite with controlled particle size and morphology through optimized processing conditions of low energy solid state reaction By pubs.rsc.org Published On :: RSC Adv., 2024, 14,36264-36272DOI: 10.1039/D4RA07076C, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sarah Baayyad, Fatima-Zahra Semlali, El Kébir Hlil, Tarik Mahfoud, Hassan El Moussaoui, Mounir El AchabySoft magnetic materials, like Ni0.5Zn0.5Fe2O4, require high temperatures and regulated environments for their manufacture and processing, which can be highly energy intensive.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Physicochemical properties and mechanism of action of a new copper(II) pyrazine-based complex with high anticancer activity and selectivity towards cancer cells By pubs.rsc.org Published On :: RSC Adv., 2024, 14,36295-36307DOI: 10.1039/D4RA06874B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.B. Rogalewicz, T. Sierański, M. Szczesio, A. Olczak, K. Gobis, C. Orlewska, I. Korona-Głowniak, A. Korga-Plewko, M. Iwan, M. Michalczuk, J. Kubik, G. Adamczuk, M. Korga, N. Rutkowska, T. Boruta, K. Gas, M. Sawicki, E. Poleszak, W. Maniukiewicz, M. Świątkowski, A. CzylkowskaThe presented work underlines the importance of coordination compounds in the development of new anticancer agents that are safer and more efficient.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Wild elephant tramples four to death in Chhattisgarh’s Jashpur By www.thehindu.com Published On :: Sun, 11 Aug 2024 01:00:00 +0530 The jumbo was being tracked by forest officials when it entered the village Full Article Other States
ph PHOTOS: New Zealand stun India to end 36-year wait By www.rediff.com Published On :: Sun, 20 Oct 2024 13:21:20 +0530 Rachin Ravindra and Will Young remained calm under pressure after the loss of two early wickets to get the job done, earning New Zealand only their third win on Indian soil in 38 attempts going back to 1955. Full Article
ph PICS: Young, Ravindra see off Bumrah, Siraj in triumph By www.rediff.com Published On :: Sun, 20 Oct 2024 14:39:15 +0530 India arrived in Bengaluru seeking a big win over the 2021 champions to improve their chances of making a third successive final in June 2025, but will now need to battle to keep alive their run of 18 straight home series victories since 2012. Full Article
ph Ahead of COP29, India to emphasise Paris Agreement red lines on climate finance By www.thehindu.com Published On :: Sat, 09 Nov 2024 19:20:55 +0530 India is expected to stick to its stance of getting developed countries to increase climate finance, with a highly placed official saying, “We are flexible and open to different kinds of finance.” The official told The Hindu, “A key concern is that developed countries are trying to include developing countries (China and India) using new terms such as ‘major economies’ in a bid to get them to be part of NCQG.” Full Article Environment
ph Researchers document huge drop in African elephants in a half century By www.thehindu.com Published On :: Tue, 12 Nov 2024 14:41:01 +0530 Fresh evidence of this comes in a study that documents alarming population declines at numerous sites across the continent over about a half century. Full Article Environment
ph Is there a scientific reason why online phishing fraudsters target senior citizens? By www.thehindu.com Published On :: Tue, 12 Nov 2024 16:52:27 +0530 A research paper documents the fact that older people tend to underestimate their cognitive decline and this could affect their finances; experts say senior citizens could be more vulnerable to cyber scamsters and to financial abuse from their own families Full Article Health
ph AAPI Chief Dr Kathula suggests fast-track green cards for Indian physicians in the US By www.thehindubusinessline.com Published On :: Sun, 06 Oct 2024 10:16:48 +0530 Voices concerns that there are many physicians who are still on H-1B work visas even after staying in the US for over 15-20 years. Full Article World
ph Vice President Harris is in ‘excellent health,’ physician says By www.thehindubusinessline.com Published On :: Sat, 12 Oct 2024 18:59:36 +0530 Her most recent physical exam in April was “unremarkable,” Simmons added Full Article World
ph At least 126 dead and missing in massive flooding, landslides in Philippines By www.thehindubusinessline.com Published On :: Sun, 27 Oct 2024 09:31:45 +0530 Weather has cleared in many areas on Saturday, allowing cleanup work in most areas Full Article World
ph Thousands join effort to clean up catastrophic Spanish floods By www.thehindubusinessline.com Published On :: Sat, 02 Nov 2024 15:44:36 +0530 Volunteers went to Valencia's City of Arts and Sciences for the first coordinated clean-up organised by regional authorities Full Article World
ph Trump, Putin speak over phone, discuss ending war in Ukraine: Report By www.thehindubusinessline.com Published On :: Mon, 11 Nov 2024 08:47:09 +0530 ‘The two men discussed the goal of peace on the European continent’ Full Article World
ph Raphael Varane, former France and Real Madrid defender, announces retirement By www.thehindu.com Published On :: Wed, 25 Sep 2024 14:59:13 +0530 Raphael Varane won the FIFA World Cup with France in 2018 and helped Real Madrid to four Champions League titles and three Spanish league trophies Full Article Football
ph Messi scores twice for Inter Miami to win his 46th career trophy —MLS Supporters Shield By www.thehindu.com Published On :: Thu, 03 Oct 2024 11:10:14 +0530 Lionel Messi and Inter Miami have another trophy, along with home-field advantage throughout the Major League Soccer playoffs Full Article Football
ph Champions League: Raphinha scores hat-trick as Barcelona romps Bayern; Liverpool, City notch up wins By www.thehindu.com Published On :: Thu, 24 Oct 2024 06:00:00 +0530 Liverpool edged Leipzig 1-0 with a goal from Darwin Nunez; Manchester City routed Sparta Prague 5-0 with Erling Haaland scoring twice. Full Article Football
ph A ‘symphony’ of young Chinese aspirations behind gold’s rise to record By www.thehindubusinessline.com Published On :: Sun, 24 Mar 2024 22:00:00 +0530 China gold reserves went up for 16 months in a row till Feb 2024; its central bank bought the precious metal covertly Full Article Gold & Silver
ph Biosphere Reserves By www.berkshirepublishing.com Published On :: Mon, 28 Jun 2021 15:15:32 +0000 Abstract: UNESCO Biosphere Reserves were first established under the Man and Biosphere Programme of UNESCO in the 1970s. Their mandate has expanded beyond conservation to include sustainable development and local capacity enhancement. As institutions under UNESCO, they also work on “building peace” by seeking to reconcile relations between peoples, and between people and the The post Biosphere Reserves appeared first on Berkshire Publishing. Full Article Encyclopedia of Sustainability Advance Articles
ph Bulk photovoltaic effect in a zero-dimensional room-temperature molecular ferroelectric [C8N2H22]1.5[Bi2I9] By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02698E, PaperZhibo Chen, Tianhong Luo, Jinrong Wen, Zhanqiang Liu, Jingshan Hou, Yongzheng Fang, Ganghua ZhangNon-toxic molecular ferroelectrics have attracted significant interest due to their unique flexibility, low costs, and environmental friendliness. However, the variety of such materials with narrow bandgaps and above room temperature...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)2MnH] on their kinetic hydricity By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02496F, PaperSergey A. Kovalenko, Ekaterina S. Gulyaeva, Elena S. Osipova, Oleg A. Filippov, Anastasia Danshina, Laure Vendier, Nikolay V. Kireev, Ivan A. Godovikov, Yves CANAC, Dmitry A. Valyaev, Natalia Belkova, Elena ShubinaOctahedral Mn(I) complexes bearing tridentate donor ligands [(L∩L’∩L’’)(CO)2MnX] have recently emerged as major players in catalytic (de)hydrogenation processes. While most of these systems are still based on structurally rigid pincer...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02690J, CommunicationAlexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di SunFirst metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Triple-shelled Ni@MnO/C hollow spheres with enhanced performance for rechargeable zinc-ion capacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02303J, PaperTao Xiang, Zaiting Qu, Daohong Zhang, Chenglong Hu, Zhen Chen, Qiufan WangNi/MnO@C nanospheres with different core–shell structures are obtained by using Ni3Mn-MOFs as templates, exhibiting excellent electrochemical properties as cathodes in zinc-ion storage.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02469A, PaperZhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei QinHeteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Oxaphosphiranes: isolable phosphorus-containing epoxide rings By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02915A, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Niklas Volk, Antonio García Alcaraz, Selvakumar Balasubramaniam, Jannik Heumann, Gregor Schnakenburg, Arturo Espinosa Ferao, Rainer StreubelA new efficient protocol for the synthesis of isolable oxaphosphiranes based on easy decomplexation is described. Theoretical studies unveil a singlet carbene-like FMO situation at phosphorus explaining the reactions with oxidants, acids and bases.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT01765J, PaperRomain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim StorrThe synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02613F, PaperAlena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. DybtsevFour new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Activation of small molecules by ambiphilic NHC-stabilized phosphinoborenium cation: formation of boreniums with B-O-C, B-O-B, and B-O-P structural motifs By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02656J, PaperTomasz Wojnowski, Anna Ordyszewska, Hanna Halenka, Iwona Anusiewicz, Jarosław Chojnacki, Kinga Kaniewska-Laskowska, Rafał GrubbaThe reactivity of the phosphinoborenium cation supported by a 1,3,4,5-tetramethylimidazolin-2-ylidene ligand toward small molecules was explored. The phosphinoborenium cation exhibited dual Lewis acid–base properties due to the presence of the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph The Bonding Situations in Ruthenium Chalcogenonitrosyl Compounds: A Physical Reasoning By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02680B, PaperRichard Fragnani Cardoso, Vinícius Acir Glitz, Renato Luis Tame Parreira, Giovanni Finoto Caramori, Luis Henrique Silveira LacerdaThis research presents, for the first time, a comprehensive and rigorous investigation of ruthenium(II) chalcogenonitrosyl bonding situations in two sets of coordination compounds: [Ru(NE)Cl2(L_{OEt})] (1a-4a) and [Ru(NE)Cl2(L_{OEt})]- (1b-4b), where E...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02721C, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias WesterhausenThe diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Design and theoretical analysis of a tunable bifunctional metasurface absorber based on vanadium dioxide and photoconductive silicon By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02563F, PaperChangfeng Fu, Xinke Wang, Yicheng Zhang, Jiaxin Ju, Wei Fan, Xiaobo Yan, Lianfu HanA bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Morphology-dependent Li+ ion dynamics in X-ray amorphous and crystalline Li3PS4 prepared by solvent-assisted synthesis By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02636E, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jonas Spychala, Christoph Mandl, Katharina Hogrefe, H. Martin R. Wilkening, Bernhard GadermaierIonic conductivity of Li3PS4 if synthesized by a solvent-assisted method strongly depends on overall and surface morphology. Amorphous Li3PS4 shows a rather high conductivity which is only slightly enhanced when going to the (nano-)crystalline form.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17742-17755DOI: 10.1039/D4DT01727G, PerspectiveEduarda Andrade, Filipe A. Almeida Paz, Flávio FigueiraMOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17963-17975DOI: 10.1039/D4DT02014F, PaperMorigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin ZhaoConstruction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Ruthenium, copper and ruthenium–copper complexes of an unsymmetrical phosphino pyridyl 1,8-naphthyridine PNNN ligand By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18037-18046DOI: 10.1039/D4DT02755H, PaperJingyun Wu, Michael A. Stevens, Michael G. Gardiner, Annie L. ColebatchA new unsymmetrical dinucleating PNNN ligand is reported, the versatility of which is demonstrated by formation of heterobimetallic, homobimetallic and monometallic complexes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Structure modification and luminescence regulation in new violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors via cation substitution By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17989-18002DOI: 10.1039/D4DT02195A, PaperJie Zhang, Langping Dong, Feng Wang, Jingshan Hou, Yongzheng FangA series of violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors with tunable luminescence for high-quality white LEDs was developed through cation regulation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18027-18036DOI: 10.1039/D4DT02642J, PaperAlexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. SukhikhBased on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Tunability of triplet excited states and photophysical behaviour of bis-cyclometalated iridium(III) complexes with imidazo[4,5-f][1,10]phenanthroline By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17934-17947DOI: 10.1039/D4DT01996B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Katarzyna Choroba, Joanna Palion-Gazda, Mateusz Penkala, Patrycja Rawicka, Barbara MachuraThe impact of cyclometalating ligands on the photophysical behaviour of heteroleptic Ir(III) complexes with imidazo[4,5-f][1,10]phenanthroline. [Ir(ppy)2(imphen)]+ is a 3MLLCT emitter, while [Ir(pybzth)2(imphen)]+ has a predominant 3LCN∩C character.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Neutral mononuclear indium(III) photosensitizers for CO2 photoreduction By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17772-17776DOI: 10.1039/D4DT02595D, CommunicationZaichao Zhang, Li-Zhi Fu, Piao He, Xiao-Yi YiNeutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligands are employed as photosensitizers in photocatalytic CO2 reduction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17976-17988DOI: 10.1039/D4DT02355B, PaperThe Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang TranVarious 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17789-17793DOI: 10.1039/D4DT02791D, CommunicationGargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. SenThe reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17777-17782DOI: 10.1039/D4DT02766C, Communication Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. MeadeA Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17783-17788DOI: 10.1039/D4DT02336F, CommunicationDanijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. SwiegersCa-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02873B, PaperSofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. IversenBy investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02703E, PaperVilakkathala U. Krishnapriya, Cherumuttathu H. SureshDinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ph A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
