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DABSO-Mediated Pummerer Reaction Enables One-Pot Synthesis of Pyrroloquinolines for Accessing Marinoquinolines: Mechanistic, Photophysical and Pharmacological Investigations

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01512F, Research Article
Rahimuddin Khan, Dipun Kumar Penthi, Aditi Chatterjee, Chandrakanta Sahoo, Shanti Gopal Patra, Viswanathan Arun Nagaraj, Tabrez Khan
A new one-pot acid- and exogenous oxidant-free synthesis of pyrrolo[2,3-c]quinolines has been developed. The strategy involves chemoselective reduction of the 3-(2-nitrophenyl)-1H-pyrroles (pyrrolnitrin derivatives) and subsequent DABSO-facilitated Pummerer reaction in the...
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Catalyst-free C–H methylation of heteroarenes enabled by electron donor–acceptor complex photoactivation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01309C, Research Article
Jiayang Wang, Baoer Shao, Haixia Ge, Huiyu Xue, Xiangyuan Ding, Yuqi Li, Peiyao Sheng
A visible-light-induced direct C–H methylation of heterocycles (including quinoxalinones, pyrazinones, quinolinones and coumarins) with methylamines via EDA complex photoactivation was developed.
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Thiocyanoalkylation of Alkenes via Dual Photoredox and Copper Catalysis

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01864H, Research Article
Xu Wang, Bi-Yin Xiao, Qi-Xuan Jiang, Wei Huang, Feng-Hua Zhang
Organic thiocyanates are commonly used as an essential organic synthesis intermediate and widely present in various drug molecules and bioactive molecules. Herein, a copper and photoredox catalyzed thiocyanoalkylation reaction of...
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Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01627K, Research Article
Bo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long Zhu
We report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.
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Magic effect of diphenylprolinol silyl ether for the enantioselective allenation of 2-alkynals

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00984C, Research Article
Guolin Wu, Zhen Liu, Shiwen Fan, Wenyao Li, Xue Zhang, Hui Qian, Shengming Ma
Chiral diphenylprolinol silyl ethers have been successfully identified for the enantioselective allenation reaction of terminal alkynes and 2-alkynals, delivering a diverse set of chiral allenynes with high efficiency.
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Visible-light responsive defluorination-acyl fluoride exchange for photoclick labeling based on phenoxazine chromophores

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01870B, Research Article
Lijun Deng, Sitong Li, Cefei Zhang, Yuqiao Zhou, Zhishan Su, Changwei Hu, Xiaohu Zhao, Zhipeng Yu
We developed a new generation of photo-DAFEx reagents to realize photoaffinity labeling for drug discovery under 405 nm light control.
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PIFA-Mediated cyclization of methyl(2-(1-phenylvinyl)phenyl)sulfane for the concise, flexible, and scalable de novo synthesis of C3-arylated benzo[b]thiophenes

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01589D, Research Article
Xinya Liu, Olivier Provot, Christine Tran, Jean-Francois Soule, Abdallah Hamze
The well-decorated arylated benzo[b]thiophene scaffold is a pivotal structural motif with diverse applications in medicinal chemistry. This paper outlines a de novo synthesis of C3-arylated benzo[b]thiophenes, showcasing its flexibility and...
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Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01641F, Research Article
Peng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai Li
An FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.
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Telangana pharmaceutical industries logged 97 major fire accidents in past decade: Fire Services Director-General Y. Nagi Reddy

The new government would like to decentralise and set up pharma villages, in 10 clusters, Special Chief Secretary Jayesh Ranjan said




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Agitated villagers chase govt officials over proposed pharma plant in Vikarabad

The villagers have been protesting for several weeks against the proposed pharma company




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India cancel intra-squad match to prioritise net practice ahead of Border-Gavaskar Trophy

India cancels intra-squad match with ‘A’ side in Australia tour for more net practice, focusing on Test series preparation




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BCCI to discuss New Zealand whitewash, some senior players could be phased out post-Australia series

There is a high possibility that the five-match Test series against Australia could be the final one for at least two of the four seniors among Rohit Sharma, Virat Kohli, Ravindra Jadeja and Ravichandran Ashwin.




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Border-Gavaskar trophy: Captain Rohit Sharma doubtful for Perth Test

Rohit along with a large India squad will depart for Perth in two batches – on November 10 and 11 – and the captain may come back home for a while due to personal reasons.




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Wriddhiman Saha announces retirement from cricket after this year's Ranji Trophy

Veteran cricketer Wriddhiman Saha announces retirement, last season in Ranji Trophy, ending a cherished journey in cricket




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Wriddhiman Saha to retire after this season Ranji Trophy




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RANJI TROPHY | Mumbai gets a Shreyas boost as it takes on Odisha

CRICKET | The defending champion will look to reignite its topsy-turvy campaign thus far with a dominant show against a side that has struggled to get going this season




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Ranji Trophy | Powerful Tamil Nadu holds all the aces against Assam

Sai Kishore’s return boosts the visiting team; Ghadigaonkar & Co. will have to rack up big scores to provide meaningful competition




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Ranji Trophy | Kerala has its task cut out against a balanced UP side

Rain is expected to play spoilsport once again; the host will be hoping its seniors deliver the goods against a formidable opponent




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Ranji Trophy | Battle of equals as Karnataka hosts Bengal

Both teams’ bench strength will be tested in this crucial encounter as some of the main players have been called up for national duty




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Australian pacer Boland looks to keep KL Rahul under pressure ahead of Border-Gavaskar Trophy

Rahul made a hundred on his debut tour to Australia in 2015, a 110 at Sydney, but his overall performance Down Under remains scratchy, evidenced by an average of 20.77 across four Tests.




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RANJI TROPHY | It is a Lad and Shreyas show as Mumbai tears into Odisha’s bowling

CRICKET | Teenager Raghuvanshi sets the ball rolling at the top of the order after visiting captain Poddar’s ill-judged move to insert the home team in




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RANJI TROPHY | Jalaj Saxena torments Uttar Pradesh with a five-wicket haul

CRICKET | Kerala seizes control as the off-spinner becomes the only player to score 6000 runs and take 400 wickets in the tournament after his latest five-wicket haul




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Ranji Trophy | Shreyas and Lad’s regal partnership takes reigning champion to mammoth score

The duo’s 354-run stand for the fourth wicket helps Mumbai declare its first innings at 602 for four before dismissing five Odisha batters for 146 at the end of day two




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Ranji Trophy | Lad revels in second innings for Mumbai

The batter’s unbeaten 169 against Odisha in the Ranji Trophy marks his highest First Class score




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Ranji Trophy | Bhambri leads the way as Chandigarh nudges ahead of Delhi

Almost all batters make handy contributions as the host takes a 48-run first-innings lead; spinners Badoni and Mathur shine with the ball for the visitor




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Ranji Trophy | Sachin Baby, Salman help Kerala seize control

The duo’s 99-run partnership for the sixth wicket helps the host reach 340 for seven; the home team leads by 178 at the end of day two




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Border-Gavaskar Trophy: Marcus Harris thrusts himself into pole position in Australia ‘bat-off’

The diminutive 32-year-old steered Australia A to 223 in reply to India A’s 161 on day two of their four-day match at the Melbourne Cricket Ground — seen as a bat-off for the Test spot left vacant by David Warner’s retirement.




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Ranji Trophy | Pacers put Bengal in driver’s seat against Karnataka

Porel’s four-for and Sindhu’s three-wicket haul help the visitor bundle out the host for 221 before reaching 127 for three in its second essay at the end of day three




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Ranji Trophy | Birla’s six-for puts Chandigarh in driving seat against Delhi

The host ends day three at 46 for no loss after dismissing the visitor for 250 in its second innings and needs 157 more runs to clinch an outright victory




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Ranji Trophy | Mulani puts Mumbai within striking distance of a big win against Odisha

The left-arm spinner’s six-wicket haul helps the defending champion secure a 317-run lead; Odisha in trouble at 126 for five after following on




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Ranji Trophy | Rain interrupts Kerala’s push for outright win against Uttar Pradesh

After conceding a 233-run lead, the visitors slip to 66 for two when a downpour ends the day’s play in the post-lunch session; Nizar misses century




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'Lengthy' physics section kept students on tenterhooks

Many of them said they had not prepared thoroughly for AIPMT as it was only ‘an option’




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Hidden Cuba: A Photojournalist’s Unauthorized Journey to Cuba to Capture Daily Life — 50 years After Castro’s Revolution

Renowned American photographer Jack Watson travelled to Cuba on a legal humanitarian visa. He chronicled his journey with breath-taking, and often heart breaking images of he Cuba people, cites, and countryside. Watson describes his visit:  “I had stepped back in time 50 years — this was my first impression of Cuba. My journey, which began […]




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Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction

RSC Adv., 2024, 14,35163-35171
DOI: 10.1039/D4RA06595F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng Huang
Graphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.
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Synthesis of F127-GA@ZnO nanogel as a cisplatin drug delivery pH-sensitive system

RSC Adv., 2024, 14,35005-35020
DOI: 10.1039/D4RA06514J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nguyen Ngoc Son, Vu Minh Thanh, Nguyen Thi Huong
In this study, a novel drug delivery system based on zinc oxide nanoparticles (ZnO NPs) was developed for the enhanced delivery of cisplatin (CPT) to improve cancer treatment.
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Dissolution of simulated nuclear waste glass at high surface area to solution volume, high pH and 70 °C: comparison of international simple glass and SON68 glass

RSC Adv., 2024, 14,35114-35127
DOI: 10.1039/D4RA04936E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Felix Brandt, Sébastien Caes, Martina Klinkenberg, Juri Barthel, Sanheng Liu, Karel Lemmens, Dirk Bosbach, Karine Ferrand
Long-term dissolution experiments on two nuclear waste glasses indicate a diffusion-controlled dissolution mechanism including the formation of a porous surface altered layer and secondary phases without a resumption to higher rates.
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Morphological analysis of Pd/C nanoparticles using SEM imaging and advanced deep learning

RSC Adv., 2024, 14,35172-35183
DOI: 10.1039/D4RA06113F, Paper
Open Access
Nguyen Duc Thuan, Hoang Manh Cuong, Nguyen Hoang Nam, Nguyen Thi Lan Huong, Hoang Si Hong
In this study, we present a comprehensive approach for the morphological analysis of palladium on carbon (Pd/C) nanoparticles utilizing scanning electron microscopy (SEM) imaging and advanced deep learning techniques.
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Design, synthesis, biological evaluation, and in silico studies of novel N-substituted-2-(3,4,5-trimethoxyphenyl)-1H-benzo[d]imidazole-6-carboxamides as promising anticancer agents

RSC Adv., 2024, 14,35323-35335
DOI: 10.1039/D4RA04492D, Paper
Open Access
Navid Dastyafteh, Manica Negahdaripour, Mohammad Hosein Sayahi, Mina Emami, Younes Ghasemi, Elham Safaei, Homa Azizian, Zahra Pakrouh Jahromi, Mehdi Asadi, Mohammad Reza Mohajeri-Tehrani, Fateme Zare, Minoo Shahidi, Zahra Pooraskari, Sayed Mahmoud Sajjadi-Jazi, Bagher Larijani, Mohammad Mahdavi, Sara Ranjbar
Synthesis and cytotoxicity evaluation of novel benzimidazoles were explained. The most potent derivative was subjected to cell cycle, apoptosis, and in silico investigations. Compound 5o proved to be a promising anticancer agent.
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Phenylsulfonate as a photolabile group for intramolecular carbon–carbon cross-coupling reactions

RSC Adv., 2024, 14,35227-35231
DOI: 10.1039/D4RA06592A, Paper
Open Access
Simon Plaize, Jean-François Morin
This study reports the use of phenylsulfonates as photolabile groups to generate aryl radicals, which undergo radical cyclization to yield triphenylene derivatives. The reaction is efficiently carried out under 365 nm with a triplet sensitizer.
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Ab initio study of electronic, elastic, thermodynamic, photocatalytic properties of double antiperovskite, Cs6AgBiX2 (X = Cl, Br, I)

RSC Adv., 2024, 14,35348-35359
DOI: 10.1039/D4RA05661B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laraib Sajid, M. Usman Saeed, S. H. Mashadi, S. Sheryar Abid, Shamiala Pervaiz, Zeeshan Ali, Yousef Mohammed Alanazi, Aziz-Ur-Rahim Bacha, Y. Saeed
We use DFT to study the structural, electronic, optical, photocatalytic, mechanical, vibrational, and thermodynamical behaviors of new double antiperovskite Cs6AgBiX2 (X = Cl, Br, I).
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Surface science studies of the coverage dependent adsorption of methyl acetate and methyl propanoate on graphite

RSC Adv., 2024, 14,35373-35385
DOI: 10.1039/D4RA04466E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jack E. Fulker, Wendy A. Brown
The adsorption of methyl acetate and methyl propanoate has been studied on a graphite surface at 28 K. TPD data show that the desorption energy of both molecules is highly coverage dependent with repulsive interactions being seen at low coverages.
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Synthesis, optical, electrochemical, and computational study of benzene/thiophene based D–π–A chromophores

RSC Adv., 2024, 14,35424-35437
DOI: 10.1039/D4RA02668C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Michaela Babejová, Iveta Třísková, Libuše Trnková, Hugo Semrád, Markéta Munzarová, Dominik Heger, Dana Nachtigallová, Milan Potáček
Synthesis of novel (D–π–A) chromophores with one electron-donating + withdrawing group at opposite ends of terphenyl, terthiophene, or 2,5-diphenylthiophene, analysed upon results of HOMO–LUMO gaps, determined via CV and in terms of MO via DFT.
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Correction: Luminescence properties of Bi3+/Sm3+ co-doped K3Gd5(PO4)6 phosphors for self-referencing optical thermometry

RSC Adv., 2024, 14,35447-35447
DOI: 10.1039/D4RA90130D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jing Wang, Mingjun Song, Junpeng Xue, Shala Bi, Hyo Jin Seo
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Construction of a zero-dimensional halide perovskite in micron scale towards a deeper understanding of phase transformation mechanism and fluorescence applications

RSC Adv., 2024, 14,35490-35497
DOI: 10.1039/D4RA06404F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lili Xie, Haiyan Qiu, Yuxin Chen, Yingxue Lu, Yanyan Chen, Lanlan Chen, Shanwen Hu
A zero-dimensional halide perovskite in micron scale is constructed to gain a deeper understanding of phase transformation mechanism and better fluorescence applications.
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Synthesis and antiproliferative activity of 2-oxo-3-phenylquinoxaline derivatives and related compounds against colon cancer

RSC Adv., 2024, 14,35679-35695
DOI: 10.1039/D4RA06822J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. S. Gomaa, Abdulghany H. A. Ahmed, S. M. El Rayes, Ibrahim A. I. Ali, Walid Fathalla, Mansour S. Alturki, Abdulaziz Hassan Al Khzem, Atiah H. Almalki, Mohammed F. Aldawsari, F. H. Pottoo, Firdos A. Khan, Mohd Amir
The impact of compound 7j on colon cancer cells (HCT-116). Fig. (A) shows the control cells Fig. (B) shows the treatment cells. The arrows show chromatin condensation, nuclear augmentation, and formation of apoptotic bodies.
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Piezoresistivity and strain-sensing behaviour of poly(butylene adipate-co-terephthalate)/multiwalled carbon nanotube nanocomposites

RSC Adv., 2024, 14,35715-35726
DOI: 10.1039/D4RA04826A, Paper
Open Access
Kedar Nath Dhakal, Ralf Lach, Wolfgang Grellmann, Beate Krause, Jürgen Pionteck, Rameshwar Adhikari
The interconnectedness of the exfoliated multi-walled carbon nanotubes well dispersed in the PBAT matrix (TEM image; left) leads to strain-sensing properties at lower strains as illustrated by the variation of ΔR/R0 as a function of mechanical strain with time (right).
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Retraction: Highly sensitive cadmium sulphide quantum dots as a fluorescent probe for estimation of doripenem in real human plasma: application to pharmacokinetic study

RSC Adv., 2024, 14,35992-35992
DOI: 10.1039/D4RA90134G, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marwa F. B. Ali, Baher I. Salman, Samiha A. Hussein, Mostafa A. Marzouq
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Characterization and quantification of the phytochemical constituents and anti-inflammatory properties of Lindera aggregata

RSC Adv., 2024, 14,36101-36114
DOI: 10.1039/D4RA05643D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Song-Song Wen, Yong-Jun Liu, Yu-Lin Liu, Yan Zhao, Xiao-Xi Xu, Chang-Chuan Guo, Chong Niu, Wei-Jian Wang, Yu-Wen Xu, Na Zhang
This study developed a method to analyze the bioactive compounds in Lindera aggregata roots, identifying 80 compounds, with 16 quantified, and found that specific compounds exhibit anti-inflammatory effects.
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Complexes between 2,2'-azobis(2-methylpropionamidine) dihydrochloride (AAPH) and cucurbit[n]uril hosts modulate the yield and fate of photolytically-generated AAPH radicals

RSC Adv., 2024, 14,35980-35991
DOI: 10.1039/D4RA07150F, Paper
Open Access
Angie C. Forero-Girón, Mauricio Oyarzún, Kevin Droguett, Denis Fuentealba, Soledad Gutiérrez-Oliva, Barbara Herrera, Alejandro Toro-Labbé, Eduardo Fuentes-Lemus, Michael J. Davies, Camilo López-Alarcón, Margarita E. Aliaga
AAPH-cucurbit[n]uril systems were experimentally and theoretically studied. Radical yields formed upon photolysis of AAPH were altered by complexation with CB[8] in a stoichiometry-dependent manner, however, radical yields were not changed by CB[6].
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From e-waste to eco-sensors: synthesis of reduced graphene oxide/ZnO from discarded batteries for a rapid electrochemical bisphenol A sensor

RSC Adv., 2024, 14,36073-36083
DOI: 10.1039/D4RA04046E, Paper
Open Access
Md Humayun Kabir, Md Yeasin Pabel, Nishat Tasnim Bristy, Md. Abdus Salam, Muhammad Shahriar Bashar, Sabina Yasmin
E-waste-derived reduced graphene oxide/ZnO forfast electrochemical detection of bisphenol A (BPA).
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