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Competition mechanism of self-trapped excitons and Te4+ ions emission in the Te4+ doped vacancy-ordered double perovskite Rb2HfCl6 and its excellent properties

Inorg. Chem. Front., 2024, 11,2457-2470
DOI: 10.1039/D4QI00109E, Research Article
Ruxin Liu, Kaishun Zou, Guanglu Zhang, Min Feng, Mingxuan Li, Juncheng Liu
The luminescence mechanism of Te4+-doped VODPs is reported. Te4+-doped Hf-based VODPs exhibit luminescence characteristics that are more in line with those of Te4+ ions, while Te4+-doped Sn- and Zr-based VODPs have STEs emission characteristics.
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A composite electrolyte based on aluminum oxide filler/polyester polymer via in situ thermal polymerization for long-cycle sodium metal batteries

Inorg. Chem. Front., 2024, 11,2300-2311
DOI: 10.1039/D4QI00391H, Research Article
Qiujun Wang, Xin He, Di Zhang, Zhaojin Li, Huilan Sun, Qujiang Sun, Bo Wang, Li-Zhen Fan
The introduction of Al2O3 regulates the solvation structure of Na+, which is conducive to the formation of inorganic-rich SEI. Na|THFA-5|Na cell maintains low polarization voltage, indicating that uniform Na depositions was successfully achieved.
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Effect of -OH on the Thermal Enhancement Properties of NIR-II Lanthanide Doped Nanoparticles in Water

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00147H, Research Article
Yingping Huang, Jie Hu, Yongwei Guo, Zihao Wang, Fulin Lin, Haomiao Zhu
Thermal enhanced nanothermometry has attracted great attention due to its high thermal sensitivity, however, most of studies are focused on the upconversion nanoparticles (NPs) in forms of powder. In the...
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00200H, Research Article
Yong-Sheng Shi, Tong Xiao, Dong-Dong Yang, Xiangjun Zheng
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Structural and electrochemical properties of Tan+1Cn MXene anode materials for metal-ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02335D, Research Article
Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
Density functional theory calculations show that Tan+1Cn and Tan+1CnO2 MXenes have excellent open circuit voltages and maximum storage capacities for use in alkali metal-ion batteries.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Anisotropic ZSM-5 nanorod assemblies: facile synthesis, epitaxial growth, and strikingly enhanced stability in benzene alkylation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00287C, Research Article
Peng Zhu, Yiren Yu, Guoshu Gao, Yumeng Zhao, Yuting Jiao, Haiou Liu, Guodong Liu, Xiongfu Zhang, Guohui Yang
A novel bundle-like ZSM-5 nanorod assembly was facilely synthesized by adopting a CTAB-aided seed-induced strategy for highly efficient alkylation of benzene with ethanol.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Advances in technical strategies for monitoring the reduction of platinum(IV) complexes

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00459K, Review Article
Open Access
Shu Chen, Qiyuan Zhou, Ka-Yan Ng, Zoufeng Xu, Weikang Xu, Guangyu Zhu
The reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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ies

Optimism in global commodities market over Chinese measures may be short-lived, say analysts

Subdued demand, struggling property sector may exert downward pressure on metals




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Crude oil futures rise amid declining US inventories

December Brent oil futures rose to $74.37, while November WTI futures climbed to $70.59.




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Kandla Customs Commissioner orders release of ship detained in organic rice export irregularities

Tells Kandla traffic manager to allow another ship to set sail after getting release order from Gujarat HC




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Crude oil futures rise as US inventories decline 

Market players are also assessing the supply risks from West Asia following the tensions in the region




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India’s diesel consumption likely to surpass 93 mt in FY25

Both August and September this year have witnessed a fall in diesel usage




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Diesel, petrol demand to grow 50,000-55,000 barrels per day Y-o-Y in Oct-Dec

India’s appetite for oil products in October-December is set to get a boost from the upcoming festival season as well as the agricultural season




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Crude oil futures dip after Israeli attack avoids Iranian oil facilities 

November natural gas futures were trading at ₹254.50 on MCX during the initial hour of trading on Monday against the previous close of ₹258.20, down by 1.43 per cent




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Crude oil trades higher as industry data shows decrease in US inventories 

Official data on crude oil inventory level in the US is expected later on Wednesday




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Communities lead

The theme on World AIDS Day (December 1) is ‘Let Communities Lead’




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Counting calories, steps and taking off-road rides

Varun Madan, Founder and CEO, Salad Days, on food, fitness, travel and much more.




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Pharmacies journey through litigations and another election

Chemists’ manifesto: Call for fair play gets louder amidst deep discounts from online pharmacies




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Pranayam, veggie smoothies and adventure sports

Dr Sanjay Katkar on staying active, healthy eating and meditation for a balanced lifestyle




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Reviewing TRIPS, an opportunity for evidence-based policies

Colombia calls for review of TRIPS Agreement implementation, highlighting need for evidence-based IP law and policy




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‘Closing the gap’ to ensure healthy babies

Despite the benefits, only half of Indian infants are breastfed successfully—what’s holding us back?




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Companies harness pester-power to boost sales



  • Bindu D Menon

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Marut Dronetech raises $6.2 mn from Lok Capital in Series A funding

Funds to be deployed on developing advanced agri drones, expanding channel partner network and service centres




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Fisheries Ministry, CMFRI, NFDB collaborate to showcase drone tech in marine sector

An awareness workshop will be held on November 8, featuring demonstrations of drone applications for tasks such as aquaculture input dispensing, water body monitoring, and marine mammal assessments




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Exporting community welcomes Tea Board’s move to issue notice to over 2,000 companies for defaulting on export returns

Every business licensee registered with Tea Board must submit monthly export returns through the online portal




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This time for Africa: Asian tea producers to explore possibilities to create market opportunities in Africa

Asia Tea Alliance plans to expand tea market in Africa to increase global consumption, focusing on sustainability and quality




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The economic impact of cashew farming: How nut agriculture fuels local economies

With proper investments and policy support, this sector could deliver even greater benefits




ies

Key challenges faced by farmer producer companies in the agricultural ecosystem

Building genuine connections and understanding the intrinsic motivations of farmers can create a vibrant ecosystem




ies

Airlines, insurance companies may relook at disruption cover

Over the last seven days nearly 100 flights operated by Indian carriers have received bomb threats posted on social media resulting in flight disruptions, diversions and scrambling of fighter jets




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Skye Air intensifies quick-commerce partnerships, targets expansion to six cities within two years

The firm focuses on delivering consignments within 10 minutes for quick-commerce clients and within four hours for e-commerce clients




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Air India, Singapore Airlines expand codeshare ties 

Duo to add 11 Indian and 40 international destinations in their first extensive expansion of arrangement since 2010




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Cabinet greenlights ₹6,800 crore railway projects in key allies-run States of Andhra Pradesh, Bihar

Emphasises development over politics, with religious and trade significance




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Pawfect buddies: Mumbai Airport revives emotional support dog program at Terminal 2

MIAL is the only Indian airport offering such a service, features nine trained dogs including a Golden Retriever, a Maltese, a rescued Husky, Shih Tzu, Lhasa Apso, and Labrador




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IAF to outsource some MRO facilities to industry for the first time

About 80 cases of outsourcing certain MRO facilities are at various stages of approvals




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Cyient DLM signs pact with Honeywell Aerospace Technologies

Cyient DLM The company signs a 16-year programme forecast to develop liquid cooling loops that will be used in select applications of Micro VCS




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Vistara bids adieu with last flight to Singapore; integrated Air India takes to the skies

UK115 flight from Delhi to Singapore was the last flight of Vistara with the code 'UK' while UK986 from Mumbai to Delhi was the carrier's last domestic flight




ies

Regional airline Trujet to cut salaries by 50-60%

Pandemic has hit us hard, says the airline in a letter to staff




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Now, you can send money abroad in 100 currencies via Axis Bank app

Customers can send up to $25,000 per transaction for various purposes




ies

Ahammune Biosciences raises Pre-Series A funding from Ideaspring Capital, Indian Angel Network




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Airtel rolls out Covid support initiative for medium, small size companies

Businesses will be able to set up a cloud communication platform with a Covid SOS feature




ies

The melodies keep coming...

Vidya Sagar talks about the melodious music of Thoppil Joppan.




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Market capitalization of privately listed companies surged 6.4 times, PSUs grew 5 times over last 10 years: Motilal Oswal




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When microplastics/plastics meet metal–organic frameworks: turning threats into opportunities

Chem. Sci., 2024, 15,17781-17798
DOI: 10.1039/D4SC05205F, Review Article
Open Access
Pengfei Wu, Mengting Guo, Ran-Wei Zhang, Qing Huang, Guibin Wang, Ya-Qian Lan
The study discussed how MOFs treat microplastics, how to make plastic-based MOFs, and how MOF@plastic composites can be used. It aids in understanding how to convert plastic/microplastic concerns into opportunities for high-valued products.
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A critical factor in reactive oxygen species (ROS) studies: the need to understand the chemistry of the solvent used: the case of DMSO

Chem. Sci., 2024, 15,17843-17851
DOI: 10.1039/D4SC05038J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shubham Bansal, Binghe Wang
Reactive oxygen species (ROS) play critical roles in normal physiological processes including cellular signaling and immune responses.
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A facile self-saturation process enabling the stable cycling of a small molecule menaquinone cathode in aqueous zinc batteries

Chem. Sci., 2024, 15,17971-17978
DOI: 10.1039/D4SC04685D, Edge Article
Open Access
Shuo Li, Guoli Zhang, Qianrui Li, Tianshun He, Xiaoqi Sun
A facile self-saturation strategy, realized by the introduction of a hydrophobic methyl group on naphthoquinone, is demonstrated to suppress the dissolution of small molecule cathode materials and achieve stable cycling in aqueous zinc cells.
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Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors

Chem. Sci., 2024, 15,18111-18126
DOI: 10.1039/D4SC04852K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Feng An, Jan Brossette, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse, Armin R. Ofial
Combined experimental and quantum-chemical studies were used to characterise the philicity/fugality features of tertiary phosphines and Michael acceptors in phospha-Michael reactions, which are key steps in phosphine-catalysed organic reactions.
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The Effect of gem-Difluorination on the Conformation and Properties of a Model Macrocyclic System

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05424E, Edge Article
Open Access
Laurent Knerr, Thomas Cogswell, Marie. Ahlqvist, Richard James Lewis, Anneli Nordqvist, Christian Sköld
Conformational control of drug candidates to engineer improved potency and ADME properties is an ongoing area of research. Macrocyclic rings tend to offer a greater degree of rigidity than non-cyclised...
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Zinc borylation and reduction by a diborane(4) species via B–O bond formation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06389A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Liam P. Griffin, Simon Aldridge
Zinc boryl and metal–metal bonded Zn(I) complexes can be accessed from a common Zn(II) iodide precursor and bis(pinacolaton)diboron(4).
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Bridge Editing of Spin-Flip Emitters gives Insight into Excited State Energies and Dynamics

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05860G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Florian Reichenauer, Robert Naumann, Christoph Förster, Winald Robert Robert Kitzmann, Antti-Pekka M. Reponen, Sascha Feldmann, Katja Heinze
Six-coordinate chromium(III) complexes with high spin-flip (SF) photoluminescence quantum yields and lifetimes (molecular rubies) have attracted huge interest in the past years due to their applicability in sensing, photocatalysis or...
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Tailoring Hierarchical MnO2 Nanostructures on Self-Supporting Cathodes for High-Mass-Loading Zinc-Ion Batteries

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06182A, Edge Article
Open Access
Weijie Zheng, Zhibiao Cui, Cong Liu, Libei Yuan, Shengsong Li, Lilin Lin, Tao Meng, Liangui Yang, Yexiang Tong, Dong Shu
Aqueous zinc-ion batteries (AZIBs) with MnO2 cathodes have promising application prospects, however, their performance is hindered by their low efficiency and insufficient life. By leveraging the nanomicellar properties of cetyltrimethylammonium...
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