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Polymerization of isoprene and butadiene with unparalleled stereoselectivity catalysed by rare-earth metal cationic species bearing a novel tridentate ligand

Polym. Chem., 2024, 15,4255-4263
DOI: 10.1039/D4PY00781F, Paper
Xiuling Wang, Yang Wang, Zhonglei Qin, Liying Shen, Xiaochao Shi
Phenylthiol-functionalized rare-earth metal cationic species showed unparalleled stereoselectivity in the polymerization of isoprene and butadiene to respectively produce cis-1,4-polyisoprene and trans-1,4-polybutadiene.
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Strategies to prepare polymers with cleavable linkages releasing active agents in acidic media

Polym. Chem., 2024, 15,4491-4518
DOI: 10.1039/D4PY00854E, Review Article
Nachnicha Kongkatigumjorn, Daniel Crespy
Hydrolysis stability of labile linkages in polymers can be tuned through careful selection of substituent groups near these linkages to selectively release active substances.
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Dibenzobarrelene-Derived Pd-NHCs: Efficient Precatalysts for the Suzuki-Miyaura Polycondensations of Dichloroarenes Monomers

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01026D, Paper
Yuman Guo, Hao Wu, Meng-Jiao Zhang, Feng-Shou Liu
The Pd-catalyzed Suzuki-Miyaura polycondensations (SMPs) has emerged as a powerful method for synthesizing conjugated polymers (CPs). While numerous reports have utilized dibromoarene and diiodoarene derivatives as monomers, research on the...
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Near-infrared activated liposomes for neuroprotection in glaucoma

J. Mater. Chem. B, 2024, 12,10902-10914
DOI: 10.1039/D4TB00745J, Paper
Dorcas Matuwana, Eunji Hong, Sizhe Huang, Xinxin Xu, Geunho Jang, Ruobai Xiao, Siyuan Rao, Qianbin Wang
Gold nanorods-encapsulated liposomes enabled the on-demand release of melatonin in mouse glaucoma models.
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Decellularization of caprine forestomach rumen tissue modified with silver nanowires as an antibacterial skin substitute scaffold in wound care therapeutics

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01560F, Paper
Athmana P. A., Asna Jaleel K. I., Sinduja Malarkodi Elangovan, Riza Paul, Naveen Subbaiyan, Parthiban Shanmugam, Gopal Shankar Krishnakumar
Caprine forestomach native collagen (CFNC) modified with silver nanowires (AgNWs) as a new class of biomimetic xenograft for skin regeneration with strong antimicrobial properties.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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A near-infrared superoxide generator based on a biocompatible indene-bearing heptamethine cyanine dye

J. Mater. Chem. B, 2024, 12,11202-11209
DOI: 10.1039/D4TB01663G, Paper
Nikita Bel’ko, Anna Mal’tanova, Anastasiya Bahdanava, Anatol Lugovski, Sviatlana Fatykhava, Polina Shabunya, Adam Smaliakou, Sergey Poznyak, Tatsiana Kulahava, Michael Samtsov
A heptamethine cyanine dye with an indene moiety and 4-meso-chloride generates superoxide inside cells upon near-infrared photoactivation, inducing cell death.
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Nordihydroguaiaretic acid microparticles are effective in the treatment of osteoarthritis

J. Mater. Chem. B, 2024, 12,11172-11186
DOI: 10.1039/D4TB01342E, Paper
Kaamini M. Dhanabalan, Bhagyashree Padhan, Ameya A. Dravid, Smriti Agarwal, Nicholas M. Pancheri, Angela Lin, Nick J. Willet, Ashok Kumar Padmanabhan, Rachit Agarwal
Sustained delivery of NDGA via polymeric microparticles maintains therapeutic levels in joints, reduces cartilage damage, and alleviates post-traumatic osteoarthritis (PTOA) in mice through ROS modulation and autophagy induction.
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Mitochondrial membrane potential-independent near-infrared fluorescent probes for viscosity-exclusive imaging

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01785D, Paper
Xiu Pan, Yu Zhao, Jia-Li Wang, Shun Feng, Xiao-Qi Yu, Ming-Yu Wu
A novel mitochondrial targeting mitochondrial membrane potential-independent near-infrared fluorescent probe, ACR-DMA, was developed which can be firmly immobilized in mitochondria for tracking of mitochondrial viscosity changes in vitro and in vivo.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Are you ready for Khatron Ke Khiladi 8?

'My mother was a stuntwoman, so she is not scared. My wife gets scared, as she was a banker.' Khatron Ke Khiladi host Rohit Shetty takes us through the upcoming eighth season.




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Are you ready for Khatron Ke Khiladi Season 8?

'None of these contestants are trained in stunts. In movies, we have cuts, safety nets, green screens, cables... but here, there is nothing. I had to keep motivating them. I would be drained out by evening at times because you are also demonstrating for them.' Rohit Shetty takes us behind the scenes of Khatron Ke Khiladi 8.












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After Bigg Boss, it's now Cabaret for Sreesanth

'It's almost more than 6 years now that I lost my love and passion, which is cricket.''So it is high time that I make a bright career this year in the entertainment industry.'





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'I am very scared to be in Bigg Boss'

'It takes a lot of courage to be in that house. It's entertaining for some and horrifying for others.'




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Jhalak's GLAMOROUS Stars Are Ready To Dance!

If these celeb sightings are anything to go by, the 10th edition of Jhalak Dikhhla Jaa is going to be a visual delight.




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BB16: Are Shalin And Tina A Couple? VOTE

What do *you* think?




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Bigg Boss 16: Are Priyanka-Ankit Dating? VOTE!

The contestants, including Priyanka's friend Archana Gautam, are convinced that the couple is putting up a show.





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'You can't prepare to jump off a building'

'We are getting a show to do stuff like jumping off a helicopter.''Even if you pay, you won't get to do these things.'




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'Bigg Boss OTT And I Are A Dream Team!'

'It feels a bit like going back to school, trying something new and exciting.'




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Are You Ready For Nimrat, Niyati, Aditi?

After displaying their sense of adventure and fear factor in Romania where the show was shot, the Khatron Ke Khiladi 14 contestants have returned to India.




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Are You Ready For KBC 16?

Amitabh Bachchan is all set to don the host's hat once again for his popular television quiz show Kaun Banega Crorepati Season 16.




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Palliative care in demand

The sector is emerging as a viable option for students looking for careers in healthcare.




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NEET nightmare haunts TN

Lack of clarity on the issue puts students, their parents in a quandary




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Farmer’s Share: A celebration of self reliant minimalism

Ambrose Kooliyath’s permaculture farm on the banks of the Nila River thrives on local resources




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‘I make a conscious effort to seek out women’s stories... men’s voices are easily heard’

American translator Daisy Rockwell on introducing Usha Priyamvada’s ‘Fifty-Five Pillars, Red Walls’ — a novel that had fell by the wayside — to a new generation of readers in English




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How discovery platforms are boosting women-run enterprises

Pandemic has hit women entrepreneurs badly — but help is at hand




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The past and the present are in constant dialogue at the Ramappa Temple

World Heritage Site tag brings droves of tourists to sleepy Palampet, where the shrine is located




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Start-ups are shaking up the disability space even as investors lag

Why don’t Venture Capitalists and funders view those with disability as consumers with a wallet and a need? ask entrepreneurs who have built promising assistive solutions




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‘The Father’: A poignant ode to caregivers

Florian Zeller’s directorial debut turns the lens on the everyday reality of caring for an elderly parent with dementia




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Explainer: What are NFTs, and why the sudden frenzy about them?

Non-fungible token means something unique that cannot be substituted with another



  • Money & Banking



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Are You Ready For The Minions?

The Minions are touring London!




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Why Are Knives Out For Daniel Craig?

The former 007 returns as the queer detective Benoit Blanc in Netflix's Knives Out.




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'We are crushed by Matthew's death'

'He would love that the world is talking about how talented he was. And he really was very talented.'




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The Oscars Are Not Always Predictable

In the biggest surprise of the night, Emma Stone grabbed the Best Actress trophy for the complex portrayal of a Frankenstein-like character Bella, in Yargos Lanthimos' electrifying and most original film Poor Things. Aseem Chhabra recaps the 96th Annual Academy Awards.




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Advancing cerumen analysis: exploring innovative vibrational spectroscopy techniques with respect to their potential as new point-of-care diagnostic tools

Analyst, 2024, 149,5381-5393
DOI: 10.1039/D4AN00868E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Edoardo Farnesi, Matteo Calvarese, Chen Liu, Carl Messerschmidt, MohammadSadegh Vafaeinezhad, Tobias Meyer-Zedler, Dana Cialla-May, Christoph Krafft, Jonas Ballmaier, Orlando Guntinas-Lichius, Michael Schmitt, Jürgen Popp
The study demonstrates the potential of advanced vibrational spectroscopy to reveal the complex molecular composition of cerumen, suggesting its promising application as a non-invasive diagnostic tool for identifying disease-related biomarkers.
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Electrochemical Sensing of Sodium ions present in Bovine Serum using 4-tert Butylcalix[4]arene as Receptor

Analyst, 2024, Accepted Manuscript
DOI: 10.1039/D4AN01297F, Paper
Adrian Ebenazer Paul, Gaurav Gaur, Abdullah Alswieleh, Jerry J. Wu, Sambandam Anandan
The concentration of sodium ions can cause severe imbalances (high pressure on blood vessels, swelling of the muscular tissues, and misfunctioning of the whole nervous system) to the system in...
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Near-infrared frequency upconversion fluorescent probe for rapid and sensitive visual detection of sulfur dioxide

Analyst, 2024, Accepted Manuscript
DOI: 10.1039/D4AN01269K, Paper
Hong Zeng, Xiao Ma, Shufen Pan, Yuting Han, Yanyan Tang, Yulan Fan, Yongquan Wu
Inflammation is a complex physiological response involving various cellular and molecular events. Sulfur dioxide (SO2), which is usually in the form of HSO3- and SO32- under physiological conditions, plays a...
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Areca influences many



  • A J Vinayak