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Stereoselective skeletal modification of tryptanthrins to install chiral piperidine-2-ones enabled by Brønsted acid catalysis

Org. Chem. Front., 2024, 11,2171-2177
DOI: 10.1039/D3QO02029K, Research Article
Rong Zeng, Xiang Zhang, Yuan-Yuan Lei, Zhuo-Zhuo Zhang, Min Jiang, Qing-Zhu Li, Jun-Long Li, Bo Han
An asymmetric formal [4 + 2] cyclisation between azlactones and aza-dienes derived from simple tryptanthrins has been developed. With this established protocol, yielding a series of novel piperidine-2-one-fused tryptanthrins with up to >99 : 1 er under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

Iron(III)/quinoxaline-derived N,N-ligand catalyzed oxygen transfer reaction of N-vinyl nitrones through selective 4π-electrocyclization and N–O bond cleavage

Org. Chem. Front., 2024, 11,2277-2282
DOI: 10.1039/D3QO01999C, Research Article
Yan-Jiao Lu, Feng-Lan Lu, Jin-Qi Zhang, Chun-Hua Chen, Cui Liang, Xiao-Pan Ma, Dong-Liang Mo
We describe an iron(III)/quinoxaline-derived N,N-ligand promoted O-transfer reaction of N-vinyl nitrones through selective O-4π-electrocyclization and N–O bond cleavage to prepare a variety of 2,5-dihydrooxazoles in good yields.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

A dearomatization–rearomatization strategy for construction of 4H-quinolizin-4-ones via C–H bond functionalization of pyridines

Org. Chem. Front., 2024, 11,2319-2325
DOI: 10.1039/D3QO01990J, Research Article
Dong Qiu, Yijin Su
Herein, the synthesis of 4H-quinolizin-4-ones from N-(2-methoxy-2-oxoethyl) pyridinium salts and alkenes through dearomative cycloaddition and rearomative ring expansion has been developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines

Org. Chem. Front., 2024, 11,2326-2331
DOI: 10.1039/D4QO00064A, Research Article
Ting-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng
An efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

NHC and photoredox catalysis dual-catalyzed 1,4-mono-/di-fluoromethylative acylation of 1,3-enynes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00372A, Research Article
Jiuli Xia, Ruiyang Ma, Lihong Wang, Jiaqiong Sun, Guangfan Zheng, Qian Zhang
NHC and photocatalysis dual-catalyzed mono/difluoromethylative acylation of 1,3-enynes was realized, providing fluormethyl-substituted allenyl ketones. SO2 might play a critical role in achieving high reactivity and selectivity.
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The content of this RSS Feed (c) The Royal Society of Chemistry




4

Stocks that will see action today: November 14, 2024

Buzzing stocks: Tata Power, India Glycols, Hero MotoCorp, BDL, Firstcry, Mamaearth, MTNL, HAL, Nazara Tech, Sobha, Glenmark Pharma, GVK Power, Medi Assist, Grasim, PNB Housing Fin, Samhi Hotels, Inox Green Energy, Varun Beverages, Piccadilly Agro, 




4

Wayanad records voter turnout of 64.72%

Good polling was reported at the landslides-affected region in Chooral Mala and tribes-populated areas in the district.




4

2024 on track to be hottest year on record




4

Four-day Africa Tech Festival 2024 kicks off in Cape Town




4

Gujarat CM approves Rs 254 Crore for multiple development projects across 14 towns




4

Swiggy-backed Rapido sees net loss at Rs 371 crore in FY24




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Initial SEI formation in LiBOB-, LiDFOB- and LiBF4-containing PEO electrolytes

J. Mater. Chem. A, 2024, 12,9184-9199
DOI: 10.1039/D3TA07175H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Edvin K. W. Andersson, Liang-Ting Wu, Luca Bertoli, Yi-Chen Weng, Daniel Friesen, Kenza Elbouazzaoui, Sophia Bloch, Ruslan Ovsyannikov, Erika Giangrisostomi, Daniel Brandell, Jonas Mindemark, Jyh-Chiang Jiang, Maria Hahlin
A limiting factor for solid polymer electrolyte (SPE)-based Li-batteries is the functionality of the electrolyte decomposition layer that is formed at the Li metal anode during battery operation.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

Unveiling the fundamental understanding of two dimensional π-conjugated FeN4+4 sites for boosting peroxymonosulfate activation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01195C, Paper
Sijia Jin, Wenxian Tan, Xiaofeng Tang, Xia Yao, Yingjian Bao, Haiyan Zhang, Shuang Song, Tao Zeng
The precisely defined FeN4+4 active sites in fully π-conjugated polyphthalocyanine frameworks establish a dual-pump-driven electron fast shuttle path—electron-rich Fe centers and electron-poor C atoms—ensuring continuous production of 1O2.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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4

Identifying lithium difluoro(oxalate)borate as a multifunctional electrolyte additive to enable high-voltage Li4Ti5O12 lithium-ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00750F, Paper
Ou Ka, Fang Cheng, Lang Wen, Xiaoqu Wang, Ting Wang, Xinyu Zeng, Wen Lu, Liming Dai
Lithium difluoro(oxalate)borate (LiDFOB) is identified as a multifunctional electrolyte additive, stabilizing the electrolyte and protecting the electrodes, to enable the LiNi0.5Mn1.5O4//Li4Ti5O12 battery with an excellent performance at 3.50 V.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

Dioxygen atom co-doping g-C3N4 for boosted photoreduction activity of CO2 and mechanistic investigation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00156G, Paper
Zhang Jiang, Mingnv Guo, Zhongqing Yang, Ruiming Fang, Ziqi Wang, Jingyu Ran
Visible-light photocatalytic reduction of carbon dioxide with the help of photocatalysts has become an important means to mitigate the greenhouse effect.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

Efficient photocatalytic hydrogen evolution based on Z-scheme 2D OV-LaVO4/Mo-doped SV-ZnIn2S4 heterojunctions

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00754A, Paper
Wei Guan, Lin Zhang, Peng Wang, Ying Wang, Haoyu Wang, Xingchen Dong, Liyan Yu, Zhixing Gan, Lifeng Dong, Lina Sui
The purposeful design and construction of two-dimensional (2D) semiconductor heterojunctions offers a promising avenue for achieving efficient photocatalytic activity. However, the challenge of enabling efficient charge migration at the interface...
The content of this RSS Feed (c) The Royal Society of Chemistry




4

Highly stable photovoltaic effects in A2+–Zr4+ (A = Ca, Sr, Ba) co-doped BiFeO3 films with self-polarization

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00649F, Paper
Lei Shi, Wenyue Zhao, Zhao Wang, Wenjing Hua, Xiaoxia Yang, Weidong Fei, Yu Zhao
The photovoltaic responses and temperature stabilities of A2+–Zr4+ (A = Ca, Sr, Ba) composite doped BiFeO3 films with self-polarization were enhanced in the R to MA phase transition.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

Bosa addresses viral Mayfield play from 49ers' win over Bucs

49ers defensive end Nick Bosa explained his side of a viral play with Buccaneers quarterback Baker Mayfield during San Francisco's 23-20 win over Tampa Bay on Sunday at Raymond James Stadium.




4

Nifty prediction today – November 13, 2024: Bearish. Go short now and on a rise

Nifty 50 November futures can fall to 23,400




4

Bank Nifty Prediction today – November 13, 2024: Short when the support is breached

Bank Nifty futures is now testing the support at 51,000




4

Coimbatore District Police arrest two men for robbing Kerala jeweller of ₹54 lakh




4

ISB Insights Forum 2024 to be held on November 15




4

Global fossil emissions to reach record high in 2024; India's share to rise by 4.6%: Report

According to a UN report released last month, India's greenhouse gas emissions surged by 6.1 per cent in 2023, contributing to 8 per cent of the global total




4

India's index of industrial production shows 3.1 per cent growth in September 2024




4

India among top 10 countries in patents, trademarks, and industrial designs: WIPO 2024 report




4

Coal import for blending purposes in power generation declines by 8.5% during April-Sept 2024




4

India's CO2 emissions account 8pc of global total, to rise by 4.6pc in 2024: Report




4

Defence Space Agency hosts first ever space exercise 'Antariksha Abhyas - 2024' in Delhi




4

Sri Lanka to hold key parliamentary vote on November 14

President Anura Kumara Dissanayake’s ruling alliance is looking to secure a majority in Parliament




4

Pyridinyl 4-(2-oxoalkylimidazolidin-1-yl)benzenesulfonates and their hydrochloride salts as novel water soluble antimitotic prodrugs bioactivated by cytochrome P450 1A1 in breast cancer cells

RSC Med. Chem., 2024, 15,3728-3745
DOI: 10.1039/D4MD00476K, Research Article
Vincent Ouellette, Chahrazed Bouzriba, Atziri Corin Chavez Alvarez, Quentin Bruxelles, Geneviève Hamel-Côté, Sébastien Fortin
New water soluble antimitotic CYP1A1-activated prodrugs named PYRAIB-SOs and their hydrochlorides targeting breast cancers.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

Asymmetric imidazole-4,5-dicarboxamide derivatives as SARS-CoV-2 main protease inhibitors: design, synthesis and biological evaluation

RSC Med. Chem., 2024, 15,3880-3888
DOI: 10.1039/D4MD00414K, Research Article
Phuong Nguyen Hoai Huynh, Phatcharin Khamplong, Minh-Hoang Phan, Thanh-Phuc Nguyen, Phuong Ngoc Lan Vu, Quang-Vinh Tang, Phumin Chamsodsai, Supaphorn Seetaha, Truong Lam Tuong, Thien Y. Vu, Duc-Duy Vo, Kiattawee Choowongkomon, Cam-Van T. Vo
Novel asymmetric imidazole-4,5-dicarboxamide derivatives were synthesized, evaluated for SARS-CoV-2 MPro inhibitory activity in vitro, and investigated for binding ability in silico.
The content of this RSS Feed (c) The Royal Society of Chemistry




4

Correction: computational design, synthesis, and assessment of 3-(4-(4-(1,3,4-oxadiazol-2-yl)-1H-imidazol-2-yl)phenyl)-1,2,4-oxadiazole derivatives as effective epidermal growth factor receptor inhibitors: a prospective strategy for anticancer therapy

RSC Med. Chem., 2024, 15,3912-3912
DOI: 10.1039/D4MD90040E, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nilesh Raghunath Khedkar, Milind Sindkhedkar, Alex Joseph
The content of this RSS Feed (c) The Royal Society of Chemistry




4

SBI, HDFC Bank, ICICI Bank figure in RBI’s 2024 list of Domestic Systemically Important Banks (D-SIBs)

Higher D-SIB surcharge fixed for SBI and HDFC Bank, will be applicable from April 01, 2025




4

Greaves Cotton Q2 net loss narrows to ₹14 crore




4

India’s office leasing soars 41% in 2024 amid rent hikes, supply crunch, and GCC growth: Cushman & Wakefield

In an interview to businessline, Cushman & Wakefield’s Veera talks about commercial space leasing outlook, trends, and rental and supply trends for the coming months




4

80.48% voter turnout recorded in Shiggaon

The polling for the byelection to Shiggaon Legislative Assembly Constituency in concluded peacefully with large number of voters turning up at 241 polling stations in the assembly segment to exercise their franchise on Wednesday




4

Swiggy pre-open trade: Shares jump in trading debut after $1.4-billion IPO

The stock listed at ₹420 on India's National Stock Exchange, compared to its issue price of ₹390




4

On the Draw — November 13, 2024




4

News from the world of Education: November 13, 2024

Information on new courses, entrance exams, admissions, scholarships, research studies, and other events from educational institutions




4

On the Draw — November 14, 2024




4

Letters to The Editor — November 14, 2024




4

Pakistan court acquits Imran Khan, his close aides in Section 144 violation case

The dismissal of the case against Khan comes as a kind of relief for someone who has been incarcerated since August last year




4

Inaugural U.S.-India Indian Ocean Dialogue to be held on November 14

The two sides will discuss measures to promote security and prosperity throughout the Indo-Pacific region.




4

64.98% cast votes in Malappuram in Wayanad bypoll

While Eranad and Wandoor registered 69.42% and 64.43% polling respectively, voting percentage in Nilambur stood at 61.91%




4

First phase of polling ends in Jharkhand with 64.86% turnout of voters

Polling was held in 15 districts of Jharkhand and the Kharsawan Assembly seat received the maximum polling of 77.32%, Ranchi, the State capital of Jharkhand witnessed the lowest polling with just 51.5%




4

Foreign banks diverge on RBI’s rate path as inflation hits 14-month high

Firm inflation and hawkish signals rule out December rate cuts, says DBS Bank; but slowing growth may sway RBI, notes Barclays Research 




4

NALCO Q2 net surges 415 per cent to ₹1,062 crore

NALCO also announced an interim dividend of ₹4 per equity share amounting to ₹734.65 crore for FY25




4

Letters to the Editor dated November 13, 2024




4

Day Trading Guide for November 14, 2024: Intraday supports, resistances for Nifty50 stocks

Here are the intraday supports and resistances for widely traded stocks such as Reliance Industries, ITC, ONGC, Infosys, HDFC Bank, TCS, and SBI



  • Day trading guide

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Today’s Stock Recommendation: November 14, 2024

The stock that we have today is Marico.