After the Panic: Are Financial Crises Demand or Supply Shocks? Evidence from International Trade [electronic journal].
Advertising as a reminder: Evidence from the Dutch State Lottery [electronic journal].
Acculturation, Education, and Gender Roles: Evidence from Canada [electronic journal].
Accountability, Political Capture and Selection into Politics: Evidence from Peruvian Municipalities [electronic journal].
2019 23rd International Conference on Applied Electromagnetics and Communications (ICECOM) [electronic journal].
Highly stable chiral Cr(III)-based metal–organic frameworks for enantioadsorption separation of aromatic alcohols
DOI: 10.1039/D4QI00113C, Research Article
Highly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.
The content of this RSS Feed (c) The Royal Society of Chemistry
Carbon dots induce abundant oxygen vacancies in CeVO4 for promoting photocatalytic selective hydrogenation of functionalized nitroarenes
DOI: 10.1039/D4QI00002A, Research Article
Carbon dots create the appropriate oxygen vacancies (OVs) in CeVO4 for the chemoselective hydrogenation of functionalized nitroarenes under light irradiation.
The content of this RSS Feed (c) The Royal Society of Chemistry
Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets
DOI: 10.1039/D3QI02507A, Research Article
The change of counter anions significantly affects the environment around Co(II) ions, leading to two zero-field single-ion magnets possessing different uniaxial anisotropies and dynamic magnetic properties.
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Rational design for broad near-infrared emission from a two-sited Rb2LiAlF6:Cr3+ phosphor with high efficiency and thermal stability for spectroscopic applications
DOI: 10.1039/D4QI00429A, Research Article
A comparative investigation of broadband near-infrared luminescence from two different occupation sites in Rb2LiAlF6:Cr3+ with high efficiency and excellent thermal stability.
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Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs
DOI: 10.1039/D4QI00462K, Research Article
The long-neglected stereochemically active lone pair groups ClO3− and BrO3− are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.
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The smallest endohedral borafullerene: structural isomerization, electronic properties, aromaticity and reactivity of U@C27B
DOI: 10.1039/D4QI00186A, Research Article
U@C27B has three interconvertible isomers with the highest metal oxidation state and strong covalency, obeying the 32-electron principle and Hirsch's aromaticity rule.
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An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues
DOI: 10.1039/D4QI00343H, Research Article
The direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.
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Understanding the synthesis mechanism, chemical structures and optical properties of aromatic carbon nitride
DOI: 10.1039/D4QI00355A, Research Article
The chemical structures and optical properties of aromatic carbon nitride and intermediates have been systematically studied; hereby the detailed synthesis mechanism of aromatic carbon nitride is explicitly proposed.
The content of this RSS Feed (c) The Royal Society of Chemistry
Radiochromic Semiconductive MOF with High Sensitivity and Fast Photochromic Response for Dual-mode X-ray Direct Detection
DOI: 10.1039/D4QI00771A, Research Article
X-ray direct detectors, which may directly convert X-rays into electrical signals through semiconductors, are highly desirable for early cancer screening and other applications. Prevailing commercial amorphous Se detectors still suffer...
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Incorporation of One-Dimensional Electron-Rich Chain in Viologen-based Coordination Polymers for Super Photochromic Properties and Improved Optical Applications in Polyvinyl Alcohol Film
DOI: 10.1039/D4QI00200H, Research Article
A viologen derivative- and a carboxylic acid -based one-dimensional (1D) cocrystal Zn(Ⅱ) coordination polymer, {[Zn(bcbpy)2][Zn(sip)Cl]·4H2O}n (1, bcbpy = 1,1'-bis (3-carboxybenzyl)-4,4'-bipyridinium, sip = 5-Sulfoisophthalate) has been produced solvothermally and structurally characterized....
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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles
DOI: 10.1039/D4QI00547C, Research Article
The modulation mechanisms of Na+ within the redox-active sites of the two-dimensional conjugated organic small-molecule 3BQ, and their impact on the initial capacity of a 3BQ cathode for Na-ion batteries, were investigated using first-principles calculations.
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Yolk-Shell type Carbon-Silica Nanoarchitecture Dispersed and Stabilized Ru Nanoparticles for Enhanced Hydrogenation of Aromatic Compounds
DOI: 10.1039/D4QI00553H, Research Article
Hydrogenation of aromatic rings can be used not only for synthesis fine chemicals, but also for hydrogen storage and transportation using organic hydride. In this paper, yolk-shell structural SiO2@Ru@NC catalyst,...
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Spinning mills in Gujarat, N. India seek quality cotton from Raichur region
CCI begins purchase of cotton for 2024-25 season at MSP from Telangana
The Centre has declared an MSP of Rs ₹7,121 per quintal for the medium staple and Rs ₹7,521 per quintal for the longer variety for the 2024-25 cropping season, an increase of around 7 per cent over previous year
Green shoots of expectations on health, from newly-minted govt
As political tides change, the public sets sights on inclusive and robust healthcare reforms
Thalassemia patients’ ask from Budget
A concerted effort from the government, healthcare institutions, NGOs and the public is essential to create a robust blood transfusion system that prioritises safety and supports patients.
Arya.ag bags $19.8 million from US International Development Finance Corporation
These funds will be utilised to connect farmers and FPOs with buyers across the country
Maharashtra cashew board plans to expand area under the crop, promote organic farming
CMFRI develops eco-friendly fish feed from black soldier fly larvae
CMFRI transferred the technology to Amala Ecoclean, a start-up focusing on sustainable waste management and environmental solutions, for large-scale commercial production
South Peninsula records 7% above normal rainfall so far, poised to get even more from later this week
Easterly to north-easterly flows starting to rebuild after being scattered by severe cyclone Dana over the Bay
Marut Dronetech raises $6.2 mn from Lok Capital in Series A funding
Funds to be deployed on developing advanced agri drones, expanding channel partner network and service centres
Urad imports from Brazil increase to 22,000 tonnes till October
Australia’s chana production in current year is estimated at about 13.3 lakh tonnes (lt) against 4.9 lt in 2023, basically for export to India
Hyderabad to host international poultry expo from November 27
A technical seminar with the theme ‘Unlocking Poultry Potential’ will be held on November 26
Chana prices crash as imports from Australia begin and sowing starts
Two-day NAARM meet on sustainable agri start-ups from November 12
Gujarat launches procurement of soyabean, urad & moong from farmers
Under the Price Support Scheme (PSS), purchases will be conducted over 90 days from 3.7 lakh farmers who have registered for this scheme
Promises fall flat for Maharashtra’s farmers amid unending agrarian crisis
In the last 9 months alone, 1,933 Maharashtra farmers took their lives, a stark testament to the ongoing agrarian crisis that remains untouched by political promises
GMR group raises ₹6,300 crore to refinance promoter entity debt
GMR group will use the proceeds to refinance all external debt of GMR Enterprise Private Limited, the promoter of GMR Airports Limited
Ashok Leyland bags order for 500 electric buses from Chennai MTC
While 400 of these 12-m ultra-low floor electric buses will be non-AC, 100 buses will be equipped with air conditioning as well
India could benefit from re-orientation of global supply chain away from China after Trump's victory: Report
The report highlighted the Trump’s plans include imposing a 60 per cent tariff on imports from China, as well as additional tariffs ranging from 10 per cent to 20 per cent on imports from other countries
Kerala set to start its seaplane service from Kochi, looks forward to boost in tourism
Roshni Nadar Malhotra takes over HCL baton from Shiv Nadar
Ahammune Biosciences raises Pre-Series A funding from Ideaspring Capital, Indian Angel Network
Dance from within
Performances by Kathak prodigy Protyasha and Manipuri by Sudip Ghosh impressed, writes Gudipoodi Srihari.
‘Maximum output from minimum space’
As tabla maestro Pandit Sanjay Mukherjee opens up on his delightful second innings, Meena Banerjee takes notes.
Is aromaticity loss necessary for transition-metal promoted arene–alkene cycloadditions?
DOI: 10.1039/D4SC05337K, Edge Article
Diene- and ene-like reactivity in transition metal coordinated arenes can be expected when there is a notable degree of aromaticity loss at the complexed arene.
The content of this RSS Feed (c) The Royal Society of Chemistry
Diverse quantum interference regimes in intramolecular singlet fission chromophores with thiophene-based linkers
DOI: 10.1039/D4SC03546A, Edge Article
This work explores intramolecular singlet fission chromophores having diverse thiophene-based linkers and highlights the relation between quantum interference and nonadiabatic coupling in the multiexciton formation step of singlet fission.
The content of this RSS Feed (c) The Royal Society of Chemistry
MR-TADF liquid crystals: towards self assembling host–guest mixtures showing narrowband emission from the mesophase
DOI: 10.1039/D4SC04429K, Edge Article
We developed a MR-TADF based, columnar liquid crystalline host system and doped it with a MR-TADF guest. Efficient FRET allowed us to construct the first columnar liquid crystal with narrowband MR-TADF from the strongly aggregated mesophase.
The content of this RSS Feed (c) The Royal Society of Chemistry
Electrochemical trifluoromethylation of alkynes: the unique role of DMSO as a masking auxiliary
DOI: 10.1039/D4SC06780K, Edge Article
An electrochemical trifluoromethylation method for terminal alkynes has been developed, facilitating the synthesis of CF3-alkynes with DMSO as a masking auxiliary.
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The chirality-induced spin selectivity effect in asymmetric spin transport: from solution to device applications
DOI: 10.1039/D4SC05736H, Review Article
This review highlights recent experimental findings related to the chirality-induced spin selectivity effect. This effect is demonstrated to explain asymmetric electron's spin transport in chiral molecules for various technological applications.
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A metabologenomics strategy for rapid discovery of polyketides derived from modular polyketide synthases
DOI: 10.1039/D4SC04174G, Edge Article
A metabologenomics workflow using mass defect filtering (MDF) and bioinformatics-based structural prediction was established for rapid screening of modular polyketide natural products, and led to the identification of 22 polyketides.
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Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes
DOI: 10.1039/D4SC06334A, Edge Article
We present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.
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Cyclic peptides targeting the SARS-CoV-2 programmed ribosomal frameshifting RNA from a multiplexed phage display library
DOI: 10.1039/D4SC04026K, Edge Article
Cyclopeptide agents targeted against the −1 programmed ribosomal frameshifting stimulatory sequence RNA pseudoknot of SARS-CoV-2 were discovered by screening a multiplexed phage display library of genetically encoded peptide macrocycles.
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