Volatile liquid precursors are provided for use in the formation of alkali metal-containing materials. The compound includes an alkali metal and an amide ligand and is a liquid at a temperature of less than about 70° C.
The novel metallocenes of the formula I in which, preferably, M1 is Zr or Hf, R1 and R2 are alkyl or halogen, R3 and R4 are hydrogen, R5 and R6 are alkyl or haloalkyl, —(CR8R9)m—R7—(CR8R9)n— is a single- or multi-membered chain in which R7 may also be a (substituted) hetero atom, m+n is zero or 1, and R10 is hydrogen, form, together with aluminoxanes as cocatalysts, a very effective catalyst system for the preparation of polyolefins of high stereospecificity and high melting point.
A method for the production of alkyl lithium compounds is disclosed, in which metallic lithium is reacted with an alkyl halide in a solvent, whereby the metallic lithium is introduced in the form of lithium particles, generated by spraying molten lithium into an inert atmosphere or into a vacuum.
A method by which a halogen atom of a halogen compound can be efficiently replaced with an electrophilic group. Also provided are: a reagent for converting a functional group through a halogen-metal exchange reaction, characterized by comprising either a mixture of a magnesium compound represented by the formula R1—Mg—X (I) (wherein R1 represents a halogen atom or an optionally substituted hydrocarbon residue; and X1 represents a halogen atom) and an organolithium compound represented by the formula R2—Li (II)(wherein R2 represents an optionally substituted hydrocarbon residue) or a product of the reaction of the magnesium compound with the organolithium compound; and a process for producing with the reagent a compound in which a halogen atom of a halogen compound has been replaced with an electrophilic group.
Pulverulent solid which consists essentially of at least one metal alkyl compound bound chemically and/or physically to a finely divided, porous, mechanically stable and chemically inert support, has a proportion by weight of metal alkyl compound of at least 5% by weight, based on the support, and has an angle of repose, determined in accordance with ISO 4324, of up to 48°. The solid allows trouble-free metering as active component into a reactor.
The present invention relates to a synthesis method of metal cyclopentadienide by direct reaction of dicyclopentadiene with a group 1 metal in the presence of an aprotic solvent. Unlike the conventional method depending on retro Diels-Alder reaction of dicyclopentadiene to generate indirectly cyclopentadiene, the method of the present invention favors generation of cyclopentadiene and metal cyclopentadienide as well by adding dicyclopentadiene directly when the reaction temperature reaches to the boiling point of a reaction solvent.
[Problem] To provide a preparation process by which an organic alkali metal compound is obtained in a high yield and a process for preparing an organic transition metal compound using the organic alkali metal compound. [Means to solve the problem] A process for preparing an organic alkali metal compound, which is characterized by adding a compound represented by the following formula (2) in the reaction of an active proton-containing compound represented by the following formula (1) with an alkali metal compound. RHp (1) In the formula (1), R is a hydrocarbon group or an amino group and may contain a halogen atom, a silicon atom, an oxygen atom or a nitrogen atom, H is an active proton, and p is the number of hydrogen atoms abstracted in the reaction with the alkali metal compound. In the formula (2), Ra to Rc are each an atom or a group selected from a hydrogen atom, a hydrocarbon group, a heteroatom-containing group and a silicon-containing group and may be the same as or different from each other, and the neighboring substituents may be bonded to each other to form a ring.
A method of purifying crude organometallic compounds using a stripping column and a gas stream is provided. This method removes relatively more volatile impurities as compared to the organometallic compound.
Provided is a welding metal in which the chemical component composition thereof is appropriately controlled; an A value that is specified by a predetermined relational expression satisfies the requirement of being 3.8% to 9.0%; an X value that is specified by a predetermined relational expression satisfies the requirement of being 0.5% or greater; the area percentage of carbide particles having a circle-equivalent diameter of 0.20 μm or greater in the welding metal is 4.0% or less; and the number of carbide particles having a circle-equivalent diameter of 1.0 μm or greater is 1000 particles/mm2 or less. This welding metal, which can exhibit not only high strength but also good low-temperature toughness and good drop-weight characteristics, is useful as a material for a pressure vessel in a nuclear power plant.
Methods for determining a recovery state of a metal alloy are disclosed herein. In one example, a fluctuation in a crystallographic grain orientation of the metal alloy is determined by utilizing electron backscatter diffraction (EBSD) data of the metal alloy. A processor of an electron backscatter diffraction machine utilizes a local orientation deviation quantifier to correlate the fluctuation in the crystallographic grain orientation of the metal alloy with a plastic strain recovery of the metal alloy. Other examples of the method are also disclosed herein.
Disclosed are metal-containing precursors having the formula Compound (I) wherein: —M is a metal selected from Ni, Co, Mn, Pd; and —each of R-1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 are independently selected from H; a C1-C4 linear, branched, or cyclic alkyl group; a C1-C4 linear, branched, or cyclic alkylsilyl group (mono, bis, or tris alkyl); a C1-C4 linear, branched, or cyclic alkylamino group; or a C1-C4 linear, branched, or cyclic fluoroalkyl group. Also disclosed are methods of synthesizing and using the disclosed metal-containing precursors to deposit metal-containing films on a substrate via a vapor deposition process.
A sheathed, annular metal fuel system is described. A metal fuel pin system is described that includes an annular metal nuclear fuel alloy. A sheath may surround the metal nuclear fuel alloy, and a cladding may surround the sheath. A gas plenum may also be present. Mold arrangements and methods of fabrication of the sheathed, annular metal fuel are also described.
The present invention provides an alkali metal salt of fluorosulfonyl imide having favorable heat resistance and a reduced content of specific impurities and a water content, and provides a method for producing an alkali metal salt of fluorosulfonyl imide, which is capable of easily removing a solvent from a reaction solution. An alkali metal salt of fluorosulfonyl imide of the present invention is represented by the following general formula (I) and has a mass loss rate of 2% or less when the alkali metal salt of fluorosulfonyl imide is kept at 100° C. for 8 hours under an air current. A method for producing an alkali metal salt of fluorosulfonyl imide of the present invention comprises a step of concentrating a solution of the alkali metal salt of fluorosulfonyl imide by bubbling a gas into a reaction solution containing the alkali metal salt of fluorosulfonyl imide, and/or concentrating a solution of the alkali metal salt of fluorosulfonyl imide by thin layer distillation.
A method is provided. The method includes acquiring a first dataset at a first energy spectrum and a second dataset at a second energy spectrum. The method also includes extracting a metal artifact correction signal using the first dataset and the second dataset or using a first reconstructed image and a second reconstructed image generated respectively from the first and the second datasets. The method further includes performing metal artifact correction on the first reconstructed image using the metal artifact correction signal to generate a first corrected image.
The present invention proposes a gap-filler insert (20) for use with cooling plates (12, 12') for a metallurgical furnace, the cooling plates (12, 12') having a front face (14, 14') directed towards the interior of the furnace, an opposite rear face (16, 16') directed towards a furnace wall (10) of the furnace and four edge faces (18, 18'). In accordance with an aspect of the present invention, the gap-filler insert (20) comprises a metal front plate (24) with a front side (24) facing the interior of the furnace and anchoring means (28, 28', 30, 30', 32, 34) for mounting the front plate (24) between two neighboring cooling plates (12, 12') in such a way that the front plate (24) extends between the edge faces (18, 18') of both cooling plates (12, 12'), and that the front side (26) of the front plate (24) is flush with the front faces (14, 14') of both cooling plates (12, 12').
A method for producing a transparent and conductive metal oxide layer on a substrate, includes atomizing at least one component of the metal oxide layer by highly ionized, high power pulsed magnetron sputtering to condense on the substrate. The pulses of the magnetron have a peak power density of more than 1.5 kW/cm2, the pulses of the magnetron have a duration of ≦200 μs, and the average increase in current density during ignition of the plasma within an interval, which is ≦0.025 ms, is at least 106 A/(ms cm2).
A metal material is provided with a bismuth coating which enables the subsequent coating to be accomplished at a high throwing power, and has excellent corrosion resistance, coating adhesion and is able to be produced with reduced damage to the environment. The metal material has a surface and a bismuth-containing layer deposited on at least a part of the surface of the metal material, wherein the percentage of bismuth atoms in the number of atoms in the surface layer of the metal material with a bismuth coating is at least 10%.
Disclosed are electrochemical cells and methods for producing a halide of a non-alkali metal and for electrorefining the halide. The systems typically involve an electrochemical cell having a cathode structure configured for dissolving a hydrogen halide that forms the halide into a molten salt of the halogen and an alkali metal. Typically a direct current voltage is applied across the cathode and an anode that is fabricated with the non-alkali metal such that the halide of the non-alkali metal is formed adjacent the anode. Electrorefining cells and methods involve applying a direct current voltage across the anode where the halide of the non-alkali metal is formed and the cathode where the non-alkali metal is electro-deposited. In a representative embodiment the halogen is chlorine, the alkali metal is lithium and the non-alkali metal is uranium.
An ash basket can act as a sieve or strainer, allowing a user to lift out the charcoal from a kamado grill, clean out the ash, and place the ash basket back into the grill for future use. The ash basket retains larger pieces of charcoal that can be reused, while allowing the ash to pass through to a bottom plate of the grill. The bottom plate has openings to permit the ash to fall to an ash collection chamber. Without the ash basket, pieces of charcoal can block the openings in the bottom plate, making ash collection difficult. Moreover, with the openings blocked, proper air flow through the openings. Finally, the ash basket creates and additional air space that covers the entire surface of the interior walls by separating the ash from the wall, improving air flow, which is critical to the kamado grill design.
Accordingly, a method of forming a metal chalcogenide material may comprise introducing at least one metal precursor and at least one chalcogen precursor into a chamber comprising a substrate, the at least one metal precursor comprising an amine or imine compound of an alkali metal, an alkaline earth metal, a transition metal, a post-transition metal, or a metalloid, and the at least one chalcogen precursor comprising a hydride, alkyl, or aryl compound of sulfur, selenium, or tellurium. The at least one metal precursor and the at least one chalcogen precursor may be reacted to form a metal chalcogenide material over the substrate. A method of forming a metal telluride material, a method of forming a semiconductor device structure, and a semiconductor device structure are also described.
A layered compound-metal particle composite 3 is obtained by the addition, to an organically modified layered compound 1 formed by the intercalation of organic ions between layers of a layered compound, of both an aqueous colloidal metal solution 2 in which metal particles are dispersed as a metal colloid in water, and a nonaqueous solvent which is a poor solvent for the metal colloid and has an excellent ability to swell the organically modified layered compound 1.
A method of photoplating a metal contact onto a surface of a cathode of a photovoltaic device is provided using light induced plating technique. The method comprises: a) immersing the photovoltaic device in a solution of metal ions, where the metal ions are a species which is to be plated onto the surface of the cathode of the photovoltaic device; and b) illuminating the photovoltaic device, using a light source of time varying intensity. This results in nett plating which is faster in a direction normal to the surface of the cathode than in a direction in a plane of the surface of the cathode.
Hemispheres and spheres are formed and employed for a plurality of applications. Hemispheres are employed to form a substrate having an upper surface and a lower surface. The upper surface includes peaks of pillars which have a base attached to the lower surface. The peaks have a density defined at the upper surface by an array of hemispherical metal structures that act as a mask during an etch to remove substrate material down to the lower surface during formation of the pillars. The pillars are dense and uniform and include a microscale average diameter. The spheres are formed as independent metal spheres or nanoparticles for other applications.
A feeding apparatus feeds a metal strip with cutaway portions in a conveying direction and includes: a reference plate on which the metal strip is placed and in which a slit is formed; moving bodies that are provided below the reference plate and are moved by driving means parallel to the reference plate in the conveying direction; feed pins that advance into the cutaway portions, are provided on the moving bodies so as to move up and down with respect to the reference plate, and pull the metal strip in the conveying direction when the moving bodies move; and at least one guide portion that contacts a side surface on an opposite side of the metal strip to the cutaway portions and guides conveyance of the metal strip.
A method of mechanically treating alloy metal surgical needles to improve bending strength is disclosed. The needles are curved and reverse-curved in this method to improve bending strength.
Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one friction reducing agent selected from the group consisting of guar gums, polyacrylamides, hydratable cellulosic materials, viscoelastic surfactants, and mixtures thereof. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for use in fracturing subterranean formations. Methods for inhibiting formation and/or precipitation of metal oxides in an aqueous composition using the fluid treatment systems or compositions also are provided.
Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one scale control agent. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for treating aqueous compositions found in subterranean formations. Methods for inhibiting formation and/or precipitation of calcium salts in an aqueous composition using the fluid treatment systems or compositions also are provided.
The present invention provides a noble metal fine particle with a protein adsorbed thereon, including a noble metal fine particle, and a protein adsorbed on a surface of the noble metal fine particle. The protein has an isoelectric point in a range of pH 4.0 to 7.5. An amount of the protein adsorbed is in a range of 3 to 55.1 wt % with respect to a total weight of the noble metal fine particle and the protein. The noble metal fine particle with a protein adsorbed thereon according to the present invention has excellent redispersibility. That is, by adjusting the pH of a noble metal fine particle dispersed liquid to the isoelectric point of the proteins and allowing the noble metal fine particles to be aggregated without adding a degrading enzyme that degrades the proteins to the noble metal fine particle dispersed liquid, it is possible to allow the noble metal fine particles with proteins adsorbed thereon withdrawn from the noble metal fine particle dispersed liquid to have an average particle diameter that is not increased significantly even after they are redispersed in another dispersion medium.
Method, apparatus, and system for preparing a cellular material based on hollow metal beads. According to the description, at least one bead chain in which said hollow metal beads are linked to one another in pairs by means of an articulation is used as elementary structure constituting the cellular material.
The invention relates to a method for shaping a barrel spring made of a unitary ribbon of metallic glass that comprises calculating the theoretical shape to be given to said unitary ribbon of metallic glass so that each segment, once the spring is fitted in the barrel, is subjected to the maximum bending momentum, shaping said ribbon by imparting bends thereto characteristic of said free theoretical shape in order to take into account a potential reduction of the bends once the ribbon is released, relaxing the ribbon in order to set the shape thereof by heating the same, and cooling down said ribbon.
A power tool for installing a metal locking tie is disclosed. The power tool includes a body and a power chassis. The body of the tool includes a gear carrier, a tensioning mechanism and a cutting mechanism. The gear carrier is positioned in the tool body and the tensioning mechanism is mounted in the gear carrier. The cutting mechanism engages the gear carrier. As the tie is tensioned, the gear carrier moves linearly in the tool body to cut the tensioned tie.
A protective metal netting comprises a plurality of longitudinal metal wires or cables (10) side by side, each interwoven with at least one adjacent longitudinal wire or cable (10) in an interweave portion (24), in which at least one of the metal wires or cables (20) has an almost rectilinear development, or in any case with loops that are less pronounced than the lower-strength neighboring cables. A machine for manufacturing interwoven metal nettings comprises a cylindrical drum (50), on the outer surface of which a plurality of pins (52) protruding radially and arranged in axial rows at equal angular intervals is fixed, with an equal pitch in all the rows. Some pins (54) present on the cylindrical drum (50) are fitted out-of-alignment with respect to the above-mentioned pitch.
A light-emitting element which emits light with high luminance and can be driven at low voltage. The light-emitting element includes n (n is a natural number of 2 or more) EL layers between an anode and a cathode, and includes a first layer, a second layer, and a third layer between an m-th (m is a natural number, 1≦m≦n−1) EL layer from the anode and an (m+1)th EL layer. The first layer functions as a charge-generation region, has hole-transport properties, and contains an acceptor substance. The third layer has electron-transport properties and contains an alkali metal or the like. The second layer formed of a metal complex having a metal-oxygen bond and an aromatic ligand is provided between the first and third layers, whereby an injection barrier at the time of injecting electrons generated in the first layer into the m-th EL layer through the third layer can be lowered.
A fireproof unit for a sliding closure at the spout of a container containing metal melt, including a fireproof adapter block that can be placed on the container spout, a fireproof bottom plate connected thereto, to which bottom plate a slidable fireproof sliding plate can be connected, wherein the sliding plate allows the sliding closure to be opened or closed. In addition to the first bottom plate connected to the adapter block, a second bottom plate adjoins the adapter block. The second bottom plate can be slid in under the adapter block to replace the first bottom plate. The adapter block has a length in the direction of the second bottom plate such that the adapter block is in sliding contact with the second bottom plate at the lower sliding surface of the adapter block.
The present invention relates to a process and apparatus for producing a fluid enriched in carbon dioxide starting from a waste gas from a ferrous metallurgy unit.
The invention relates to a metal-cutting machining process for a semi-finished product having a predetermined shape and at least one machining surface which has the steps: applying a protective foil having a predetermined elongation at break to the at least one machining surface with a predetermined adhesive force, placing a metal-cutting tool in a predetermined position above the machining surface, exerting a predetermined mechanical force in a predetermined direction for a predetermined length of time to the tool for carrying out a metal-cutting process on the semi-finished product and lifting the tool from the at least one machining surface after the predetermined length of time. In order to protect the semi-finished products from damage through the machining residues and at the same time not to impair the drilling performance, according to the invention through the adhesion an adhesive force is produced between the protective foil and the machining surface of substantially 10 N/25 mm and a protective foil is used which has an elongation at break of between 80 and 120%.
Disclosed is an improved pipe cutting tool based upon a ratchet closure action wherein handles are pivotedly attached to allow successive movement of a cutting blade in response to the squeezing of the handles. The handles are also hingedly coupled to the cutting member to maintain the cutting member in a position perpendicular to the tubular item to be cut while allowing the operator to squeeze the handles at offset angles, up to and including a right angle cut. The hinged handles allow for offset operation without forgoing the ease of operation by the consumer or causing a large reduction in the mechanical advantage. A ratchet allows sequential advancement of a cutting member toward a tubular shaped jaw that holds the item to be cut.
This disclosure generally relates to high-volume and cost-effective methods for producing non-spherical metal particles, particularly methods for producing metal cubes having rounded edges. The metal cubes having rounded edges are useful as ballistic shot in shotshell loads for hunting, where the particle shape imparted by the disclosed process packs to a higher density than spherical shot in the same volume.
Core-shell particles encapsulated by a thin film of a catalytically active metal are described. The particles are preferably nanoparticles comprising a non-noble core with a noble metal shell which preferably do not include Pt. The non-noble metal-noble metal core-shell nanoparticles are encapsulated by a catalytically active metal which is preferably Pt. The core-shell nanoparticles are preferably formed by prolonged elevated-temperature annealing of nanoparticle alloys in an inert environment. This causes the noble metal component to surface segregate and form an atomically thin shell. The Pt overlayer is formed by a process involving the underpotential deposition of a monolayer of a non-noble metal followed by immersion in a solution comprising a Pt salt. A thin Pt layer forms via the galvanic displacement of non-noble surface atoms by more noble Pt atoms in the salt. The overall process is a robust and cost-efficient method for forming Pt-coated non-noble metal-noble metal core-shell nanoparticles.
This invention relates to power metallurgical material, production method and application thereof. A metallurgy powder material with pressure-proof & good compactness, satisfactory to the component content requirements for 316 stainless steel, wherein, 5˜9% (by weight) of Fe3P (or Fe3PO4). The powder metallurgical material has properties of pressure resistance and corrosion resistance, and excellent compactness.
A pump for pumping molten metal and delivering flux includes a refractory base that can be submerged in molten metal including an impeller chamber, an inlet and an outlet. A refractory shaft sleeve has upper and lower end portions and is fastened to the base at the lower end portion. A motor is disposed near the upper end portion of the shaft sleeve. A refractory shaft extends in the shaft sleeve and is connected to the motor near the upper end portion of the shaft sleeve. A refractory impeller is connected to the shaft and is rotatable in the impeller chamber. A flux feeding device feeds flux into the shaft sleeve. Also featured is a method for delivering flux in the shaft sleeve of the pump and a method for cleaning flux accretions in the shaft sleeve.
A method of making metal nanoparticles and carbon nanotubes is disclosed. A mixture of a transition metal compound and an aromatic polymer, a precursor of an aromatic polymer, or an aromatic monomer is heated to form a metal nanoparticle composition, optionally containing carbon nanotubes.
The invention relates to a composition for synthesizing bimetallic nanoparticles, wherein the composition contains a first organometallic precursor and a second organometallic precursor having different decomposition rates and contained within an ionic liquid solution. The invention also relates to a method for synthesizing bimetallic nanoparticles, in which the composition is transformed under a hydrogen gas pressure between 0.1 and 10 MPa at a temperature between 0 and 150° C. until a suspension of bimetallic nanoparticles is obtained. The resulting nanoparticles are useful in diverse fields including the fields of catalysis and microelectronics.
The present invention provides a process for recovering valuable metals from precious metal smelting slag, comprising: smelting the precious metal smelting slag and a flux in a top-blown rotary furnace to produce a lead-bismuth alloy, wherein the precious metal smelting slag comprises Au, Ag, Bi and Pb; electrolyzing the lead-bismuth alloy at a current density ranging from 60 to 110 A/m2 to obtain lead cathode and lead anode slime; refining the lead anode slime to produce bismuth and silver-zinc crust, and extracting gold and silver separately from the silver-zinc crust. Through utilizing a top-blown rotary furnace as the smelting apparatus and adjusting the ratio of the flux, the present invention enriches the valuable metals gold, silver, bismuth, lead or the like to lead-bismuth alloy, ensures lower contents of gold, silver, bismuth and lead in the reducing slag and thereby increases the comprehensive recovery rates of gold, silver, bismuth and lead from the precious metal smelting slag.
A metal-bonded graphite foam composite includes a ductile metal continuous phase and a dispersed phase that includes graphite foam particles.
The invention relates to sputter targets and methods for depositing a layer from a sputter target. The method preferably includes the steps of: placing a sputter target in a vacuum chamber; placing a substrate having a substrate surface in the vacuum chamber; reducing the pressure in the vacuum chamber to about 100 Torr or less; removing atoms from the surface of the sputter target while the sputter target is in the vacuum chamber (e.g., using a magnetic field and/or an electric field). The deposited layer preferably is a molybdenum containing alloy including about 50 atomic percent or more molybdenum, 0.5 to 45 atomic percent of a second metal element selected from the group consisting of niobium and vanadium; and 0.5 to 45 atomic percent of a third metal element selected from the group consisting of tantalum, chromium, vanadium, niobium, and titanium.
Methods of forming metal matrix nanocomposites are provided. The methods include the steps of introducing a master metal matrix nanocomposite into a molten metal at a temperature above the melting temperature of the master metal matrix nanocomposite, allowing at least a portion of the master metal matrix nanocomposite to mix with the molten metal and, then, solidifying the molten metal to provide a second metal matrix nanocomposite.
The invention is directed to a process and apparatus for recovering metals from bottom ash from incineration plants, such as municipal waste incineration plants. The process includes directing a feed containing ash into an oxidizing unit, wherein at least part of the metals is oxidized in the presence of one or more acids and at least one oxygen donor, thus producing a stream comprising metal ions. From this stream the metals of interest are selected and converted into metallic form.
The present invention aims at improving a recovery rate of a positive-pole active substance and preventing a recovery loss of valuable metals when a positive-pole active substance is separated from a lithium ion battery. In the present invention, a material resulting from battery dismantling obtained by dismantling a lithium ion battery is stirred using a surfactant solution, whereby a positive-pole active substance is separated from a positive-electrode substrate. Also, it is preferable that an alkaline solution is added to a positive-electrode material of a material resulting from battery dismantling, thereby dissolving a positive-electrode substrate to which a positive-pole active substance adheres to obtain a slurry containing the positive-pole active substance, and a surfactant solution is added to the slurry to disperse the positive-pole active substance in the slurry, whereby the positive-pole active substance is separated from the alkaline solution.