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Stability of the ketyl radical as a descriptor in the electrochemical coupling of benzaldehyde

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00282H, Paper
Jacob Anibal, Arnav Malkani, Bingjun Xu
Electroreductive coupling is an emerging pathway for the renewable upgrading of biomass derived oxygenates. This work investigates electrochemical benzaldehyde reduction on Au, Cu, Pt and Pd using reactivity testing and in situ spectroscopy.
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Facet-Dependent Activity of Hematite Nanocrystals toward Oxygen Evolution Reaction

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00655F, Paper
Toshihiro Takashima, Shota Hemmi, Qingyu Liu, Hiroshi Irie
Electrocatalytic activity of hematite exposed with different facets toward the oxygen evolution reaction (OER) was investigated. Hematite nanoparticles with pseudo cubic, hexagonal bipyramid, and plate morphologies were prepared, which predominantly...
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Interfacial Effect of Co4S3-Co9S8 Nanoparticles Hosted onto rGO Sheets Derived from Molecular Precursor Pyrolysis on Enhancing Electrochemical Behaviour†

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00564A, Paper
Mengmeng He, Linchao Zhu, Yanyan Liu, Hao Wen, Yunxia Hu, Baojun Li
The reasonable design and synthesis of Co-based compound with superior electrochemical activity and durability have aroused tremendous research interests. Herein, a simple molecular precursor pyrolysis strategy is proposed to fabricate...
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Hierarchical Z-scheme 1D/2D architecture with TiO2 nanowires decorated by MnO2 nanosheets for efficient adsorption and full spectrum photocatalytic degradation of organic pollutants

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00419G, Paper
Jiejing Zhang, Yajie Hu, Hong Zheng, Pengyi Zhang
Constructing composite photocatalysts with efficient photocatalytic activity, wide optical response range and excellent stability has great significance for the removal of organic pollutants in water. Herein, we report a novel...
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Speciality chemical maker Rossari Biotech receives Sebi's approval for IPO

Market sources said the IPO size will be worth Rs 700 crore




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Two-step tumor-targeting therapy via integrating metabolic lipid-engineering with in situ click chemistry

Biomater. Sci., 2020, 8,2283-2288
DOI: 10.1039/D0BM00088D, Paper
Guihong Lu, Liping Zuo, Jinfeng Zhang, Houshun Zhu, Wanru Zhuang, Wei Wei, Hai-Yan Xie
A highly efficient two-step targeting strategy integrating metabolic lipid-engineering with in situ click chemistry is developed, thus significantly improved the tumor theranostic performance of the red blood cells ghosts based drug delivery.
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A fluorinated low-molecular-weight PEI/HIF-1α shRNA polyplex system for hemangioma therapy

Biomater. Sci., 2020, 8,2129-2142
DOI: 10.1039/D0BM00171F, Paper
Xiaoshuang Guo, Zihan Yuan, Yang Xu, Minyan Wei, Zhiwei Fang, Wei-En Yuan
RNAi technology targeting HIF-1α could benefit hemangioma therapy effectively and FPEI polyplexes which could inhibit the expression of HIF-1α at the translational level can provide a practicable strategy for clinical hemangioma treatment in the future.
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Arbitrarily-shaped microgels composed of chemically unmodified biopolymers

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/C9BM02056J, Paper
Yadu N. Vakkipurath Kodakkadan, Kristyna Idzakovicova, Josef Sepitka, Daniël ten Napel, Eric Safai, Petr Cigler, Frantisek Štěpánek, Ivan Rehor
We introduce a method for photolithographic synthesis of arbitrarily shaped microgels composed purely of a biopolymer of choice.
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Messenger RNA/polymeric carrier nanoparticles for delivery of heme oxygenase-1 gene in the post-ischemic brain

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00076K, Paper
Jungju Oh, Sang-Mi Kim, Eun-Hye Lee, Minkyung Kim, Youngki Lee, Seung Hwan Ko, Ji Hoon Jeong, Chang-Hwan Park, Minhyung Lee
Heme oxygenase-1 messenger RNA (HO1-mRNA) was delivered into the post-ischemic brain, using a polymeric carrier. Therapeutic efficacy of HO1-mRNA delivery was compared with that of HO1-plasmid DNA (HO1-pDNA) in ischemia-reperfusion rat models.
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Photothermal augment stromal disrupting effects for enhanced Abraxane synergy chemotherapy in pancreatic cancer PDX mode

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00549E, Paper
Tianhong Teng, Ronggui Lin, Ziguo Lin, Kun Ke, Xianchao Lin, Maoen Pan, Da Zhang, Heguang Huang
Preparation of Abraxane@MoSe2 and its PTT effect augment stromal disrupting effects for enhanced Abraxane synergy chemotherapy in pancreatic cancer PDX mode.
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Disulfiram-Gold-Nanorod Integrate for Effective Tumor Targeting and Photothermal-Chemical Synergistic Therapy

Biomater. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0BM00062K, Paper
Chaoli Xu, Ting Zhang, Guangming Lu, Kun Chen, Jun Tao, Yunlei Zhang, Zhaogang Teng, Bin Yang
Herein, we successfully constructed a combined therapeutic nanoplatform with high tumor targeting for cancer treatment by integrating gold nanorods with disulfiram (denoted Au-DSF). The Au-DSF integrates possess a uniform length...
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Dual-responsive click-crosslinked micelles designed for enhanced chemotherapy for solid tumors

Biomater. Sci., 2020, 8,2507-2513
DOI: 10.1039/D0BM00078G, Paper
Rong Jin, Jing Sun, Liefu Zhou, Xuelian Guo, Aoneng Cao
Core-crosslinked dual-responsive micelles can be readily constructed from a pair of clickable copolymers and applied for controlled release of anticancer drugs in cancer therapy.
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A nanosystem loaded with perfluorohexane and rose bengal coupled upconversion nanoparticles for multimodal imaging and synergetic chemo-photodynamic therapy of cancer

Biomater. Sci., 2020, 8,2488-2506
DOI: 10.1039/C9BM02081K, Paper
Hai-yan Wang, Li Hou, Hai-liang Li, Xu Wang, Yang Cao, Bo-yu Zhang, Jing-tao Wang, Shi-jie Wei, Hong-wan Dang, Hai-tao Ran
A novel nanosystem (FURH-PFH-NPs) combined with LIFU and laser irradiation realized multimodal imaging, targeted release of HCPT, UCNPs-RB and synergetic chemo-photodynamic therapy of cancer.
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Injectable hydrogel systems with multiple biophysical and biochemical cues for bone regeneration

Biomater. Sci., 2020, 8,2537-2548
DOI: 10.1039/D0BM00104J, Paper
Weinan Cheng, Zhaozhao Ding, Xin Zheng, Qiang Lu, Xiangdong Kong, Xiaozhong Zhou, Guozhong Lu, David L. Kaplan
Tunable multiple angiogenic and osteogenic cues were introduced into hydrogel systems simultaneously to optimize the niches for bone regeneration.
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Nanomedicine – a promising therapy for hematological malignancies

Biomater. Sci., 2020, 8,2376-2393
DOI: 10.1039/D0BM00129E, Review Article
Lifen Huang, Jun Huang, Junbin Huang, Hongman Xue, Zhiqing Liang, Jun Wu, Chun Chen
Nanoparticles (NPs) are used for the diagnosis and treatment of hematological tumors by loading various pharmacodynamic molecules.
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Thyroid endocrine status and biochemical stress responses in adult male Wistar rats chronically exposed to pristine polystyrene nanoplastics

Toxicol. Res., 2019, 8,953-963
DOI: 10.1039/C9TX00147F, Paper
Fatemeh Amereh, Akbar Eslami, Simin Fazelipour, Mohammad Rafiee, Mohammad Ismail Zibaii, Mohammad Babaei
At this time, little is known about the long-term effects of micro(nano)plastics on public health. In the present study, early warning signs of thyroid endocrine disruption were noticed in adult Wistar rats from the ingestion of virgin polystyrene nanoparticles.
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Astilbin attenuates cerebral ischemia/reperfusion injury by inhibiting the TLR4/MyD88/NF-κB pathway

Toxicol. Res., 2019, 8,1002-1008
DOI: 10.1039/C9TX00222G, Paper
Jing Li, Zhaowei Gu, Yue Liu, Yu Wang, Min Zhao
Ischemic stroke is the second most common cause of death worldwide and cerebral ischemia/reperfusion (I/R) injury also leads to serious tissue damage.
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Phytochemicals protect L02 cells against hepatotoxicity induced by emodin via the Nrf2 signaling pathway

Toxicol. Res., 2019, 8,1028-1034
DOI: 10.1039/C9TX00220K, Paper
Yan Yan, Kang Wang, Xu Tang, Jun-feng Gao, Bin-yu Wen
Dihydromyricetin (DMY), hyperoside and silybin are phytochemicals that belong to a class called flavonoids, and they have been used in liver protection pharmaceutical preparations, but the specific mechanism of these chemicals is still unclarified.
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Facile fabrication of sponge-like porous micropillar arrays via an electrochemical process

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR01518K, Paper
Deyin Zheng, Chang-Hwan Choi, Xin Zhao, Guangyi Sun
Highly ordered and aligned pore structures perpendicular to the exposed surfaces are achieved on the surfaces of 3D Si microstructures.
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Characteristics of crystalline sputtered LaFeO3 thin films as photoelectrochemical water splitting photocathodes

Nanoscale, 2020, 12,9653-9660
DOI: 10.1039/D0NR01762K, Paper
Min-Kyu Son, Hyunwoong Seo, Motonori Watanabe, Masaharu Shiratani, Tatsumi Ishihara
A transparent crystalline sputtered LaFeO3 photocathode with an early onset potential for stable photoelectrochemical water splitting.
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Designing transition-metal-boride-based electrocatalysts for applications in electrochemical water splitting

Nanoscale, 2020, 12,9327-9351
DOI: 10.1039/D0NR01279C, Review Article
Yuanyuan Jiang, Yizhong Lu
Recent progresses made in transition metal boride (TMB)-based electrocatalysts for electrochemical water splitting are summarized.
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Supramolecular chemistry of carbon nano-onions

Nanoscale, 2020, 12,9352-9358
DOI: 10.1039/D0NR01713B, Minireview
Michał Bartkowski, Silvia Giordani
An exhaustive and succinct minireview of the various reported approaches to the non-covalent surface modification of carbon nano-onions (CNOs).
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2D molybdenum disulphide nanosheets incorporated with single heteroatoms for the electrochemical hydrogen evolution reaction

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR01295E, Minireview
Thomas H. M. Lau, John S. Foord, S. C. Edman Tsang
2D nanosheets give enhanced surface area to volume ratios in particle morphology and they can also provide defined surface sites to disperse foreign atoms.
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Triplet photosensitizer-nanotube conjugates: synthesis, characterization and photochemistry of charge stabilizing, palladium porphyrin/carbon nanotube conjugates

Nanoscale, 2020, 12,9890-9898
DOI: 10.1039/D0NR02136A, Paper
Luis M. Arellano, Habtom B. Gobeze, María J. Gómez-Escalonilla, José Luis G. Fierro, Francis D'Souza, Fernando Langa
SWCNTs covalently modified with a triplet photosensitizer, palladium porphyrin, have been newly prepared and photoinduced charge separation is reported.
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The greatest jigsaw puzzle of them all




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'Papa' Hemingway wrote his best in Key West




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"Dad" Gandy's "wild, visionary scheme"




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Hemingway's hangout




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Using stated choice methods in the design of payments for environmental service schemes




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The marriage record of Singleton, Henry J. and McEachem, Lizze J




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The marriage record of Reynolds, M. L. and Barthem, Ella




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Laurita, a cigar label made by G. F. Hemler for the Lindura Havana Cigar Company.




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Chemistry students in good mood




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Leaf with the end of I Esadras (Nehemiah), and the beginning of II Esadras




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Leaf with the end of I Esadras (Nehemiah), and the beginning of II Esadras




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Bonfils(?). Marché de Bethléem. - Marketplace at Bethlehem. "No. 1042."




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Unknown studio. Chemin de fer de Mürren, Grütschalp. "No. 964." "Edit PHOTOGLOB."




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Schrœder & Cie. Interlaken, Chemin finiculaire de Mürren la grande Montée. "No. 908."




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Anna Hempel




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To Bring Them Within Reach




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Cesar and Casimiro with an unidentified dignitary between them




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Waterfront. Tall slender palm trees, water behind them, buildings in background including Soreno Hotel




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Waterfront. Tall palm trees, three people under them, looking across water toward buildings in background




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Esther Stewart Kahn postcard showing Williams Park; a concert in the bandshell with a large audience; writing on back: "This shows the band shell and some of the crowd who go to hear them. The band is playing the Star Spangled Banner and that is the




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Children playing music in a band, adults standing behind them listening; Yacht Club in background




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Children before playing music in a band, adults standing behind them; Yacht Club in background




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Chemistry and agriculture buildings, University of Florida, Gainesville, Fla




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Elk Club, Board of Trade, Hemming Park, Jacksonville, Fla




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Skyline and Hemming Park from St. James Bldg., Jacksonville, Fla




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Confederate Monument, Hemming Park, Jacksonville, Fla