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Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction

RSC Adv., 2024, 14,35163-35171
DOI: 10.1039/D4RA06595F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng Huang
Graphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effective BPA degradation in water: the integration of bimetallic UiO-66 Ce–Zr

RSC Adv., 2024, 14,35090-35096
DOI: 10.1039/D4RA06460G, Paper
Open Access
Leidy Marcela Gallo, Juan L. Obeso, Nora S. Portillo-Vélez, Carlos E. Garduño-Albino, Catalina V. Flores, Leonardo Herrera-Zuñiga, Alejandro Islas-Jácome, Ricardo A. Peralta, Carolina Leyva
In this work, a bimetallic MOF UiO-66 Ce–Zr to degrade bisphenol A (BPA) in water was synthesised. The material exhibited a remarkable degradation efficiency of 84.3% under UV irradiation for 240 minutes.
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Investigation of the titanium-mediated catalytic enantioselective oxidation of aryl benzyl sulfides containing heterocyclic groups

RSC Adv., 2024, 14,35105-35113
DOI: 10.1039/D4RA07088G, Paper
Open Access
Maria Annunziata M. Capozzi, Angel Alvarez-Larena, Joan F. Piniella Febrer, Cosimo Cardellicchio
Enantiopure benzyl heteroaryl sulfoxides were obtained by asymmetric oxidation. However, two benzimidazolyl sulfoxides were found to be conglomerates.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Newly synthesized sulfonamide derivatives explored for DNA binding, enzyme inhibitory, and cytotoxicity activities: a mixed computational and experimental analyses

RSC Adv., 2024, 14,35047-35063
DOI: 10.1039/D4RA06412G, Paper
Open Access
Nasima Arshad, Yasir Mehmood, Hammad Ismail, Fouzia Perveen, Aneela Javed, Pervaiz Ali Channar, Aamer Saeed, Sadia Naseem, Fatima Naseer
This work reports synthesis, characterization, DNA, enzyme binding and cytotoxicity activity of three 4-((3-arylthiazolo[3,4-d]isoxazol-5-yl)amino)benzene sulfonamide derivatives with a thaizaole(3,4-d)isoxazole-based fused ring heterocyclic system.
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Clues from an ionic cocrystal structure: from catalysis to mechanochemistry

RSC Adv., 2024, 14,34843-34847
DOI: 10.1039/D4RA05652C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bandana Sar, Mollah Rohan Ahsan, Arijit Mukherjee
A crystal structure is no longer conceived as a static entity; rather, it often mirrors crystallization pathways, linking crystal structures with a solution scenario.
The content of this RSS Feed (c) The Royal Society of Chemistry




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An exceptional water stable terbium-based metal–organic framework for selective detection of pesticides

RSC Adv., 2024, 14,35220-35226
DOI: 10.1039/D4RA06622G, Paper
Open Access
Ching-Ping Liu, Ting-En Lin, Jung-Chang Chiang, Bo-Jhen Chen, Po-Hsiu Chien, Su-Ying Chien, Gene-Hsiang Lee, Yen-Hsiang Liu, Kuang-Lieh Lu
The terbium-based metal–organic frameworks (Tb-MOFs) were synthesized successfully under hydrothermal conditions, which could maintain at least 90% of the emission intensity after storage in water for several months.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Transient crystallisation of rare earth carbonates during the hydrothermal oxidation of siderite

RSC Adv., 2024, 14,35305-35322
DOI: 10.1039/D4RA05212A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Maddin M., Rateau R., Szucs A. M., Terribili L., Rodriguez-Blanco J. D.
The researchers investigated the interaction between multi-component rare earth element-bearing aqueous solutions and siderite grains under hydrothermal conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ab initio study of electronic, elastic, thermodynamic, photocatalytic properties of double antiperovskite, Cs6AgBiX2 (X = Cl, Br, I)

RSC Adv., 2024, 14,35348-35359
DOI: 10.1039/D4RA05661B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Laraib Sajid, M. Usman Saeed, S. H. Mashadi, S. Sheryar Abid, Shamiala Pervaiz, Zeeshan Ali, Yousef Mohammed Alanazi, Aziz-Ur-Rahim Bacha, Y. Saeed
We use DFT to study the structural, electronic, optical, photocatalytic, mechanical, vibrational, and thermodynamical behaviors of new double antiperovskite Cs6AgBiX2 (X = Cl, Br, I).
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DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction

RSC Adv., 2024, 14,35475-35489
DOI: 10.1039/D4RA03676J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Batoul Alipour
The mechanism and origin of stereoselectivity for the synthesis of asymmetric organosilanes using NHC are theoretically investigated.
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Superior low temperature activity over α-MnO2/β-MnOOH catalyst for selective catalytic reduction of NOx with ammonia

RSC Adv., 2024, 14,35498-35504
DOI: 10.1039/D4RA05934D, Paper
Open Access
Masanori Takemoto, Haruko Fujinuma, Yoshihiro Sugawara, Yukichi Sasaki, Kenta Iyoki, Tatsuya Okubo, Kazuya Yamaguchi, Toru Wakihara
α-MnO2/β-MnOOH catalysts were synthesized by post-synthetic planetary ball milling for OMS-2, enhancing catalytic activity in low-temperature NH3-SCR.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Statistically driven automated method for catalytic glucose conversion optimisation

RSC Adv., 2024, 14,35578-35584
DOI: 10.1039/D4RA06038E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joseph Install, Rui Zhang, Jukka Hietala, Timo Repo
A statistically driven, automated approach to optimize glucose transformations to platform chemicals, methyl lactate and levulinic acid, is reported.
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Harnessing the UiO-67 metal–organic framework for advanced detection of cadmium ions in water bodies

RSC Adv., 2024, 14,35618-35627
DOI: 10.1039/D4RA06811D, Paper
Open Access
Bhuvaneswari Selvaraj, Lakshmi Priya G., Selva Balasubramanian
Heavy metal ions are hazardous pollutants that pose serious threats to ecosystems and human health, making it imperative to detect and monitor their presence in water for environmental protection.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Zeolitic imidazolate framework-67 in chitosan-grafted hydrogel as an effective catalyst for peroxymonosulfate activation to degrade antibiotics and dyes

RSC Adv., 2024, 14,35628-35637
DOI: 10.1039/D4RA06537A, Paper
Open Access
Atipong Nachaichot, Kunlarat Phonlakan, Supinya Nijpanich, Soraya Pornsuwan, Surangkhana Budsombat
Zeolitic imidazolate framework-67 (ZIF-67) was synthesized in situ in the hydrogel of chitosan-grafted poly(acrylic acid) (chitosan-g-PAA) to activate peroxymonosulfate (PMS) and degrade tetracycline (TC).
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Synthesis of supramolecular polymers with calix[4]arene and β-cyclodextrin and their application in heavy metal ion absorption

RSC Adv., 2024, 14,35697-35703
DOI: 10.1039/D4RA05559D, Paper
Open Access
Jian-Jian Bian, Shi-Jin Tang, Jiao Miao, Rui Lin, Guo-Li Huang, Ming-Yu Teng, Xiao-Mei Li
Two categories of supramolecular polymer monomers were produced by introducing the ureidopyrimidone quadruple-hydrogen bonding assemblies on the calix[4]arene and the β-cyclodextrin host units, which adsorbed up to 99% of Pb2+ and Cd2+.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Review of iodine behavior from nuclear fuel dissolution to environmental release

RSC Adv., 2024, 14,35255-35274
DOI: 10.1039/D4RA06494A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chelsie L. Beck, Juan Cervantes, Steven Chiswell, Allison T. Greaney, Katherine R. Johnson, Tatiana G. Levitskaia, Leigh R. Martin, Gavin McDaniel, Stephen Noble, Jason M. Rakos, Brian J. Riley, Andrew Ritzmann, Joel M. Tingey
During nuclear fuel reprocessing, radioiodine, can be released.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tailoring dual cross-linked polymer-ionic liquid composites by blending co-crystallizable polymers for stretchable electronics

RSC Adv., 2024, 14,36022-36030
DOI: 10.1039/D4RA05968A, Paper
Open Access
Minjun Kim, Moonsung Park, Hobin Seon, Sohyun Choi, Hee Joong Kim, Sangwon Kim
A dual cross-linked polymer-ionic liquid composite exhibits self-healing capabilities and is ideal for wearable strain sensor applications.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of Cu/Mn/Ce polymetallic oxide catalysts and catalytic ozone treatment of wastewater

RSC Adv., 2024, 14,35993-36004
DOI: 10.1039/D4RA06052K, Paper
Open Access
Jinlong Zhong, Xue feng Mao, Guanyu Wang, Heng Li, Junfang Li, Sijian Qu, Jianwei Zhao
Non-homogeneous ozone-catalyzed oxidation technology is one of the effective ways of treating wastewater, the core of which lies in the development of efficient ozone oxidation catalysts.
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Stability and magnetic properties of transition metal (V, Cr, Mn, and Fe) doped cobalt oxide clusters: a density functional theory investigation

RSC Adv., 2024, 14,36031-36039
DOI: 10.1039/D4RA05482B, Paper
Open Access
Nguyen Thi Mai, Tran Dang Thanh, Do Hung Manh, Nguyen Thi Ngoc Anh, Ngo Thi Lan, Phung Thi Thu, Nguyen Thanh Tung
Con−1TMOn−2+ (n = 6–8), (TM = V, Cr, Mn, and Fe) clusters are investigated using density functional theory calculations.
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Polyether-based polyurethane electrolyte for lithium metal battery: a perspective

RSC Adv., 2024, 14,36152-36160
DOI: 10.1039/D4RA06863G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Peng Cui, Yifan Li, YuXing Liu, Siqi Wang, Xingyu Tang, Yihong Ye, Hance Su, Chun Sun
Mechanism of increasing ionic conductivity of polyether-based polyurethane electrolyte.
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Chitosan supported ionic liquid, a multifaceted catalyst for streamlined and efficient synthesis of carboxylic, amino acid and carbohydrate esters

RSC Adv., 2024, 14,36193-36208
DOI: 10.1039/D4RA05725B, Paper
Open Access
Praachi Kakati, Satish Kumar Awasthi
Development of a solid heterogeneous catalyst in the form of an ionic liquid incorporated in chitosan which shows high recyclability. This was used in a solvent free esterification reaction of carboxylic acids, amino acids and carbohydrates.
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Distance-based paper microfluidic devices for rapid visual quantification of heavy metals in herbal supplements and cosmetics

RSC Adv., 2024, 14,36142-36151
DOI: 10.1039/D4RA05358C, Paper
Open Access
Yanawut Manmana, Mirek Macka, Nantana Nuchtavorn
The ion exchange paper shows strongly retain anionic metallochromic reagents, enabling clear endpoint detection on DμPADs. This method allows rapid heavy metal screening in real samples, with the predeposited reagents stable for at least 2 months.
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In silico molecular docking and ADMET prediction of biogenic zinc oxide nanoparticles: characterization, and in vitro antimicrobial and photocatalytic activity

RSC Adv., 2024, 14,36209-36225
DOI: 10.1039/D4RA06890D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hajara Akhter, Susmita Sarker Ritu, Shahariar Siddique, Fariha Chowdhury, Rehnuma Tasmiyah Chowdhury, Samina Akhter, Mahmuda Hakim
A facile green route to synthesize zinc oxide nanoparticles using watermelon rind extract with antimicrobial and photocatalytic potential.
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Porous CaMnO3-promoted g-C3N4 as an effective photocatalyst for tetracycline degradation

RSC Adv., 2024, 14,36181-36192
DOI: 10.1039/D4RA06407K, Paper
Open Access
Bo Zhang, Chaoqi Li, Shasha Liu, Lixuan Zhuang, Weiqi Zhang, Limei Huang, Zhenzhen Jia, Dongdong Chen, Xiang Li
Non-expensive CaMnO3 perovskite oxide can assist in developing efficient g-C3N4-based photocatalysts aimed at removing antibiotics from wastewater.
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Improving the catalytic performance of Co/BaCeO3 catalyst for ammonia synthesis by Y-modification of the perovskite-type support

RSC Adv., 2024, 14,36281-36294
DOI: 10.1039/D4RA06251E, Paper
Open Access
Magdalena Zybert, Hubert Ronduda, Wojciech Patkowski, Andrzej Ostrowski, Kamil Sobczak, Wioletta Raróg-Pilecka
The beneficial effect of Y3+ ions incorporated into BaCeO3 support structure stems from the strengthening of the electron-donating ability, i.e., better charge transfer from the support to the active metal, enhancing N2 dissociation.
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Madhya Pradesh Cabinet meets in tribal queen’s capital on her 500th birth anniversary

The Cabinet has approved additional assistance of up to ₹3,900 per hectare to farmers under the Rani Durgavati Shri Anna Protsahan Yojana, over the minimum purchase price




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Police constable suspended for stalking woman in Ratlam




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NSCN (I-M) seeks third-party intervention to break talks deadlock

Accusing the Centre of betraying the Framework Agreement of 2015, the Naga extremist group led by Thuingaleng Muivah threatened to return to violent ways




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Brainstorming for new science portal

We need to start brainstorming for ideas and features that we want on the new science portal so we'll be prepared for when we locate a web designer.

Here are a list of some other science library websites. Not all are great but I'd like for us to discuss what elements we like and which features we don't like (just as important). Please feel free to post links to other libraries you think are worthy of critique. Also, if there are general guidelines and features that you'd like to include please post about those too.

My first impression looking at these sites is how busy they all are. Lots of links and it seems overwhelming at first glance. Its a decision that we'll have to make about how much information should be quickly accessible on the main page but yet still easily usable. Caltech's library page is the most easily navigated, IMO. I like the quick drop down boxes and the selection of links. I especially like the menu for authors - as the issue of open access and author rights becomes more important on campus, we'll need to take an active role in helping the faculty understand their rights and options for publishing.


Berkeley: Chemistry: http://www.lib.berkeley.edu/CHEM/
Engineering: http://www.lib.berkeley.edu/ENGI/
Physics/Ay: http://www.lib.berkeley.edu/PHYS/

Caltech: http://library.caltech.edu/

Chicago : http://www1.lib.uchicago.edu/e/crerar/index.php3

Irvine: http://www.lib.uci.edu/libraries/science.html

Michigan: http://www.lib.umich.edu/science/

MIT Science Library: http://libraries.mit.edu/science/

Oregon Science Library: http://libweb.uoregon.edu/scilib/

Santa Cruz: http://libweb.uoregon.edu/scilib/




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Web address for Science Portal in progress

The URL for the mock-up Leila showed last Tuesday is:
lnadams.org/msl.htm

Please remember that this is just a design layout, the links do not work, and it is subject to extreme change.

Comments are highly encouraged! Please post to this blog or email Sara or Joe.




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India Open under-23 athletics: Talented athletes eager to prove their worth

The athletes will look to perform well ahead of the Asian and World championships next year.




tal

Check out India's lowest totals in Test cricket

India's overall lowest, however, was recorded four years ago against Australia when they were shot out for a mere 36 at Adelaide.




tal

WHO, 50 countries warn United Nations of increasing ransomware attacks against hospitals

Such attacks on hospitals “can be issues of life and death” World Health Organization head Tedros Adhanom Ghebreyesus, who addressed the U.N. Security Council, said




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Fight over including carbon border tax in agenda delays climate talks on day one

Agenda disputes are common at UN climate conferences but this one is especially significant as countries have limited time to agree on a new climate finance goal.




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Iran launches missile barrage at Israel, warns of ‘crushing’ retaliation if provoked

Israeli air defences intercepted many of the missiles, with no reported casualties. Meanwhile, the US pledged military support for Israel, and the UN called for a ceasefire amid concerns over escalating regional conflict 




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US and India can work together on mental health, says US Surgeon General Vivek Murthy

US Surgeon General Murthy says it is time to prioritise and accelerate the work on mental health, because the consequences have been too high




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Israel-Iran tensions escalate: Retaliatory strikes target military installations in Tehran

The Israeli military cited continuous Iranian attacks from multiple fronts since October 7, affirming Israel’s right to retaliate




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Trump talks Xi, tariffs and aliens in freewheeling Joe Rogan podcast

The conversation stretched long enough that Trump ended up hours late for a rally in swing-state Michigan, where hundreds of supporters trickled out of the venue as temperatures dropped while waiting for him to arrive




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World Bank in talks to help finance $28 billion Turkish energy upgrade, Anadolu reports

Humberto Lopez was quoted on Saturday as saying the World Bank was in talks with Turkey's ministry of energy about the matter



  • Money & Banking

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Taliban administration officials to attend UN climate conference in Azerbaijan

Taliban officials have taken part in U.N.-organised meetings on Afghanistan in Doha, and Taliban ministers have attended forums in China and Central Asia in the past two years




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UN climate talks to focus on money to help poor nations cut carbon pollution

About 77% of the heat-trapping gas in the atmosphere now comes from the G20 rich nations, many of whom are now cutting back on their pollution, something that is not happening in most poor nations or China




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Write Alt Text Like You’re Talking To A Friend

“There was this dog wearing safety glasses, surrounded by chemistry equipment, saying ‘I have no idea what I’m doing.’”




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FIFA bans Italian player Curto for 10 games for discrimination toward South Korean opponent

Curto also must do community services and undergo training and education with an organization approved by FIFA




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Serie A leader Napoli scores late to beat struggling Lecce and Atalanta routs Verona

Serie A leader Napoli has needed a late score from captain Giovanni Di Lorenzo to secure a 1-0 victory over struggling Lecce




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RBI’s gold holdings now exceed India’s annual demand for the precious metals

Central bank embarks on gold buying spree, adds 25 tonnes to forex reserves



  • Gold & Silver

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Augmont ties up with fintech players to offer digital gold services

The company’s digital platform can help users transact in the yellow metal



  • Gold & Silver

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Will ‘one nation, one gold rate’ add to the yellow metal’s sheen?

Industry moots policy to bring transparency that can boost customer confidence



  • Gold & Silver

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65% of millennials prefer digital gold over traditional for its ease of access and convenience: Moneyview survey

Digital gold can be easily converted to cash or physical gold, giving investors flexibility to trade without incurring heavy transaction costs or delays



  • Gold & Silver

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An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02690J, Communication
Alexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di Sun
First metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...
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Achieving isopropenyl-enriched polyisoprene: unraveling the role of bidentate vs. tridentate iron precatalysts through ligand framework design

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02659D, Paper
Sunny Sohail, Yanping Ma, Qaiser Mahmood, Zexu Hu, Yizhou Wang, Tongling Liang, Wen-Hua Sun
The coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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High-pressure synthesis and crystal structure analysis of PbTeO4, a UV transparent material

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02697G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Michael Hladik, Armin Penz, Felix R. S. Purtscher, Thomas S. Hofer, Gunter Heymann, Matthias Weil
Crystal structure of PbTeO4 with presumed position of the PbII lone-pair electrons (turquoise spheres). The electron localization function was used to emphasize the presence of the electron lone pair E.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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