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Improving the catalytic performance of Co/BaCeO3 catalyst for ammonia synthesis by Y-modification of the perovskite-type support

RSC Adv., 2024, 14,36281-36294
DOI: 10.1039/D4RA06251E, Paper
Open Access
Magdalena Zybert, Hubert Ronduda, Wojciech Patkowski, Andrzej Ostrowski, Kamil Sobczak, Wioletta Raróg-Pilecka
The beneficial effect of Y3+ ions incorporated into BaCeO3 support structure stems from the strengthening of the electron-donating ability, i.e., better charge transfer from the support to the active metal, enhancing N2 dissociation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Panel formed to monitor opening of treasury of Jagannath temple in Puri to meet on July 6

The last inventory of Ratna Bhandar was taken 46 years ago in 1978




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Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02440K, Paper
Rebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig Andrews
Five complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective

Dalton Trans., 2024, 53,17742-17755
DOI: 10.1039/D4DT01727G, Perspective
Eduarda Andrade, Filipe A. Almeida Paz, Flávio Figueira
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Pandemonium : bird flu, mad cow disease, and other biological plagues of the 21st century / Andrew Nikiforuk

Toronto : Viking Canada ; New York, NY : Penguin Group (USA), 2006




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Sustainable treatment for low ammonia nitrogen sewage wastewater in cold climates: natural polymer gel–organic synthetic polymer embedded anammox bacteria immobilized pellets

Environ. Sci.: Water Res. Technol., 2024, 10,2809-2830
DOI: 10.1039/D4EW00538D, Paper
Jun Li, Salma Tabassum, Hüseyin Altundag
Denitrification effect of the hybrid carrier-embedded anammox bacteria pellets to treat NH4+–N urban sewage wastewater at low temperature through batch and continuous tests.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Tata Projects sees green hydrogen, green ammonia, pump storage hydro as pillars of growth

“Sustainability is a critical element for us and we see in this sustainability journey, a lot of opportunities will open up in new sectors,” said Vinayak Pai, MD & CEO, Tata Projects in an interview




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The Hindu Lit Fest 2024 | ‘Mutual funds give access to equity, debt and gold through one route,’ says Monika Halan

The author of Let’s Talk Mutual Funds on why mutual funds should be a part of the Indian investor’s portfolio




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Monica Raymund and Rebecca Cutter on ‘Hightown’ Season 3: ‘We’re going out with a bang’

Monica Raymund, who plays the lead in the crime drama set in Provincetown, Massachusetts, and Rebecca Cutter, the creator of the show, say the third and final season will see the characters end up in a place that feels at once shocking and inevitable




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Coordination environment-tailored electronic structure of single atomic copper sites for efficient electrochemical nitrate reduction toward ammonia

Energy Environ. Sci., 2024, 17,8360-8367
DOI: 10.1039/D4EE02746A, Paper
Tianchi Huang, Taiyu Liang, Jiao You, Qihua Huo, Shuai Qi, Jingwen Zhao, Na Meng, Jinglian Liao, Chunyan Shang, Hengpan Yang, Qi Hu, Chuanxin He
A robust strategy is developed to finely tune the electronic structure of Cu by employing single atomic Cu–N–C via both first and second coordination shell engineering, thereby boosting the performance for the nitrate reduction reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photoelectrochemical nitrate denitrification towards acidic ammonia synthesis on copper-decorated black silicon

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04438J, Paper
Yuchan Li, Qi Zhang, Huan Dai, Dong He, Zunjian Ke, Xiangheng Xiao
This work highlights the exceptional performance and great potentials of a Cu nanoparticle decorated silicon nanowire arrays (Cu–Si NWs) for photoelectrocatalytic nitrate reduction to ammonia in acidic electrolyte and in realistic wastewater.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Theory-guided development of a barium-doped cobalt catalyst for ammonia decomposition

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02874K, Paper
Alexander Gunnarson, Ang Cao, Olivia F. Sloth, Miriam Varón, Ruben Bueno Villoro, Thomas Veile, Christian D. Damsgaard, Cathrine Frandsen, Jens K. Nørskov, Ib Chorkendorff
This work describes the theory-guided design and experimental validation of a barium-doped cobalt catalyst for ammonia decomposition.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Unraveling the relationship between the phenethylammonium-induced 2D phase on the perovskite surface and inverted wide bandgap perovskite solar cell performance

Energy Environ. Sci., 2024, 17,8658-8669
DOI: 10.1039/D4EE02133A, Paper
Xiaomin Huo, Silvia Mariotti, Yaoyao Li, Ting Guo, Chenfeng Ding, Penghui Ji, Shuai Yuan, Tongtong Li, Ning Meng, Xiaomin Liu, Jiahao Zhang, Ilhem Nadia Rabehi, Yu Zhang, Suling Zhao, Hengyuan Wang, Dandan Song, Luis K. Ono, Zheng Xu, Yabing Qi
We studied the impact of phenethylammonium chloride on PIN-structured wide bandgap perovskite solar cells. Elimination of the 2D phase results in a champion efficiency of 20.61% and a VOC loss of only 410 mV with hysteresis-free J–V curves.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electrodialysis and nitrate reduction (EDNR) to enable distributed ammonia manufacturing from wastewaters

Energy Environ. Sci., 2024, 17,8787-8800
DOI: 10.1039/D4EE03002H, Paper
Open Access
Jinyu Guo, Matthew J. Liu, Chloe Laguna, Dean M. Miller, Kindle S. Williams, Brandon D. Clark, Carolina Muñoz, Sarah J. Blair, Adam C. Nielander, Thomas F. Jaramillo, William A. Tarpeh
Underutilized wastewaters containing dilute levels of reactive nitrogen (Nr) can help rebalance the nitrogen cycle.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Development of an automated platform for monitoring microfluidic reactors through multi-reactor integration and online (chip-)LC/MS-detection

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00004H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hannes Westphal, Simon Schmidt, Sanjay Lama, Matthias Polack, Chris Weise, Toni Oestereich, Rico Warias, Tanja Gulder, Detlev Belder
Biocatalysis with packed-bed microreactors: a novel method combining microreactor technology, multi-reactor integration, and online (chip-)LC/MS analysis in a sequential automated workflow.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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At-line monitoring of hydrogen peroxide released from its photocatalytic and continuous synthesis

React. Chem. Eng., 2024, 9,777-781
DOI: 10.1039/D3RE00659J, Communication
Open Access
Anders Ø. Tjell, Lars-Erik Meyer, Barbara Jud, Selin Kara, Torsten Mayr
Photocatalytic synthesis of H2O2 in a continuous operation set-up using nitrogen-doped carbon nanodots (N-CNDs) and simultaneous determination of generated H2O2.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Cardamonin protects against diabetic cardiomyopathy by activating macrophage NRF2 signaling through molecular interaction with KEAP1

Food Funct., 2024, 15,11083-11095
DOI: 10.1039/D4FO03543G, Paper
Wenshan Nan, Jialin Yin, Wenhao Hao, Huali Meng, Junduo Wu, Xiao Yin, Hao Wu
Cardamonin inhibited macrophage M1 polarization in diabetic cardiomyopathy by binding to KEAP1, leading to the dissociation of NRF2 from KEAP1. This promoted NRF2 nuclear translocation and antioxidant gene expression in M1 polarized macrophages.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Why Cambodia’s novel H5N1 reassortant virus needs close monitoring

All available data suggest human infections caused by the reassortant virus are attributed to direct poultry-to-human transmission, with no evidence of human-to-human spread




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Hydrolysis of ammonia borane for green hydrogen production over a Pd/C3N4 nanocatalyst synthesized by electron beam irradiation

Catal. Sci. Technol., 2024, 14,6338-6350
DOI: 10.1039/D4CY00761A, Paper
Manish Shingole, Seemita Banerjee, Priyanka Ruz, Asheesh Kumar, Pratibha Sharma, V. Sudarsan
Room temperature hydrolysis of ammonia borane in presence of electron beam irradiated Pd-C3N4 catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Heterostructure engineered construction of N-doped CuO@Co3O4 for highly efficient electrocatalytic reduction of nitrate to ammonia

Catal. Sci. Technol., 2024, 14,6372-6379
DOI: 10.1039/D4CY00905C, Paper
Shi-Jiao Dong, Sai Huang, Ao Wang, Yan Meng, Gang Xu, Jun-Ling Song
The electrochemical reduction of nitrate to NH3 can be a promising and sustainable alternative for the industrially used, energy-intensive Haber–Bosch process under mild conditions and also solve the issue of nitrate nitrogen pollution in water.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Unraveling the Ammonia Sensing Behavior and Degradation Pathways of Novel Lead-Free MA2CuBr4 based Ammonia Sensor

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR02943G, Communication
Abinash Tiwari, Arjumand Mir, Aswani Yella
We report a lead-free copper-based halide perovskite gas sensor to detect ammonia gas at ambient temperature. The sensor uses methylammonium copper bromide as the active material and can trace ammonia...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dynamic monitoring of the fibrosis disease by a collagen targeting near infrared probe

Biomater. Sci., 2024, 12,1924-1931
DOI: 10.1039/D3BM01926H, Paper
Xiaoke Zhang, Qianwen Yang, Sensen Zhou, Cheng Li, Xiqun Jiang
A H2O2-sensitive macromolecular optical probe which can effectively bind to collagen was developed for real time noninvasive visualization of fibrotic tissues.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dressed to represent India | Debating ceremonial and corporate uniforms

With National Handloom Day approaching, and in light of Team India’s official Olympic outfits attracting flak, designers weigh in on the challenges of creating ceremonial and corporate uniforms




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JGC develops new ammonia production process




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Birch reduction runs ammonia-free

Crown ethers simplify the set-up of classic reaction




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Advancing green chemistry in environmental monitoring: the role of electropolymerized molecularly imprinted polymer-based electrochemical sensors

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03250K, Tutorial Review
Christopher Mwanza, Wei-Zhi Zhang, Kalulu Mulenga, Shou-Nian Ding
Molecularly imprinted polymers (MIPs) are synthetic materials designed to mimic the natural “lock and key” mechanism observed in biomolecular systems, such as the interactions between antibodies and antigens.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Active Hydrogen Tuning by Copper-Cobalt Bimetal Catalysts for Boosting Ammonia Electrosynthesis from Simulated Waster Water

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04120H, Paper
Chunqi Yang, Chang Liu, Jingwen Zhuang, Ziyan Yang, Aiping Chen, Yuhang Li, Chunzhong Li
Electrochemical nitrate reduction reaction (NO3RR) represents a promising approach to balance the nitrogen cycle, converting environmental pollutant NO3− to valuable ammonia (NH3). However, the whole reaction involves complex protons-coupled electron...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Review of carbon-based catalysts for electrochemical nitrate reduction and green ammonia synthesis

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04640D, Tutorial Review
Guanting Liao, Richard L. Smith Jr., Haixin Guo, Xinhua Qi
This work aims to review the latest developments in carbon-based electrocatalysts applied in electrocatalytic nitrate reduction, including pure carbon materials, heteroatom doping or metal-bonding catalysts, and carbon substrate-supported composites.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rising gamer-star’s search for an Esports bride through a matrimonial ad hits a dead end




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What Is Walking Pneumonia? Is It A Serious Condition?

Walking pneumonia (WP) is the infection of the lungs or say, a milder form of pneumonia that affects the upper and lower respiratory tract. It is also known as 'atypical pneumonia' as the bacteria behind the condition is an atypical bacteria




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Omaha/Council Bluffs Area Gas Stations, Owned by Mega Saver and Tobacco and Phones 4 Less, Agree to Upgrade Spill Monitoring and Alarm Systems

Environmental News FOR IMMEDIATE RELEASE




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An enzyme-based protocol for cell-free synthesis of nature-identical capsular oligosaccharides from Actinobacillus pleuropneumoniae serotype 1 [Enzymology]

Actinobacillus pleuropneumoniae (App) is the etiological agent of acute porcine pneumonia and responsible for severe economic losses worldwide. The capsule polymer of App serotype 1 (App1) consists of [4)-GlcNAc-β(1,6)-Gal-α-1-(PO4-] repeating units that are O-acetylated at O-6 of the GlcNAc. It is a major virulence factor and was used in previous studies in the successful generation of an experimental glycoconjugate vaccine. However, the application of glycoconjugate vaccines in the animal health sector is limited, presumably because of the high costs associated with harvesting the polymer from pathogen culture. Consequently, here we exploited the capsule polymerase Cps1B of App1 as an in vitro synthesis tool and an alternative for capsule polymer provision. Cps1B consists of two catalytic domains, as well as a domain rich in tetratricopeptide repeats (TPRs). We compared the elongation mechanism of Cps1B with that of a ΔTPR truncation (Cps1B-ΔTPR). Interestingly, the product profiles displayed by Cps1B suggested processive elongation of the nascent polymer, whereas Cps1B-ΔTPR appeared to work in a more distributive manner. The dispersity of the synthesized products could be reduced by generating single-action transferases and immobilizing them on individual columns, separating the two catalytic activities. Furthermore, we identified the O-acetyltransferase Cps1D of App1 and used it to modify the polymers produced by Cps1B. Two-dimensional NMR analyses of the products revealed O-acetylation levels identical to those of polymer harvested from App1 culture supernatants. In conclusion, we have established a protocol for the pathogen-free in vitro synthesis of tailored, nature-identical App1 capsule polymers.




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OCZ testimonies

some testimonies from Aussies who attended the 2010 OCZ and outreaches




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Gathering Coronavirus data from states: More central monitoring teams is a good idea

Even now, a state like West Bengal’s data looks dodgy; others like Gujarat and UP also pose challenges




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Tenshi Log Monitoring Program 0.12

Tenshi is a log monitoring program, designed to watch a log file for lines matching user defined regular expression and report on the matches. The regular expressions are assigned to queues which have an alert interval and a list of mail recipients. Queues can be set to send a notification as soon as there is a log line assigned to it, or to send periodic reports.




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Tenshi Log Monitoring Program 0.13

Tenshi is a log monitoring program, designed to watch a log file for lines matching user defined regular expression and report on the matches. The regular expressions are assigned to queues which have an alert interval and a list of mail recipients. Queues can be set to send a notification as soon as there is a log line assigned to it, or to send periodic reports.




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Tenshi Log Monitoring Program 0.14

Tenshi is a log monitoring program, designed to watch a log file for lines matching user defined regular expression and report on the matches. The regular expressions are assigned to queues which have an alert interval and a list of mail recipients. Queues can be set to send a notification as soon as there is a log line assigned to it, or to send periodic reports.




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Tenshi Log Monitoring Program 0.15

tenshi is a log monitoring program, designed to watch one or more log files for lines matching user defined regular expressions and report on the matches. The regular expressions are assigned to queues which have an alert interval and a list of mail recipients. Queues can be set to send a notification as soon as there is a log line assigned to it, or to send periodic reports.




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Tenshi Log Monitoring Program 0.16

tenshi is a log monitoring program, designed to watch one or more log files for lines matching user defined regular expressions and report on the matches. The regular expressions are assigned to queues which have an alert interval and a list of mail recipients. Queues can be set to send a notification as soon as there is a log line assigned to it, or to send periodic reports.




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Tenshi Log Monitoring Program 0.17

tenshi is a log monitoring program, designed to watch one or more log files for lines matching user defined regular expressions and report on the matches. The regular expressions are assigned to queues which have an alert interval and a list of mail recipients. Queues can be set to send a notification as soon as there is a log line assigned to it, or to send periodic reports.




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Iraq Collapse May Pose New WMD Threat, Say UN Monitors




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Some of our corrupt leaders are pastors, vehemently wicked, demonic – Bishop Olumakaiye

Bishop of Lagos Diocese (Anglican Communion), Rt. Rev. Humphrey Olumakaiye, in this interview, speaks on the coronavirus crisis raging across the world, war against corruption and the security challenge facing Nigeria among other issues. corrupt leaders

The post Some of our corrupt leaders are pastors, vehemently wicked, demonic – Bishop Olumakaiye appeared first on Vanguard News.




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Up Your Gaming Resolution With the Best 4K Gaming Monitors

Looking for the next level gaming? We've picked out the best 4K gaming monitors that will give you the sharpest picture you've ever experienced.





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GameStop's PC gaming sale discounts ASUS monitors, Razer mice and more

GameStop might just help you put the finishing touches on your computer setup. It’s running a PC gaming sale between now and May 16th that promises deals on a slew of hardware. To start, it’s offering a $100 gift coupon if you buy any MSI laptop with...




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India Nature Watch - Having a big meal! Two-striped jumping spider (Telamonia) with blue bottlefly kill




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India Nature Watch - Icheumonidae wasp - Sphelodon phoxopteridis

ID credit to Sivakumar Sir.




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SCOOP: Tiger Shroff's Baaghi 3 makers yet to receive Rs. 40 crores; monies stuck due to lockdown

The coronavirus pandemic has brought the entire country to a complete stand-still and one of the most hit industries is Bollywood. Not just have the releases been stalled, but also the shooting schedules have been indefinitely cancelled. Bollywood Hungama has exclusively learnt that producer Sajid Nadiadwala and his studio partner; Fox Star Studios are yet to receive money from their distributors for their recently released film Baaghi 3.

“It is usually a three to four week clearance window, but since the national lockdown, the workings in the industry were halted, with cinema halls downing their shutters. The top four national multiplex chains – PVR, INOX, CINEPOLIS and Carnival – will transfer the money to the stakeholders once the business is back to normal,” revealed a source close to the development. An estimated amount due to from the National Multiplex Chains is approximately Rs. 15 crores, while the other plexes and single screens are liable to pay around Rs. 20 to 25 crores, total amounting to Rs 35 to 40 crores.

Hungama has also learnt that the producers too are not putting any pressure on the national multiplex chains as well as the independent sub-distributors in the interiors to clear their dues due to the situation of chronic cash crunch in the country. “It’s a long term association and the losses due to delay in payments will be made up for in the future slate of release for the studio. Sajid Nadiadwala, on other hand, has got enough revenue from satellite, digital and sale of theatrical rights to not just recover the budget, but also make profits,” the source explained.

Baaghi 3 released on March 6 and was doing just about average business at the box-office. However, owing to the complete closure of cinema halls a week after its release, the Studio Partner, Fox Star Studios, will lose money on the product. “Even without lockdown, the project was a loss making venture for Fox Star Studios due to the price of acquisition.”

Also Read: Tiger Shroff’s Baaghi 3 may not re-release in theatres; will release now on digital platform




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Is it Good for Parents to Monitor their Children?

A lot of parents think it is alright to give their children smartphones, however, these devices can leave them...




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Monitoring investment and trade measures

G20 Leaders are firmly committed to open trade and investment and to resisting protectionism in all its forms. They have mandated WTO, OECD and UNCTAD – the leading international organisations in the area of international trade and investment policies – to monitor policy developments and report publicly on these commitments.