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Evaluating protocols for reproducible targeted metabolomics by NMR

Analyst, 2024, 149,5423-5432
DOI: 10.1039/D4AN01015A, Paper
Darcy Cochran, Panteleimon G. Takis, James L. Alexander, Benjamin H. Mullish, Nick Powell, Julian R. Marchesi, Robert Powers
Evaluating how sample preparation methods and data analysis platforms impact measured metabolite concentrations underscores the need for a universal consensus in the followed approaches for metabolomics data analysis.
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Screen printed 3D microfluidic paper-based and modifier-free electroanalytical device for clozapine sensing

Analyst, 2024, 149,5411-5422
DOI: 10.1039/D4AN01136H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mohammad Hossein Ghanbari, Markus Biesalski, Oliver Friedrich, Bastian J. M. Etzold
Screen printing was employed for the first time to examine the effect of electrode size and arrangement on the performance of a microfluidic paper-based electroanalytical device for clozapine sensing.
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A gold nanomaterial-integrated distance-based analytical device for uric acid quantification in human urine samples

Analyst, 2024, 149,5518-5526
DOI: 10.1039/D4AN01139B, Paper
Tapparath Leelasattarathkul, Thithawat Trakoolwilaiwan, Kawin Khachornsakkul
A simple and low-cost distance-based paper analytical device (dPAD) was combined with gold nanomaterials for uric acid quantification.
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Acoustic levitation and manipulation of columns of droplets with integrated optical detection for parallelisation of reactions

Analyst, 2024, 149,5546-5554
DOI: 10.1039/D4AN01096E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruchi Gupta, Nicholas J. Goddard
In this work, acoustically levitated droplets serve as wells of microtitre plates and are acoustically manipulated to perform chemical and biological reactions in a non-contact fashion.
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Molecularly imprinted polymer sensors for biomarker detection in cardiovascular diseases

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01103A, Critical Review
Wenteng Tang, Junlei Han, Wenhong Zhang, Huimin Li, Jun Chen, Wei Song, Li Wang
Molecularly imprinted polymer sensors, combined with electrochemical, optical, thermal, and acoustic detection technologies, detect biomarkers for key cardiovascular diseases: coronary artery disease, acute myocardial infarction, and heart failure.
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Exploring gunshot residue detection in fingerprints by functionalized particle-coupled matrix-assisted laser desorption/ionization mass spectrometry

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01260G, Paper
Sunil S. Adav, Yan Wen Crystal Tan, Choon Teck Low, Song Wei Loo, Ridhwan Yusoff, Archana Gautam, Yuk Lin Yong, Chiew Yung Yang, Chin Chin Lim, Kee Woei Ng
In firearm forensic investigations, detecting gunshot residue (GSR) is crucial for linking firearms to suspects and determining firing distance for forensic reconstruction.
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Electrochemically modulated surface plasmon waves for characterization and interrogation of DNA-based sensors

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01164C, Paper
Anil Sharma, Thomas Hulse, Aymen H. Qatamin, Monica Moreno, Klester S. Souza, Marcelo B. Pereira, Fabricio S. Campos, Leandro B. Carneiro, Antonio M. H. de Andrade, Paulo M. Roehe, Flavio Horowitz, Sergio B. Mendes
This article focuses on the application of electrochemically modulated surface plasmon waves for structural characterization and for assessing signal transduction performance of redox-labeled DNA-based sensing platforms.
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Machine-learning-accelerated structure prediction of PtSnO nanoclusters under working conditions

Phys. Chem. Chem. Phys., 2024, 26,27624-27632
DOI: 10.1039/D4CP03769C, Paper
Fanke Zeng, Wanglai Cen
Credible property calculations based on the structure prediction of multi-component catalyst clusters under working conditions via a machine-learning-accelerated genetic algorithm and ab initio thermodynamics approach.
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Electrochemical system of nitrogen-doped TiO2, Fe–N–C, and copper hexacyanoferrate electrodes for photo-assisted energy conversion in acidic wastewater treatment

Phys. Chem. Chem. Phys., 2024, 26,27498-27509
DOI: 10.1039/D4CP02063D, Paper
Bianca Tainá Ferreira, Matheus Martins, Fritz Huguenin
This study examines the electrochemical performance of nitrogen-doped TiO2, Fe–N–C, and CuHCF electrodes for energy conversion in acidic solution neutralization, capturing 62.9 kJ per mole of protons.
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Hydrogen bond network structures of protonated 2,2,2-trifluoroethanol/ethanol mixed clusters probed by infrared spectroscopy combined with a deep-learning structure sampling approach: the origin of the linear type network preference in protonated fluoroal

Phys. Chem. Chem. Phys., 2024, 26,27751-27762
DOI: 10.1039/D4CP03534H, Paper
Po-Jen Hsu, Atsuya Mizuide, Jer-Lai Kuo, Asuka Fujii
Infrared spectroscopy combined with a deep-learning structure sampling approach reveals the origin of the unusual structure preference in protonated fluorinated alcohol clusters.
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Simulated conformality of atomic layer deposition in lateral channels: the impact of the Knudsen number on the saturation profile characteristics

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP00131A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christine Gonsalves, Jorge A. Velasco, Jihong Yim, Jänis Järvilehto, Ville Vuorinen, Riikka L. Puurunen
Systematic analysis of saturation profile characteristics allowed development of an extended slope method that relates the slope of the adsorption front to the sticking coefficient for any Knudsen number.
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Hydrogen tunneling with an atypically small KIE measured in the mediated decomposition of the Co(CH3COOH)+ complex

Phys. Chem. Chem. Phys., 2024, 26,27741-27750
DOI: 10.1039/D4CP02722A, Paper
Open Access
Simon U. Okafor, Gabriele Pinto, Michael Brdecka, William Smith, Tucker W. R. Lewis, Michael Gutierrez, Darrin J. Bellert
Rate-limiting hydrogen/deuterium tunneling rate constants are measured in the photon initiated decay of Co(CH3COOH)+ with small KIE values.
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Unveiling the potential of aluminum-decorated 3D phosphorus graphdiyne as a catalyst for N2O reduction

Phys. Chem. Chem. Phys., 2024, 26,27677-27683
DOI: 10.1039/D4CP02686A, Paper
Shehzad Ahmed, Adnan Ali Khan, Danish Khan, Awais Ghani, Rashid Ahmad, Tian Xiaoqing, Imran Muhammad
This study reveals the exceptional reactivity and efficiency of 3D-Al/PGDYN catalysts for the reduction of N2O and CO with minimal energy barriers.
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Influence of symmetry breaking on the absorption spectrum of crystal violet: from isolated cations at 5 K to room temperature solutions

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03825H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alexander Schäfer, Samuele Giannini, Dmitry Strelnikov, Theresa Mohr, Fabrizio Santoro, Javier Cerezo, Manfred M. Kappes
Theoretical and experimental spectroscopy of crystal violet resolves the influence of temperature and symmetry breaking on absorption properties in different environments.
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Photofragmentation and fragment analysis; Coriolis interactions in excited states of CH3

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03292F, Paper
Meng-Xu Jiang, Ágúst Kvaran
Formation, energetics and fragmentations relevant to the methyl radical, with main emphasis on dramatic effects of Coriolis interaction within its excited states.
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A Comprehensive Guide for Accurate Conformational Energies of Microsolvated Li+ Clusters with Organic Carbonates

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03487B, Paper
Arseniy A. Otlyotov, Andrey Moshchenkov, Timofey P. Rozov, Anna A. Tuma, Alexander S. Ryzhako, Yury Minenkov
Organic carbonates and their mixtures are frequently used in electrolyte solutions in lithium-ion batteries. Rationalization and tuning of the related Li+ solvation processes are rooted in the proper identification of...
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Simulation study of the conformation and dynamics of substrate-supported ring and linear polymer films

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02794A, Paper
Jianhua Huang, Hongzhu Ji, Jin Zhang, Zhunpeng Wang
Ring polymers in substrate-supported films exhibit stronger adsorbability, less deformation, and similar dynamics suppression compared to linear polymers.
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A composite of pineapple leaf-derived porous carbon integrated with ZnCo-MOF for high-performance supercapacitors

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02882A, Paper
Xiaoxiao Ma, Yunfan Bai, Shuangli Chen, Zhixian He, Pingping Wu, Yabing Qi, Sijing Zhang
Pineapple leaf-derived biochar (PLB) served as a carrier for ZnCo-MOF in the preparation of ZnCo-MOF@PLB-800. The porous structure of PLB reduced ZnCo-MOF aggregation, enhancing electron transfer and the conductivity of the electrode material.
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Thoughtfully curated Deepavali hamper guide for Visakhapatnam

These Visakhapatnam-based enterprises have curated sustainable Deepavali hampers spreading festive joy with handmade gifts



  • Life & Style

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Handmade and hand-painted diyas for Deepavali

Meet these women whose handcrafted and hand-painted diyas will light up homes this Deepavali



  • Life & Style

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Targeted protein degradation directly engaging lysosomes or proteasomes

Chem. Soc. Rev., 2024, 53,3253-3272
DOI: 10.1039/D3CS00344B, Tutorial Review
Open Access
Jiseong Kim, Insuk Byun, Do Young Kim, Hyunhi Joh, Hak Joong Kim, Min Jae Lee
This review delineates emerging technologies for targeted protein degradation that directly involve lysosomes or proteasomes. It explores their unique features, advantages, and limitations, offering perspectives on future therapeutic applications.
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Organoboron-mediated polymerizations

Chem. Soc. Rev., 2024, 53,3384-3456
DOI: 10.1039/D3CS00115F, Review Article
Yao-Yao Zhang, Guan-Wen Yang, Chenjie Lu, Xiao-Feng Zhu, Yuhui Wang, Guang-Peng Wu
This review provides a comprehensive summary of organoboron-mediated free radical polymerization, Lewis pair polymerization, ionic polymerization, and polyhomologation, laying the groundwork for further establishment of polymerization methods.
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Correlating concerted cations with oxygen redox in rechargeable batteries

Chem. Soc. Rev., 2024, 53,3561-3578
DOI: 10.1039/D3CS00550J, Review Article
Shiqi Wang, Lifan Wang, David Sandoval, Tongchao Liu, Chun Zhan, Khalil Amine
This review underscores the critical importance of oxygen redox and elucidates the precise commonalities of cations in regulating oxygen redox.
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Thermally activated structural phase transitions and processes in metal–organic frameworks

Chem. Soc. Rev., 2024, 53,3606-3629
DOI: 10.1039/D3CS01105D, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Celia Castillo-Blas, Ashleigh M. Chester, David A. Keen, Thomas D. Bennett
The structural knowledge of metal–organic frameworks is crucial for understanding and developing new efficient materials for industrial implementation.
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Advances in morphology-controlled alumina and its supported Pd catalysts: synthesis and applications

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00776F, Review Article
Yanpeng Yang, Chenglin Miao, Ruoyu Wang, Rongxin Zhang, Xiaoyu Li, Jieguang Wang, Xi Wang, Jiannian Yao
This review highlights the preparation and regulation strategies of alumina materials from different dimensions and summarizes the preparation, metal–support interaction, and application of Pd/Al2O3 catalysts on important industrial catalysis.
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Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00185K, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lars J. C. van der Zee, Jelle Hofman, Joost M. van Gaalen, J. Chris Slootweg
Here, we discuss predicting thermal and photoinduced single-electron transfer (SET) in frustrated Lewis pairs (FLPs) and characterizing the resulting radical pair. We then extend these methods' application to main-group chemistry.
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Engineered two-dimensional nanomaterials based diagnostics integrated with internet of medical things (IoMT) for COVID-19

Chem. Soc. Rev., 2024, 53,3774-3828
DOI: 10.1039/D3CS00719G, Review Article
Mohd. Abubakar Sadique, Shalu Yadav, Raju Khan, Avanish K. Srivastava
Engineered 2D nanomaterials-based smartphone-assisted detection approaches integrated with IoMT, focusing on reliable, sensitive, and rapid diagnostics for COVID-19.
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Mitochondria-targeted BODIPY dyes for small molecule recognition, bio-imaging and photodynamic therapy

Chem. Soc. Rev., 2024, 53,3976-4019
DOI: 10.1039/D3CS00456B, Review Article
Sisi Wang, Lizhi Gai, Yuncong Chen, Xiaobo Ji, Hua Lu, Zijian Guo
This review focuses on the design strategy, spectroscopic characteristics, and functionalization of mitochondrion-targeted BODIPY dyes, providing an overview of these dyes for mitochondrion-targeted bioimaging and photodynamic therapy.
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MOTORSPORTS | Young Indian racers excited for Formula 4 Indian championship




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Motivated India eye German scalp to script another historic chapter in Olympic men's hockey

India won last of their eight Olympic gold medals way back in the 1980 Moscow Games. Paris provides them a great opportunity to make history.




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Amit Rohidas on red-card incident: I am indebted to teammates for not once letting me feel ostracized

Rohidas was penalised in the 17th minute of the quarterfinals for a swinging stick that inadvertently struck British forward Will Calnan in the face.




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Watch: PR Sreejesh: Like Rahul Dravid, I wanted to start coaching juniors




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Harmanpreet, Sreejesh shortlisted for FIH Hockey Stars Awards

Both Harmanpreet and Sreejesh played vital roles in India's splendid campaign in the Paris Olympics where the team claimed a bronze medal




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Keen contest expected as an on-the-rise India takes on World No. 2 Germany

The host is struggling with a few injuries; Harmanpreet will have Vivek Sagar Prasad as his deputy while the visiting team will sport a new look




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‘383 toilets constructed’




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Astronomy for curious kids : an illustrated introduction to the Solar System, our galaxy, space travel--and more! / [Giles Sparrow ; illustrated by Nik Neves]

Sparrow, Giles, 1970- author




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Biindigen! : Amik says welcome / Nancy Cooper ; illustrated by Joshua Mangeshig Pawis-Steckley

Cooper, Nancy, 1967- author




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Change is in the air : carbon, climate, Earth, and us / Debbie Levy ; illustrated by Alex Boersma

Levy, Debbie, author




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Engineering for curious kids : an illustrated introduction to building machines and amazing structures! / [author: Chris Oxlade ; illustrator: Alex Foster]

Oxlade, Chris, author




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The forest keeper : the true story of Jadav Payeng / by Rina Singh ; illustrated by Ishita Jain

Singh, Rina, 1955- author




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A girl can build anything / written by e.E. Charlton-Trujillo and Pat Zietlow Miller ; illustrated by Keisha Morris

Charlton-Trujillo, e. E., author




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The girl who planted trees / written by Caryl Hart ; illustrated by Anastasia Suvorova

Hart, Caryl, author




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Gravity is bringing me down / by Wendelin Van Draanen ; illustrated by Cornelia Li

Van Draanen, Wendelin, author




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The Great Lakes : our freshwater treasure / by Barb Rosenstock ; illustrated by Jamey Christoph

Rosenstock, Barb, author




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How to spacewalk : step-by-step with shuttle astronauts / created by Kathryn D. Sullivan, the first American woman to walk in space, and Michael J. Rosen ; illustrated with images from NASA and drawings by Michael J. Rosen

Sullivan, Kathy, 1951- author




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Isabel and the invisible world / Alan Lightman ; illustrated by Ramona Kaulitzki

Lightman, Alan P., 1948- author




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The leaf detective : how Margaret Lowman uncovered secrets in the rainforest / Heather Lang ; illustrated by Jana Christy

Lang, Heather, 1966- author




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Let's build a dam! / written and translated by Daniel Fehr ; illustrated by Mariachiara Di Giorgio

Fehr, Daniel, author, translator




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Life / written by Cynthia Rylant ; illustrated by Brendan Wenzel

Rylant, Cynthia, author




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The lodge that Beaver built / Randi Sonenshine ; illustrated by Anne Hunter

Sonenshine, Randi, 1968- author